MX2012006465A - Metodos y sistemas para controlar el tamaño de particulas de polimeros. - Google Patents

Metodos y sistemas para controlar el tamaño de particulas de polimeros.

Info

Publication number
MX2012006465A
MX2012006465A MX2012006465A MX2012006465A MX2012006465A MX 2012006465 A MX2012006465 A MX 2012006465A MX 2012006465 A MX2012006465 A MX 2012006465A MX 2012006465 A MX2012006465 A MX 2012006465A MX 2012006465 A MX2012006465 A MX 2012006465A
Authority
MX
Mexico
Prior art keywords
particle size
size
polymer particle
polymer
catalyst
Prior art date
Application number
MX2012006465A
Other languages
English (en)
Other versions
MX345996B (es
Inventor
John D Hottovy
Gregory G Hendrickson
Original Assignee
Chevron Phillips Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co filed Critical Chevron Phillips Chemical Co
Publication of MX2012006465A publication Critical patent/MX2012006465A/es
Publication of MX345996B publication Critical patent/MX345996B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1812—Tubular reactors
    • B01J19/1837—Loop-type reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00734—Controlling static charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00247—Fouling of the reactor or the process equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00254—Formation of unwanted polymer, such as "pop-corn"
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La presente invención proporciona técnicas para producir partículas poliméricas de un tamaño sólo ligeramente más grande que el tamaño de los finos poliméricos. La técnica puede prevenir o limitar la ocurrencia de las obstrucciones del reactor asociadas con partículas de polímero grandes. La técnica también puede proporcionar un porcentaje en peso mayor de sólidos en el reactor. El tamaño de partícula de polímero deseado puede lograrse empleando un catalizador que tiene partículas de un tamaño determinado con base en la productividad de catalizador esperada. En algunas modalidades, el tamaño de partícula del catalizador puede determinarse con base en la productividad del catalizador esperada, la densidad de partícula del polímero, la densidad de la partícula de catalizador y/o el tamaño de partícula del polímero.
MX2012006465A 2009-12-07 2010-11-09 Metodos y sistemas para controlar el tamaño de particulas de polimeros. MX345996B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/632,490 US8058367B2 (en) 2004-08-27 2009-12-07 Methods and systems for controlling polymer particle size
PCT/US2010/056024 WO2011071640A1 (en) 2009-12-07 2010-11-09 Methods and systems for controlling polymer particle size

Publications (2)

Publication Number Publication Date
MX2012006465A true MX2012006465A (es) 2012-07-03
MX345996B MX345996B (es) 2017-03-01

Family

ID=43530963

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012006465A MX345996B (es) 2009-12-07 2010-11-09 Metodos y sistemas para controlar el tamaño de particulas de polimeros.

Country Status (10)

Country Link
US (2) US8058367B2 (es)
EP (1) EP2510018B1 (es)
CN (1) CN102648215A (es)
BR (1) BR112012013878A2 (es)
CA (1) CA2783087C (es)
ES (1) ES2562261T3 (es)
IN (1) IN2012DN05047A (es)
MX (1) MX345996B (es)
RU (1) RU2573401C2 (es)
WO (1) WO2011071640A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9163564B2 (en) 2010-06-21 2015-10-20 Chevron Phillips Chemical Company Lp Method and system for energy generation in a chemical plant by utilizing flare gas
US8703063B2 (en) 2010-06-21 2014-04-22 Chevron Phillips Chemical Company Lp System and method for closed relief of a polyolefin loop reactor system
US8396600B2 (en) 2010-07-23 2013-03-12 Chevron Phillips Chemical Company Lp Prediction and control solution for polymerization reactor operation
EP2447290A1 (en) * 2010-11-01 2012-05-02 Ineos Commercial Services UK Limited Chromium catalysed ethylene copolymer powder
US8703883B2 (en) 2012-02-20 2014-04-22 Chevron Phillips Chemical Company Lp Systems and methods for real-time catalyst particle size control in a polymerization reactor
US9340629B2 (en) * 2012-12-13 2016-05-17 Chevron Phillips Chemical Company Lp Polyethylene production with multiple polymerization reactors
US9789463B2 (en) 2014-06-24 2017-10-17 Chevron Phillips Chemical Company Lp Heat transfer in a polymerization reactor
US10029230B1 (en) 2017-01-24 2018-07-24 Chevron Phillips Chemical Company Lp Flow in a slurry loop reactor
US20230331875A1 (en) * 2022-04-19 2023-10-19 Chevron Phillips Chemical Company Lp Loop slurry periodogram control to prevent reactor fouling and reactor shutdowns

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925338A (en) * 1973-03-16 1975-12-09 Monsanto Co Control of polymer particle size in olefin polymerization
NL7502153A (nl) * 1974-02-27 1975-08-29 Monsanto Co Werkwijze voor de regeling van de deeltjes- grootte bij de polymerisatie van alkenen.
IN160886B (es) 1983-04-25 1987-08-15 Babcock & Wilcox Co
FR2562077B1 (fr) 1984-03-30 1986-06-27 Bp Chimie Sa Dispositif et procede d'introduction d'une poudre a activite catalytique dans un reacteur de polymerisation a lit fluidise
SU1741114A1 (ru) * 1989-06-19 1992-06-15 Охтинское научно-производственное объединение "Пластполимер" Способ управлени процессом каталитической (со)полимеризации этилена в газовой фазе
CA2023745A1 (en) 1989-11-27 1991-05-28 Kelly E. Tormaschy Control of polymerization reaction
DE19943206A1 (de) 1999-09-09 2001-03-15 Elenac Gmbh Verfahren zum Herstellen von Philips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Particle-Form-Verfahren
US6528448B1 (en) 2000-04-28 2003-03-04 Phillips Petroleum Company Polymerization catalyst compositions and processes to produce polymers and bimodal polymers
FR2809810A1 (fr) 2000-06-06 2001-12-07 Bp Chemicals Snc Dispositif et procede pour mesurer la temperature des parois d'un equipement
DE10048003A1 (de) 2000-09-26 2002-04-11 Basell Polypropylen Gmbh Verfahren zur Voraktivierung von Katalysatoren
US7402635B2 (en) 2003-07-22 2008-07-22 Fina Technology, Inc. Process for preparing polyethylene
EP1563903A1 (en) 2004-02-13 2005-08-17 Total Petrochemicals Research Feluy Swell control in slurry loop reactor
ATE489409T1 (de) 2004-02-13 2010-12-15 Total Petrochemicals Res Feluy Verfahren zur verbesserung der copolymerisation von ethylen und einem olefin-comonomer in einem schlaufenpolymerisationsreaktor
US7645841B2 (en) * 2004-08-27 2010-01-12 Chevron Phillips Chemical Company Lp Method and system to reduce polymerization reactor fouling
EP1859858A1 (en) 2006-05-26 2007-11-28 INEOS Manufacturing Belgium NV Loop type reactor for polymerization

Also Published As

Publication number Publication date
IN2012DN05047A (es) 2015-10-09
EP2510018A1 (en) 2012-10-17
EP2510018B1 (en) 2016-01-27
US20100130704A1 (en) 2010-05-27
RU2012128524A (ru) 2014-01-20
WO2011071640A1 (en) 2011-06-16
BR112012013878A2 (pt) 2016-05-10
US8187547B2 (en) 2012-05-29
RU2573401C2 (ru) 2016-01-20
US20120070345A1 (en) 2012-03-22
CN102648215A (zh) 2012-08-22
MX345996B (es) 2017-03-01
ES2562261T3 (es) 2016-03-03
CA2783087C (en) 2015-02-10
CA2783087A1 (en) 2011-06-16
US8058367B2 (en) 2011-11-15

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