MX2008016162A - Active ingredient combinations with insecticidal and acaricidal properties. - Google Patents

Abstract

The invention relates to novel active ingredient combinations containing compounds of formula (I) or (II) and the active ingredients (1) to (23) listed in the description. Said combinations have excellent insecticidal and acaricidal properties.

Description

COMBINATIONS OF ACTIVE INGREDIENTS WITH INSECTICIDES AND ACARICIDES PROPERTIES DESCRIPTION OF THE INVENTION The present invention relates to novel combinations of active compound consisting, first of all, of cyclic ketoenols, and secondly, of known insecticidally active compounds in additional form, wherein the combinations are highly suitable for controlling the animal pests such as insects and unwanted acarids. It is well known that certain cyclic ketoenols have herbicidal, insecticidal, and acaricidal properties. The activity of these compounds is good; however, sometimes it is not satisfactory in low ranges of application. The lH-3-arylpyrrolidine-2,4-dione derivatives (WO 98/05638) and their cis-isomers (WO 04/007448), are known to have insecticidal and / or acaricidal activity. Further known are mixtures of compounds from Patent Publication WO 98/05638 with other insecticides and / or acaricides: Patent Publications WO 01/89300, WO 02/00025, WO 02/05648, WO 02/17715 , WO 02/19824, WO 02/30199, WO 02/37963, WO 05/004603, WO 05/053405, WO 06/089665, DE-A-10342673. However, the activity of these mixtures is not always satisfactory. Ref .: 198918 It has now been found that active compound combinations comprising a compound of the formula or (II): (l) (ll) and A) pyrethroids, preferably 1. acrinatrin Known from Patent Publication EP-A-048 186 and / or 2. Alpha-cypermethrin Known from Patent Publication EP-A-067 461 betaciflutric Known from Patent Publication EP-A-206 149 and / or 4. Cyhalothrin Known from Patent Publication DE-A-2 802 962 and / or 5. Cypermethrin Known from Patent Publication DE-A-2 326 077 deltamethrin Known from Patent Publication DE-A-2 326 077 and / or 7. esfenvalerate Known from Patent Publication DE-A-2 737 297 and / or 8. etofenprox Known from Patent Publication DE-A-3 117 510 and / or 9. fenpropatrin Known from Patent Publication DE-A-2 231 312 and / or 10. fenvalerate Known from Patent Publication DE-A-2 335 347 and / or 11. flucitrinate Known from Patent Publication DE-A-2 757 066 and / or ?? 13. permethrin Known from Patent Publication DE-A-2 326 077 and / or 14. taufluvalinate Known from Patent Publication EP-A-038 617 and / or 15. Tralometrine Known from Patent Publication DE-A-2 742 546 and / or zeta-cypermethrin Known from Patent Publication EP-A-026 542 and / or 17. Cyfluthrin Known from the Publication, Patent DE-A-27 09 264 and / or 18. bifenthrin Known from Patent Publication EP-A-049 977 and / or 19. cycloprothrin Known from Patent Publication DE-A-37 08 231 and / or 22. pyrethrin R = -CH3 or -C02CH3 Ri = -CH = CH2 or -CH3 or -CH2CH3 Known from The Pesticide Manual, 1977, 11th Edition, p. 1056 and / or 23. resmethrin Known from Patent Publication GB-A-1 168 797 have very good insecticidal and / or acaricidal properties. Surprisingly, the insecticidal and / or acaricidal activity of the active compound combination according to the present invention is substantially greater than the activities of the active compound of the prior art originating from Patent Publication WO 02/00025, which consists of mixtures of cis / trans isomers of the formula Ia or (a) (|| -a) Preference is given to the active compound combinations comprising the compounds of the formula (I) and at least one active compound of the compounds from 1 to 23. Preference is given to the combination of compounds active compound comprising the compounds of the formula (II) and at least one active compound of the compounds from 1 to 23. In addition, the active compound combinations may also comprise fungicide additives., acaricide or insecticidally active additionally. The improved activity becomes evident when the active compounds in the active compound combinations according to the present invention are present in certain weight ratios. Preferably, the weight ratios of the active compounds in the active compound combinations can vary within a relatively wide range. In general, the combinations according to the present invention comprise active compounds of the formula (I) or (II), and the mixing part in the preferred and particularly preferred mixing ratios stated in the table below. continued: * mixing ratios are based on weight proportions. The proportion will be understood as the active compound of the formula (I): mixing part or formula (II): mixing part Mixing portion Mixing Ratio Ratio preferred mixed mixing particularly particularly preferred preferred Acrynatrin 125: 1 at 1:50 25: 1 at 1:10 10: 1 at 1: 1 Alpha-cypermethrin 125: 1 at 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 Betacyltruthrin 125: 1 to 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 Cihalotrine 125: 1 to 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 Cypermethrin 125: 1 to 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 Deltamethrin 125: 1 to 1:50 25: 1 to 1: 3 10: 1 to 1 : 1 Esfenvalerate 125: 1 to 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 Etofenprox 25: 1 to 1:10 10: 1 to 1: 5 5: 1 to 1: 3 Fenpropathrin 25: 1 at 1:10 10: 1 at 1: 5 5: 1 at 1: 3 Fenvalerate 125: 1 at 1: 5 25: 1 at 1: 3 10: 1 at 1: 1 Flucitrinate 125: 1 at 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 lamnbda-cyhalothrin 125: 1 to 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 gamma-cyhalothrin 125: 1 to 1: 5 25: 1 a 1: 3 10: 1 to 1: 1 Permethrin 25: 1 to 1:10 10: 1 to 1: 5 5: 1 to 1: 3 Taufluvalinate 25: 1 to 1: 5 10: 1 to 1: 5 5: 1 to 1: 2 Tralometrine 125: 1 to 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 zeta-cypermethrin 125: 1 to 1: 5 25: 1 to 1: 3 10: 1 to 1: 2 Cyfluthrin 125: 1 to 1: 5 25: 1 to 1: 3 10: 1 to 1: 1 Bifenthrin 125: 1 to 1:10 10: 1 to 1: 5 5: 1 to 1: 1 Cycloprothromin 25: 1 to 1 : 10 10: 1 to 1: 5 5: 1 to 1: 3 Eflusilanate 25: 1 to 1:10 10: 1101: 5 5: 1 to 1: 3 Fubfenprox 25: 1 to 1:10 10: 1 to 1: 5 5: 1 to 1: 3 Pyrethrins 125: 1 to 1:10 25: 1 to 1: 5 5: 1 to 1: 1 Resmethrin 125: 1 to 1:10 25: 1101: 5 5: 1 to 1: 1 The active compound combinations according to the present invention are suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and / or arachnids, found in viticulture, in fruit cultivation, in gardening, in agriculture, in animal health, in forests, in the proportion of stored products and in the protection of materials and also in the hygiene sector. They are effective against resistant and normally sensitive species and against all stages or individual stages of development. The aforementioned pests include: From the order of Isopoda, for example, Oniscus asellus, Armadillidium vulgare, Porcellio scaber. From the order of Diplopoda, for example, Blaniulus guttulatus. From the order of Chilopoda, for example, Geophilus carpophagus, spp. Scutigera. From the order of Symphyla, for example, Scutigerella immaculata. From the order of Thysanura, for example, Lepisma saccharina.

From the order of Collembola, for example, Onychiurus armatus. From the order of Orthoptera, for example, Acheta domesticus, spp. Gryllotalpa, Locusta migratoria migratorioides, spp. Melanoplus, Schistocerca gregaria. From the order of Blattaria, for example, Blatta orientalis, American Periplaneta, Leucophaea maderae, Germanic Blattella. From the order of Dermaptera, for example, Forfícula auricularia. From the order of Isoptera, for example, spp. Reticulitermes From the order of Phthiraptera, for example, Pediculus humanus corporis, spp. Haematopinus, spp. Linognathus, spp. Trichodectes, spp. Damalinia. From the order of Thysanoptera, for example, Hercinotrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentalis. From the order of Heteroptera, for example, spp. Euiygaster, Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, spp. Triatoma. From the order of Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera yastatrix, spp. Pemphigus, Macrosiphum avenae, spp. yzus, Phorodon humuli, Rhopalosiphum padi, spp. Empoasca, Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatollus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, spp. Pseudococcus, spp. Psylla. From the order of Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithcolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, spp. Lymantria, Bucculatrix thurberiella, Phyllocnistis citrella, spp. Agrotis, spp. Euxoa, spp. Feltia, Earias insulana, spp. Heliothis, Mamestra brassicae, Panolis flammea, spp. Spodoptera, Trichoplusia ni, Carpocapsa pomonella, spp. Pieris, spp. Chilo, Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneur fumiferana, Clysia ambiguella, Homona magnanimous, Tortrix viridana, spp. Cnaphalocerus, Oulema oryzae. From the order of Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, thoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, spp. Diabrotica, Psylliodes chrysocephala, Epilachna varivestis, spp. Atomaria, Oryzaephilus surinamensis, spp. Anthonomus, spp. Sitophilus, Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, spp. Dermestes, spp. Trogoderma, spp. Anthrenus, spp. Attagenus, spp. Lyctus, Meligethes aeneus, spp. Ptinus, Niptus hololeucus, Gibbium psylloides, spp. Tribolium, Tenebrio molitor, spp. Agriotes, spp. Conoderus, Melolontha melolontha, Amphimallon soistitialis, Costelytra zealandica, Lissorhoptrus oryzophilus. From the order of Hymenoptera, for example, spp. Diprion, spp. Hoplocampa, spp. Lasius, Monomorium pharaonis, spp. Vespa From the order of Diptera, for example, spp. Aedes, spp. Anopheles, spp. Culex, Drosophila melanogaster, spp. Musca, spp. Fannia, Calliphora erythrocephala, spp. Lucilia, spp. Chrysomyia, spp. Cuterebra, spp. Gastrophilus, spp. Hyppobosca, spp. Stomoxys, spp. Oestrus, spp. Hypoderma, spp. Tabanus, spp. Tannia, Bibio hortulanus, Oscinella frit, spp. Phorbia, Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Typula paludosa, spp. Hylemyia, spp. Liriomyza. From the order of Siphonaptera, for example, Xenopsylla cheopis, spp. Ceratophyllus. From the Arachnida class, for example, Scorpio maurus, Latrodectus mactans, Acarus siró, spp. Argas, spp. Ornithodoros, Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, spp. Boophilus, spp. Rhipicephalus, spp. Amblyomma, spp. Hyalomma, spp. Ixodes, spp. Psoroptes, spp. Chorioptes, spp. Sarcoptes, spp. Tarsonemus, spp. Bryobia praetiosa, spp. Panonychus, spp. Tetranychus, spp. Hemitarsonemus, spp. Brevipalpus. The plant-parasite nematodes include, for example, spp. Pratylenchus, Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, spp. Heterodera, spp. Globodera, spp. Meloidogyne, spp. Aphelenchoides, spp. Longidorus, spp.

Xiphinema, spp. Trichodorus, spp. Bursaphelenchus. Combinations of active compound can be converted into customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with active compound and micro-encapsulations. in polymeric materials. These formulations are produced in a known manner, for example, by mixing the active compounds with extenders, that is, liquid solvents and / or solid solvents, optionally with the use of surfactants, that is, emulsifiers and / or dispersants and / or processors. foam. If the extender used is water, it is also possible, for example, to use organic solvents in the form of co-solvents. The following are particularly suitable with liquid solvents: aromatics such as xylene, toluene or alkylnaphthalenes, chlorinated aliphatic hydrocarbons and chlorinated aromatics such as chlorobenzenes, chloroethylenes and methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, for example oil fractions mineral, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, ethyl methyl ketone, isobutyl methyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, or in addition water. Suitable solid carriers are: for example, ammonium salts and natural earth minerals such as kaolins, clays, talc, gypsum, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic earth materials such as highly dispersed silica, alumina and silicates; suitable solid carriers for granules are: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, or in addition synthetic granules of organic and inorganic food, and granules of organic material such as sawmill dust, husks of coconut, corn cobs and tobacco stems; Suitable emulsifiers and / or foam formers are, for example, nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene alcohol ethers, for example, alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulphates, arylsulfonates, or in addition protein hydrolysates; suitable dispersants are: for example lignosulfite waste liquors and methylcellulose. Products that provide sticky properties such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latexes, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, or in addition natural phospholipids such as cephalins and lecithins and synthetic phospholipids, can be used in the formulations. Other possible additives are mineral and vegetable oils. It is possible to use dyes such as inorganic pigments, for example, iron oxide, titanium oxide and Prussian Blue, and organic dyes such as dyes and alizarin, azo dyes and metal phthalocyanine dyes, and trace nutrients such as iron salts , manganese, boron, copper, cobalt, molybdenum and zinc. The formulations generally comprise between 0.1 and 95% by weight of the active compound, preferably between 0.5 and 90%.

Combinations of active compound, according to the present invention can be present in commercially available formulations and in the forms of use, prepared from these formulations, as a mixture with other active compounds, such as insecticides, attractants, sterilants, bactericides. , acaricides, nematicides, fungicides, growth regulating substances or herbicides. Insecticides include, for example, phosphates, carbonates, carboxylates, chlorinated hydrocarbons, phenylureas and substances produced by microorganisms, among others.

Mixtures with other known active compounds, such as herbicides or with fertilizers and growth regulators are also possible. When used as insecticides, combinations of active compound according to the present invention, can also be present in their commercially available formulations, and in the forms of use, prepared from these formulations, as a mixture with synergists. The synergists are compounds that increase the action of the active compounds, without being necessary for the aggregate synergist to be active by itself. The content of the active compound of the use forms prepared from the commercially available formulations can vary within wide limits. The concentration of active compound of the forms of use can be from 0.0000001 to 95% by weight of the active compound, preferably between 0.0001 and 1% by weight. The compounds are used in a customary manner suitable for the forms of use. In accordance with the present invention, it is possible to treat all plants and parts of plants. In the present invention it will be understood that the term "plants" means all plants and populations of plants, such as wild plants or desired and unwanted crop plants (including naturally occurring harvest plants). Harvest plants can be plants that can be obtained through breeding and optimization methods or through biotechnological and genetic engineering methods, methods or combinations of these methods, including plants transgenic and including plant crops that may or may not be protected by hatchery certificates. The parts of the plants, it will be understood that they mean all the parts and organs of the plants above the ground and below the earth, such as suckers, leaves, flowers and roots, whose examples can be mentioned as the leaves, needles, stems, trunks, flowers, bodies of fruit, fruits and seeds and also roots, tubers and rhizomes. Parts of the plants also include harvested plants and vegetative and generative propagating material, for example, seedlings, tubers, rhizomes, cuttings, and seeds. The treatment according to the present invention of the plants and parts of the plants with the active compound combinations, is carried out directly or by the action in their environment, habitat or storage area according to the customary treatment methods, for example, bathing, spraying, evaporation, atomization, emission, brushing and, in the case of propagation material, in particular in the case of seeds, also by coating one layer or multiple layers. As mentioned above, it is possible to treat all the plants and their parts according to the present invention. In a preferred embodiment, wild plant species and plant cultures, or those obtained by conventional biological breeding methods, are treated as it crosses and fusion of protoplasts, and parts of them. In a further preferred embodiment, transgenic plants and plant cultures obtained by genetic engineering methods are treated, if appropriate, in combination with conventional methods (Genetic Modified Organisms), and parts thereof. The terms "parts", "plant parts" and "plant part" have been explained above. Particularly preferred, in plant culture plants which are in each case commercially available or in use, are treated in accordance with the present invention. Depending on the species of plant or plant culture, its location and growth conditions (soil, climate, vegetation period, diet), the treatment according to the present invention can also result in superadditive ("synergistic") effects. Therefore, for example, reduced application ranges and / or an expansion of the activity spectrum and / or an increase in the activity of the substances and compositions that can be used according to the present invention are expected, better growth of plants, increased tolerance to high or low temperatures, increased tolerance to drought or salt content of water or soil, increased flowering performance, easier harvesting, accelerated maturation, higher harvest yields, better quality and / or higher nutritional value of the products harvested, better storage stability and / or processing capacity of harvested products, it is possible that they exceed the effects that really do. Transgenic plants or plant crops (for example those obtained by genetic engineering), which are preferred and which will be treated in accordance with the present invention, include all plants, which, in the genetic modification, received genetic material that imparts treatments useful particularly suitable for these plants. Examples of such treatments are for better plant growth, increased tolerance to high or low temperatures, increased tolerance to droughts or water or soil salt content, increased flowering performance, easier harvests, accelerated maturation, higher yields of harvest, better quality and / or greater nutritional value of harvested products, better storage stability and / or processing capacity of harvested products. Additional examples and with particular emphasis on said properties, are a better defense of plants against animal and microbial pests, such as insects, mites, phytopathogenic fungi, bacteria and / or viruses, and also increased tolerance of plants to certain compounds herbicidally. assets. Examples of transgenic plants that may be mentioned are important crop plants, such as cereals (wheat, rice), corn, beans soybeans, potatoes, cotton, oilseed rape and also fruit plants (with apple fruits, pears, citrus and grapes) and a particular emphasis is placed on corn, soybeans, potatoes, cotton and seed rape of oil. The treatments that are particularly emphasized are for the increased defense of plants against insects by toxins formed in plants, in particular, those formed in plants by genetic material from Bacillus Thuringiensis (for example through the genes Cry1A (a), Cry1A (b), Cry1A (c) CryIIA, CryIIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CrylF and also combinations thereof) (hereinafter referred to as "Bt plants"). The treatments that are particularly emphasized, are for increased tolerance. of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinothricin (for example the "PAT" gene). The genes in question that impart the desired treatments are also present in combination with others in the transgenic plants. Examples of "Bt plants" that may be mentioned are maize varieties, cotton varieties, soybean varieties, and potato varieties that are sold under the tradenames YIELD GARD® (for example, corn, cotton, kidney beans). soybean), KnockOut® (for example, corn), StarLink® (for example, corn), Bollgard® (cotton), Nucota® (cotton) and NewLeaf® (potato). The examples of tolerant herbicide plants that may be mentioned are corn varieties, cotton varieties and soybean varieties sold under the trade names of Roundup Ready® (tolerance to glyphosate, for example corn, cotton, soybeans), Liberty Link® (tolerance to phosphinothricin, for example oilseed rape), IMI® (tolerance to imidazolinones) and STS® (tolerance to sulfonylureas, eg, corn). Herbicide-resistant plants (plants raised in a conventional manner for herbicide tolerance) which may be mentioned, include the varieties sold under the trade name Clearfield® (for example corn). Of course, these manifestations also apply to plant crops that have these genetic treatments or that will still be developed, where the plants will be developed and / or commercialized in the future. The plants described can be treated according to the present invention in a particularly convenient manner with the mixture of the active compound according to the present invention. The preferred ranges stated above for mixtures also apply to the treatment of these plants. Particular emphasis is placed on the treatment of plants with the mixtures specifically mentioned in the present text. The expected action of a given combination of two active compounds, can be calculated as indicated below, according to the Publication of S.R. Colby, Weeds 15 (1967), 20-22: If X, is the extermination range, expressed as a percentage of the untreated control when the active compound A is used in an application range of mg / ha or in a concentration of m ppm. And, it is the extermination range, expressed as a percentage of the untreated control, when the active compound B is used in a range of application of ng / ha or a concentration of n ppm and E, is the range of extermination, expressed as a percentage of untreated control when active compounds A and B are used in application ranges of m or n / ha or in a concentration of m and ppm, then E = X + Y - 100 If the actual extermination range exceeds the calculated value, the extermination of the combination is superadditive, that is, there is a synergistic effect. In this case, the extermination range actually observed must exceed the value calculated using the previous formula for the expected extermination range (E) Example A Myzus persicae test Solvent: 78 parts by weight of acetone 1.5 parts by weight of dimethylformamide Emulsifier: 0.5 parts by weight polyglycol alkylaryl ether. To produce a suitable preparation of the active compound, 1 part by weight of the active compound is mixed with the expressed amounts of the solvents and the emulsifier, and the concentrate is diluted with water containing emulsifier to the desired concentration. The leaves of cabbage (Brassica olerácea) which were heavily infected by the green peach aphid (Myzus persicae), were treated by spraying with the preparation of the active compound of the desired concentration. After the desired period of time, the extermination was determined in%. 100% means that all the aphids had been exterminated; 0% means that none of the aphids had been exterminated. The determined extermination ranges enter the Colby formula. In this test, for example, the following combinations of active compound according to the present application, show a synergistically enhanced activity compared to the active compounds applied individually.

Table A Insects that damage plants Myzus persicae test Table A-1 Table A-2 * Found = activity found Cale. = activity calculated using the Coiby formula.

Example B Phaedon cochleariae larvae test Solvent: 78 parts by weight of acetone 1.5 parts by weight of dimethylformamide Emulsifier: 0.5 parts by weight polyglycol alkylaryl ether. To produce a suitable preparation of the active compound, 1 part by weight of the active compound was mixed with the manifested amounts of solvents and emulsifiers, and the concentrate was diluted with water containing emulsifier to the desired concentration. Cabbage leaves were treated. { Brassica oleracea) by spraying with the preparation of the active compound of the desired concentration, and they were populated with mustard beetle larvae [Phaedon cochleariae], while the leaves were still wet.

After the desired period of time, the extermination was determined in%. 100% means that the entire beetle larva had been exterminated; 0% means that no beetle larvae had been exterminated. The determined extermination ranges are entered into Colby's formula. In this test, the following combinations of active compound according to the present application, show a synergistically enhanced activity compared to the active compounds applied individually.

Table B Insects that damage the plants Larvae test Phaedon cochleariae * Found = activity found ** Cale. = activity calculated using the Coiby formula.

Example C Spodoptera frugiperda larva test Solvent: 78 parts by weight of acetone 1.5 parts by weight of dimethylformamide Emulsifier: 0.5 parts by weight of polyglycol ether of alkylaryl. To produce a suitable preparation of active compound, 1 part by weight of the active compound was mixed with the manifested amounts of solvents and emulsifiers, and the concentrate was diluted with water containing emulsion at the desired concentration. Cabbage leaves (Brassica olerácea) were treated by spraying with the preparation of the active compound of the desired concentration, and were populated with mothworm larvae (Spodoptera frugiperda), while the leaves were still moist. After the desired period of time, the extermination was determined in%. 100% means that all the caterpillars had been exterminated; 0% means that none of the caterpillars had been exterminated. The determined extermination ranges were entered into Colby's formula. In this test, the following combinations of active compound according to the present application show synergistically and improved activity compared to the active compounds applied individually.

Table C Insects that damage plants Larvae test Spodoptera frugiperda Cale. = activity calculated using the Colby formula. Example D Tetranychus test (resistant treatment-OP / spray) Solvent: 78 parts by weight of acetone 1.5 parts by weight of dimethylformamide Emulsifier: 0.5 parts by weight polyglycol alkylaryl ether. To produce a suitable preparation of the active compound, 1 part by weight of the active compound was mixed with the manifested amounts of solvent and emulsifier, and the concentrate was diluted with water containing emulsifier to the desired concentration.

Disks of bean leaves. { Phaseolus vulgaris) which were infested by all stages of greenhouse red spider mite (Tetranychus urticae), were sprayed with an active compound preparation of the desired concentration. After the desired period of time, the extermination was determined in%. 100% means that all spider mites have been exterminated; 0% means that none of the spider mites had been exterminated. In this test, the following combination of active compound according to the present application, showed a synergistically improved activity compared to the active compounds applied individually. Table D Mites damaging plants Tetranychus urticae test Table D 1 Cale. = activity calculated using the Colby formula.

Table D Mites damaging plants Tetranychus urticae test Table D 2 Cale. = activity calculated using the Coiby formula. Example E Test of Aphis gossypii Solvent: 7 parts by weight of the dimethylformamide Emulsifier: 2 parts by weight of alkylaryl polyglycol ether. To produce a suitable preparation of the active compound, 1 part by weight of the active compound was mixed with the expressed amounts of the solvent and emulsifier, and the Concentrate was diluted with the water containing emulsifier to the desired concentration. Cotton sheets. { Gossypium herbaceum) that were very infected by the cotton aphid. { Aphis gossypii), they were treated by bathing in the preparation of active compound of the desired concentration. After the desired period of time, the extermination was determined in%. 100% means that all the aphids had been exterminated; 0% means that none of the aphids had been exterminated. The determined extermination ranges were entered into Colby's formula. In this test, for example, the following combinations of active compound according to the present application, showed a synergistically improved activity compared to the active compounds applied individually. Table E Insects that damage plants Test of Aphis gossypii Cale. = activity calculated using the Colby formula.

Example F Critical concentration test / ground insects-treatment of transgenic plants Test insect: Diabrotica balteata - larva on the ground Solvent: 7 parts by weight of acetone Emulsifier: 2 parts by weight polyglycol alkylaryl ether. To produce a suitable preparation of the active compound, 1 part by weight of the active compound was mixed with the manifested amount of solvent, the amount of emulsifier was added and the concentrate was diluted with water to the desired concentration. The preparation of the active compound is poured into the earth. Here, the concentration of the active compound in the preparation is virtually immaterial, only the amount by weight of the active compound per unit volume of soil, which manifests in ppm (mg / 1), is what matters. The earth is filled in jars of 0.251, and these are allowed to settle at a temperature of 20 ° C. Immediately after the preparation, 5 ears of corn germinated previously from the YIELD GUARD crop (trademark Monsanto Comp. E.U.A.) were placed in each jar. After 2 days, the appropriate test insects were placed on the treated soil. After 7 additional days, the effectiveness of the active compound was determined by counting the corn plants that had emerged (all plants emerged = 100% activity). Example G Test of Heliothis virescens - treatment of transgenic plants Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl polyglycol ether. To produce a suitable preparation of the active compound, 1 part by weight of the active compound was mixed with the manifested amount of solvent, and the amount of emulsifier was expressed, the concentrate was diluted with water to the desired concentration. Soya bean sprouts (Glycine max) from the Roundup Ready crop (trademark of Monsanto Comp. EUA) were treated, spraying with the preparation of the active compound of the desired concentration and populated with the tobacco worm Heliothis virescens, while the leaves They were still wet. After the desired period of time, the extermination of the insects was determined. Example H Test Myzus persicae - treatment of transgenic plants Solvent: 7 parts by weight of acetone Emulsifier: 2 parts by weight of alkylaryl polyglycol ether. To produce a suitable preparation of the active compound, 1 part by weight of the active compound was mixed with the amount of solvent and the amount of emulsifier, and the concentrate was diluted with water to the desired concentration. The transgenic cabbage plants (Brassica oleracea), which were heavily infected by the green peach aphid Myzus persicae, were treated by rolling them with the preparation of the active compound at the desired concentration. After the desired period of time, the extermination of the insects was determined. It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention is that which is clear from the present description of the invention.

Claims (7)

1. CLAIMS Having described the invention as above, the content of the following claims is claimed as property: 1. A combination of active compound characterized in that it comprises compounds of the formula (I) or (II):
2. O) (II) and at least one of the following compounds: acrylamine alpha-cypermethrin beta cyflutrin cyhalothrin cypermethrin deltamethrin esfenvalerate etofenprox fenpropathrin fenvalerate flucitrinate lambda-cyhalothrin gamma-cyhalothrin permethrin tau-fuuvalinate tralometrine zeta-cypermethrin cyfluthrin bifenthrin cycloprotrin eflusilanate fubfenprox pyrethrin resmethrin 2. The active compound combination according to claim 1, characterized in that it comprises the compound of the formula (I).
3. 3. The active compound combination according to claim 1, characterized in that it comprises the compound of the formula (II).
4. 4. The use of the active compound combinations according to claim 1, to control pests of animals.
5. 5. A method for controlling pests of animals, characterized in that the active compound combinations of according to claim 1, they are allowed to act on animal pests and / or their habitas.
6. 6. A process for preparing insecticidal and / or acaricidal compositions, characterized in that the active compound combinations according to claim 1 are mixed with extenders and / or surfactants.
7. 7. A composition characterized in that it comprises a combination of active compound according to claim 1, for controlling pests of animals.