MX2008001059A - Fungicidas de 6-fenil-pirazolopirimidina-7-ilamina. - Google Patents

Info

Publication number

MX2008001059A

MX2008001059A MX2008001059A MX2008001059A MX2008001059A MX 2008001059 A MX2008001059 A MX 2008001059A MX 2008001059 A MX2008001059 A MX 2008001059A MX 2008001059 A MX2008001059 A MX 2008001059A MX 2008001059 A MX2008001059 A MX 2008001059A

Authority

MX

Mexico

Prior art keywords

formula

alkyl

compounds

compound

methyl

Prior art date

2005-07-27

Links

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• Global Dossier
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• KKEOHSAYYNDJJC-UHFFFAOYSA-N 6-phenylpyrazolo[4,3-d]pyrimidin-7-amine Chemical compound C1=NC2=CN=NC2=C(N)N1C1=CC=CC=C1 KKEOHSAYYNDJJC-UHFFFAOYSA-N 0.000 title claims abstract description 4
• 239000000417 fungicide Substances 0.000 title description 12
• 150000001875 compounds Chemical class 0.000 claims abstract description 120
• 241000233866 Fungi Species 0.000 claims abstract description 14
• 238000000034 method Methods 0.000 claims abstract description 9
• 230000003032 phytopathogenic effect Effects 0.000 claims abstract description 4
• -1 phenoxy, phenylthio, benzyloxy Chemical group 0.000 claims description 143
• 239000000203 mixture Substances 0.000 claims description 34
• 125000000217 alkyl group Chemical group 0.000 claims description 24
• 229910052736 halogen Inorganic materials 0.000 claims description 17
• 150000002367 halogens Chemical class 0.000 claims description 17
• 229910052739 hydrogen Inorganic materials 0.000 claims description 14
• 239000001257 hydrogen Substances 0.000 claims description 14
• 125000003545 alkoxy group Chemical group 0.000 claims description 11
• 125000001188 haloalkyl group Chemical group 0.000 claims description 11
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
• 239000000463 material Substances 0.000 claims description 10
• PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims description 10
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
• 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 7
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
• 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims description 6
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
• 229920006395 saturated elastomer Polymers 0.000 claims description 6
• 229910052717 sulfur Inorganic materials 0.000 claims description 6
• JVVRJMXHNUAPHW-UHFFFAOYSA-N 1h-pyrazol-5-amine Chemical compound NC=1C=CNN=1 JVVRJMXHNUAPHW-UHFFFAOYSA-N 0.000 claims description 5
• 125000003342 alkenyl group Chemical group 0.000 claims description 5
• 229910052760 oxygen Inorganic materials 0.000 claims description 5
• 239000007787 solid Substances 0.000 claims description 5
• 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 4
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
• 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 4
• 125000004414 alkyl thio group Chemical group 0.000 claims description 4
• 125000003118 aryl group Chemical group 0.000 claims description 4
• 239000000460 chlorine Substances 0.000 claims description 4
• 229910052801 chlorine Inorganic materials 0.000 claims description 4
• 125000005842 heteroatom Chemical group 0.000 claims description 4
• 150000002431 hydrogen Chemical class 0.000 claims description 4
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
• 229910052757 nitrogen Inorganic materials 0.000 claims description 4
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
• 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 3
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
• 125000002947 alkylene group Chemical group 0.000 claims description 3
• 125000000304 alkynyl group Chemical group 0.000 claims description 3
• 229910021529 ammonia Inorganic materials 0.000 claims description 3
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
• 229910052794 bromium Inorganic materials 0.000 claims description 3
• 125000004122 cyclic group Chemical group 0.000 claims description 3
• 230000000855 fungicidal effect Effects 0.000 claims description 3
• 125000005702 oxyalkylene group Chemical group 0.000 claims description 3
• 125000005865 C2-C10alkynyl group Chemical group 0.000 claims description 2
• 150000001264 acyl cyanides Chemical class 0.000 claims description 2
• 125000005092 alkenyloxycarbonyl group Chemical group 0.000 claims description 2
• 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 2
• 125000005225 alkynyloxycarbonyl group Chemical group 0.000 claims description 2
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
• 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
• 125000000000 cycloalkoxy group Chemical group 0.000 claims description 2
• 125000005366 cycloalkylthio group Chemical group 0.000 claims description 2
• 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 2
• 230000002538 fungal effect Effects 0.000 claims description 2
• 239000002689 soil Substances 0.000 claims description 2
• 238000004519 manufacturing process Methods 0.000 claims 2
• 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 1
• 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 1
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
• 239000007788 liquid Substances 0.000 claims 1
• 125000003884 phenylalkyl group Chemical group 0.000 claims 1
• 230000003071 parasitic effect Effects 0.000 abstract 1
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
• 241000196324 Embryophyta Species 0.000 description 22
• 239000002904 solvent Substances 0.000 description 22
• 238000009472 formulation Methods 0.000 description 19
• 235000013339 cereals Nutrition 0.000 description 17
• 240000007594 Oryza sativa Species 0.000 description 14
• 235000007164 Oryza sativa Nutrition 0.000 description 14
• 240000008042 Zea mays Species 0.000 description 14
• 235000002017 Zea mays subsp mays Nutrition 0.000 description 14
• 235000009566 rice Nutrition 0.000 description 14
• 239000000839 emulsion Substances 0.000 description 13
• 239000012895 dilution Substances 0.000 description 12
• 238000010790 dilution Methods 0.000 description 12
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
• 239000000243 solution Substances 0.000 description 11
• 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 10
• 238000006243 chemical reaction Methods 0.000 description 10
• 235000005822 corn Nutrition 0.000 description 10
• 239000000843 powder Substances 0.000 description 10
• 239000000725 suspension Substances 0.000 description 10
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
• 229910052783 alkali metal Inorganic materials 0.000 description 9
• 239000002270 dispersing agent Substances 0.000 description 9
• 239000006185 dispersion Substances 0.000 description 9
• 239000008187 granular material Substances 0.000 description 9
• 239000003921 oil Substances 0.000 description 9
• 235000013311 vegetables Nutrition 0.000 description 9
• 239000002253 acid Substances 0.000 description 8
• 239000003995 emulsifying agent Substances 0.000 description 8
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
• IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 7
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
• 235000021307 Triticum Nutrition 0.000 description 7
• 241000209140 Triticum Species 0.000 description 7
• 150000001340 alkali metals Chemical class 0.000 description 7
• 239000002585 base Substances 0.000 description 7
• 230000000694 effects Effects 0.000 description 7
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
• 235000010469 Glycine max Nutrition 0.000 description 6
• 244000068988 Glycine max Species 0.000 description 6
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
• SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 6
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
• 239000000969 carrier Substances 0.000 description 6
• JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
• 238000002360 preparation method Methods 0.000 description 6
• 241000894007 species Species 0.000 description 6
• 239000008096 xylene Substances 0.000 description 6
• 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 5
• 229920000742 Cotton Polymers 0.000 description 5
• 244000299507 Gossypium hirsutum Species 0.000 description 5
• 235000021536 Sugar beet Nutrition 0.000 description 5
• 235000014787 Vitis vinifera Nutrition 0.000 description 5
• 240000006365 Vitis vinifera Species 0.000 description 5
• 150000007513 acids Chemical class 0.000 description 5
• 239000006072 paste Substances 0.000 description 5
• PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 4
• MPDXYVOXVJOKIN-UHFFFAOYSA-N 1h-pyrazolo[4,3-d]pyrimidin-7-amine Chemical class NC1=NC=NC2=C1NN=C2 MPDXYVOXVJOKIN-UHFFFAOYSA-N 0.000 description 4
• 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
• SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
• 241000233654 Oomycetes Species 0.000 description 4
• 240000003768 Solanum lycopersicum Species 0.000 description 4
• 235000002595 Solanum tuberosum Nutrition 0.000 description 4
• 244000061456 Solanum tuberosum Species 0.000 description 4
• 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 4
• 150000001298 alcohols Chemical class 0.000 description 4
• 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
• 239000011230 binding agent Substances 0.000 description 4
• 230000015572 biosynthetic process Effects 0.000 description 4
• 125000004432 carbon atom Chemical group C* 0.000 description 4
• 239000003795 chemical substances by application Substances 0.000 description 4
• 235000014113 dietary fatty acids Nutrition 0.000 description 4
• XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
• 239000004495 emulsifiable concentrate Substances 0.000 description 4
• 238000001704 evaporation Methods 0.000 description 4
• 230000008020 evaporation Effects 0.000 description 4
• 239000000194 fatty acid Substances 0.000 description 4
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• 239000000499 gel Substances 0.000 description 4
• 150000002430 hydrocarbons Chemical group 0.000 description 4
• WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
• 229910052500 inorganic mineral Inorganic materials 0.000 description 4
• 235000009973 maize Nutrition 0.000 description 4
• AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 4
• 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 4
• BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
• 239000011707 mineral Substances 0.000 description 4
• 235000010755 mineral Nutrition 0.000 description 4
• XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 4
• 229920000151 polyglycol Polymers 0.000 description 4
• 239000010695 polyglycol Substances 0.000 description 4
• 235000012015 potatoes Nutrition 0.000 description 4
• 238000003786 synthesis reaction Methods 0.000 description 4
• 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 4
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
• WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
• 240000008067 Cucumis sativus Species 0.000 description 3
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
• 241000221785 Erysiphales Species 0.000 description 3
• 241000221787 Erysiphe Species 0.000 description 3
• 240000005979 Hordeum vulgare Species 0.000 description 3
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• 240000005561 Musa balbisiana Species 0.000 description 3
• 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
• 240000000111 Saccharum officinarum Species 0.000 description 3
• 235000007201 Saccharum officinarum Nutrition 0.000 description 3
• ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
• 150000001342 alkaline earth metals Chemical class 0.000 description 3
• 235000012211 aluminium silicate Nutrition 0.000 description 3
• 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
• 239000004359 castor oil Substances 0.000 description 3
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• ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
• 150000002334 glycols Chemical class 0.000 description 3
• 208000015181 infectious disease Diseases 0.000 description 3
• 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 3
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• PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 description 2
• 125000004973 1-butenyl group Chemical group C(=CCC)* 0.000 description 2
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• WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
• OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
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• PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
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