MX170501B - , "procedimiento para recobrar metacroleina - Google Patents

, "procedimiento para recobrar metacroleina

Info

Publication number
MX170501B
MX170501B MX016303A MX1630389A MX170501B MX 170501 B MX170501 B MX 170501B MX 016303 A MX016303 A MX 016303A MX 1630389 A MX1630389 A MX 1630389A MX 170501 B MX170501 B MX 170501B
Authority
MX
Mexico
Prior art keywords
methacrolein
methacrylic acid
gas
aqueous phase
acid
Prior art date
Application number
MX016303A
Other languages
English (en)
Inventor
Hiroshi Yoshida
Masao Baba
Syoichi Matsumoto
Masatoshi Ueoka
Yosuke Ogata
Original Assignee
Nippon Catalytic Chem Ind
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Catalytic Chem Ind filed Critical Nippon Catalytic Chem Ind
Publication of MX170501B publication Critical patent/MX170501B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/783—Separation; Purification; Stabilisation; Use of additives by gas-liquid treatment, e.g. by gas-liquid absorption
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención se refiere a un procedimiento para recuperar metacroleína, caracterizado porque comprende una etapa de reacción (A) que comprende oxidar catalíticamente isobutileno, t-butanol, metacroleína, aldehído de isobutilo o ácido isobutírico, o una mezcla de los mismos, con un gas que contiene oxígeno molecular en una fase de vapor, una etapa de condensación (B) de ácido metacrílico, una etapa de extracción (C) de ácido metacrílico, una etapa de recuperación (D) de metacroleína, que comprende poner en contacto un gas que contiene metacroleína y ácido metacrílico descargado con una fase acuosa que contiene ácido metacrílico y ácido acético, mediante lo cual se recupera metacroleína y el ácido metacrílico contenido en el gas dentro de la fase acuosa, una etapa de desorción (E) de metacroleína, y una etapa de recuperación (F) de ácido metacrílico.
MX016303A 1988-06-03 1989-06-02 , "procedimiento para recobrar metacroleina MX170501B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13562588 1988-06-03

Publications (1)

Publication Number Publication Date
MX170501B true MX170501B (es) 1993-08-26

Family

ID=15156180

Family Applications (1)

Application Number Title Priority Date Filing Date
MX016303A MX170501B (es) 1988-06-03 1989-06-02 , "procedimiento para recobrar metacroleina

Country Status (9)

Country Link
US (1) US5248819A (es)
EP (1) EP0345083B1 (es)
JP (1) JPH0684326B2 (es)
KR (1) KR950000640B1 (es)
BR (1) BR8902564A (es)
CA (1) CA1307004C (es)
DE (1) DE68904815T2 (es)
ES (1) ES2039862T3 (es)
MX (1) MX170501B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4225321A1 (de) * 1992-07-31 1994-02-03 Basf Ag Verfahren zur Abtrennung von Methacrolein aus einem gasförmigen Gemisch
DE4321513A1 (de) * 1993-06-29 1995-01-12 Hoechst Ag Verfahren zur Reinigung von Abwässern der Aldolisierungsreaktion
US5877345A (en) * 1997-02-07 1999-03-02 Rohm And Haas Company Process for producing butyl acrylate
DE19709392A1 (de) * 1997-03-07 1998-09-10 Basf Ag Verfahren zur Extraktion von (Meth)acrylsäure
DE19709471A1 (de) * 1997-03-07 1998-09-10 Basf Ag Verfahren zur Herstellung von (Meth)acrylsäure
JP2003238485A (ja) * 2001-12-10 2003-08-27 Nippon Shokubai Co Ltd （メタ）アクリル酸の捕集方法および装置
US7649112B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
EP2085376B1 (en) 2008-01-30 2012-09-05 Evonik Röhm GmbH Process for preparation of high purity methacrylic acid
CA2781246A1 (en) 2011-07-14 2013-01-14 Rohm And Haas Company Method for removal of organic compounds from waste water streams in a process for production of (meth)acrylic acid
WO2013163806A1 (en) 2012-05-03 2013-11-07 Evonik Industries Ag Process for preparation of highly pure, non-yellowing methacrylic acid
JP2016516732A (ja) 2013-03-18 2016-06-09 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ メタクリル酸及びメタクリル酸エステルの製造方法
EP3608305A1 (en) 2018-08-10 2020-02-12 Röhm GmbH Process for producing methacrylic acid or methacrylic acid esters
EP3945086B1 (de) * 2020-07-30 2022-10-26 Röhm GmbH C-4 basiertes verfahren zur herstellung von mma unter rückführung und recyclierung von methacrolein
CN112057946A (zh) * 2020-08-10 2020-12-11 金沂蒙集团有限公司 一种乙醛合成丁烯醛的废水资源化利用的方法及装置
WO2022214860A1 (en) * 2021-04-06 2022-10-13 Bharat Petroleum Corporation Limited A process for recovering methacrolein from a reactor effluent stream containing methacrolein and methacrylic acid

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS547768B2 (es) * 1973-01-06 1979-04-10
JPS6059891B2 (ja) * 1977-09-28 1985-12-27 住友化学工業株式会社 メタクロレインおよびメタクリル酸の分離方法
US4166774A (en) * 1977-12-05 1979-09-04 The Standard Oil Company Acrylic acid recovery and purification
US4147721A (en) * 1978-04-06 1979-04-03 Halcon Research And Development Corporation Process for recovering methacrylic acid
JPH0615497B2 (ja) * 1985-10-24 1994-03-02 日本化薬株式会社 メタクリル酸の回収方法
JPH0832218B2 (ja) * 1993-04-14 1996-03-29 東京都 魚介用水供給方法及び装置

Also Published As

Publication number Publication date
ES2039862T3 (es) 1993-10-01
US5248819A (en) 1993-09-28
KR950000640B1 (ko) 1995-01-26
JPH0276835A (ja) 1990-03-16
DE68904815T2 (de) 1993-08-26
EP0345083A2 (en) 1989-12-06
JPH0684326B2 (ja) 1994-10-26
BR8902564A (pt) 1990-01-23
KR910000591A (ko) 1991-01-29
EP0345083B1 (en) 1993-02-10
EP0345083A3 (en) 1990-04-25
CA1307004C (en) 1992-09-01
DE68904815D1 (de) 1993-03-25

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