MX168595B - Procedimiento para la preparacion de derivados de azolilo que tienen actividad fungicida - Google Patents
Procedimiento para la preparacion de derivados de azolilo que tienen actividad fungicidaInfo
- Publication number
- MX168595B MX168595B MX007428A MX742887A MX168595B MX 168595 B MX168595 B MX 168595B MX 007428 A MX007428 A MX 007428A MX 742887 A MX742887 A MX 742887A MX 168595 B MX168595 B MX 168595B
- Authority
- MX
- Mexico
- Prior art keywords
- formula
- preparation
- procedure
- fungicide activity
- azolyl derivatives
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- -1 AZOLYL Chemical class 0.000 title 1
- 230000000694 effects Effects 0.000 title 1
- 230000000855 fungicidal effect Effects 0.000 title 1
- 239000000417 fungicide Substances 0.000 title 1
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 abstract 2
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000001447 alkali salts Chemical class 0.000 abstract 1
- 239000000010 aprotic solvent Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
- C07D317/22—Radicals substituted by singly bound oxygen or sulfur atoms etherified
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invención se refiere a procedimiento para la preparación de compuestos que tienen la fórmula general I: caracterizado porque consiste en someter a reacción de transcetalización los cetales que tienen la fórmula: II, con una alfa-bromocetona que tiene la fórmula: en presencia de un catalizador ácido, a una temperatura que va de 60 a 140 grados C, y condensar el producto intermedio que se obtiene y que corresponde a la fórmula IV; con una sal alcalina de un azol que tiene la fórmula V: en un solvente aprótico dipolar, a una temperatura que va de 20 grados C a la temperatura de reflujo de los reactivos.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT21194/86A IT1196528B (it) | 1986-07-21 | 1986-07-21 | Azolilderivati ad attivita' antifungina |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX168595B true MX168595B (es) | 1993-06-01 |
Family
ID=11178188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX007428A MX168595B (es) | 1986-07-21 | 1987-07-20 | Procedimiento para la preparacion de derivados de azolilo que tienen actividad fungicida |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US4810718A (es) |
| EP (1) | EP0254632B1 (es) |
| JP (1) | JPH07615B2 (es) |
| KR (1) | KR950013769B1 (es) |
| CN (1) | CN1020905C (es) |
| AR (1) | AR244684A1 (es) |
| AT (1) | ATE77377T1 (es) |
| AU (1) | AU596199B2 (es) |
| BR (1) | BR8703801A (es) |
| CA (1) | CA1320489C (es) |
| DE (1) | DE3779827T2 (es) |
| EG (1) | EG18444A (es) |
| ES (1) | ES2042594T3 (es) |
| HU (1) | HU204524B (es) |
| IL (1) | IL83227A (es) |
| IT (1) | IT1196528B (es) |
| MX (1) | MX168595B (es) |
| NZ (1) | NZ221106A (es) |
| ZA (1) | ZA875225B (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1186784B (it) * | 1985-11-04 | 1987-12-16 | Montedison Spa | Azoliderivati ad attivita' antufungina |
| MY100575A (en) * | 1985-11-22 | 1990-12-15 | Ciba Geigy Ag | Microbicides |
| KR100518747B1 (ko) * | 2003-08-27 | 2005-10-05 | 벤텍스 주식회사 | 3층 구조를 갖는 흡수속건 섬유 시이트 |
| CN101899040B (zh) * | 2010-07-23 | 2012-07-11 | 周保东 | 苯醚甲环唑的制备工艺 |
| JP5958905B2 (ja) * | 2011-10-20 | 2016-08-02 | 公立大学法人秋田県立大学 | 植物成長調節剤 |
| KR102280643B1 (ko) | 2019-10-22 | 2021-07-22 | 주식회사 포스코 | 고온 산화 저항성 및 고온 강도가 우수한 크롬 강판 및 그 제조 방법 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4101666A (en) * | 1975-10-06 | 1978-07-18 | Janssen Pharmaceutica N.V. | 1-(2-Ar-4-R-1,3-dioxolan-2-ylmethyl)imidazoles |
| AU524832B2 (en) * | 1978-07-25 | 1982-10-07 | Janssen Pharmaceutica N.V. | 1-(2-aryl-1,3-dioxan-2-ylmethyl)-1h-imidazoles and 1h-1,2,4 -triazoles |
| US4338327A (en) * | 1978-10-06 | 1982-07-06 | Janssen Pharmaceutica, N.V. | Substituted 1-(2-aryl-1,3-dioxolan-2-ylmethyl)-1H-1,2,4-triazoles |
| DE2918894A1 (de) * | 1979-05-10 | 1980-11-20 | Bayer Ag | Fluorierte 1-triazolyl-butan-derivate, verfahren zu ihrer herstellung und ihre verwendung als fungizide |
| US4616027A (en) * | 1982-08-14 | 1986-10-07 | Pfizer Inc. | Antifungal 1-aryl-1-fluoroalkyl-2-(1H-1,2,4-triazol-1-yl)ethanols |
| DE3232737A1 (de) * | 1982-09-03 | 1984-03-08 | Bayer Ag, 5090 Leverkusen | 2-aryl-2-azolylmethyl-1,3-dioxepine |
| DE3401694A1 (de) * | 1984-01-19 | 1985-07-25 | Basf Ag, 6700 Ludwigshafen | Azolylmethylcycloacetale, verfahren zu ihrer herstellung und ihre verwendung als arzneimittel |
| IT1186784B (it) * | 1985-11-04 | 1987-12-16 | Montedison Spa | Azoliderivati ad attivita' antufungina |
| MY100575A (en) * | 1985-11-22 | 1990-12-15 | Ciba Geigy Ag | Microbicides |
-
1986
- 1986-07-21 IT IT21194/86A patent/IT1196528B/it active
-
1987
- 1987-07-16 US US07/074,352 patent/US4810718A/en not_active Expired - Fee Related
- 1987-07-16 AU AU75738/87A patent/AU596199B2/en not_active Ceased
- 1987-07-16 ZA ZA875225A patent/ZA875225B/xx unknown
- 1987-07-17 DE DE8787401680T patent/DE3779827T2/de not_active Expired - Lifetime
- 1987-07-17 AT AT87401680T patent/ATE77377T1/de active
- 1987-07-17 NZ NZ221106A patent/NZ221106A/xx unknown
- 1987-07-17 IL IL83227A patent/IL83227A/xx unknown
- 1987-07-17 ES ES87401680T patent/ES2042594T3/es not_active Expired - Lifetime
- 1987-07-17 EP EP87401680A patent/EP0254632B1/en not_active Expired - Lifetime
- 1987-07-20 EG EG421/87A patent/EG18444A/xx active
- 1987-07-20 MX MX007428A patent/MX168595B/es unknown
- 1987-07-20 JP JP62179257A patent/JPH07615B2/ja not_active Expired - Lifetime
- 1987-07-20 AR AR87308189A patent/AR244684A1/es active
- 1987-07-20 CA CA000542471A patent/CA1320489C/en not_active Expired - Fee Related
- 1987-07-21 CN CN87105176A patent/CN1020905C/zh not_active Expired - Fee Related
- 1987-07-21 KR KR1019870007876A patent/KR950013769B1/ko not_active Expired - Fee Related
- 1987-07-21 HU HU873368A patent/HU204524B/hu not_active IP Right Cessation
- 1987-07-21 BR BR8703801A patent/BR8703801A/pt not_active IP Right Cessation
-
1989
- 1989-02-14 US US07/310,338 patent/US4940724A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0254632B1 (en) | 1992-06-17 |
| EG18444A (en) | 1993-02-28 |
| IL83227A (en) | 1991-11-21 |
| IT1196528B (it) | 1988-11-16 |
| HUT44901A (en) | 1988-05-30 |
| CN87105176A (zh) | 1988-04-20 |
| HU204524B (en) | 1992-01-28 |
| US4810718A (en) | 1989-03-07 |
| CA1320489C (en) | 1993-07-20 |
| ZA875225B (en) | 1988-01-22 |
| EP0254632A3 (en) | 1989-03-22 |
| KR880001640A (ko) | 1988-04-25 |
| AR244684A1 (es) | 1993-11-30 |
| JPH07615B2 (ja) | 1995-01-11 |
| AU7573887A (en) | 1988-01-28 |
| JPS6393780A (ja) | 1988-04-25 |
| US4940724A (en) | 1990-07-10 |
| ES2042594T3 (es) | 1993-12-16 |
| BR8703801A (pt) | 1988-03-29 |
| AU596199B2 (en) | 1990-04-26 |
| IL83227A0 (en) | 1987-12-31 |
| DE3779827D1 (de) | 1992-07-23 |
| KR950013769B1 (ko) | 1995-11-15 |
| NZ221106A (en) | 1990-09-26 |
| CN1020905C (zh) | 1993-05-26 |
| DE3779827T2 (de) | 1992-12-24 |
| IT8621194A0 (it) | 1986-07-21 |
| ATE77377T1 (de) | 1992-07-15 |
| EP0254632A2 (en) | 1988-01-27 |
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