MX166196B - Metodo para formar una matriz resistente a la atricion, incorporando ingredientes cataliticos cristalinos - Google Patents

Metodo para formar una matriz resistente a la atricion, incorporando ingredientes cataliticos cristalinos

Info

Publication number
MX166196B
MX166196B MX012608A MX1260888A MX166196B MX 166196 B MX166196 B MX 166196B MX 012608 A MX012608 A MX 012608A MX 1260888 A MX1260888 A MX 1260888A MX 166196 B MX166196 B MX 166196B
Authority
MX
Mexico
Prior art keywords
attrition resistant
forming
mixing
resistant matrix
matrix
Prior art date
Application number
MX012608A
Other languages
English (en)
Inventor
Terrance J Velten
Edward J Demmel
Original Assignee
Terrance J Velten
Edward J Demmel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Terrance J Velten, Edward J Demmel filed Critical Terrance J Velten
Publication of MX166196B publication Critical patent/MX166196B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a un método para formar una matriz resistente a la atrición que tiene hasta aproximadamente 60 por ciento en peso de un ingrediente catalítico cristalino pequeño, el método se caracteriza porque comprende: (a) mezclar una sílice coloidal con una mezcla del ingrediente catalizador, en donde por lo menos un ingrediente de la mezcla es un material catalizador cristalino pequeño, con agua suficiente para formar una primera suspensión acuosa espesa; (b) mezclar la primera suspensión acuosa espesa con una alúmina dispersa en ácido hasta una relación total de sílice coloidal a alúmina dispersa de aproximadamente 5:1 a aproximadamente 1:1 en peso, para formar una segunda suspensión acuosa espesa; (c) mezclar la segunda suspensión acuosa espesa con agua suficiente para formar una formulación rociable, uniforme resultante; (d) secar por rociadura la formulación rociable para formar partículas del aglutinante de matriz microesferoidales; y (e) calcinar las partículas del aglutinante de la matriz para producir partículas de matriz resistentes a la atrición.
MX012608A 1987-08-12 1988-08-10 Metodo para formar una matriz resistente a la atricion, incorporando ingredientes cataliticos cristalinos MX166196B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/084,685 US4826793A (en) 1987-08-12 1987-08-12 Method of incorporating small crystalline catalytic ingredients into an attrition-resistant matrix

Publications (1)

Publication Number Publication Date
MX166196B true MX166196B (es) 1992-12-23

Family

ID=22186581

Family Applications (1)

Application Number Title Priority Date Filing Date
MX012608A MX166196B (es) 1987-08-12 1988-08-10 Metodo para formar una matriz resistente a la atricion, incorporando ingredientes cataliticos cristalinos

Country Status (5)

Country Link
US (1) US4826793A (es)
EP (1) EP0377586A4 (es)
JP (1) JPH02501454A (es)
MX (1) MX166196B (es)
WO (1) WO1989001362A1 (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5298153A (en) * 1987-05-07 1994-03-29 Union Oil Company Of California Cracking process using an attrition resistant catalyst
US4987110A (en) * 1987-05-07 1991-01-22 Union Oil Company Of California Attrition resistant cracking catalyst
US4946814A (en) * 1989-03-10 1990-08-07 Thiele-Kaolin Company Process for improving the physical and catalytic properties of fluid cracking catalysts
US5866496A (en) * 1989-03-10 1999-02-02 Thiele Kaolin Company Cracking catalyst and process for preparing same
US5330943A (en) * 1989-03-10 1994-07-19 Thiele Kaolin Company Process for improving the physical and catalytic properties of a fluid cracking catalyst
US5401704A (en) * 1990-10-23 1995-03-28 Mobil Oil Corporation Hydrocracking catalyst and process using small crystal size zeolite Y
FR2670687A1 (fr) * 1990-12-21 1992-06-26 Shell Int Research Procede pour l'extrusion d'aluminosilicates cristallins.
WO1995018675A1 (en) * 1994-01-11 1995-07-13 E.I. Du Pont De Nemours And Company Attrition resistant zeolite catalysts for production of methylamines in fluidized bed reactors
WO1997012011A1 (en) * 1995-09-25 1997-04-03 Intercat, Inc. Bottoms cracking catalysts
US5900383A (en) * 1996-01-02 1999-05-04 New Life Catalyst, Inc. Process for increasing the activity of zeolite containing particulate solids
US5888919A (en) * 1996-11-25 1999-03-30 Bartholic; David B. Process for zeolitic catalyst reactivation
RU2127632C1 (ru) * 1998-07-28 1999-03-20 Институт катализа им.Г.К.Борескова Сибирского отделения РАН Способ приготовления цеолитсодержащего катализатора для крекинга нефтяных фракций
US6107238A (en) * 1998-09-30 2000-08-22 E. I. Du Pont De Nemours And Company Process for manufacture and use of improved attrition resistant catalyst
IT1303713B1 (it) * 1998-11-06 2001-02-23 Enichem Spa Processo per la preparazione di catalizzatori a base di zeolite tipomfi.
KR100580939B1 (ko) * 1998-12-31 2006-08-18 주식회사 엘지생활건강 포장용 파우치_
DE60218699D1 (de) * 2001-07-02 2007-04-19 Exxonmobil Chem Patents Inc Inhibierung der katalysatorverkokung bei der herstellung eines olefins
US6872680B2 (en) * 2002-03-20 2005-03-29 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7271123B2 (en) * 2002-03-20 2007-09-18 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion process
AU2004285450B2 (en) 2003-10-20 2010-01-14 Gregory K. Frykman Zeolite molecular sieves for the removal of toxins
RU2300420C2 (ru) * 2005-06-28 2007-06-10 Институт проблем переработки углеводородов Сибирского отделения Российской Академии наук Способ приготовления микросферического катализатора для крекинга нефтяных фракций
FR2916654B1 (fr) * 2007-06-04 2011-04-08 Ceca Sa Agglomeres spheriques a base de zeolite(s), leur procede d'obtention et leur utilisation dans les procedes d'adsorption ou en catalyse.
KR20100075960A (ko) * 2007-10-29 2010-07-05 디에스엠 아이피 어셋츠 비.브이. 레스베라트롤 및 펙틴을 함유하는 조성물
US20120165182A1 (en) * 2010-03-25 2012-06-28 Augusto Rodolfo Quinones Catalyst Formulations with Improved Performance via Variable Composition Control as a Function of Particle Size
EP2855012B1 (en) 2012-05-25 2019-06-26 Saudi Arabian Oil Company Catalyst for enhanced propylene in fluidized catalytic cracking
CN104096590B (zh) * 2013-04-10 2016-09-14 上海碧科清洁能源技术有限公司 混合分子筛催化剂及其制备方法和应用
JP7512196B2 (ja) 2017-12-11 2024-07-08 ビーエーエスエフ コーポレーション 残油分解触媒のための反応性シリカ－アルミナマトリックス成分組成物

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3515680A (en) * 1966-09-29 1970-06-02 Air Prod & Chem Contact masses containing faujasite
US3523092A (en) * 1967-11-14 1970-08-04 Exxon Research Engineering Co Method of preparing supported crystalline alumino-silicate zeolites
US3518206A (en) * 1968-05-17 1970-06-30 Du Pont Supported catalysts composed of substrate coated with colloidal silica and catalyst
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US4326993A (en) * 1979-12-17 1982-04-27 Mobil Oil Corporation Novel cracking catalysts and catalyst supports
ATE17826T1 (de) * 1981-02-09 1986-02-15 Union Oil Co Katalysator fuer die kohle nwasserstoffkonvertierung.
US4513091A (en) * 1983-02-14 1985-04-23 Mobil Oil Corporation Hydrothermal zeolite activation
US4605637A (en) * 1983-02-14 1986-08-12 Mobil Oil Corporation Hydrothermal activation of acid zeolites with aluminum phosphates
NL189549C (nl) * 1983-09-22 1993-05-17 Catalysts & Chem Ind Co Werkwijze ter bereiding van een voor toepassing bij het kraken van koolwaterstoffen geschikte samenstelling.
US4594332A (en) * 1983-10-20 1986-06-10 Basf Aktiengesellschaft Preparation of hard, fracture-resistant catalysts from zeolite powder
JPS60193543A (ja) * 1984-03-15 1985-10-02 Shokubai Kasei Kogyo Kk 炭化水素接触分解用触媒組成物の製造法
US4684475A (en) * 1984-07-23 1987-08-04 First Brands Corporation Organophosphate and silicate containing antifreeze
US4560542A (en) * 1984-12-06 1985-12-24 Exxon Research And Engineering Co. Method for the preparation of zeolites using a low water low alkali metal content gel
EP0220616B1 (en) * 1985-10-31 1991-07-03 Union Oil Company Of California Hydrocarbon conversion catalyst and process for selectively making middle distillates

Also Published As

Publication number Publication date
JPH02501454A (ja) 1990-05-24
US4826793A (en) 1989-05-02
EP0377586A1 (en) 1990-07-18
WO1989001362A1 (en) 1989-02-23
EP0377586A4 (en) 1991-01-30

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