MX165741B - Oxidacion selectiva del hidrogeno - Google Patents

Oxidacion selectiva del hidrogeno

Info

Publication number
MX165741B
MX165741B MX001570A MX157086A MX165741B MX 165741 B MX165741 B MX 165741B MX 001570 A MX001570 A MX 001570A MX 157086 A MX157086 A MX 157086A MX 165741 B MX165741 B MX 165741B
Authority
MX
Mexico
Prior art keywords
hydrogen
oxidation
metal
hydrocarbons
effluent
Prior art date
Application number
MX001570A
Other languages
English (en)
Inventor
David Eugene Mackowiak
Mark Joseph O'hara
Tomatsu Imai
Jeffery Christopher Bricker
Original Assignee
Uop Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Inc filed Critical Uop Inc
Publication of MX165741B publication Critical patent/MX165741B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para la oxidación selectiva del hidrógeno, el cual comprende poner en contacto un efluente de la zona de deshidrogenación que comprende una mezcla de hidrocarburos sin convertir, hidrocarburos deshidrogenados, hidrógeno y vapor, con un gas que contiene oxígeno, en la presencia de un catalizador de oxidación, que consta esencialmente de un metal noble del Grupo VIII, un metal del Grupo IVA y un metal del Grupo IA o IIA compuestos sobre un soprote de alúmina que se ha calcinado a una temperatura en el margen de 900 a 1500 grados C, aproximadamente, antes de la impregnación sobre todas las porciones metálicas del catalizador de oxidación, con condiciones de oxidación, para oxidar selectivamente el hidrógeno en el efluente para la exclusión substancial de oxidación de los hidrocarburos sin convetir y deshidrogenados y en seguida retirar y recuperar los hidrocarburos deshidrogenados.
MX001570A 1985-03-06 1986-02-17 Oxidacion selectiva del hidrogeno MX165741B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/708,832 US4565898A (en) 1985-03-06 1985-03-06 Dehydrogenation of dehydrogenatable hydrocarbons

Publications (1)

Publication Number Publication Date
MX165741B true MX165741B (es) 1992-12-03

Family

ID=24847348

Family Applications (1)

Application Number Title Priority Date Filing Date
MX001570A MX165741B (es) 1985-03-06 1986-02-17 Oxidacion selectiva del hidrogeno

Country Status (17)

Country Link
US (1) US4565898A (es)
EP (1) EP0196758B1 (es)
JP (1) JPS61225140A (es)
KR (1) KR870001081B1 (es)
AU (1) AU583887B2 (es)
BR (1) BR8600943A (es)
CA (1) CA1240709A (es)
DE (1) DE3667164D1 (es)
ES (1) ES8704147A1 (es)
IN (1) IN163845B (es)
MX (1) MX165741B (es)
NZ (1) NZ215144A (es)
PT (1) PT82112B (es)
SG (1) SG54190G (es)
SU (1) SU1493098A3 (es)
YU (1) YU43694B (es)
ZA (1) ZA861006B (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4565898A (en) * 1985-03-06 1986-01-21 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
IN165974B (es) * 1985-06-05 1990-02-17 Uop Inc
US4717779A (en) * 1985-09-11 1988-01-05 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4599471A (en) * 1985-09-16 1986-07-08 Uop Inc. Method for oxygen addition to oxidative reheat zone of hydrocarbon dehydrogenation process
US4691071A (en) * 1986-12-11 1987-09-01 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4812597A (en) * 1987-09-02 1989-03-14 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4788371A (en) * 1987-12-30 1988-11-29 Uop Inc. Catalytic oxidative steam dehydrogenation process
GB8805447D0 (en) * 1988-03-08 1988-04-07 British Petroleum Co Plc Chemical process
GB8807732D0 (en) * 1988-03-31 1988-05-05 Bp Chem Int Ltd Hydrocarbon dehydrogenation reactions
US4827066A (en) * 1988-05-23 1989-05-02 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4886928A (en) * 1988-09-26 1989-12-12 Uop Hydrocarbon dehydrogenation process
US5191131A (en) * 1988-12-05 1993-03-02 Research Association For Utilization Of Light Oil Process for preparation of lower aliphatic hydrocarbons
US4914075A (en) * 1988-12-05 1990-04-03 Uop Dehydrogenation catalyst composition
US4914249A (en) * 1988-12-29 1990-04-03 Uop Dehydrogenation of dehydrogenatable hydrocarbons
GB9117216D0 (en) * 1991-08-09 1991-09-25 British Petroleum Co Plc Process for the production of mono-olefins
JP3860625B2 (ja) * 1996-08-19 2006-12-20 三菱化学株式会社 水素の酸化触媒、水素の選択的酸化方法、及び炭化水素の脱水素方法
US6242379B1 (en) 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts
US6756339B1 (en) 1998-04-01 2004-06-29 Sud-Chemie Inc. Dehydrogenation catalysts
MXPA01008496A (es) 1999-02-22 2003-06-06 Symyx Technologies Inc Composiciones que comprenden niquel y su uso como catalizadores en la deshidrogenacion oxidanxte de alcanos.
GB0129611D0 (en) * 2001-12-11 2002-01-30 Bp Chem Int Ltd Process for production of styrene
US6858769B2 (en) * 2002-10-18 2005-02-22 Uop Llc Lithium aluminate layered catalyst and a selective oxidation process using the catalyst
CA2610943C (en) 2005-06-10 2011-05-24 Mitsubishi Chemical Corporation Process for producing styrene
CA2668032A1 (en) * 2006-11-20 2008-05-29 Basf Se Process for dehydrogenating hydrocarbons comprising dehydrogenation and oxidation steps
US8809609B2 (en) * 2008-11-07 2014-08-19 Sued-Chemie Catalysts Japan, Inc. Dehydrogenation catalyst for alkyl aromatic compounds exhibiting high performance in the presence of high-concentration CO2
US20140371503A1 (en) * 2013-06-18 2014-12-18 Uop Llc Single stage reactor system with oxidative preheat for dehydrogenation of hydrocarbons
CN111054382B (zh) * 2018-10-16 2022-12-09 中国石油化工股份有限公司 用于有机液体储氢材料脱氢的催化剂
CN117258819B (zh) * 2023-04-07 2025-07-25 中南大学 一种一维氮磷氧催化剂及其制备和在脱氢制备含烯化合物中的应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1869681A (en) * 1930-03-24 1932-08-02 Standard Oil Dev Co Method for the froduction of normally liquid hydrocarbons from gastcus or lower boiling hydrocarbon matebials
US3437703A (en) * 1966-05-05 1969-04-08 Foster Grant Co Inc Catalytic dehydrogenation process and compositions
US3670044A (en) * 1969-07-18 1972-06-13 Phillips Petroleum Co Catalytic dehydrogenation process
BE789153A (fr) * 1971-09-23 1973-03-22 Aquitaine Petrole Perfectionnement a la fabrication du styrene
JPS4956930A (es) * 1972-09-25 1974-06-03
US3904703A (en) * 1973-04-09 1975-09-09 El Paso Products Co Dehydrogenation process
CA1211131A (en) * 1981-04-28 1986-09-09 Tamotsu Imai Dehydrogenation of dehydrogenatable hydrocarbons
US4435607A (en) * 1981-04-28 1984-03-06 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4376225A (en) * 1981-08-05 1983-03-08 Uop Inc. Dehydrogenation process utilizing indirect heat exchange and direct combustion heating
JPS5889945A (ja) * 1981-11-26 1983-05-28 Mitsubishi Petrochem Co Ltd エチルベンゼン脱水素反応生成物中の水素の選択的酸化触媒
US4409417A (en) * 1982-07-26 1983-10-11 Texaco Inc. Process of dehydrogenation of hydrocarbons
US4560818A (en) * 1984-12-24 1985-12-24 Mobil Oil Corporation Process for the oxidative dehydrogenation of ethyltoluene to methylstyrene
US4565898A (en) * 1985-03-06 1986-01-21 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons

Also Published As

Publication number Publication date
NZ215144A (en) 1988-09-29
ES552671A0 (es) 1987-03-16
KR860007183A (ko) 1986-10-08
PT82112B (pt) 1987-12-30
ES8704147A1 (es) 1987-03-16
PT82112A (en) 1986-03-01
US4565898A (en) 1986-01-21
AU583887B2 (en) 1989-05-11
JPS61225140A (ja) 1986-10-06
IN163845B (es) 1988-11-26
SG54190G (en) 1990-09-07
CA1240709A (en) 1988-08-16
EP0196758A1 (en) 1986-10-08
DE3667164D1 (de) 1990-01-04
KR870001081B1 (en) 1987-06-04
ZA861006B (en) 1986-09-24
YU43694B (en) 1989-10-31
BR8600943A (pt) 1986-11-11
YU33586A (en) 1988-02-29
EP0196758B1 (en) 1989-11-29
SU1493098A3 (ru) 1989-07-07
JPH0433769B2 (es) 1992-06-04
AU5330686A (en) 1986-09-11

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