MD501C2 - 2-anylin-pyrimidine derivatives, or salts thereof, manifesting fungicidal activity - Google Patents
2-anylin-pyrimidine derivatives, or salts thereof, manifesting fungicidal activityInfo
- Publication number
- MD501C2 MD501C2 MD94-0208A MD940208A MD501C2 MD 501 C2 MD501 C2 MD 501C2 MD 940208 A MD940208 A MD 940208A MD 501 C2 MD501 C2 MD 501C2
- Authority
- MD
- Moldova
- Prior art keywords
- halogen
- alkyl
- anylin
- manifesting
- salts
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/30—Halogen atoms or nitro radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/38—One sulfur atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/42—One nitrogen atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Compound of formula:where R1 and R2 independently one from another means hydrogen, halogen, C1-C3 - alkyl, C1-C2 - haloalkyl, C1-C3 - alcoxy or C1-C3- halogenalkoxy;R3 - hydrogen, C1-C4 - alkyl, or C1-C4- alkyl substututed by a halogen, hydroxy - and/or cyano-group cyclopropyl or substituted up to three times equally or differently by a methyl and/or halogen cyclopropyl;R4 - C3-C6- cycloalkyl or substituted up to three times equally or differently by a methyl and/or halogen;They possess valuable microbicidic and insecticidic properties. The new biological active substances may be used for plant protection, for cultivated plants affection by phytopathogenic microorganisms or harmful insects prevention and for pest control thereof.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH375087 | 1987-09-28 | ||
| CH133388 | 1988-04-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD501B1 MD501B1 (en) | 1996-03-29 |
| MD501C2 true MD501C2 (en) | 1996-09-30 |
Family
ID=25687372
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MD94-0102A MD370C2 (en) | 1987-09-28 | 1994-04-28 | Method of fungi controlling |
| MD94-0208A MD501C2 (en) | 1987-09-28 | 1994-07-14 | 2-anylin-pyrimidine derivatives, or salts thereof, manifesting fungicidal activity |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MD94-0102A MD370C2 (en) | 1987-09-28 | 1994-04-28 | Method of fungi controlling |
Country Status (32)
| Country | Link |
|---|---|
| US (2) | US4931560A (en) |
| EP (1) | EP0310550B1 (en) |
| JP (1) | JPH0649689B2 (en) |
| KR (1) | KR920006738B1 (en) |
| CN (1) | CN1017993B (en) |
| AR (1) | AR245700A1 (en) |
| AU (1) | AU619762B2 (en) |
| BG (1) | BG60541B1 (en) |
| BR (1) | BR8804955A (en) |
| CA (1) | CA1317952C (en) |
| CY (1) | CY1770A (en) |
| CZ (2) | CZ279022B6 (en) |
| DE (1) | DE3881320D1 (en) |
| DK (2) | DK168598B1 (en) |
| ES (1) | ES2054867T3 (en) |
| FI (1) | FI98913C (en) |
| HK (1) | HK21394A (en) |
| HU (1) | HU203879B (en) |
| IE (1) | IE62424B1 (en) |
| IL (1) | IL87866A (en) |
| LV (3) | LV10613B (en) |
| MD (2) | MD370C2 (en) |
| NO (1) | NO176178C (en) |
| NZ (1) | NZ226323A (en) |
| PH (1) | PH26459A (en) |
| PL (1) | PL156233B1 (en) |
| PT (1) | PT88596B (en) |
| RU (6) | RU2014327C1 (en) |
| SK (1) | SK279313B6 (en) |
| UA (2) | UA19303A (en) |
| YU (1) | YU48390B (en) |
| ZW (1) | ZW12788A1 (en) |
Families Citing this family (92)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2058332T3 (en) * | 1987-06-11 | 1994-11-01 | Ciba Geigy Ag | MICROBICIDES. |
| JP2603108B2 (en) * | 1988-06-24 | 1997-04-23 | イハラケミカル工業株式会社 | Anilinopyrimidine derivative |
| GB8823288D0 (en) * | 1988-10-04 | 1988-11-09 | Schering Agrochemicals Ltd | Herbicides |
| AU644159B2 (en) * | 1990-05-17 | 1993-12-02 | Novartis Ag | 2-anilino-4-cyanopyrimidine derivatives |
| GB9117486D0 (en) * | 1991-08-13 | 1991-09-25 | Schering Ag | Fungicides |
| EP0548025B1 (en) * | 1991-12-19 | 1996-04-17 | Ciba-Geigy Ag | Microbicide |
| AU652302B2 (en) * | 1991-12-19 | 1994-08-18 | Novartis Ag | Microbicides |
| US5276186A (en) | 1992-03-11 | 1994-01-04 | Ciba-Geigy Corporation | Process for the production of guanidine derivatives |
| DE4318372B4 (en) * | 1992-06-10 | 2010-10-28 | BASF Agro B.V., Arnhem (NL)-Wädenswil-Branch | Fungicidal mixtures |
| US5574064A (en) * | 1993-04-28 | 1996-11-12 | Kumiai Chemical Industry Co., Ltd. | Amino-acid amide derivatives, agricultural or horticultural fungicides, and method for producing the same |
| DE4318285A1 (en) * | 1993-06-02 | 1994-12-08 | Bayer Ag | Fungicidal active ingredient combinations |
| CH686061A5 (en) * | 1993-06-04 | 1995-12-29 | Ciba Geigy Ag | Microbicides. |
| RU2127054C1 (en) * | 1993-06-28 | 1999-03-10 | Новартис Аг | Plant fungicide, a method of struggle against fungi |
| UA39100C2 (en) * | 1993-06-28 | 2001-06-15 | Новартіс Аг | BACTERICIDAL AGENT FOR PLANTS, METHOD FOR CONTROL OF FUNGAL DISEASES OF PLANTS AND VEGETABLE MATERIAL FOR REPRODUCTION |
| US5436248A (en) * | 1993-07-02 | 1995-07-25 | Ciba-Geigy Corporation | Microbicides |
| GB9314128D0 (en) * | 1993-07-08 | 1993-08-18 | Schering Agrochemicals Ltd | Fungicidal composition |
| JP3634409B2 (en) * | 1993-09-13 | 2005-03-30 | ビーエーエスエフ アクチェンゲゼルシャフト | Disinfectant mixture |
| DE59410036D1 (en) * | 1993-11-09 | 2002-03-14 | Syngenta Participations Ag | Crystal modification of (4-cyclopropyl-6-methyl-pyrimidin-2-yl) - phenyl-amine, and process for its preparation |
| AT406837B (en) * | 1994-02-10 | 2000-09-25 | Electrovac | METHOD AND DEVICE FOR PRODUCING METAL-MATRIX COMPOSITES |
| TW286264B (en) | 1994-05-20 | 1996-09-21 | Ciba Geigy Ag | |
| US5519026A (en) * | 1994-06-27 | 1996-05-21 | Ciba-Geigy Corporation | Microbicides |
| DE4444928A1 (en) | 1994-12-16 | 1996-06-27 | Hoechst Schering Agrevo Gmbh | Process for the preparation of 2-anilino-pyridine derivatives |
| FR2729051B1 (en) * | 1995-01-09 | 2000-12-08 | Rhone Poulenc Agrochimie | NEW FUNGICIDE COMPOSITION BASED ON A DICARBOXIMIDE COMPOUND |
| JP2000505783A (en) * | 1995-12-14 | 2000-05-16 | ビーエーエスエフ アクチェンゲゼルシャフト | 2- (O- [Pyrimidin-4-yl] methyleneoxy) phenylacetic acid derivatives and their use for controlling harmful fungi and small animals |
| WO1997037535A2 (en) * | 1996-04-11 | 1997-10-16 | Novartis Ag | Pesticidal compositions of cyprodinil and myclobutanil or ipridione |
| DE59706103D1 (en) * | 1996-04-26 | 2002-03-07 | Basf Ag | FUNGICIDAL MIXTURES |
| AU712970B2 (en) * | 1996-05-04 | 1999-11-18 | Yuhan Corporation | Process for preparation of pyrimidine derivatives |
| TW440563B (en) * | 1996-05-23 | 2001-06-16 | Hoffmann La Roche | Aryl pyrimidine derivatives and a pharmaceutical composition thereof |
| GB9619534D0 (en) * | 1996-09-19 | 1996-10-30 | Agrevo Uk Ltd | Fungicidal composition |
| US6297236B1 (en) | 1998-04-06 | 2001-10-02 | Bayer Aktiengesellschaft | Fungicide active substance combinations |
| DE19716257A1 (en) | 1997-04-18 | 1998-10-22 | Bayer Ag | Fungicidal active ingredient combination |
| AU4503499A (en) | 1998-06-10 | 1999-12-30 | Basf Aktiengesellschaft | Use of 2-(n-phenylamino)pyrimidines as fungicides, and novel 2-(n-phenylamino)pyrimidines |
| WO2001019801A1 (en) * | 1999-09-16 | 2001-03-22 | Rimma Iliinichna Ashkinazi | Bioactive substance containing derivatives of 2-amino-6-aryloxypyrimidines and intermediary products of synthesis thereof |
| US6624183B2 (en) * | 1999-12-13 | 2003-09-23 | Bayer Aktiengesellschaft | Fungicidal combinations of active substances |
| DE10019758A1 (en) | 2000-04-20 | 2001-10-25 | Bayer Ag | Fungicidal combinations containing known methoxyimino-acetic acid amide derivatives useful for the control of phytopathogenic fungi |
| DE10103832A1 (en) * | 2000-05-11 | 2001-11-15 | Bayer Ag | Synergistic combination of fungicides for use in plant protection, comprises 2-(pyrimidinyloxy-phenyl)-2-(methoxyimino)-N-methyl-acetamide derivative and e.g. spiroxamine, quinoxyfen or tebuconazole |
| KR20010112817A (en) * | 2000-06-15 | 2001-12-22 | 황재관 | Method for isolating physiologically active materials from green tea |
| DE10049804A1 (en) * | 2000-10-09 | 2002-04-18 | Bayer Ag | Agent containing synergistic mixture comprising phenyl-pyrroline ketoenol derivatives with fungicides and acaricides useful especially in plant protection |
| MXPA03010810A (en) * | 2001-05-29 | 2004-03-22 | Schering Ag | Cdk inhibiting pyrimidines, production thereof and their use as medicaments. |
| DE10207376B4 (en) | 2002-02-22 | 2005-03-03 | Degussa Ag | Process for the preparation of 2-anilino-4,6-dimethylpyrimidine |
| PT1521526E (en) * | 2002-07-08 | 2007-03-30 | Basf Ag | Dithianon-based fungicidal mixtures |
| DE10347090A1 (en) | 2003-10-10 | 2005-05-04 | Bayer Cropscience Ag | Synergistic fungicidal drug combinations |
| DE10349501A1 (en) | 2003-10-23 | 2005-05-25 | Bayer Cropscience Ag | Synergistic fungicidal drug combinations |
| WO2005104847A1 (en) | 2004-04-30 | 2005-11-10 | Basf Aktiengesellschaft | Fungicidal mixtures |
| US7091202B2 (en) * | 2004-09-15 | 2006-08-15 | Bristol-Myers Squibb Company | 4-arylspirocycloalkyl-2-aminopyrimidine carboxamide KCNQ potassium channel modulators |
| WO2006035069A1 (en) * | 2004-09-30 | 2006-04-06 | Tibotec Pharmaceuticals Ltd. | Hiv inhibiting 5-substituted pyrimidines |
| CA2582533A1 (en) * | 2004-10-22 | 2006-05-04 | Janssen Pharmaceutica N.V. | Use of anilinopyrimidines in wood protection |
| EP1938691A3 (en) | 2004-12-17 | 2009-07-22 | Devgen NV | Nematicidal compositions |
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| MX2007015376A (en) | 2005-06-09 | 2008-02-14 | Bayer Cropscience Ag | Active substance combinations. |
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| GB0706044D0 (en) * | 2007-03-28 | 2007-05-09 | Syngenta Ltd | C0-Crystals |
| AU2008240710A1 (en) | 2007-04-23 | 2008-10-30 | Basf Se | Plant productivity enhancement by combining chemical agents with transgenic modifications |
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| CN101311170B (en) | 2007-05-25 | 2010-09-15 | 中国中化股份有限公司 | Substituted pyrimidine ether compounds and their applications |
| US8349877B2 (en) | 2007-09-26 | 2013-01-08 | Basf Se | Ternary fungicidal compositions comprising boscalid and chlorothalonil |
| DE102007045920B4 (en) | 2007-09-26 | 2018-07-05 | Bayer Intellectual Property Gmbh | Synergistic drug combinations |
| US8575187B2 (en) | 2008-02-06 | 2013-11-05 | Janssen Pharmaceutica, Nv | Combinations of anilinopyrimidines and pyrion compounds |
| BRPI0911134B1 (en) | 2008-03-21 | 2017-01-17 | Sumitomo Chemical Co | plant disease control composition, plant disease control method, and use |
| MX2011009732A (en) | 2009-03-25 | 2011-09-29 | Bayer Cropscience Ag | Synergistic combinations of active ingredients. |
| CN101906075B (en) | 2009-06-05 | 2012-11-07 | 中国中化股份有限公司 | E-type phenyl acrylic acid ester compound containing substituted anilino pyrimidine group and applications thereof |
| MX2012000566A (en) | 2009-07-16 | 2012-03-06 | Bayer Cropscience Ag | Synergistic active substance combinations containing phenyl triazoles. |
| WO2011026796A1 (en) | 2009-09-01 | 2011-03-10 | Basf Se | Synergistic fungicidal mixtures comprising lactylates and method for combating phytopathogenic fungi |
| AU2011347752A1 (en) | 2010-12-20 | 2013-07-11 | Basf Se | Pesticidal active mixtures comprising pyrazole compounds |
| CN102067852A (en) * | 2011-01-20 | 2011-05-25 | 陕西美邦农药有限公司 | Fungicide combination containing polyoxin and pyrimidine compound |
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| PL2688405T3 (en) | 2011-03-23 | 2018-05-30 | Basf Se | Compositions containing polymeric, ionic compounds comprising imidazolium groups |
| JP2014525424A (en) | 2011-09-02 | 2014-09-29 | ビーエーエスエフ ソシエタス・ヨーロピア | Agricultural mixture containing arylquinazolinone compounds |
| CN102388890B (en) * | 2011-10-09 | 2013-08-28 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing SYP-3375 and cyprodinil |
| ES2402036B1 (en) * | 2011-10-13 | 2014-03-10 | Consejo Superior De Investigaciones Científicas (Csic) | HAVE CONJUGATED AND ANTIBODIES FOR THE FUNGICIDE CIPRODINIL. |
| BR122019015134B1 (en) | 2012-06-20 | 2020-04-07 | Basf Se | pesticide mixture, composition, agricultural composition, methods for combating or controlling invertebrate pests, for the protection of growing plants or plant propagation material, for the protection of plant propagation material, use of a pesticide mixture and methods for combating harmful phytopathogenic fungi and to protect plants from harmful phytopathogenic fungi |
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| JP2013032375A (en) * | 2012-10-05 | 2013-02-14 | Japan Enviro Chemicals Ltd | Antifungal composition |
| US20150257383A1 (en) | 2012-10-12 | 2015-09-17 | Basf Se | Method for combating phytopathogenic harmful microbes on cultivated plants or plant propagation material |
| BR112015014753B8 (en) | 2012-12-20 | 2020-03-03 | Basf Agro Bv | compositions, use of a composition, method for combating phytopathogenic fungi and use of the components |
| EP2783569A1 (en) | 2013-03-28 | 2014-10-01 | Basf Se | Compositions comprising a triazole compound |
| MD4301C1 (en) * | 2013-06-12 | 2015-03-31 | Институт Генетики, Физиологии И Защиты Растений Академии Наук Молдовы | 1-epi-5-O-alozilantirinozide for the treatment of lettuce seeds |
| EP2835052A1 (en) | 2013-08-07 | 2015-02-11 | Basf Se | Fungicidal mixtures comprising pyrimidine fungicides |
| WO2015036059A1 (en) | 2013-09-16 | 2015-03-19 | Basf Se | Fungicidal pyrimidine compounds |
| CN105722833A (en) | 2013-09-16 | 2016-06-29 | 巴斯夫欧洲公司 | Fungicidal pyrimidine compounds |
| PE20160679A1 (en) | 2013-10-18 | 2016-08-04 | Eisai Randd Man Co Ltd | FGFR4 PYRIMIDINE INHIBITORS |
| EP2979549A1 (en) | 2014-07-31 | 2016-02-03 | Basf Se | Method for improving the health of a plant |
| CN107075712A (en) | 2014-10-24 | 2017-08-18 | 巴斯夫欧洲公司 | Non-amphoteric, quaternizable and water-soluble polymers that alter the surface charge of solid particles |
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| CN106035340A (en) * | 2016-05-20 | 2016-10-26 | 南京华洲药业有限公司 | Spiroxamine and cyprodinil containing fungicidal composition and application thereof |
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|---|---|---|---|---|
| US4600428A (en) * | 1982-10-06 | 1986-07-15 | Ciba-Geigy Corporation | N-(cyclopropyl-pyrimidinyl-N'-(aryl-sulfonyl) ureas having herbicidal activity |
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| HU206337B (en) * | 1988-12-29 | 1992-10-28 | Mitsui Petrochemical Ind | Process for producing pyrimidine derivatives and pharmaceutical compositions |
-
1988
- 1988-09-20 DE DE8888810640T patent/DE3881320D1/en not_active Expired - Lifetime
- 1988-09-20 ES ES88810640T patent/ES2054867T3/en not_active Expired - Lifetime
- 1988-09-20 EP EP88810640A patent/EP0310550B1/en not_active Expired - Lifetime
- 1988-09-21 US US07/247,203 patent/US4931560A/en not_active Expired - Lifetime
- 1988-09-26 NZ NZ226323A patent/NZ226323A/en unknown
- 1988-09-26 AR AR88312041A patent/AR245700A1/en active
- 1988-09-26 PL PL1988274899A patent/PL156233B1/en unknown
- 1988-09-26 FI FI884409A patent/FI98913C/en not_active IP Right Cessation
- 1988-09-26 BR BR8804955A patent/BR8804955A/en not_active IP Right Cessation
- 1988-09-26 ZW ZW127/88A patent/ZW12788A1/en unknown
- 1988-09-26 CA CA000578360A patent/CA1317952C/en not_active Expired - Lifetime
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- 1988-09-28 IL IL87866A patent/IL87866A/en active Protection Beyond IP Right Term
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1989
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- 1989-09-20 RU SU894614995A patent/RU2043025C1/en active
- 1989-09-20 RU SU894614930A patent/RU2002416C1/en active
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1990
- 1990-01-24 RU SU904742906A patent/RU2017735C1/en active
- 1990-01-24 RU SU904742847A patent/RU2009134C1/en active
- 1990-03-19 US US07/496,381 patent/US4997941A/en not_active Expired - Lifetime
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1992
- 1992-04-14 RU SU925011341A patent/RU2045520C1/en active
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1993
- 1993-05-25 LV LVP-93-409A patent/LV10613B/en unknown
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- 1993-07-20 DK DK085993A patent/DK170161B1/en not_active IP Right Cessation
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1994
- 1994-03-10 HK HK213/94A patent/HK21394A/en not_active IP Right Cessation
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1995
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4600428A (en) * | 1982-10-06 | 1986-07-15 | Ciba-Geigy Corporation | N-(cyclopropyl-pyrimidinyl-N'-(aryl-sulfonyl) ureas having herbicidal activity |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| CHPR | Change of proprietorship |
Free format text: NOVARTIS AG, CH |
|
| IF99 | Valid patent on 19990615 |
Free format text: EXPIRES: 20120414 |
|
| MK4A | Patent for invention expired |