MD4069C1 - Bromo-{3-[(2-hydroxy-5-nitro-benzylidene)-amino]-propane-1,2-dihydroxy}(1-)copper and process for the cultivation of cyanobacterium Spirulina platensis - Google Patents
Bromo-{3-[(2-hydroxy-5-nitro-benzylidene)-amino]-propane-1,2-dihydroxy}(1-)copper and process for the cultivation of cyanobacterium Spirulina platensis Download PDFInfo
- Publication number
- MD4069C1 MD4069C1 MDA20100015A MD20100015A MD4069C1 MD 4069 C1 MD4069 C1 MD 4069C1 MD A20100015 A MDA20100015 A MD A20100015A MD 20100015 A MD20100015 A MD 20100015A MD 4069 C1 MD4069 C1 MD 4069C1
- Authority
- MD
- Moldova
- Prior art keywords
- cultivation
- spirulina platensis
- copper
- benzylidene
- dihydroxy
- Prior art date
Links
- 235000016425 Arthrospira platensis Nutrition 0.000 title abstract 4
- 240000002900 Arthrospira platensis Species 0.000 title abstract 4
- 241001464430 Cyanobacterium Species 0.000 title abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052802 copper Inorganic materials 0.000 title abstract 3
- 239000010949 copper Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- -1 2-hydroxy-5-nitro-benzylidene Chemical group 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 abstract 2
- 239000002028 Biomass Substances 0.000 abstract 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 abstract 1
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000001110 calcium chloride Substances 0.000 abstract 1
- 235000011148 calcium chloride Nutrition 0.000 abstract 1
- 229910001628 calcium chloride Inorganic materials 0.000 abstract 1
- 229910052927 chalcanthite Inorganic materials 0.000 abstract 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 abstract 1
- 235000019797 dipotassium phosphate Nutrition 0.000 abstract 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 abstract 1
- 239000012153 distilled water Substances 0.000 abstract 1
- 229910052564 epsomite Inorganic materials 0.000 abstract 1
- 239000011565 manganese chloride Substances 0.000 abstract 1
- 235000002867 manganese chloride Nutrition 0.000 abstract 1
- 229910052603 melanterite Inorganic materials 0.000 abstract 1
- 235000015097 nutrients Nutrition 0.000 abstract 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 abstract 1
- 229910052939 potassium sulfate Inorganic materials 0.000 abstract 1
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 235000010344 sodium nitrate Nutrition 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 abstract 1
- 229910000368 zinc sulfate Inorganic materials 0.000 abstract 1
- 239000011686 zinc sulphate Substances 0.000 abstract 1
- 235000009529 zinc sulphate Nutrition 0.000 abstract 1
Landscapes
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Abstract
The invention relates to chemistry and biotechnology, namely to the synthesis of a new coordinative compound from the class of salicylideneaminoalcoholates of transition metals and to a process for the cultivation of cyanobacterium Spirulina platensis.It is claimed: a new coordinative compound, bromo-{3-[(2-hydroxy-5-nitro-benzylidene)-amino]-propane-1,2-dihydroxy}(1-)copper of the formula:and a process for the cultivation of cyanobacterium Spirulina platensis, which includes cultivation on a Zarrouk nutrient medium, containing, g/L: NaNO3 - 2.5; NaHCO3 -16.8; NaCl -1.0; K2SO4 - 1.0; K2HPO4 - 0.5; MgSO4·7H2O - 0.2; CaCl2 - 0.04; FeSO4·7H2O - 0.01; EDTA - 0.08; H3BO3 - 0.00286; MnCl2·4H2O - 0.00181; ZnSO4·7H2O - 0.00022; CuSO4·5H2O - 0.00008; MoO3 - 0.000015 and distilled water to 1L, at pH 9.5…10.0, at a temperature of 32°C, light of 2000…3000 lx, at the same time on the 2nd day of cultivation is added the specified coordinative compound, in a concentration of 5…6 mg/L.The technical result is to increase the copper content in the biomass of cyanobacterium Spirulina platensis up to 10.39…11.14 mg%, and to reduce the length of cultivation up to 7 days.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20100015A MD4069C1 (en) | 2010-02-08 | 2010-02-08 | Bromo-{3-[(2-hydroxy-5-nitro-benzylidene)-amino]-propane-1,2-dihydroxy}(1-)copper and process for the cultivation of cyanobacterium Spirulina platensis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20100015A MD4069C1 (en) | 2010-02-08 | 2010-02-08 | Bromo-{3-[(2-hydroxy-5-nitro-benzylidene)-amino]-propane-1,2-dihydroxy}(1-)copper and process for the cultivation of cyanobacterium Spirulina platensis |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD4069B1 MD4069B1 (en) | 2010-09-30 |
| MD4069C1 true MD4069C1 (en) | 2011-04-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MDA20100015A MD4069C1 (en) | 2010-02-08 | 2010-02-08 | Bromo-{3-[(2-hydroxy-5-nitro-benzylidene)-amino]-propane-1,2-dihydroxy}(1-)copper and process for the cultivation of cyanobacterium Spirulina platensis |
Country Status (1)
| Country | Link |
|---|---|
| MD (1) | MD4069C1 (en) |
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| MD4254C1 (en) * | 2012-11-05 | 2014-05-31 | Институт Микробиологии И Биотехнологии Академии Наук Молдовы | Hexafluorotitanate-bis[(dimethylglyoximato)-di-(thiocarbamide)cobalt(III)] dihydrate and process for cultivation of microalga Porphyridium cruentum with the use thereof |
| MD4253C1 (en) * | 2012-11-05 | 2014-05-31 | Институт Микробиологии И Биотехнологии Академии Наук Молдовы | Sulphato-bis(nicotinoylhydrazone)-2,6-diacetylpyridin-cobalt(II )monomethanol trihydrate and process for cultivation of microalga Porphyridium cruentum with the use thereof |
| MD4255C1 (en) * | 2012-11-05 | 2014-05-31 | Институт Микробиологии И Биотехнологии Академии Наук Молдовы | Tetraisothiocyanatocobaltate of bis(nicotinoylhydrazone)-2,6-diformil-4-methylphenol(methanol)(aqua)cobalt(II) and process for cultivation of microalga Porphyridium cruentum with the use thereof |
| MD4278C1 (en) * | 2013-04-30 | 2014-10-31 | Институт Химии Академии Наук Молдовы | Compound bis{bis(dimethylglyoximato)chloro}-µ-3-formylpiridineisonicotinoylhydrazone-di-cobalt(III) and process for cultivation of microalga Porphyridium cruentum with its use |
| MD4303C1 (en) * | 2013-07-05 | 2015-04-30 | Институт Химии Академии Наук Молдовы | Bis(dimethylglyoximato)chloro(isonicotinoylhydrazone-2-hydroxy-1-naphthaldehyde)cobalt(III) and process for cultivation of Porphyridium cruentum microalga with the use thereof |
| MD4326C1 (en) * | 2013-10-22 | 2015-09-30 | Институт Химии Академии Наук Молдовы | N-(D8,13-Bicyclohomofarnesenoylamino)carbazole compound and process for cultivation of Nostoc linckia cyanobacterium with its use |
| MD4327C1 (en) * | 2013-10-22 | 2015-09-30 | Институт Химии Академии Наук Молдовы | N-(D8,13-Bicyclohomofarnesenoyl)-3-amino-1,2,4-triazole compound and process for cultivation of Nostoc linckia cyanobacterium with its use |
| MD4356C1 (en) * | 2014-07-09 | 2016-02-29 | Институт Химии Академии Наук Молдовы | Bis[N'-(2-hydroxy-kO-benzylidene)pyridine-4-carbohydrazidate(-1)-k2N',O]iron(III) nitrate - water (2/3) and process for cultivation of microalga Porphyridium cruentum with its use |
| MD4365C1 (en) * | 2014-07-09 | 2016-03-31 | Институт Химии Академии Наук Молдовы | Bis[1-phenyl-3-methyl-6-(pyridinium-4-yl)-4,5-diaza-hexa-1,3,5-triene-1,6-diolato-O1,N4,O6]iron(III) nitrate and process for cultivation of microalga Porphyridium cruentum with its use |
| MD4366C1 (en) * | 2014-07-09 | 2016-03-31 | Институт Химии Академии Наук Молдовы | Bis[1-phenyl-3-methyl-6-(pyridinium-4-il)-4,5-diaza-hexa-1,3,5-triene-1-hydroxy-6-olato-O1,N4,O6]iron(II)sulphate tetrahydrate and process for cultivation of microalga Porphyridium cruentum with its use |
| MD4367C1 (en) * | 2014-07-09 | 2016-03-31 | Институт Химии Академии Наук Молдовы | Bis[N'-(2-hydroxy-kO-3-carboxybenzilidene)pyridine-3-carbohydrazidate(-1)-k2N',O]iron(III) perchlorate - water (4/5) and process for cultivation of microalga Porphyridium cruentum with its use |
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| MD4319C1 (en) * | 2013-10-17 | 2015-08-31 | Государственный Университет Молд0 | Bis[(iminodiacetate)oxothiomolybdate(V)]tetraphenylphosphonium hydrate and process for cultivation of Spirulina platensis cyanobacterium with the use thereof |
| CN107486167A (en) * | 2017-09-08 | 2017-12-19 | 江南大学 | A kind of blue-green algae base foaming sorbing material |
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| JPS6287087A (en) * | 1985-10-11 | 1987-04-21 | Nippon Supirurina Kk | Alga of genus spirulina containing minor element in human living body in high concentration and production thereof |
| SU1662442A1 (en) * | 1988-07-29 | 1991-07-15 | Кишиневский Государственный Университет Им.В.И.Ленина | Method for spiruline cultivation |
| RO111470B1 (en) * | 1995-05-15 | 1996-10-31 | Centrul De Cercetari Pentru Te | Form of spirulina platensis ( nordst ) geitl which is growing environment and cultivating process in continuous flow for spiruline platensis mutant (nordst) geitl |
| MD2195G2 (en) * | 2002-05-27 | 2003-12-31 | Государственный Университет Молд0 | Nitrate of (µ3-oxo)-tris-{(µ2-Ophenoxy)-2-[(2-hydroxybenzylidene)amino-2-hydroxy- methylpropane]-1,3-diolo-aquacopper (II)} dihydrate |
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| MD3625G2 (en) * | 2007-07-11 | 2009-01-31 | Государственный Университет Молд0 | Heptaazotate of hexa-(µ-?-alanine -(O,O'))-µ3-oxo-tri(aqua)triferrum(III) 3,5-hydrate and process for Spirulina platensis biomass obtaining |
| FR2929957A1 (en) * | 2008-04-10 | 2009-10-16 | Zesiger Michel Claude Hours | Metal-phycocyanin comprising combination of protein constituent of cyanobacteria, and phycocyanin, with a divalent metal e.g. chromium and copper, useful for the preparation of compositions e.g. for micro-nutrition and cosmetics |
-
2010
- 2010-02-08 MD MDA20100015A patent/MD4069C1/en not_active IP Right Cessation
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6287087A (en) * | 1985-10-11 | 1987-04-21 | Nippon Supirurina Kk | Alga of genus spirulina containing minor element in human living body in high concentration and production thereof |
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| RO111470B1 (en) * | 1995-05-15 | 1996-10-31 | Centrul De Cercetari Pentru Te | Form of spirulina platensis ( nordst ) geitl which is growing environment and cultivating process in continuous flow for spiruline platensis mutant (nordst) geitl |
| MD2386C2 (en) * | 2001-05-15 | 2004-10-31 | Институт Микробиологии И Биотехнологии Академии Наук Молдовы | Process for cultivation of cyanobacterium Spirulina platensis |
| MD2258C2 (en) * | 2001-10-04 | 2004-03-31 | Государственный Медицинский И Фармацевтический Университет "Nicolae Testemitanu" Республики Молдова | Chelating copper (II) complexes active in respect of gram-positive microorganisms |
| MD2195G2 (en) * | 2002-05-27 | 2003-12-31 | Государственный Университет Молд0 | Nitrate of (µ3-oxo)-tris-{(µ2-Ophenoxy)-2-[(2-hydroxybenzylidene)amino-2-hydroxy- methylpropane]-1,3-diolo-aquacopper (II)} dihydrate |
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| CN1587373A (en) * | 2004-08-28 | 2005-03-02 | 北海市康福保健食品有限公司 | Use of L-arginine, L-ornithine or L-citrulline as spirulina princeps growing regulator |
| KR100816877B1 (en) * | 2007-03-23 | 2008-03-26 | 한국생명공학연구원 | Bacterial Spirulina pratensis C5500 [BTCC 11039XP] with excellent growth rate and aseptic induction method |
| MD3625G2 (en) * | 2007-07-11 | 2009-01-31 | Государственный Университет Молд0 | Heptaazotate of hexa-(µ-?-alanine -(O,O'))-µ3-oxo-tri(aqua)triferrum(III) 3,5-hydrate and process for Spirulina platensis biomass obtaining |
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| Title |
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| Gannikar Disyawongs. Accumulation of Copper, Mercury and Lead in Spirulina platensis studied in Zarrouk’s Medium. The Journal of KMITNB., Vol. 12, No. 4, Oct-Dec. * |
| Gannikar Disyawongs. Accumulation of Copper, Mercury and Lead in Spirulina platensis studied in Zarrouk’s Medium. The Journal of KMITNB., Vol. 12, No. 4, Oct-Dec. 2002, p.33-35 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD4254C1 (en) * | 2012-11-05 | 2014-05-31 | Институт Микробиологии И Биотехнологии Академии Наук Молдовы | Hexafluorotitanate-bis[(dimethylglyoximato)-di-(thiocarbamide)cobalt(III)] dihydrate and process for cultivation of microalga Porphyridium cruentum with the use thereof |
| MD4253C1 (en) * | 2012-11-05 | 2014-05-31 | Институт Микробиологии И Биотехнологии Академии Наук Молдовы | Sulphato-bis(nicotinoylhydrazone)-2,6-diacetylpyridin-cobalt(II )monomethanol trihydrate and process for cultivation of microalga Porphyridium cruentum with the use thereof |
| MD4255C1 (en) * | 2012-11-05 | 2014-05-31 | Институт Микробиологии И Биотехнологии Академии Наук Молдовы | Tetraisothiocyanatocobaltate of bis(nicotinoylhydrazone)-2,6-diformil-4-methylphenol(methanol)(aqua)cobalt(II) and process for cultivation of microalga Porphyridium cruentum with the use thereof |
| MD4278C1 (en) * | 2013-04-30 | 2014-10-31 | Институт Химии Академии Наук Молдовы | Compound bis{bis(dimethylglyoximato)chloro}-µ-3-formylpiridineisonicotinoylhydrazone-di-cobalt(III) and process for cultivation of microalga Porphyridium cruentum with its use |
| MD4303C1 (en) * | 2013-07-05 | 2015-04-30 | Институт Химии Академии Наук Молдовы | Bis(dimethylglyoximato)chloro(isonicotinoylhydrazone-2-hydroxy-1-naphthaldehyde)cobalt(III) and process for cultivation of Porphyridium cruentum microalga with the use thereof |
| MD4326C1 (en) * | 2013-10-22 | 2015-09-30 | Институт Химии Академии Наук Молдовы | N-(D8,13-Bicyclohomofarnesenoylamino)carbazole compound and process for cultivation of Nostoc linckia cyanobacterium with its use |
| MD4327C1 (en) * | 2013-10-22 | 2015-09-30 | Институт Химии Академии Наук Молдовы | N-(D8,13-Bicyclohomofarnesenoyl)-3-amino-1,2,4-triazole compound and process for cultivation of Nostoc linckia cyanobacterium with its use |
| MD4356C1 (en) * | 2014-07-09 | 2016-02-29 | Институт Химии Академии Наук Молдовы | Bis[N'-(2-hydroxy-kO-benzylidene)pyridine-4-carbohydrazidate(-1)-k2N',O]iron(III) nitrate - water (2/3) and process for cultivation of microalga Porphyridium cruentum with its use |
| MD4365C1 (en) * | 2014-07-09 | 2016-03-31 | Институт Химии Академии Наук Молдовы | Bis[1-phenyl-3-methyl-6-(pyridinium-4-yl)-4,5-diaza-hexa-1,3,5-triene-1,6-diolato-O1,N4,O6]iron(III) nitrate and process for cultivation of microalga Porphyridium cruentum with its use |
| MD4366C1 (en) * | 2014-07-09 | 2016-03-31 | Институт Химии Академии Наук Молдовы | Bis[1-phenyl-3-methyl-6-(pyridinium-4-il)-4,5-diaza-hexa-1,3,5-triene-1-hydroxy-6-olato-O1,N4,O6]iron(II)sulphate tetrahydrate and process for cultivation of microalga Porphyridium cruentum with its use |
| MD4367C1 (en) * | 2014-07-09 | 2016-03-31 | Институт Химии Академии Наук Молдовы | Bis[N'-(2-hydroxy-kO-3-carboxybenzilidene)pyridine-3-carbohydrazidate(-1)-k2N',O]iron(III) perchlorate - water (4/5) and process for cultivation of microalga Porphyridium cruentum with its use |
Also Published As
| Publication number | Publication date |
|---|---|
| MD4069B1 (en) | 2010-09-30 |
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