MD2146C2 - Materiale dielectrice pe bază de combinaţii coordinative heteronucleare ale cobaltului(III) şi bismutului(III) - Google Patents
Materiale dielectrice pe bază de combinaţii coordinative heteronucleare ale cobaltului(III) şi bismutului(III) Download PDFInfo
- Publication number
- MD2146C2 MD2146C2 MDA20010218A MD20010218A MD2146C2 MD 2146 C2 MD2146 C2 MD 2146C2 MD A20010218 A MDA20010218 A MD A20010218A MD 20010218 A MD20010218 A MD 20010218A MD 2146 C2 MD2146 C2 MD 2146C2
- Authority
- MD
- Moldova
- Prior art keywords
- iii
- heteronuclear
- bismuth
- tetraacetatobismuthate
- dielectric materials
- Prior art date
Links
- 239000003989 dielectric material Substances 0.000 title abstract 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 title 2
- 229910052797 bismuth Inorganic materials 0.000 title 1
- JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 title 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- JDIBGQFKXXXXPN-UHFFFAOYSA-N bismuth(3+) Chemical class [Bi+3] JDIBGQFKXXXXPN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000004870 electrical engineering Methods 0.000 abstract 1
- QVVPWDIQTGSUOY-UHFFFAOYSA-N ethane-1,2-diamine;dihydrate Chemical compound O.O.NCCN QVVPWDIQTGSUOY-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Invenţia se referă la un grup de compuşi coordinativi heteronucleari din clasa aminopolicarboxilaţilor bismutului(III) cu unele elemente din blocul d. Aceşti complecşi au conductibilitatea electrică specifică (ρ) înaltă şi pot fi utilizaţi în electrotehnică în calitate de materiale dielectrice.Esenţa invenţiei constă în obţinerea dimerilor acvaetilendiamintetraacetatobismutat(III)de 1,6-[dinitrotetraamincobalt(III)] trihidrat, acvaetilendiamintetraacetatobismutat(III) de 1,2-[dinitrotetraamincobalt(III)], etilendiamintetraacetatobismutat(III) de carbonatotetraamincobalt(III) trihidrat şi etilendiamintetraacetatobismutat(III) de oxalatotetraamincobalt(III) dihidrat cu formula generală:I-IVunde X=NO2(I, II), ½CO3(III), ½C2O4(IV); Y=NH3(I), NO2(II), ½CO3(III), ½C2O4(IV); Z=NO2(I), NH3(II-IV); n = 0(II), 2(IV), 3(I, III); Ow=H2O(I, II).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20010218A MD2146C2 (ro) | 2001-07-12 | 2001-07-12 | Materiale dielectrice pe bază de combinaţii coordinative heteronucleare ale cobaltului(III) şi bismutului(III) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20010218A MD2146C2 (ro) | 2001-07-12 | 2001-07-12 | Materiale dielectrice pe bază de combinaţii coordinative heteronucleare ale cobaltului(III) şi bismutului(III) |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD2146B1 MD2146B1 (ro) | 2003-04-30 |
| MD2146C2 true MD2146C2 (ro) | 2003-10-31 |
Family
ID=19739895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MDA20010218A MD2146C2 (ro) | 2001-07-12 | 2001-07-12 | Materiale dielectrice pe bază de combinaţii coordinative heteronucleare ale cobaltului(III) şi bismutului(III) |
Country Status (1)
| Country | Link |
|---|---|
| MD (1) | MD2146C2 (ro) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD2213C2 (ro) * | 2001-09-18 | 2004-01-31 | Государственный Университет Молд0 | Trihidraţii etilendiamintetraacetatobismutatului (III) de nitropentaaminocobalt (III) şi etilendiamintetraacetatobismutatului (III) de (tiocianato-N)pentaaminocobalt (III) ca materiale dielectrice |
| MD2479G2 (ro) * | 2003-05-14 | 2005-01-31 | Государственный Университет Молд0 | Dodecahidratul (dietilentriaminpentaacetato)bismutatului(III) de hexaamincobalt(III) în calitate de material dielectric. |
| MD2476G2 (ro) * | 2003-05-14 | 2005-01-31 | Государственный Университет Молд0 | Trihidratul catena-[(µ2-(O,O')-etilendiamintetraacetato)bismutatului(III)] de hexaaquacupru(II) în calitate de catalizator al procesului de radioliză a apei |
| MD2786G2 (ro) * | 2004-05-11 | 2006-02-28 | Государственный Университет Молд0 | Inhibitori ai leucemiei umane mieloide în bază de combinaţii coordinative heteronucleare ale cobaltului(III) si bismutului(III) |
| MD3942C2 (ro) * | 2009-01-22 | 2010-02-28 | Институт Химии Академии Наук Молдовы | Complecşi ai fierului şi cobaltului cu acidul furan-2-carboxilic cu proprietăţi antituberculoase |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD2450G2 (ro) * | 2002-06-18 | 2004-11-30 | Государственный Университет Молд0 | Catalizator de descompunere radiolitică a apei |
| MD2240G2 (ro) * | 2002-10-23 | 2004-02-29 | Государственный Университет Молд0 | Nonahidrat al bis(nitrilotriacetat)bismutatului(III) de tris(tiosemicarbazid)cobalt(III) ca material dielectric. |
| RU2458039C1 (ru) * | 2010-11-30 | 2012-08-10 | Учреждение Российской академии наук Институт химии и химической технологии Сибирского отделения РАН (ИХХТ СО РАН) | Способ получения гетероядерных ацетатов палладия с цветными металлами |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1257075A1 (ru) * | 1984-08-25 | 1986-09-15 | Ордена Трудового Красного Знамени Институт Химии Ан Мсср | Катена- @ -диметилглиоксим-дихлоротетра( @ , @ -диэтилникотинамид)железо (П) в качестве диэлектрического материала и способ его получени |
-
2001
- 2001-07-12 MD MDA20010218A patent/MD2146C2/ro not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1257075A1 (ru) * | 1984-08-25 | 1986-09-15 | Ордена Трудового Красного Знамени Институт Химии Ан Мсср | Катена- @ -диметилглиоксим-дихлоротетра( @ , @ -диэтилникотинамид)железо (П) в качестве диэлектрического материала и способ его получени |
Non-Patent Citations (3)
| Title |
|---|
| Gmelins Handbuch der Anorganischen Chemie, Kobalt, Teil B, Die Ammine des Kobalts, Berlin,1930, S. 376 * |
| Summers S. P., Abboud K. A., Farrah S. R., Palenik G. J. Synthesis and Structures of Bismuth(III) Complexes with Nitrilotriacetic Acid, Ethylenediaminetetraacetic Acid and Diethylenetriaminepentaacetic Acid // Inorg. Chem., 1994, Vol. 33, p. 88-92 * |
| Таблицы физических величин / Под ред. И. К. Кикоина. Москва, Атомиздат, 1976, c. 321-332 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD2213C2 (ro) * | 2001-09-18 | 2004-01-31 | Государственный Университет Молд0 | Trihidraţii etilendiamintetraacetatobismutatului (III) de nitropentaaminocobalt (III) şi etilendiamintetraacetatobismutatului (III) de (tiocianato-N)pentaaminocobalt (III) ca materiale dielectrice |
| MD2479G2 (ro) * | 2003-05-14 | 2005-01-31 | Государственный Университет Молд0 | Dodecahidratul (dietilentriaminpentaacetato)bismutatului(III) de hexaamincobalt(III) în calitate de material dielectric. |
| MD2476G2 (ro) * | 2003-05-14 | 2005-01-31 | Государственный Университет Молд0 | Trihidratul catena-[(µ2-(O,O')-etilendiamintetraacetato)bismutatului(III)] de hexaaquacupru(II) în calitate de catalizator al procesului de radioliză a apei |
| MD2786G2 (ro) * | 2004-05-11 | 2006-02-28 | Государственный Университет Молд0 | Inhibitori ai leucemiei umane mieloide în bază de combinaţii coordinative heteronucleare ale cobaltului(III) si bismutului(III) |
| MD3942C2 (ro) * | 2009-01-22 | 2010-02-28 | Институт Химии Академии Наук Молдовы | Complecşi ai fierului şi cobaltului cu acidul furan-2-carboxilic cu proprietăţi antituberculoase |
Also Published As
| Publication number | Publication date |
|---|---|
| MD2146B1 (ro) | 2003-04-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| KA4A | Patent for invention lapsed due to non-payment of fees (with right of restoration) | ||
| MM4A | Patent for invention definitely lapsed due to non-payment of fees |