MD2146C2 - Dielectric materials on base of heteronuclear coordinative combinations of cobalt (III) and bismuth (III) - Google Patents

Dielectric materials on base of heteronuclear coordinative combinations of cobalt (III) and bismuth (III) Download PDF

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Publication number
MD2146C2
MD2146C2 MDA20010218A MD20010218A MD2146C2 MD 2146 C2 MD2146 C2 MD 2146C2 MD A20010218 A MDA20010218 A MD A20010218A MD 20010218 A MD20010218 A MD 20010218A MD 2146 C2 MD2146 C2 MD 2146C2
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MD
Moldova
Prior art keywords
iii
heteronuclear
bismuth
tetraacetatobismuthate
dielectric materials
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MDA20010218A
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Romanian (ro)
Russian (ru)
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MD2146B1 (en
Inventor
Аурелиан ГУЛЯ
Виталие СТЭВИЛЭ
Виктор ЦАПКОВ
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Государственный Университет Молд0
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Application filed by Государственный Университет Молд0 filed Critical Государственный Университет Молд0
Priority to MDA20010218A priority Critical patent/MD2146C2/en
Publication of MD2146B1 publication Critical patent/MD2146B1/en
Publication of MD2146C2 publication Critical patent/MD2146C2/en

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Abstract

The invention relates to a group of heteronuclear coordinative compounds from the class of bismuth (III) aminopolycarboxylates with some α-elements. These complexes have high specific electric conductivity (p) and may be applied in electrical engineering in the capacity of dielectric materials.Summary of the invention consists in obtaining of tryhidrate aquaethylenediamine tetraacetatobismuthate(III)1,6-[dinitrotetraaminecobalt(III)], aquaethylenediamine tetraacetatobismuthate(III)1,2-[dinitrotetraaminecobalt(III)], tryhidrate ethylenediamine tetraacetatobismuthate(III)carbonatotetraaminecobalt(III) and dihydrate ethylenediamine tetraacetatobismuthate (III) oxalatotetraaminecobalt (III) dimmers of general formula:where X = NO2 (I, II), 1/2 CO3 (III), 1/2 C2O4 (IV); Y = NH3 (I), NO2 (II), 1/2 CO3 (III), 1/2 C2O4 (IV); Z = NO2 (I), NH3 (II-IV); n = O(II), 2 (IV), 3 (I, III); Ow = H2O (I, II).
MDA20010218A 2001-07-12 2001-07-12 Dielectric materials on base of heteronuclear coordinative combinations of cobalt (III) and bismuth (III) MD2146C2 (en)

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Application Number Priority Date Filing Date Title
MDA20010218A MD2146C2 (en) 2001-07-12 2001-07-12 Dielectric materials on base of heteronuclear coordinative combinations of cobalt (III) and bismuth (III)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MDA20010218A MD2146C2 (en) 2001-07-12 2001-07-12 Dielectric materials on base of heteronuclear coordinative combinations of cobalt (III) and bismuth (III)

Publications (2)

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MD2146B1 MD2146B1 (en) 2003-04-30
MD2146C2 true MD2146C2 (en) 2003-10-31

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MDA20010218A MD2146C2 (en) 2001-07-12 2001-07-12 Dielectric materials on base of heteronuclear coordinative combinations of cobalt (III) and bismuth (III)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD2213C2 (en) * 2001-09-18 2004-01-31 Государственный Университет Молд0 Trihydrates of ethylenediamine tetraacetatobismuthate (III) of nitropentaaminocobalt (III) and ethylenediamine tetraacetatobismuthate (III) of (thiocyanato-N)pentaaminocobalt (III) as dielectric materials
MD2476G2 (en) * 2003-05-14 2005-01-31 Государственный Университет Молд0 Trihydrate of catena-[(µ2-O,O')-ethylenediamine tetraacetato)bismuthate(III)] of hexaaquacopper(II) in the capacity of catalyst in the water radiolysis process
MD2479G2 (en) * 2003-05-14 2005-01-31 Государственный Университет Молд0 Dodecahydrate of (diethylene-triamine-penta-acetato)bismuthate(III) of hexaaminecobalt(III) as dielectric material
MD2786G2 (en) * 2004-05-11 2006-02-28 Государственный Университет Молд0 Inhibitors of human myeloid leukemia on base of heteronuclear coordinative compounds of cobalt(III) and bismuth(III)
MD3942C2 (en) * 2009-01-22 2010-02-28 Институт Химии Академии Наук Молдовы Iron and cobalt complexes with 2-furoic acid possessing antituberculous properties

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD2450G2 (en) * 2002-06-18 2004-11-30 Государственный Университет Молд0 Catalyst for water radiolytic decomposition
MD2240G2 (en) * 2002-10-23 2004-02-29 Государственный Университет Молд0 Nonahydrate of bis (nitrilotriacetate) bismuthate (III) of tris (thiosemicarbazide) cobalt (III) as dielectric material
RU2458039C1 (en) * 2010-11-30 2012-08-10 Учреждение Российской академии наук Институт химии и химической технологии Сибирского отделения РАН (ИХХТ СО РАН) Method of producing heteronuclear acetates of palladium with non-ferrous metals

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1257075A1 (en) * 1984-08-25 1986-09-15 Ордена Трудового Красного Знамени Институт Химии Ан Мсср Catena-m-dimethylglyoxime-dichlorotetra (n-n-di- ethyl nicotinamide)iron(ii) usedas dielectric material and method of its production

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1257075A1 (en) * 1984-08-25 1986-09-15 Ордена Трудового Красного Знамени Институт Химии Ан Мсср Catena-m-dimethylglyoxime-dichlorotetra (n-n-di- ethyl nicotinamide)iron(ii) usedas dielectric material and method of its production

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Gmelins Handbuch der Anorganischen Chemie, Kobalt, Teil B, Die Ammine des Kobalts, Berlin,1930, S. 376 *
Summers S. P., Abboud K. A., Farrah S. R., Palenik G. J. Synthesis and Structures of Bismuth(III) Complexes with Nitrilotriacetic Acid, Ethylenediaminetetraacetic Acid and Diethylenetriaminepentaacetic Acid // Inorg. Chem., 1994, Vol. 33, p. 88-92 *
Таблицы физических величин / Под ред. И. К. Кикоина. Москва, Атомиздат, 1976, c. 321-332 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD2213C2 (en) * 2001-09-18 2004-01-31 Государственный Университет Молд0 Trihydrates of ethylenediamine tetraacetatobismuthate (III) of nitropentaaminocobalt (III) and ethylenediamine tetraacetatobismuthate (III) of (thiocyanato-N)pentaaminocobalt (III) as dielectric materials
MD2476G2 (en) * 2003-05-14 2005-01-31 Государственный Университет Молд0 Trihydrate of catena-[(µ2-O,O')-ethylenediamine tetraacetato)bismuthate(III)] of hexaaquacopper(II) in the capacity of catalyst in the water radiolysis process
MD2479G2 (en) * 2003-05-14 2005-01-31 Государственный Университет Молд0 Dodecahydrate of (diethylene-triamine-penta-acetato)bismuthate(III) of hexaaminecobalt(III) as dielectric material
MD2786G2 (en) * 2004-05-11 2006-02-28 Государственный Университет Молд0 Inhibitors of human myeloid leukemia on base of heteronuclear coordinative compounds of cobalt(III) and bismuth(III)
MD3942C2 (en) * 2009-01-22 2010-02-28 Институт Химии Академии Наук Молдовы Iron and cobalt complexes with 2-furoic acid possessing antituberculous properties

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Publication number Publication date
MD2146B1 (en) 2003-04-30

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MM4A Patent for invention definitely lapsed due to non-payment of fees