MA32361B1 - PROCESS FOR THE CONVERSION OF BIOGAS TO LIQUID FUEL - Google Patents
PROCESS FOR THE CONVERSION OF BIOGAS TO LIQUID FUELInfo
- Publication number
- MA32361B1 MA32361B1 MA33324A MA33324A MA32361B1 MA 32361 B1 MA32361 B1 MA 32361B1 MA 33324 A MA33324 A MA 33324A MA 33324 A MA33324 A MA 33324A MA 32361 B1 MA32361 B1 MA 32361B1
- Authority
- MA
- Morocco
- Prior art keywords
- biogas
- liquid
- gas
- product
- withdrawn
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title abstract 5
- 238000006243 chemical reaction Methods 0.000 title abstract 3
- 239000000446 fuel Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000007789 gas Substances 0.000 abstract 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000029087 digestion Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- 239000003345 natural gas Substances 0.000 abstract 1
- 239000005416 organic matter Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/341—Apparatus, reactors with stationary catalyst bed
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/02—Non-metals
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1025—Natural gas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1048—Middle distillates
- C10G2300/1051—Kerosene having a boiling range of about 180 - 230 °C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1048—Middle distillates
- C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1048—Middle distillates
- C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Processing Of Solid Wastes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Catalysts (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
Abstract
Selon l'invention, des biogaz tels que le gaz naturel et d'autres gaz aptes à être biologiquement produits par digestion de matière organique sont convertis en un combustible liquide hydrocarboné brûlant proprement dans un procédé dans lequel un biogaz est introduit dans une cuve de réaction où le biogaz est en contact avec une fraction de pétrole liquide et un catalyseur en métal de transition immergé dans le liquide, du gaz produit vaporisé est soutiré d'une phase de vapeur au-dessus du niveau du liquide, condensé et introduit dans une cuve de produit où le condensat est séparé du gaz non condensé et soutiré en tant que combustible produit liquide. Le gaz non condensé peut être recyclé vers la cuve de réaction.According to the invention, biogas such as natural gas and other gases capable of being biologically produced by digestion of organic matter are converted into a clean burning hydrocarbon liquid fuel in a process in which a biogas is introduced into a reaction vessel. wherein the biogas is in contact with a liquid petroleum fraction and a transition metal catalyst immersed in the liquid, vaporized product gas is withdrawn from a vapor phase above the liquid level, condensed and introduced into a vessel of product where the condensate is separated from the uncondensed gas and withdrawn as a liquid product fuel. The uncondensed gas can be recycled to the reaction vessel.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/098,513 US20090249682A1 (en) | 2008-04-07 | 2008-04-07 | Conversion of biogas to liquid fuels |
US12/171,801 US7880044B2 (en) | 2008-04-07 | 2008-07-11 | Conversion of biogas to liquid fuels |
US12/212,968 US7897124B2 (en) | 2008-09-18 | 2008-09-18 | Continuous process and plant design for conversion of biogas to liquid fuel |
PCT/US2009/036054 WO2009126379A1 (en) | 2008-04-07 | 2009-03-04 | Process for conversion of biogas to liquid fuel |
Publications (1)
Publication Number | Publication Date |
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MA32361B1 true MA32361B1 (en) | 2011-06-01 |
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MA33324A MA32361B1 (en) | 2008-04-07 | 2010-11-03 | PROCESS FOR THE CONVERSION OF BIOGAS TO LIQUID FUEL |
Country Status (19)
Country | Link |
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US (1) | US20110000128A1 (en) |
EP (1) | EP2268379A4 (en) |
KR (1) | KR20110036697A (en) |
CN (1) | CN102006920A (en) |
AR (1) | AR070939A1 (en) |
AU (1) | AU2009234105A1 (en) |
BR (1) | BRPI0910440A2 (en) |
CL (1) | CL2009000564A1 (en) |
CO (1) | CO6310969A2 (en) |
EA (1) | EA201001602A1 (en) |
EC (1) | ECSP10010595A (en) |
GE (1) | GEP20125688B (en) |
MA (1) | MA32361B1 (en) |
MX (1) | MX2010010995A (en) |
NZ (1) | NZ588113A (en) |
PE (1) | PE20100038A1 (en) |
UA (1) | UA98225C2 (en) |
WO (1) | WO2009126379A1 (en) |
ZA (1) | ZA201006621B (en) |
Families Citing this family (18)
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US7897124B2 (en) * | 2008-09-18 | 2011-03-01 | Gunnerman Rudolf W | Continuous process and plant design for conversion of biogas to liquid fuel |
US8226817B2 (en) * | 2010-01-04 | 2012-07-24 | Gunnerman Rudolf W | Non-fractionation process for production of low-boiling fuel from crude oil |
WO2011066058A1 (en) * | 2009-11-30 | 2011-06-03 | Conocophillips Company | A blended fuel composition having improved cold flow properties |
FI123497B (en) * | 2010-08-20 | 2013-05-31 | Timo Nylander | A process for the production of fuel from organic waste or biomass and a gasification plant |
US9109177B2 (en) * | 2011-12-12 | 2015-08-18 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
US8945373B2 (en) | 2011-12-22 | 2015-02-03 | Iogen Corporation | Method for producing renewable fuels |
US8658026B2 (en) | 2011-12-22 | 2014-02-25 | Iogen Corporation | Method for producing fuel with renewable content having reduced lifecycle greenhouse gas emissions |
US8715488B1 (en) | 2013-01-07 | 2014-05-06 | Clean Global Energy, Inc. | Method and apparatus for making hybrid crude oils and fuels |
DE102014209216B4 (en) * | 2014-05-15 | 2018-08-23 | Glatt Gmbh | Catalytically active porous element and process for its preparation |
US10416729B2 (en) * | 2016-09-27 | 2019-09-17 | Seagate Technology Llc | Mounting structure for hard disk drives |
CN106823750A (en) * | 2017-03-24 | 2017-06-13 | 华北电力大学(保定) | It is a kind of to be aoxidized for magnesium processes desulfurization sulfite salt and the device for cooperateing with demercuration |
KR102068337B1 (en) * | 2018-04-03 | 2020-01-20 | 한국기계연구원 | System for producing bio-oil from pyrolysis of biomass and plastics |
CA3130709A1 (en) | 2019-02-20 | 2020-08-27 | Kara Technologies Inc. | Catalyst structure and method of upgrading hydrocarbons in the presence of the catalyst structure |
CN112717839B (en) * | 2020-12-25 | 2022-05-03 | 江苏新河农用化工有限公司 | Fluidized reaction device and method for oxidizing m-xylene by using same |
CA3214940A1 (en) | 2021-04-15 | 2022-10-20 | Iogen Corporation | Process and system for producing low carbon intensity renewable hydrogen |
CA3214954A1 (en) | 2021-04-22 | 2022-10-27 | Patrick J. Foody | Process and system for producing fuel |
US11807530B2 (en) | 2022-04-11 | 2023-11-07 | Iogen Corporation | Method for making low carbon intensity hydrogen |
CZ2022301A3 (en) | 2022-07-06 | 2024-01-17 | Dereroy & Co., A.S. | A method of homolytic and heterolytic bond cleavage in molecules of gases and liquids with the primary release of binding energy, the use of this energy to change the internal geometric architecture of some molecules leading to the synthesis of new chemical compounds and a device for its implementation |
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US2438029A (en) * | 1944-05-03 | 1948-03-16 | Texas Co | Method of effecting catalytic conversions |
US3993600A (en) * | 1973-08-23 | 1976-11-23 | Matthey Bishop, Inc. | Catalyst support assembly |
US4082262A (en) * | 1977-02-14 | 1978-04-04 | Halm Instrument Co., Inc. | Feeder hopper for documents |
US4172842A (en) * | 1977-12-29 | 1979-10-30 | Texaco Inc. | Conversion of hydrogen and carbon monoxide into C1 -C4 range hydrocarbons |
US4252736A (en) * | 1979-06-01 | 1981-02-24 | Mobil Oil Corporation | Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors |
GB9114314D0 (en) * | 1991-07-02 | 1991-08-21 | British Petroleum Co Plc | Catalyst treatment for fisher-tropsch process |
US5269909A (en) * | 1991-10-29 | 1993-12-14 | Intevep, S.A. | Process for treating heavy crude oil |
US6068760A (en) * | 1997-08-08 | 2000-05-30 | Rentech, Inc. | Catalyst/wax separation device for slurry Fischer-Tropsch reactor |
AU2001269854B2 (en) * | 2000-06-13 | 2005-08-18 | Conocophillips Company | Supported nickel-magnesium oxide catalysts and processes for the production of syngas |
DE10030011A1 (en) * | 2000-06-17 | 2002-01-03 | Sgl Carbon Ag | Molded part made of ceramic derived from polymers |
GB2401112C (en) * | 2002-02-13 | 2007-01-16 | Sasol Technology | Process for starting up a fischer-tropsch reactor |
CN1236016C (en) * | 2003-04-25 | 2006-01-11 | 谢福胜 | Method and device for producing vapour, coal, diesel oil using waste plastic, rubber, machine oil |
WO2005017069A1 (en) * | 2003-06-24 | 2005-02-24 | Fusheng Xie | A process and a device for producing gasoline, kerosene and diesel oil from waste plastic, rubber and machine oil |
EP1658354B1 (en) * | 2003-08-22 | 2008-12-17 | Sasol Technology (Proprietary) Limited | Process for synthesising hydrocarbons |
US7899401B2 (en) * | 2004-06-04 | 2011-03-01 | Panasonic Corporation | Radio communication device |
US20060054865A1 (en) * | 2004-09-14 | 2006-03-16 | Conocophillips Company | Fischer-Tropsch naphtha as blendstock for denatured alcohol |
AU2006327030B2 (en) * | 2005-12-22 | 2010-09-02 | Shell Internationale Research Maatschappij B.V. | Zirconium stabilised Fischer Tropsch catalyst and catalyst support |
US20090249682A1 (en) * | 2008-04-07 | 2009-10-08 | Gunnerman Rudolf W | Conversion of biogas to liquid fuels |
US7897124B2 (en) * | 2008-09-18 | 2011-03-01 | Gunnerman Rudolf W | Continuous process and plant design for conversion of biogas to liquid fuel |
US8226817B2 (en) * | 2010-01-04 | 2012-07-24 | Gunnerman Rudolf W | Non-fractionation process for production of low-boiling fuel from crude oil |
US7806947B2 (en) * | 2009-08-31 | 2010-10-05 | Gunnerman Rudolf W | Liquid hydrocarbon fuel from methane assisted by spontaneously generated voltage |
-
2009
- 2009-03-04 CN CN2009801125637A patent/CN102006920A/en active Pending
- 2009-03-04 EP EP09730699.7A patent/EP2268379A4/en not_active Withdrawn
- 2009-03-04 MX MX2010010995A patent/MX2010010995A/en not_active Application Discontinuation
- 2009-03-04 KR KR1020107024698A patent/KR20110036697A/en not_active Application Discontinuation
- 2009-03-04 NZ NZ588113A patent/NZ588113A/en not_active IP Right Cessation
- 2009-03-04 EA EA201001602A patent/EA201001602A1/en unknown
- 2009-03-04 GE GEAP200911994A patent/GEP20125688B/en unknown
- 2009-03-04 BR BRPI0910440A patent/BRPI0910440A2/en not_active IP Right Cessation
- 2009-03-04 WO PCT/US2009/036054 patent/WO2009126379A1/en active Application Filing
- 2009-03-04 UA UAA201013194A patent/UA98225C2/en unknown
- 2009-03-04 AU AU2009234105A patent/AU2009234105A1/en not_active Abandoned
- 2009-03-04 US US12/682,511 patent/US20110000128A1/en not_active Abandoned
- 2009-03-10 CL CL2009000564A patent/CL2009000564A1/en unknown
- 2009-04-06 PE PE2009000486A patent/PE20100038A1/en not_active Application Discontinuation
- 2009-04-06 AR ARP090101215A patent/AR070939A1/en unknown
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2010
- 2010-09-15 ZA ZA2010/06621A patent/ZA201006621B/en unknown
- 2010-10-07 CO CO10124683A patent/CO6310969A2/en not_active Application Discontinuation
- 2010-11-03 MA MA33324A patent/MA32361B1/en unknown
- 2010-11-05 EC EC2010010595A patent/ECSP10010595A/en unknown
Also Published As
Publication number | Publication date |
---|---|
BRPI0910440A2 (en) | 2015-09-29 |
EP2268379A1 (en) | 2011-01-05 |
AR070939A1 (en) | 2010-05-19 |
MX2010010995A (en) | 2011-03-01 |
EA201001602A1 (en) | 2011-06-30 |
AU2009234105A1 (en) | 2009-10-15 |
EP2268379A4 (en) | 2014-01-22 |
KR20110036697A (en) | 2011-04-08 |
US20110000128A1 (en) | 2011-01-06 |
NZ588113A (en) | 2012-05-25 |
CL2009000564A1 (en) | 2009-11-13 |
WO2009126379A1 (en) | 2009-10-15 |
ZA201006621B (en) | 2012-02-29 |
ECSP10010595A (en) | 2011-03-31 |
UA98225C2 (en) | 2012-04-25 |
CN102006920A (en) | 2011-04-06 |
CO6310969A2 (en) | 2011-08-22 |
GEP20125688B (en) | 2012-11-12 |
PE20100038A1 (en) | 2010-02-02 |
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