LU87130A1 - USE OF 2-HYDROXY-4-METHOBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THE SAME - Google Patents
USE OF 2-HYDROXY-4-METHOBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THE SAME Download PDFInfo
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- LU87130A1 LU87130A1 LU87130A LU87130A LU87130A1 LU 87130 A1 LU87130 A1 LU 87130A1 LU 87130 A LU87130 A LU 87130A LU 87130 A LU87130 A LU 87130A LU 87130 A1 LU87130 A1 LU 87130A1
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- LU
- Luxembourg
- Prior art keywords
- hair
- hydroxy
- sulfonic acid
- methoxybenzophenone
- weight
- Prior art date
Links
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- 239000000203 mixture Substances 0.000 claims description 82
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 claims description 31
- 239000002537 cosmetic Substances 0.000 claims description 26
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- NSAOIAYLNQLPAZ-UHFFFAOYSA-N 4-hydroxy-5-(2-hydroxy-4-methoxy-5-sulfobenzoyl)-2-methoxybenzenesulfonic acid;sodium Chemical compound [Na].[Na].C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC(S(O)(=O)=O)=C(OC)C=C1O NSAOIAYLNQLPAZ-UHFFFAOYSA-N 0.000 description 1
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- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
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- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
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- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 1
- WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
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- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
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- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical class C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
Utilisation de l'acide 2-hydroxy-4-méthoxybenzophënone-5-sulfonique ou de ses sels pour la protection des cheveux contre les agressions atmosphériques, et en particulier contre la lumière, et procédé de protection des cheveux utilisant ce composé.Use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts for protecting the hair against atmospheric aggressions, and in particular against light, and method for protecting the hair using this compound.
5 ·5 ·
La présente invention a pour objet l'utilisation de l'acide 2-hydroxy-4-mëthoxybenzophénone-5-sulfonique et de ses sels en tant qu'agents de protection de la kératine des cheveux contre les agressions atmosphériques, et en particulier contre la lumière, et un 10 procédé de protection des cheveux contre les agressions atmosphériques, et en particulier contre la lumière.The subject of the present invention is the use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts as agents for protecting hair keratin against atmospheric aggressions, and in particular against light, and a method of protecting the hair against atmospheric aggressions, and in particular against light.
On sait depuis longtemps que la lumière agresse la kératine des cheveux. De nombreuses publications divulguent que la lumière naturelle détruit certains aminoacides des cheveux et qu'en altérant 15 la fibre capillaire, elle en diminue les propriétés mécaniques; par diminution des propriétés mécaniques, on entend principalement la diminution du palier à 15% d'extension.We have known for a long time that light attacks hair keratin. Numerous publications disclose that natural light destroys certain amino acids of the hair and that, by altering the hair fiber, it reduces their mechanical properties; the term “reduction in mechanical properties” is understood mainly to mean a decrease in the bearing to 15% extension.
Le palier à 15% d'extension est le poids qu'il faut appliquer à un cheveu mouillé d'une longueur donnée pour l'allonger de 15%. Plus 20 le poids est élevé, plus le cheveu est élastique et résistant.The plateau at 15% extension is the weight that must be applied to a wet hair of a given length to lengthen it by 15%. The higher the weight, the more elastic and resistant the hair.
Pour lutter contre l'agression de la kératine des cheveux par la lumière, on a déjà proposé d'utiliser des substances susceptibles de filtrer les radiations lumineuses. En particulier, on a essayé des agents filtrants bien connus de la technique, tels que des dérivés de 25 la benzophénone, par exemple la 2-hydroxy-4-méthoxybenzophénone, et la 2,2'-dihydroxy-4,4'-diméthoxy-5,5'-disulfobenzophénone disodique 2 ou encore des dérivés du dibenzoylméthane, par exemple le 4-tert-butyl-4'-méthoxydibenzoylméthane ou l'acide p-aminobenzolque et ses dérivés tels que le p-diméthylaminobenzoate de 2-êthylhexyle, le tosylate de (4'-diméthylaminobenzoyloxyéthyl) diméthyl alkyl 5 ^C16-C18^ a^onium (ESCALOL 537 Q), des cinnamates tels que le p-méthoxycinnamate de 2-éthylhexyle ou encore l’acide 2-phênyl-benzimidazole-5-sulfonique.To fight against the aggression of hair keratin by light, it has already been proposed to use substances capable of filtering light radiation. In particular, filter agents well known in the art have been tried, such as derivatives of benzophenone, for example 2-hydroxy-4-methoxybenzophenone, and 2,2'-dihydroxy-4,4'-dimethoxy -5.5'-disulfobenzophenone disodium 2 or alternatively dibenzoylmethane derivatives, for example 4-tert-butyl-4'-methoxydibenzoylmethane or p-aminobenzolque acid and its derivatives such as 2-ethylhexyl p-dimethylaminobenzoate, (4'-dimethylaminobenzoyloxyethyl) dimethyl alkyl 5 ^ C16-C18 ^ a ^ onium (ESCALOL 537 Q) tosylate, cinnamates such as 2-ethylhexyl p-methoxycinnamate or 2-phenyl-benzimidazole-5 acid -sulfonic.
Cependant, ces substances filtrantes ne se sont pas révélées efficaces pour préserver les propriétés mécaniques des cheveux, à 10 savoir leur élasticité, contre les effets néfastes de la lumière.However, these filtering substances have not been found to be effective in preserving the mechanical properties of the hair, namely its elasticity, against the harmful effects of light.
Il est, au contraire, apparu que leur présence dans certaines compositions cosmétiques pouvait même accentuer la dégradation des propriétés mécaniques, notamment la diminution du palier à 15% d'extension.On the contrary, it appeared that their presence in certain cosmetic compositions could even accentuate the degradation of the mechanical properties, in particular the reduction of the plateau to 15% of extension.
15 La demanderesse a maintenant découvert, de façon tout à fait surprenante, que l'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique vendu par exemple sous la dénomination "UVINUL MS40" par BASF, ou ses sels, pouvaient préserver les propriétés mécaniques des cheveux de la dégradation par la lumière. Cette propriété a pu être mise en 20 évidence par exposition en lumière naturelle (milieu ensoleillé) et en lumière artificielle (émetteur au xénon d'un appareil de vieillissement accéléré du type SUNTEST HANAU).The Applicant has now discovered, quite surprisingly, that the 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid sold for example under the name "UVINUL MS40" by BASF, or its salts, could preserve the properties mechanics of hair from light degradation. This property could be demonstrated by exposure to natural light (sunny environment) and to artificial light (xenon emitter of an accelerated aging apparatus of the SUNTEST HANAU type).
La présente invention a donc pour objet l'utilisation de l'acide 2-hydroxy-4-methoxybenzophénone-5-sulfonique ou de ses sels en tant 25 qu’agents de protection des propriétés mécaniques des cheveux, et essentiellement du palier à 15% d'extension au mouillé, contre la dégradation provoquée par les agressions atmosphériques, et en particulier par la lumière.The present invention therefore relates to the use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts as agents for protecting the mechanical properties of the hair, and essentially the 15% level. extension in the wet, against degradation caused by atmospheric aggressions, and in particular by light.
Par sels de l'acide suifonique précité, on entend plus 30 particulièrement les sels métalliques tels que les sels alcalins ou alcalino-terreux, les sels d'ammonium et d'amines.By salts of the abovementioned sulfonic acid is meant more particularly the metal salts such as alkali or alkaline earth salts, ammonium and amine salts.
Selon la présente invention, on utilise l'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique ou ses sels pour préserver les propriétés mécaniques des cheveux des agressions de la lumière, en 35 des quantités au moins égales à 0,3% en poids d'acide libre, et de 3 préférence comprises entre 0,3 et 9% en poids d'acide libre, dans un support cosmétiquement acceptable. La concentration minimale de 0,3%, correspond à une concentration molaire pour 100 g de composition d'environ 1 millimole d'acide qui peut être utilisé sous forme libre, 5 ou salifié par un hydroxyde métallique, l'ammoniaque ou une amine.According to the present invention, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts are used to preserve the mechanical properties of the hair from light aggression, in amounts at least equal to 0.3% by weight of free acid, and preferably between 0.3 and 9% by weight of free acid, in a cosmetically acceptable carrier. The minimum concentration of 0.3% corresponds to a molar concentration per 100 g of composition of approximately 1 millimole of acid which can be used in free form, or salified with a metal hydroxide, ammonia or an amine.
L'acide 2-hydroxy-4-mëthoxybenzophénone-5-sulfonique ou ses sels selon l'invention peuvent être utilisés pour protéger les cheveux naturels ou sensibilisés. On entend par "cheveux sensibilisés", des cheveux ayant subi une traitement de permanente, de coloration ou de 10 décoloration.The 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts according to the invention can be used to protect natural or sensitized hair. The term "sensitized hair" means hair which has undergone a treatment for perming, coloring or bleaching.
Les compositions cosmétiques pour cheveux, utilisées conformément à l'invention pour les protéger contre la dégradation par la lumière et contenant à titre de composé actif l'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique ou ses sels, peuvent se présenter 15 sous forme de solutions ou dispersions aqueuses, alcooliques ou hydroalcooliques (l'alcool étant le plus souvent un alcanol inférieur tel que l'éthanol ou l'isopropanol), épaissies ou non, de crèmes, de gels, de mousses aérosols ou de sprays et contenir les adjuvants habituellement utilisés dans les compositions capillaires et adaptés 20 à l'application envisagée.Cosmetic compositions for hair, used in accordance with the invention to protect them against degradation by light and containing as active compound 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts, may be present. in the form of aqueous, alcoholic or hydroalcoholic solutions or dispersions (the alcohol most often being a lower alkanol such as ethanol or isopropanol), thickened or not, creams, gels, aerosol foams or sprays and contain the adjuvants usually used in hair compositions and suitable for the intended application.
Ces compositions peuvent être ou non suivies d'un rinçage et peuvent constituer des shampooings, des après-shampooings, des produits à rincer à appliquer avant ou après shampooing, avant ou après coloration ou décoloration, avant ou après permanente ou 25 défrisage, des compositions non rincées telles que des lotions, gels, crèmes, sprays ou mousses pour la mise en plis, pour le brushing, des laques ou sprays pour le maintien de la coiffure et des compositions restructurantes.These compositions may or may not be followed by a rinsing and may constitute shampoos, conditioners, rinsing products to be applied before or after shampooing, before or after coloring or discoloration, before or after perming or straightening, compositions leave-in rinses such as lotions, gels, creams, sprays or foams for styling, for brushing, hairsprays or sprays for maintaining the hairstyle and restructuring compositions.
Lorsque les compositions cosmétiques utilisées selon l'invention 30 constituent des compositions non suivies d'un rinçage, l'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique ou ses sels, en tant qu'agent actif préservant les propriétés mécaniques des cheveux contre la lumière, est présent à raison de 0,3 à 5% en poids d'acide libre par rapport au poids total de la composition, et de préférence 35 à raison de 0,3 à 3,5% en poids d'acide libre.When the cosmetic compositions used according to the invention constitute compositions not followed by rinsing, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts, as active agent preserving the mechanical properties of the hair against light, is present in an amount of 0.3 to 5% by weight of free acid relative to the total weight of the composition, and preferably in an amount of 0.3 to 3.5% by weight of acid free.
% 4% 4
Lorsque les compositions cosmétiques utilisées selon l’invention, constituent des compositions suivies d’un rinçage, l’acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique ou ses sels est présent à raison de 0,5 a 9% en poids d’acide libre, et de préférence 5 de 0,5 à 6% en poids d'acide libre, par rapport au poids total de la composition.When the cosmetic compositions used according to the invention constitute compositions followed by rinsing, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts is present in an amount of 0.5 to 9% by weight d free acid, and preferably 5 from 0.5 to 6% by weight of free acid, relative to the total weight of the composition.
Les compositions cosmétiques pour cheveux selon l'invention ont un pïï compris entre 2 et 9 et de préférence entre 4 et 8.The cosmetic compositions for hair according to the invention have a pïï between 2 and 9 and preferably between 4 and 8.
Les compositions cosmétiques utilisées selon l'invention peuvent 10 également renfermer des agents cosmétiques bien connus dans la technique sous réserve qu'ils n’altèrent pas eux-mêmes les propriétés mécaniques de la kératine des cheveux.The cosmetic compositions used according to the invention may also contain cosmetic agents well known in the art provided that they do not themselves alter the mechanical properties of keratin in the hair.
Les adjuvants ou agents cosmétiques généralement présents dans les compositions cosmétiques utilisées selon l'invention sont par 15 exemple des agents de surface cationiques, anioniques, amphoteres, non-ioniques ou leurs mélanges, des épaississants, des polymères anioniques, non-ioniques, amphoteres, cationiques ou leurs mélanges, des adoucissants, des conservateurs, des agents de moussage, des stabilisateurs de mousse, des électrolytes, des agents de régulation 20 de pH, des agents anti-gras, des agents séquestrants, des parfums, des colorants, des propulseurs, des solvants organiques.The adjuvants or cosmetic agents generally present in the cosmetic compositions used according to the invention are, for example, cationic, anionic, amphoteric, nonionic surfactants or their mixtures, thickeners, anionic, nonionic, amphoteric polymers, cationic or mixtures thereof, softeners, preservatives, foaming agents, foam stabilizers, electrolytes, pH regulating agents, anti-fat agents, sequestering agents, perfumes, dyes, propellants , organic solvents.
Les agents tensio-actifs cationiques, anioniques, non-ioniques, amphotères ou leurs mélanges sont généralement utilisés dans des proportions de 0,1 à 50% en poids, et de préférence de 0,5 à 30% en 25 poids, par rapport au poids total de la composition.Cationic, anionic, nonionic, amphoteric surfactants or mixtures thereof are generally used in proportions of 0.1 to 50% by weight, and preferably 0.5 to 30% by weight, relative to the total weight of the composition.
Lorsque les compositions cosmétiques pour cheveux utilisées selon l’invention constituent des shampooings, ceux-ci sont essentiellement caractérisés par le fait qu'ils contiennent, outre l’acide sulfonique ou ses sels ci-dessus défini, au moins un agent de 30 surface anionique, non-ionique, cationique, amphotère ou un mélange de tels agents de surface, en milieu aqueux. Les shampooings peuvent également contenir différents adjuvants tels que des colorants, des conservateurs, des agents épaississants, des agents stabilisateurs de mousse, des synergistes, des agents adoucissants, des électrolytes, 35 des séquestrants, une ou plusieurs résines cosmétiques, des parfums, 5 des essences naturelles ainsi que tout autre adjuvant utilisé habituellement dans un shampooing. Dans ces shampooings, la concentration d’agent de surface est généralement comprise entre 2 et 50% en poids. Leur pH est généralement compris entre 3 et 9.When the cosmetic compositions for hair used according to the invention constitute shampoos, these are essentially characterized by the fact that they contain, in addition to the sulfonic acid or its salts defined above, at least one anionic surfactant , non-ionic, cationic, amphoteric or a mixture of such surfactants, in an aqueous medium. Shampoos can also contain various adjuvants such as colorants, preservatives, thickeners, foam stabilizers, synergists, softeners, electrolytes, sequestrants, one or more cosmetic resins, perfumes, natural essences as well as any other adjuvant usually used in a shampoo. In these shampoos, the concentration of surfactant is generally between 2 and 50% by weight. Their pH is generally between 3 and 9.
5 Lorsque les compositions utilisées selon l’invention constituent des compositions non rincées - lotion, crème, gel, mousse, spray ou laque pour le brushing, pour la mise en plis, pour coiffer ou traiter la chevelure - elles comprennent généralement, dans un milieu aqueux, alcoolique ou hydroalcoolique, outre l’acide sulfonique ou ses sels, 10 au moins un polymère cationique, anionique, non-ionique, amphotère ou un mélange de tels polymères dans des quantités comprises généralement entre 0,1 et 10% et de préférence entre 0,1 et 3% en poids, et éventuellement des agents anti-moussants.When the compositions used according to the invention constitute leave-in compositions - lotion, cream, gel, mousse, spray or lacquer for brushing, for styling, for styling or treating the hair - they generally comprise, in a medium aqueous, alcoholic or hydroalcoholic, in addition to sulfonic acid or its salts, at least one cationic, anionic, non-ionic, amphoteric polymer or a mixture of such polymers in amounts generally between 0.1 and 10% and preferably between 0.1 and 3% by weight, and optionally anti-foaming agents.
Lorsque les compositions capillaires selon l’invention 15 constituent des lotions rincées, appelées également "rinse", elles sont appliquées avant ou après coloration ou décoloration, avant ou après permanente, avant ou après shampooing ou entre deux temps de shampooing, puis rincées après un temps de pose.When the hair compositions according to the invention constitute rinsed lotions, also called "rinse", they are applied before or after coloring or bleaching, before or after perming, before or after shampooing or between two shampooing times, then rinsed off after a exposure time.
Ces compositions peuvent être des solutions aqueuses ou hydro-20 alcooliques comprenant éventuellement des tensio-actifs; elles peuvent être aussi des émulsions ou des gels. Ces compositions peuvent également être pressurisées en aérosol sous forme de sprays ou mousses.These compositions can be aqueous or aqueous-alcoholic solutions optionally comprising surfactants; they can also be emulsions or gels. These compositions can also be pressurized as an aerosol in the form of sprays or foams.
Dans ces compositions rincées, la concentration en agents 25 tensio-actif s peut varier entre 0,1 et 10%, et de préférence entre 0,5 et 7% en poids. Elles peuvent également contenir des polymères non-ioniques, cationiques, anioniques, amphotères ou leurs mélanges.In these rinsed compositions, the concentration of surfactants can vary between 0.1 and 10%, and preferably between 0.5 and 7% by weight. They can also contain nonionic, cationic, anionic, amphoteric polymers or their mixtures.
Quand les compositions capillaires se présentent sous forme de gels, à rincer ou non, elles contiennent des épaississants en 30 présence ou non de solvants.When the hair compositions are in the form of gels, to be rinsed or not, they contain thickeners in the presence or not of solvents.
Les épaississants peuvent être l’alginate de sodium, la gomme arabique ou la gomme de xanthane ou des dérivés cellulosiques tels que la méthyl cellulose, 1’hydroxyméthyl cellulose, 1’hydroxyéthyl cellulose, l’hydroxypropyl cellulose, la carboxyméthyl cellulose ou 35 des polymères carboxyliques tels que les "Carbopol". On peut 6 également obtenir un épaississement des lotions par mélange de polyéthylène glycol et de stéarate ou distéarate de polyéthylène glycol ou par un mélange d'esters phosphoriques et d'amides. La concentration en épaississant peut varier de 0,1 à 30%, et de 5 préférence de 0,2 à 15% en poids, par rapport au poids total de la composition.The thickeners can be sodium alginate, gum arabic or xanthan gum or cellulose derivatives such as methyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose or polymers carboxylic such as "Carbopol". A thickening of the lotions can also be obtained by mixing polyethylene glycol and polyethylene glycol stearate or distearate or by a mixture of phosphoric esters and amides. The thickener concentration can vary from 0.1 to 30%, and preferably from 0.2 to 15% by weight, relative to the total weight of the composition.
On peut utiliser également un agent épaississant qui résulte de l'interaction ionique d'un polymère cationique constitué par un copolymère de cellulose ou d'un dérivé de cellulose greffés par un 10 sel de monomère hydrosoluble d'ammonium quaternaire (vendus sous les dénominations "CELQUAT H 100" ou "CELQUAT L 200") et d'un polymère anionique carboxylique ayant une viscosité capillaire absolue dans le dimêthylformamide ou le méthanol à une concentration de 5% et à 30°C, -3 inférieure ou égale à 30.10 Pa.s.It is also possible to use a thickening agent which results from the ionic interaction of a cationic polymer constituted by a cellulose copolymer or a cellulose derivative grafted by a salt of water-soluble quaternary ammonium monomer (sold under the names " CELQUAT H 100 "or" CELQUAT L 200 ") and an anionic carboxylic polymer having an absolute capillary viscosity in dimethylformamide or methanol at a concentration of 5% and at 30 ° C, -3 less than or equal to 30.10 Pa. s.
15 Cet épaississant est décrit dans la demande de brevet FR 2 598 611.This thickener is described in patent application FR 2 598 611.
Quand les compositions capillaires se présentent sous forme de mousses, à rincer ou non, elles contiennent un agent de moussage en milieu aqueux ou hydroalcoolique, en présence d'un gaz propulseur.When the hair compositions are in the form of foams, to be rinsed or not, they contain a foaming agent in an aqueous or hydroalcoholic medium, in the presence of a propellant gas.
20 Comme agent de moussage, on peut utiliser des tensio-actifs anioniques, non-ioniques, cationiques, amphotères ou leurs mélanges, des polymères non ioniques, anioniques, cationiques ou leurs mélanges, de l'alcool polyvinylique issu de polyacétate de vinyle hydrolysé dont le taux d'hydrolyse est égal ou inférieur à 97% comme 25 décrit dans la demande de brevet FR 2 598 613.As foaming agent, anionic, nonionic, cationic, amphoteric surfactants or mixtures thereof, nonionic, anionic, cationic polymers or mixtures thereof, polyvinyl alcohol derived from hydrolyzed polyvinyl acetate, which may be used the hydrolysis rate is equal to or less than 97% as described in patent application FR 2 598 613.
Pour former une mousse, on préfère utiliser une association de polymère cationique et de polymère anionique, au moins l'un des deux polymères étant moussant en solution aqueuse. De telles associations sont décrites dans le brevet FR 2 505 348.To form a foam, it is preferred to use a combination of cationic polymer and anionic polymer, at least one of the two polymers being foaming in aqueous solution. Such associations are described in patent FR 2 505 348.
30 Les gaz propulseurs utilisés pour pressuriser ces compositions destinées à former des mousses, sont présents dans des proportions ne dépassant pas 25% et de préférence 15% par rapport au poids total de la composition. On peut utiliser à titre de gaz propulseur le gaz carbonique, l'azote, le protoxyde d'azote, les hydrocarbures volatils 35 tels que le butane, l'isobutane, le propane et leurs mélanges, les 7 hydrocarbures chlorés et/ou fluorés non hydrolysables tels que ceux vendus sous les dénominations "FREON" ou "DYMEL" par la Société DU PONT de NEMOURS.The propellants used to pressurize these compositions intended to form foams are present in proportions not exceeding 25% and preferably 15% relative to the total weight of the composition. Carbon dioxide, nitrogen, nitrous oxide, volatile hydrocarbons such as butane, isobutane, propane and mixtures thereof, non-chlorinated and / or fluorinated hydrocarbons can be used as the propellant. hydrolyzable such as those sold under the names "FREON" or "DYMEL" by the company DU PONT de NEMOURS.
Lorsque la composition se présente sous forme de spray ou de 5 laque, elle renferme dans un milieu alcoolique ou hydroalcoolique, une résine filmogène en présence éventuellement d'un gaz propulseur. On utilise de préférence, comme résine filmogène, un polymère anionique contenant des unités d’acides acrylique ou mêthacrylique, d’acide crotonique ou d’acides OC,^-dicarboxyliques insaturés.When the composition is in the form of a spray or a lacquer, it contains, in an alcoholic or hydroalcoholic medium, a film-forming resin, optionally in the presence of a propellant. Preferably used, as film-forming resin, an anionic polymer containing units of acrylic or methacrylic acids, crotonic acid or OC, ^ - unsaturated dicarboxylic acids.
10 Les agents propulseurs utilisés dans ces formulations sous forme de laques peuvent être choisis parmi les hydrocarbures volatils tels que le n-butane, le propane, l’isobutane ou leurs mélanges ou un mélange de ces hydrocarbures avec des hydrocarbures chlorés et/ou fluorés tels que les composés vendus sous la dénomination de "FREON" 15 ou "DYMEL" par la Société DU PONT de NEMOURS et plus particulièrement les hydrocarbures fluorochlorés tels que le monofluorotrichloro-mêthane, le difluorodichlorométhane, le tétrafluorodichloroéthane ou les mélanges de ces derniers.The propellants used in these lacquer formulations can be chosen from volatile hydrocarbons such as n-butane, propane, isobutane or mixtures thereof or a mixture of these hydrocarbons with chlorinated and / or fluorinated hydrocarbons such that the compounds sold under the name of "FREON" 15 or "DYMEL" by the company DU PONT de NEMOURS and more particularly fluorochlorinated hydrocarbons such as monofluorotrichloro-methane, difluorodichloromethane, tetrafluorodichloroethane or mixtures of the latter.
Il peuvent également être choisis parmi les hydrocarbures 20 chlorés et/ou fluorés susdécrits et leurs mélanges, le diméthyléther, le gaz carbonique ou le protoxyde d’azote.They can also be chosen from the chlorinated and / or fluorinated hydrocarbons described above and their mixtures, dimethyl ether, carbon dioxide or nitrous oxide.
La phase propulsive, dans ces compositions de laque représente 30 à 80% du poids total de la composition pressurisée.The propellant phase, in these lacquer compositions represents 30 to 80% of the total weight of the pressurized composition.
Quand les compositions capillaires de l’invention constituent 25 des lotions restructurantes, elles contiennent des produits renforçant la chaîne kératinique des cheveux. A cette classe de produits appartiennent les dérivés méthylolés tels que ceux décrits dans les brevets français n° 1 527 085 et 1 519 979.When the hair compositions of the invention constitute restructuring lotions, they contain products which strengthen the keratin chain of the hair. Methylol derivatives such as those described in French patents 1,527,085 and 1,519,979 belong to this class of products.
La présente invention vise également un procédé de protection de 30 la kératine des cheveux contre les agressions atmosphériques, et en particulier contre la lumière, consistant à appliquer sur les cheveux au moins 30 mg/g de cheveux d'une composition cosmétique contenant au moins 0,3% en poids d’acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique éventuellement salifié, dans un support cosmétiquernent 35 acceptable.The present invention also relates to a method for protecting the keratin of the hair against atmospheric aggressions, and in particular against light, consisting in applying to the hair at least 30 mg / g of hair of a cosmetic composition containing at least 0 , 3% by weight of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid optionally salified, in a cosmetically acceptable carrier.
88
Selon un mode de réalisation préféré, la composition cosmétique contient 0,3 à 9% en poids d’acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique qui peut être neutralisé par un hydroxyde métallique, l'ammoniaque ou une amine.According to a preferred embodiment, the cosmetic composition contains 0.3 to 9% by weight of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid which can be neutralized by a metal hydroxide, ammonia or an amine.
5 Les exemples suivants illustrent l'invention sans pour autant la limiter.The following examples illustrate the invention without limiting it.
9 EXEMPLE 19 EXAMPLE 1
On prépare un shampooing protecteur des cheveux de composition suivante : - Acide 2-hydroxy-4 méthoxy-benzophénone-5- 5 sulfonique vendu sous la dénomination "UVINUL MS 40" par la société BASF 1 g - Alkyl éther sulfate de sodium oxyéthyléné à 2,2 moles d’oxyde d’éthylène enA protective hair shampoo of the following composition is prepared: - 2-Hydroxy-4-methoxy-benzophenone-5 - 5 sulfonic acid sold under the name "UVINUL MS 40" by the company BASF 1 g - Alkyl ether sulfate sodium oxyethylenated to 2 , 2 moles of ethylene oxide in
solution aqueuse à 25% de matière active (MA) 6,2 g MA25% aqueous solution of active ingredient (MA) 6.2 g MA
10 ~ Diéthanolamide de coprah vendu sous la dénomination "COMPERLAN KD" par la société HENKEL 4 g - Acide chlorhydrique qs pH : 5 - Conservateur, colorant, parfum qs - Eau qsp 100 g 15 Sur des cheveux décolorés ayant été lavés cinq fois à l’aide de ce shampooing, puis exposés 120 heures au Suntest, on constate une amélioration importante de la valeur moyenne du palier à 15% d’extension au mouillé par rapport à des cheveux décolorés ayant subi un traitement analogue mais avec la base de shampooing sans "UVINUL 20 “S 40".10 ~ Coconut diethanolamide sold under the name "COMPERLAN KD" by the company HENKEL 4 g - Hydrochloric acid qs pH: 5 - Preservative, dye, perfume qs - Water qs 100 g 15 On bleached hair having been washed five times with l using this shampoo, then exposed 120 hours to Suntest, there is a significant improvement in the average value of the level at 15% wet extension compared to bleached hair having undergone a similar treatment but with the base of shampoo without "UVINUL 20“ S 40 ".
L’épreuve du Suntest s’effectue à l’aide d’un appareil "SUNTESTThe Suntest test is carried out using a "SUNTEST" device
HANAU" qui est constitué d’un émetteur au Xénon et d’un système de filtres produisant un rayonnement correspondant dans une très large mesure au rayonnement solaire. Le rayonnement énergétique est de 585 2 25 W/m environ dans le domaine de longueurs d’ondes comprises entre 300 et 830 nm (rayonnement global).HANAU "which consists of a Xenon transmitter and a filter system producing a radiation corresponding to a very large extent to solar radiation. The energy radiation is approximately 585 2 25 W / m in the range of lengths waves between 300 and 830 nm (global radiation).
30 10 EXEMPLE 230 10 EXAMPLE 2
On prépare une mousse de coiffage protectrice des cheveux de composition suivante : - Copolymère vinylméthyléther/anhydride maléique 5 monoestérifié avec le butanol, vendu à 50% de matière active (MA) dans l'éthanol sous la dénomination "GANTREZ ES 425" par la sociétéA protective styling foam for the hair of the following composition is prepared: - Vinyl methyl ether / maleic anhydride 5 copolymer monoesterified with butanol, sold at 50% of active material (MA) in ethanol under the name "GANTREZ ES 425" by the company
GENERAL ANILIN 0,6 g MAGENERAL ANILIN 0.6 g MA
- Hydroxyéthylcellulose greffée par du chlorure 10 de diallyldiméthyl ammonium, vendue par la société NATIONAL STARCH sous la dénomination "CELQUAT L 200" 0,5 g - Polymère cationique siliconé vendu par la société UNION CARBIDE sous la dénomination 15 "UCAR SILICONE ALE 56" en solution aqueuse- Hydroxyethylcellulose grafted with 10 diallyldimethyl ammonium chloride, sold by the company NATIONAL STARCH under the name "CELQUAT L 200" 0.5 g - Cationic silicone polymer sold by the company UNION CARBIDE under the name 15 "UCAR SILICONE ALE 56" in aqueous solution
à 35% de matière active (MA) 0,2 g MAat 35% active ingredient (MA) 0.2 g MA
- Acide 2-hydroxy-4 méthoxybenzophénone-5-sulfonique vendu sous la dénomination "UVINUL MS 40" par la société BASF 0,5 g 20 - Alcool éthylique qs : 10° - 2-amino-2-méthyl-propan-l-ol qs pH : 7,5 - Parfum, colorant, conservateur qs - Eau qsp 100 g- 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid sold under the name "UVINUL MS 40" by the company BASF 0.5 g 20 - Ethyl alcohol qs: 10 ° - 2-amino-2-methyl-propan-l- ol qs pH: 7.5 - Perfume, color, preservative qs - Water qs 100 g
On conditionne la composition ci-dessus dans un dispositif 25 aérosol : - Composition 90 g - Fréons 12/114 (57/43 en poids) 10 gThe above composition is conditioned in an aerosol device: - Composition 90 g - Freons 12/114 (57/43 by weight) 10 g
Total 100 g 30Total 100 g 30
Fréon 12 = difluorodichlorométhaneFreon 12 = difluorodichloromethane
Fréon 114 = 1,2-dichlorotétrafluoroêthane 35 11Freon 114 = 1,2-dichlorotetrafluoroethane 35 11
Des cheveux naturels permanentes reçoivent une application de cette mousse puis, sans rinçage consecutif, sont soumis à 180 heures d'exposition au Suntest, comme décrit à l’exemple 1.Permanent natural hair receives an application of this foam and then, without subsequent rinsing, is subjected to 180 hours of exposure to Suntest, as described in Example 1.
Par rapport à des cheveux de même nature traités de façon 5 analogue mais à l’aide d'une mousse ne renfermant pas d’"UVINUL MSCompared to hair of the same kind treated in a similar manner but using a foam which does not contain "UVINUL MS
40", on enregistre une amélioration significative de la valeur moyenne du palier à 15% d’extension au mouillé, 1040 ", there is a significant improvement in the average value of the bearing at 15% wet extension, 10
XX
a 12 * EXEMPLE 3a 12 * EXAMPLE 3
On prépare un gel de coiffage protecteur des cheveux de composition suivante : - Acide 2-hydroxy-4-méthoxybenzophënone-5- ' 5 sulfonique vendu sous la dénomination "ÜVINUL MS 40" par la société BASF 0,3 g - Copolymere acide mêthacrylique/mithacrylateA protective styling gel for the hair of the following composition is prepared: - 2-Hydroxy-4-methoxybenzophenone-5- '5 sulfonic acid sold under the name "ÜVINUL MS 40" by the company BASF 0.3 g - Methacrylic acid copolymer / mithacrylate
de méthyle 50/50 0,8 g MAmethyl 50/50 0.8 g MA
- Hydroxyëthylcellulose greffée par du chlorure 10 de diallyldiméthyl ammonium vendue par la société National STARCH sous la dénomination "CELQUAT L200" 0,8 g - Polymère cationique siliconé vendu par la société DOW CORNING sous la dénomination 15 "EMULSION CATIONIQUE DC 929" en solution- Hydroxyethylcellulose grafted with 10 diallyldimethyl ammonium chloride sold by the company National STARCH under the name "CELQUAT L200" 0.8 g - Cationic silicone polymer sold by the company DOW CORNING under the name 15 "CATIONIC EMULSION DC 929"
aqueuse à 35% de matière active (MA) 0,3 g MAaqueous at 35% active ingredient (MA) 0.3 g MA
- 2-amino-2-méthyl propan-l-ol qs pH : 7,5 - Alcool éthylique qs 10° - Parfum, colorant, conservateur qs 20 - Eau qsp 100 g- 2-amino-2-methyl propan-l-ol qs pH: 7.5 - Ethyl alcohol qs 10 ° - Perfume, color, preservative qs 20 - Water qs 100 g
On traite des cheveux décolorés, par trois applications avec ce gel de coiffage, puis, sans les rincer, on les soumet à 120 heures d'exposition au Suntest.Bleached hair is treated by three applications with this styling gel, then, without rinsing it, it is subjected to 120 hours of exposure to Suntest.
Comparativement à des cheveux de même nature, traités de la même 25 façon mais à l'aide dudit gel sans "UVINUL MS 40", on constate une amélioration significative de la valeur moyenne du palier à 15% d'extension au mouillé.Compared to hair of the same kind, treated in the same way but using said gel without "UVINUL MS 40", there is a significant improvement in the average value of the plateau at 15% wet extension.
30 13 EXEMPLE 430 13 EXAMPLE 4
On prépare le spray de coiffage de composition suivante : - Terpolymere acide crotonique/4-tert.butyl benzoate de vinyle/acétate de vinyle/ (10/25/65), préparé 5 suivant le brevet français n° 2 439 798 (ex. 19) 6 g - 2-amino-2 méthyl propan-l-ol qs pour neutralisation - Acide 2-hydroxy-4-mithoxybenzophénone-5-sulfonique vendu sous la dénomination "UVINUL MS 40" par la société BASF 1 g 10 - Parfum qs - Alcool éthylique qsp 100 gThe styling spray of the following composition is prepared: - Terpolymer crotonic acid / 4-tert.butyl vinyl benzoate / vinyl acetate / (10/25/65), prepared according to French Patent No. 2,439,798 (ex. 19) 6 g - 2-amino-2 methyl propan-l-ol qs for neutralization - 2-hydroxy-4-mithoxybenzophenone-5-sulfonic acid sold under the name "UVINUL MS 40" by BASF 1 g 10 - Perfume qs - Ethyl alcohol qs 100 g
On conditionne la composition ci-dessus dans un flacon pompe.The above composition is packaged in a pump bottle.
Une application de ce spray de coiffage sur des cheveux décolorés que l’on ne rince pas et que l'on soumet ensuite à 120 15 heures d'exposition au Suntest permet d'améliorer de façon très appréciable la valeur moyenne du palier à 15% d'extension au mouillé par rapport à des cheveux de même nature, ayant subi un traitement analogue à l'aide d'un spray de composition identique sans "UVINUL MS 40".An application of this styling spray to bleached hair which is not rinsed and which is then subjected to 120 15 hours of exposure to Suntest makes it possible to very appreciably improve the average value of the level at 15%. extension in the wet compared to hair of the same kind, having undergone a similar treatment using a spray of identical composition without "UVINUL MS 40".
2020
Claims (16)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU87130A LU87130A1 (en) | 1988-02-11 | 1988-02-11 | USE OF 2-HYDROXY-4-METHOBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THE SAME |
| AT0019489A ATA19489A (en) | 1988-02-11 | 1989-01-31 | USE OF 2-HYDROXY-4-METHOXYBENZOPHENONE-5-SULFONIC ACID AND METHOD FOR PROTECTING HAIR FROM LIGHT |
| CH444/89A CH678010A5 (en) | 1988-02-11 | 1989-02-09 | |
| FR8901704A FR2627085B1 (en) | 1988-02-11 | 1989-02-09 | USE OF 2-HYDROXY-4-METHOXYBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THIS COMPOUND |
| BE8900134A BE1003099A5 (en) | 1988-02-11 | 1989-02-10 | USE OF 2-HYDROXY-4-METHOXYBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THIS COMPOUND. |
| DE19893904054 DE3904054C2 (en) | 1988-02-11 | 1989-02-10 | Use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or salts thereof |
| JP1032572A JP2720884B2 (en) | 1988-02-11 | 1989-02-10 | Hair composition |
| IT8967073A IT1232710B (en) | 1988-02-11 | 1989-02-10 | USE OF 2 HYDROXY ACID 4 METHOXYBENZOFENON 5 SULPHONIC OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSION, IN PARTICULAR AGAINST LIGHT, AND PROCEDURE FOR THE PROTECTION OF HAIR USING SUCH COMPOUND |
| DE3943861A DE3943861B4 (en) | 1988-02-11 | 1989-02-10 | Use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts for reducing the decrease in elasticity of the hair in case of damage of the hair keratin by atmospheric agents |
| GB8903068A GB2215602B (en) | 1988-02-11 | 1989-02-10 | A process for protecting the hair using 2-hydroxy-4-methoxybenzophenone-5- sulphonic acid or a salt thereof |
| CA000590897A CA1341189C (en) | 1988-02-11 | 1989-02-13 | Use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts for the protection of hair against atmospheric agressions, and particularly against light, and process for hairprotection with this compound |
| US07/962,676 US5240695A (en) | 1988-02-11 | 1992-10-19 | Use of 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid or its salts for protecting the hair against environmental attacking agents, and especially against light and process for protecting the hair using the compound |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU87130 | 1988-02-11 | ||
| LU87130A LU87130A1 (en) | 1988-02-11 | 1988-02-11 | USE OF 2-HYDROXY-4-METHOBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THE SAME |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU87130A1 true LU87130A1 (en) | 1989-09-20 |
Family
ID=19731022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU87130A LU87130A1 (en) | 1988-02-11 | 1988-02-11 | USE OF 2-HYDROXY-4-METHOBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THE SAME |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JP2720884B2 (en) |
| AT (1) | ATA19489A (en) |
| BE (1) | BE1003099A5 (en) |
| CA (1) | CA1341189C (en) |
| CH (1) | CH678010A5 (en) |
| DE (1) | DE3943861B4 (en) |
| FR (1) | FR2627085B1 (en) |
| GB (1) | GB2215602B (en) |
| IT (1) | IT1232710B (en) |
| LU (1) | LU87130A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8903777D0 (en) * | 1989-02-20 | 1989-04-05 | Unilever Plc | Shampoo composition |
| US5186928A (en) * | 1989-02-20 | 1993-02-16 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Shampoo composition |
| US5045307A (en) * | 1990-01-09 | 1991-09-03 | Colgate-Palmolive Company | Composition that protects dyed hair from fading |
| DE69212254T2 (en) * | 1991-08-14 | 1996-12-19 | Kao Corp | Hair care products |
| JPH05286830A (en) * | 1992-04-10 | 1993-11-02 | Kao Corp | Hair treating agent composition |
| FR2719468B1 (en) * | 1994-05-05 | 1996-05-31 | Oreal | Cosmetic compositions based on certain bioflavonoids and uses in particular in the hair field. |
| FR2880801B1 (en) | 2005-01-18 | 2008-12-19 | Oreal | COMPOSITION FOR TREATING KERATIN FIBERS COMPRISING AROMATIC ALCOHOL, AROMATIC CARBOXYLIC ACID AND PROTECTIVE AGENT |
| US8790623B2 (en) | 2005-01-18 | 2014-07-29 | Il'Oreal | Composition for treating keratin fibers, comprising at least one aromatic alcohol, at least one aromatic carboxylic acid, and at least one protecting agent |
| FR2887440B1 (en) | 2005-06-28 | 2009-07-10 | Oreal | PROCESS FOR PHOTOPROTECTIVE TREATMENT OF KERATIN FIBERS BY HEAT APPLICATION |
| US7998464B2 (en) | 2005-09-29 | 2011-08-16 | L'oreal S.A. | Process for the photoprotective treatment of artificially dyed keratin fibers by application of a liquid water/steam mixture |
| FR2940068A1 (en) * | 2008-12-22 | 2010-06-25 | Oreal | Composition, useful for e.g. cleaning keratin materials, comprises anionic surfactants, carboxylic anionic surfactants, amphoteric and/or zwitterionic surfactants, alkyl(poly)glycoside nonionic surfactants, cationic polymers, and filters |
| FR2955255B1 (en) | 2010-01-15 | 2012-02-24 | Oreal | COSMETIC COMPOSITION COMPRISING A HYDROPHILIC GRAFT POLYSACCHARIDE AND COSMETIC TREATMENT METHOD |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3577528A (en) * | 1966-05-27 | 1971-05-04 | Zotos Int Inc | Two phase hair conditioner compositions |
| DE2046818A1 (en) * | 1970-09-23 | 1972-03-30 | Wella Ag, 6100 Darmstadt | Hair dyeing and setting preparations - contng benzimidazole benzophenone and phenylglyoxylic acid derivs |
| US3670074A (en) * | 1971-01-22 | 1972-06-13 | Cyril Doner | Sunscreen formulation containing triethanolamine neutralized 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid |
| FR2509989A1 (en) * | 1981-07-27 | 1983-01-28 | Oreal | Cosmetic contg. water soluble sunscreening agent - in aq. phase of water in oil dispersion |
| US4567038A (en) * | 1985-03-06 | 1986-01-28 | Revlon, Inc. | Sunscreen composition for hair protection |
-
1988
- 1988-02-11 LU LU87130A patent/LU87130A1/en unknown
-
1989
- 1989-01-31 AT AT0019489A patent/ATA19489A/en not_active Application Discontinuation
- 1989-02-09 CH CH444/89A patent/CH678010A5/fr not_active IP Right Cessation
- 1989-02-09 FR FR8901704A patent/FR2627085B1/en not_active Expired - Lifetime
- 1989-02-10 GB GB8903068A patent/GB2215602B/en not_active Expired - Lifetime
- 1989-02-10 BE BE8900134A patent/BE1003099A5/en not_active IP Right Cessation
- 1989-02-10 DE DE3943861A patent/DE3943861B4/en not_active Expired - Lifetime
- 1989-02-10 IT IT8967073A patent/IT1232710B/en active
- 1989-02-10 JP JP1032572A patent/JP2720884B2/en not_active Expired - Fee Related
- 1989-02-13 CA CA000590897A patent/CA1341189C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| GB8903068D0 (en) | 1989-03-30 |
| GB2215602B (en) | 1991-10-02 |
| DE3943861B4 (en) | 2013-08-08 |
| CH678010A5 (en) | 1991-07-31 |
| JP2720884B2 (en) | 1998-03-04 |
| FR2627085A1 (en) | 1989-08-18 |
| ATA19489A (en) | 1997-09-15 |
| FR2627085B1 (en) | 1994-10-28 |
| BE1003099A5 (en) | 1991-11-26 |
| IT1232710B (en) | 1992-03-04 |
| CA1341189C (en) | 2001-02-27 |
| IT8967073A0 (en) | 1989-02-10 |
| JPH01294613A (en) | 1989-11-28 |
| GB2215602A (en) | 1989-09-27 |
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