LU85279A1 - FUNGICIDAL COMPOSITION BASED ON ALUMINUM TRIS ETHYL PHOSPHONATE - Google Patents
FUNGICIDAL COMPOSITION BASED ON ALUMINUM TRIS ETHYL PHOSPHONATE Download PDFInfo
- Publication number
- LU85279A1 LU85279A1 LU85279A LU85279A LU85279A1 LU 85279 A1 LU85279 A1 LU 85279A1 LU 85279 A LU85279 A LU 85279A LU 85279 A LU85279 A LU 85279A LU 85279 A1 LU85279 A1 LU 85279A1
- Authority
- LU
- Luxembourg
- Prior art keywords
- phosethyl
- composition
- strong base
- composition according
- pages
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 23
- 230000000855 fungicidal effect Effects 0.000 title claims description 3
- 239000007983 Tris buffer Substances 0.000 title description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title description 2
- 229910052782 aluminium Inorganic materials 0.000 title description 2
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 title description 2
- OIPMQULDKWSNGX-UHFFFAOYSA-N bis[[ethoxy(oxo)phosphaniumyl]oxy]alumanyloxy-ethoxy-oxophosphanium Chemical compound [Al+3].CCO[P+]([O-])=O.CCO[P+]([O-])=O.CCO[P+]([O-])=O OIPMQULDKWSNGX-UHFFFAOYSA-N 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical group [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 5
- 239000001639 calcium acetate Substances 0.000 claims description 5
- 235000011092 calcium acetate Nutrition 0.000 claims description 5
- 229960005147 calcium acetate Drugs 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 4
- 208000031888 Mycoses Diseases 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical group [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims 1
- 239000000920 calcium hydroxide Substances 0.000 claims 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims 1
- 238000002347 injection Methods 0.000 description 7
- 239000007924 injection Substances 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 241000233866 Fungi Species 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000207199 Citrus Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000233614 Phytophthora Species 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- -1 phosphorous acid ester Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 244000025272 Persea americana Species 0.000 description 1
- 235000008673 Persea americana Nutrition 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 241000233618 Phytophthora cinnamomi Species 0.000 description 1
- 241001281803 Plasmopara viticola Species 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000009109 curative therapy Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- XRBGEQKKQIRUOE-UHFFFAOYSA-N dialuminum ethyl phosphite Chemical group [Al+3].[Al+3].CCOP([O-])[O-].CCOP([O-])[O-].CCOP([O-])[O-] XRBGEQKKQIRUOE-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 208000037921 secondary disease Diseases 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
I»I "
KK
La présente invention a pour objet de nouvelles compositions fongicides à base d'ester de l'acide phosphoreux ainsi qu'un procédé de lutte contre les maladies fongiques des plantes à l'aide de ces compositions.The present invention relates to new fungicidal compositions based on phosphorous acid ester and a method of combating fungal diseases of plants using these compositions.
5 Le brevet français 2 254 276 décrit des composi tions pour la lutte contre les maladies fongiques des * plantes contenant comme matière active» au moins un sel d'un acide alcoyl phosphoreux. Ces compositions sont efficaces contre de nombreux champignons phytophages tels 10 que les Phycomycètes notamment Plasmopara viticola et divers Phytophthora. En pratique» c'est 1 *éthylphosphite d'aluminium ou tris éthyl phosphonate d'aluminium ou encore Phosethyl-Al qui est utilisé commercialement sous forme d'une poudre mouillable en traitement par pulvérisation 15 foliaire. Si cette présentation est pleinement efficace dans ces conditions, notamment pour la protection de la vigne, son efficacité est plus longue à se manifester lorsqu'on l'applique curativement sur des cultures tropicales attaquées, souvent fortement, par des champignons du 20 type Phytophthora, comme Phytophthora cinnamomi, responsable de la pourriture de l'avocat ou des agrumes.French patent 2 254 276 describes compositions for the control of fungal diseases of plants containing as active ingredient at least one salt of an alkyl phosphorous acid. These compositions are effective against numerous phytophagous fungi such as Phycomycetes, notably Plasmopara viticola and various Phytophthora. In practice, it is aluminum ethyl phosphite or aluminum tris ethyl phosphonate or also Phosethyl-Al which is used commercially in the form of a wettable powder in treatment by foliar spraying. If this presentation is fully effective under these conditions, in particular for the protection of the vine, its effectiveness takes longer to manifest itself when it is applied curatively to tropical crops attacked, often strongly, by fungi of the Phytophthora type, like Phytophthora cinnamomi, responsible for avocado or citrus rot.
En effet, les quantités absorbées par un feuillage peu absorbant sont relativement faibles, insuffisantes quand on traite curativement des arbres déjà atteints. Cela 25 nécessite des applications plus nombreuses rendant le traitement prohibitif, de toute façon lent, voire insuffisant en raison de la gravité de l'attaque des champignons.In fact, the quantities absorbed by poorly absorbent foliage are relatively small, insufficient when curatively treating already affected trees. This requires more applications making the treatment prohibitive, in any case slow, or even insufficient due to the severity of the attack by the fungi.
» Il a maintenant été trouvé que ces maladies peuvent être efficacement combattues par application, notamment par 30 injection dans les troncs d'arbres d'une solution aqueuse stabilisée de phoséthyl-Al. Mais ceci pose un problème dans la mesure où cette matière active donne lieu, en milieu aqueux, à une hydrolyse diminuant sensiblement et progressivement sa concentration rendant impossible l'obtention de 35 compositions aqueuses concentrées stables dans le temps.It has now been found that these diseases can be effectively combated by application, in particular by injection into the tree trunks of a stabilized aqueous solution of phosethyl-Al. However, this poses a problem insofar as this active material gives rise, in an aqueous medium, to a hydrolysis which substantially and gradually decreases its concentration, making it impossible to obtain concentrated aqueous compositions which are stable over time.
/f /// Λ Ί 2 t L’invention concerne donc un procédé de stabilisation des solutions aqueuses de phoséthyl Al caractérisé en ce qu’on ajoute à la solution aqueuse de phoséthyl Al contenant, comme stabilisant, un sel hydrosoluble d’acide « 5 faible et de base forte. L’invention concerne également les solutions aqueuses de phoséthyl Al stabilisées par ce procédé. Comme acide faible, on entend un acide minéral comme les sels d’acide de l’acide phosphoreux ou phosphoni-" que mais de préférence organique, comme par exemple alipha- 10 tique comme l’acide acétique, propionique, butyrique, fumarique, oxalique, lactique, citrique ou encore un acide aminé comme l’acide éthylène diamine tétracétique./ f /// Λ Ί 2 t The invention therefore relates to a process for stabilizing aqueous solutions of phosethyl Al, characterized in that the aqueous solution of phosethyl Al containing, as stabilizer, a water-soluble salt of acid is added “ 5 weak and strong base. The invention also relates to aqueous solutions of phosethyl Al stabilized by this process. By weak acid is meant a mineral acid such as the acid salts of phosphorous or phosphonic acid but preferably organic, such as, for example, aliphatic such as acetic, propionic, butyric, fumaric, oxalic acid. , lactic, citric or an amino acid such as ethylene diamine tetracetic acid.
Comme base forte on peut utiliser une base organique, telle qu’une amine tertiaire ou de préférence minérale 15 comme les hydroxydes alcalins et alcalino terreux de préférence de bonne solubilité dans l’eau, comme la soude la potasse ou la chaux.As a strong base, an organic base can be used, such as a tertiary or preferably mineral amine such as alkali and alkaline earth hydroxides, preferably of good solubility in water, such as sodium hydroxide, potash or lime.
La quantité du stabilisant dépend de la nature de celui-ci et de la concentration du phoséthyl Al dans la 20 composition aqueuse. En effet, si le stabilisant est soit en quantité trop faible ou au contraire en quantité trop forte, la solution n’est pas limpide ce qui signifie que la solubilisation de la matière active est insuffisante avec pour conséquence une limitation correspondante de l’effica-25 cité. De manière surprenante on a de plus constaté que la quantité la plus appropriée n’est pas celle correspondant àThe amount of stabilizer depends on the nature of it and the concentration of phosethyl Al in the aqueous composition. In fact, if the stabilizer is either in too small an amount or, on the contrary, in too strong an amount, the solution is not clear, which means that the solubilization of the active material is insufficient with the consequence of a corresponding limitation of the efficacy. 25 cited. Surprisingly, we have also found that the most appropriate quantity is not that corresponding to
TT
la stoechiométrie. Par exemple, dans le cas de l’acétate de calcium une quantité environ moitié de la stoechiométrie donne une solution limpide stable alors que la dose double 30 donne lieu à un précipité.stoichiometry. For example, in the case of calcium acetate an amount about half of the stoichiometry gives a stable clear solution while the double dose 30 gives rise to a precipitate.
La composition aqueuse selon l’invention peut également contenir d’autre adjuvants hydrosolubles tels que agents tensio actifs bien que cela ne soit pas nécessaire pour les solutions injectables. Elle peut aussi contenir 35 certains oligo-éléments favorables a la croissance des * 1 3 arbres ou à la lutte contre les carences, tels que des sels de zinc, manganèse, fer, du bore en quantités appropriées.The aqueous composition according to the invention may also contain other water-soluble adjuvants such as surfactants, although this is not necessary for the injectable solutions. It may also contain certain trace elements which are favorable for the growth of trees or for combating deficiencies, such as zinc salts, manganese, iron, boron in appropriate quantities.
Le phoséthyl-Al est présent dans les compositions selon l'invention à une concentration généralement comprise « 5 entre 1 et 120 g/1 et de préférence entre 10 et 110 g/1.Phosethyl-Al is present in the compositions according to the invention at a concentration generally of “5 between 1 and 120 g / 1 and preferably between 10 and 110 g / 1.
Cette solution peut être appliquée par tout traitement approprié tel que pulvérisation foliaire, trempage des racines. On a obtenu d'excellents résultats par injection dans le tronc d'arbres malades comme par exemple des avoca-10 tiers, mais le procédé est applicable a d'autres arbres telles que agrumes ou encore hévéa ou cacao. Le traitement se fait en pratiquant d'abord des trous répartis dans le tronc de l'arbre.This solution can be applied by any suitable treatment such as foliar spray, soaking of the roots. Excellent results have been obtained by injection into the trunk of diseased trees such as, for example, avocado-thirds, but the process is applicable to other trees such as citrus or even rubber or cocoa. The treatment is done by first making holes distributed in the trunk of the tree.
Dans une seconde étape, on injecte dans les trous, 15 par tout dispositif adéquat, avec ou sans mise sous pression, une quantité définie de la solution aqueuse .2 utilisée de Phoséthyl-Al qui peut varier de 0,1 à 5 g/m de sol couvert par le feuillage.In a second step, a defined quantity of the aqueous solution .2 used of Phosethyl-Al which can vary from 0.1 to 5 g / m 2 is injected into the holes, by any suitable device, with or without pressurization. of soil covered by foliage.
L'absorption du liquide se fait lentement, le 20 liquide étant maintenu de préférence sous pression dans l'appareil d'injection. Quand l'injection est terminée, il peut être souhaitable de boucher le ou les trous à l'aide d'un matériau non agressif vis à vis du tissu végétal, comme par exemple une cire qui peut contenir des adjuvants 25 tels que désinfectants pour réduire le risque d'introduction de maladies secondaires. Le nombre de traitement est ' très limité, en particulier par rapport au nombre d'inter ventions nécessaires avec la pulvérisation foliaire. Par exemple, la première année, sur un arbre bien atteint, un 30 traitement curatif efficace est obtenu avec deux injections, les années suivantes, un traitement une fois par an suffisant au maintien de l'arbre sain ou en voie de guérison. L’efficacité du traitement est remarquable, des arbres gravement atteints pouvant être guéris en 2 ans, ce qui est 35 surprenant, quand on sait que d'autres fongicides systémi- i ., 4 ques normalement actifs sur ces champignons sont inefficaces en injection dans les mêmes conditions.The absorption of the liquid takes place slowly, the liquid preferably being kept under pressure in the injection apparatus. When the injection is complete, it may be desirable to plug the hole (s) with a material which is not aggressive towards the plant tissue, such as for example a wax which may contain adjuvants such as disinfectants to reduce the risk of introduction of secondary diseases. The number of treatments is very limited, in particular compared to the number of interventions necessary with foliar spraying. For example, in the first year, on a well-affected tree, an effective curative treatment is obtained with two injections, in the following years, treatment once a year sufficient to keep the tree healthy or recovering. The effectiveness of the treatment is remarkable, severely affected trees can be cured in 2 years, which is surprising, when it is known that other systemic fungicides which are normally active on these fungi are ineffective in injection into the same conditions.
Les exemples suivants illustrent la préparation d’une composition selon l’invention et son application par 5 injection dans les troncs d'arbres malades.The following examples illustrate the preparation of a composition according to the invention and its application by injection into the trunks of diseased trees.
Exemple 1:Example 1:
On prépare, par dissolution successive dans l'eau, de Phoséthyl-Al et le cas échéant d'acétate de calcium les trois compositions pondérales suivantes s 10 Invention Témoin 1 2The following three weight compositions are prepared by successive dissolution in water of Phosethyl-Al and, where appropriate, of calcium acetate.
Phoséthyl-ΆΙ technique à 98 % ...... 102 ... 102 .. 10298% technical phosethyl-... ...... 102 ... 102 .. 102
Acétate de calcium ................. - .... 33 ... 67Calcium acetate ................. - .... 33 ... 67
Eau ... qsp .. 1 litre ............. 898 ... 865 .. 831 15Water ... qsp .. 1 liter ............. 898 ... 865 .. 831 15
Les quantités d’acétate ajoutées correspondent respectivement à la moitié de la quantité stoechiométrique pour la composition 1 et à la totalité de cette quantité stoechiométrique pour la composition 2, 20 Les trois solutions sont soumises à un test de stabilité pendant 1 mois à 50°C, au bout duquel on évalue la dégradation relative du Phoséthyl-Al et l'aspect de la solution. Les résultats sont consignés dans le tableau suivant : 25The amounts of acetate added correspond respectively to half of the stoichiometric amount for composition 1 and to all of this stoichiometric amount for composition 2, The three solutions are subjected to a stability test for 1 month at 50 ° C. , at the end of which the relative degradation of Phosethyl-Al and the appearance of the solution are evaluated. The results are recorded in the following table: 25
. Critère d’évaluation 1 I Invention I. Assessment criterion 1 I Invention I
au bout de 1 mois à 50°C | Témoin 11 21after 1 month at 50 ° C | Witness 11 21
Dégradation relative I I IRelative degradation I I I
30 du Phoséthyl-Al I 100 % I 12 % 12 % I30 Phosethyl-Al I 100% I 12% 12% I
___!_*____!_L___! _ * ____! _ L
Aspect de la solution I I IAspect of the solution I I I
(initialement limpide) I précipité | limpide précipitél(initially clear) I precipitated | clear precipitated
__________________I___________1_________L__________________I___________1_________L
35 -, -* 535 -, - * 5
Ce tableau montre clairement que» au bout de 1 mois a 50°C : - dans la solution témoin, le phoséthyl-Al est complètement dégradé et que la solution précipite. Cette solution n'est * 5 donc ni stable» ni limpide ; - dans les solutions 1 et 2 selon l'invention, la dégradation du phoséthyl-Al est limitée de manière acceptable ; de plus, alors que la solution 2 donne lieu à un léger précipité, la solution 1 est limpide. Donc seule la solution 1 10 est pleinement satisfaisante.This table clearly shows that "after 1 month at 50 ° C.: - in the control solution, the phosethyl-Al is completely degraded and the solution precipitates. This solution is * 5 therefore neither stable nor clear; - In solutions 1 and 2 according to the invention, the degradation of phosethyl-Al is limited in an acceptable manner; moreover, while solution 2 gives rise to a slight precipitate, solution 1 is clear. So only solution 1 10 is fully satisfactory.
Exemple 2 :Example 2:
On prépare deux compositions par dilution respectivement une fois et deux fois de la composition 1 obtenue à l'exemple 1. On obtient ainsi des compositions contenant 15 respectivement 51 et 20,5 grammes de phoséthyl Al à 98 % et 16,5 et 8,25 grammes d'acétate de calcium.Two compositions are prepared by diluting respectively once and twice of the composition 1 obtained in Example 1. This gives compositions containing 15 respectively 51 and 20.5 grams of 98% phosethyl Al and 16.5 and 8, 25 grams of calcium acetate.
•4 la• 4 la
Claims (8)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8305562 | 1983-03-31 | ||
| FR8305562A FR2543405B1 (en) | 1983-03-31 | 1983-03-31 | FUNGICIDAL COMPOSITION BASED ON ALUMINUM TRIS ETHYL PHOSPHONATE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU85279A1 true LU85279A1 (en) | 1985-10-14 |
Family
ID=9287542
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU85279A LU85279A1 (en) | 1983-03-31 | 1984-03-30 | FUNGICIDAL COMPOSITION BASED ON ALUMINUM TRIS ETHYL PHOSPHONATE |
Country Status (22)
| Country | Link |
|---|---|
| JP (1) | JPS59184112A (en) |
| AU (1) | AU562117B2 (en) |
| BE (1) | BE899299A (en) |
| BR (1) | BR8401472A (en) |
| CH (1) | CH660282A5 (en) |
| DE (1) | DE3410011A1 (en) |
| ES (1) | ES8504434A1 (en) |
| FR (1) | FR2543405B1 (en) |
| GB (1) | GB2137498B (en) |
| GR (1) | GR79874B (en) |
| HK (1) | HK25790A (en) |
| HU (1) | HU194707B (en) |
| IL (1) | IL71368A (en) |
| IT (1) | IT1179361B (en) |
| KE (1) | KE3891A (en) |
| LU (1) | LU85279A1 (en) |
| MA (1) | MA20074A1 (en) |
| NL (1) | NL8400974A (en) |
| OA (1) | OA07694A (en) |
| PT (1) | PT78349B (en) |
| SG (1) | SG37389G (en) |
| ZA (1) | ZA842365B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2569530B1 (en) * | 1984-08-29 | 1986-09-05 | Rhone Poulenc Agrochimie | FUNGICIDAL COMPOSITION BASED ON ALUMINUM TRIS ETHYL PHOSPHONATE |
| US4935410A (en) * | 1983-03-31 | 1990-06-19 | Rhone-Poulenc Agrochimie S.A. | Fungicidal aluminum tris-alkyl-phosphonate composition |
| JPH0617288B2 (en) * | 1986-05-07 | 1994-03-09 | クミアイ化学工業株式会社 | Agro-horticultural wettable powder composition |
| JP2840847B2 (en) * | 1989-01-23 | 1998-12-24 | ローヌ・プーランアグロ株式会社 | Stabilized pesticide composition |
| DE4142974C2 (en) * | 1991-12-24 | 1996-05-30 | Alexander Burkhart Gross Und E | Fungicidal compositions |
| FR2738112B1 (en) * | 1995-09-05 | 1997-09-26 | Rhone Poulenc Agrochimie | METHOD FOR IMPROVING BANANA FRUIT YIELDS |
| WO1999004630A1 (en) * | 1997-07-21 | 1999-02-04 | Rhone-Poulenc Agro | Agrochemical composition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2112136A6 (en) * | 1970-11-06 | 1972-06-16 | Dynachim Sarl | Pesticidal organophosphorus compositions - stabilized with aminoacid salts |
| FR2254276B1 (en) * | 1973-12-14 | 1977-03-04 | Philagro Sa | |
| FR2377155A1 (en) * | 1977-01-14 | 1978-08-11 | Philagro Sa | FUNGICIDE COMPOSITIONS BASED ON ALCOYLPHOSPHITES |
| IT7824613A0 (en) * | 1977-06-17 | 1978-06-15 | Shell Int Research | PROCESS FOR THE STABILIZATION OF OXYMIC DICARBAMATES. |
| EP0038778A3 (en) * | 1980-04-21 | 1981-11-25 | Ciba-Geigy Ag | Alkyl phosphonites, process for their preparation and the use of alkyl phosphonites as fungicides |
| US4382091A (en) * | 1981-04-30 | 1983-05-03 | Syntex (U.S.A.) Inc. | Stabilization of 1-substituted imidazole derivatives in talc |
| CA1173748A (en) * | 1981-05-21 | 1984-09-04 | Robert G. Eagar, Jr. | Dialdehyde containing compositions |
-
1983
- 1983-03-31 FR FR8305562A patent/FR2543405B1/en not_active Expired
-
1984
- 1984-03-19 DE DE19843410011 patent/DE3410011A1/en active Granted
- 1984-03-27 IL IL71368A patent/IL71368A/en unknown
- 1984-03-28 JP JP59060523A patent/JPS59184112A/en active Granted
- 1984-03-28 NL NL8400974A patent/NL8400974A/en not_active Application Discontinuation
- 1984-03-28 GR GR74240A patent/GR79874B/el unknown
- 1984-03-29 GB GB08408138A patent/GB2137498B/en not_active Expired
- 1984-03-29 IT IT47965/84A patent/IT1179361B/en active
- 1984-03-29 MA MA20296A patent/MA20074A1/en unknown
- 1984-03-29 AU AU26239/84A patent/AU562117B2/en not_active Ceased
- 1984-03-29 ZA ZA842365A patent/ZA842365B/en unknown
- 1984-03-30 CH CH1632/84A patent/CH660282A5/en not_active IP Right Cessation
- 1984-03-30 BR BR8401472A patent/BR8401472A/en not_active IP Right Cessation
- 1984-03-30 PT PT78349A patent/PT78349B/en not_active IP Right Cessation
- 1984-03-30 BE BE0/212672A patent/BE899299A/en not_active IP Right Cessation
- 1984-03-30 ES ES531128A patent/ES8504434A1/en not_active Expired
- 1984-03-30 HU HU841289A patent/HU194707B/en not_active IP Right Cessation
- 1984-03-30 LU LU85279A patent/LU85279A1/en unknown
- 1984-03-30 OA OA58269A patent/OA07694A/en unknown
-
1989
- 1989-06-14 SG SG373/89A patent/SG37389G/en unknown
- 1989-06-21 KE KE3891A patent/KE3891A/en unknown
-
1990
- 1990-04-04 HK HK257/90A patent/HK25790A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH660282A5 (en) | 1987-04-15 |
| IT8447965A0 (en) | 1984-03-29 |
| ES531128A0 (en) | 1985-04-16 |
| OA07694A (en) | 1985-05-23 |
| AU2623984A (en) | 1984-10-04 |
| IT1179361B (en) | 1987-09-16 |
| PT78349A (en) | 1984-04-01 |
| ES8504434A1 (en) | 1985-04-16 |
| KE3891A (en) | 1989-09-01 |
| JPH0573721B2 (en) | 1993-10-15 |
| ZA842365B (en) | 1984-12-24 |
| HUT36685A (en) | 1985-10-28 |
| NL8400974A (en) | 1984-10-16 |
| GR79874B (en) | 1984-10-31 |
| IL71368A (en) | 1987-09-16 |
| IT8447965A1 (en) | 1985-09-29 |
| MA20074A1 (en) | 1984-10-01 |
| FR2543405B1 (en) | 1986-01-03 |
| FR2543405A1 (en) | 1984-10-05 |
| HK25790A (en) | 1990-04-12 |
| BR8401472A (en) | 1984-11-06 |
| IL71368A0 (en) | 1984-06-29 |
| DE3410011C2 (en) | 1993-01-28 |
| GB2137498A (en) | 1984-10-10 |
| GB8408138D0 (en) | 1984-05-10 |
| BE899299A (en) | 1984-10-01 |
| GB2137498B (en) | 1986-07-09 |
| HU194707B (en) | 1988-03-28 |
| JPS59184112A (en) | 1984-10-19 |
| SG37389G (en) | 1989-10-13 |
| DE3410011A1 (en) | 1984-10-04 |
| PT78349B (en) | 1986-07-22 |
| AU562117B2 (en) | 1987-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6024986A (en) | Method of protecting growing plants from the effects of plant pathogens | |
| ES2732553T3 (en) | New procedure for treating pre-harvest or post-harvest vegetable products with phosphonic acid and an essential oil | |
| CA2183995A1 (en) | Plant protection using fish oil | |
| LU85279A1 (en) | FUNGICIDAL COMPOSITION BASED ON ALUMINUM TRIS ETHYL PHOSPHONATE | |
| FR2569530A1 (en) | FUNGICIDE COMPOSITION BASED ON TRIS ETHYL PHOSPHONATE ALUMINUM | |
| US4935410A (en) | Fungicidal aluminum tris-alkyl-phosphonate composition | |
| BG62835B1 (en) | Two- and three-component fungicidal mixtures | |
| CA2285649C (en) | Synergetic fungicide composition | |
| FR2530416A1 (en) | IMPROVED METHOD FOR COMBATTING FUNGICIDAL MYCETES AND COMBINATIONS USED THEREIN | |
| FR2955741A1 (en) | HERBICIDE COMPOSITION AND USES | |
| FR2867026A1 (en) | Low toxicity plant fungicide compositions, useful e.g. for controlling mildew in vines, comprising phosphite and essential vegetable oil(s) | |
| JP2002505659A (en) | Herbicide formulations and methods for controlling plants | |
| DE2203228A1 (en) | Fungicidal compositions for use in agriculture and horticulture | |
| RU2804372C2 (en) | Sustainable environmentally friendly fertilizer designed to combat pests and physiological disorders of fruit | |
| KR102608329B1 (en) | Control composition for bryophytes | |
| JPH03279305A (en) | Inhibitor of formation of pollen of needle-leaf tree such as tree of taxodiaceae or cupressaceae | |
| KR20030069973A (en) | Application of hydrogen peroxide generating agent for clean crop production | |
| WO1995028840A1 (en) | Hydrogen peroxide composition formulated for the preventive and curative treatment of diseases affecting the foliage and aerial parts of plants | |
| JP2006076920A (en) | Moss controlling agent for turf | |
| JPH0733603A (en) | Cut flower vitality retainer and method for retaining cut flower vitality | |
| US5224981A (en) | Methods and compositions for treating plants exposed to salt | |
| JPH08268819A (en) | Agent for preventing spreading of blossom blight (hypha) of apple tree, fungicide and its use | |
| CA2139825A1 (en) | Fungicide | |
| GB2218907A (en) | Combatting brown plant hopper eggs | |
| FR2488490A1 (en) | Control of growth of mono- and di-cotyledonous weeds - by post=emergence application of asulam with low doses of paraquat |