LT6131B - Installation for sewage sludge recovery and recycling into ecological products - Google Patents
Installation for sewage sludge recovery and recycling into ecological products Download PDFInfo
- Publication number
- LT6131B LT6131B LT2013073A LT2013073A LT6131B LT 6131 B LT6131 B LT 6131B LT 2013073 A LT2013073 A LT 2013073A LT 2013073 A LT2013073 A LT 2013073A LT 6131 B LT6131 B LT 6131B
- Authority
- LT
- Lithuania
- Prior art keywords
- sewage sludge
- combustion chamber
- combustion
- recycling
- burner
- Prior art date
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
- F23G5/0276—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/04—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment drying
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
- F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/44—Details; Accessories
- F23G5/46—Recuperation of heat
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/001—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals for sludges or waste products from water treatment installations
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/10—Drying by heat
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/30—Pyrolysing
- F23G2201/303—Burning pyrogases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/40—Gasification
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2204/00—Supplementary heating arrangements
- F23G2204/20—Supplementary heating arrangements using electric energy
- F23G2204/201—Plasma
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2205/00—Waste feed arrangements
- F23G2205/12—Waste feed arrangements using conveyors
- F23G2205/121—Screw conveyor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2206/00—Waste heat recuperation
- F23G2206/10—Waste heat recuperation reintroducing the heat in the same process, e.g. for predrying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2206/00—Waste heat recuperation
- F23G2206/20—Waste heat recuperation using the heat in association with another installation
- F23G2206/202—Waste heat recuperation using the heat in association with another installation with an internal combustion engine
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/12—Heat utilisation in combustion or incineration of waste
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Gasification And Melting Of Waste (AREA)
- Treatment Of Sludge (AREA)
Abstract
Description
Išradimas priklauso nuotekų dumblo utilizavimo - perdirbimo sričiai ir gali būti panaudotas šilumos ir elektros energijos gamybai.The invention relates to the field of utilization and recycling of sewage sludge and can be used for the production of heat and electricity.
Žinomas artimiausias pareikštam techniniam sprendimui išradimas, aprašytas RU patente Nr. 2182884, TPKK: F 23 G 5/027, F 23 G 7/00, publ. 2002, skirtas utilizuoti organines, buitines ir komunalines, atliekas, sudarytas iš utilizuojamų medžiagų priėmimo bunkerio, transportavimo priemonės, pirolizės reaktoriaus su reakcine kamera, dujų paskirstymo sistemos, degimo kameros su degikliu, įrengtos apatinėje pirolizės reaktoriaus dalyje, ir pelenų surinkimo talpos. Pirolizės reaktorių kaitina deginant dujų mišinį, sudarytą iš paduodamo oro ir grįžtamųjų dujų, išsiskyrusių pirolizės metu.The closest known invention to the technical solution disclosed in RU patent no. 2182884, TPKK: F 23 G 5/027, F 23 G 7/00, publ. 2002 for the disposal of organic, municipal and municipal waste consisting of a recovery hopper, conveyor, pyrolysis reactor with reaction chamber, gas distribution systems, combustion chamber at the bottom of the pyrolysis reactor, and ash collection vessel. The pyrolysis reactor is heated by combustion of a gas mixture consisting of feed air and recycle gas released during pyrolysis.
Žinomas techninis sprendimas nesudaro sąlygų pasiekti efektyvaus utilizavimo proceso dėl nepakankamai aukštos kaitros temperatūros. Be to, žinomo techninio sprendimo funkcinės galimybės yra ribotos.A well-known technical solution does not allow an efficient recovery process to be achieved due to insufficient heating temperature. In addition, the functional capabilities of a known technical solution are limited.
Išradimo tikslas - užtikrinti ekologišką ir efektyvų utilizavimo - perdirbimo procesą, pakeliant kaitros temperatūrą, ir išplėsti funkcines galimybes, panaudojant utilizavimo metu gautus ekologiškus produktus.The purpose of the invention is to ensure an ecological and efficient recovery - recycling process by raising the heating temperature and to extend the functional possibilities by utilizing the ecological products obtained during the utilization.
Išradimas iliustruojamas brėžiniu, kuriame pavaizduota nuotekų dumblo utilizavimo - perdirbimo į ekologišką produkciją įrenginio principinė schema, kur 1 metalinis indas nuotekų dumblo užkrovimui, 2 - pirmoji degimo kamera, 3 - nuotekų dumblo deginimo katilas, 4 - nuotekų dumblo transportavimo sraigtinis transporteris, 5 - elektros variklis, 6 - antroji degimo kamera, 7 - kietųjų dalelių surinktuvas, 8 filtras, 9 - biodujų surinktuvas, 10 -'elektros generatorius, 11 - pagrindinis dujinis degiklis, 12 - erdvinės kanalinės patenkančio oro iš aplinkos pakaitinimo grotelės, 13 - universalus plazminis-dujinis degiklis, 14 - plazminis šaltinis ir dujų talpa, 15 pelenų tiektuvas su sraigtiniu transporteriu ir elektriniu varikliu 17, 16 - pelenų surinkimo dėžė, 17 - elektros variklis, 18 - dūmtraukis, 19 - dūmtraukio traukos reguliatorius, 20 - elektros maitinimo linija.The invention is illustrated in the drawing, which shows a schematic diagram of a sewage sludge utilization - recycling plant into organic production, where 1 metal vessel for sewage sludge loading, 2 - first combustion chamber, 3 - sewage sludge burning boiler, 4 - sewage sludge transport screw conveyor, 5 - electric engine, 6 - Second combustion chamber, 7 - Particle collector, 8 filter, 9 - Biogas collector, 10 - Power generator, 11 - Main gas burner, 12 - Spatial duct for supply air from the heating grate, 13 - Universal plasma- gas burner, 14 - plasma source and gas tank, 15 ash feeder with screw conveyor and electric motor 17, 16 - ash bin, 17 - electric motor, 18 - chimney, 19 - chimney draft regulator, 20 - power supply line.
Nuotekų dumblo užkrovimui skirtas metalinis indas 1, o nuotekų dumblo transportavimui bei padavimui j pirmojoje degimo kameroje 2 įtaisytą nuotekų dumblo deginimo katilą 3 įrengtas sraigtinis transporteris 4, varomas elektrine pavara, kurios mechaninės energijos šaltinis yra elektrinis variklis 5. Kad iš nuotekų dumblo, transportuojant jį sraigtiniu transporteriu 4, įtaisytu antroje degimo kameroje 6, atskirti kietąsias daleles, po sraigtiniu transporteriu 4 įrengtas kietųjų dalelių surinktuvas 7 ir, kad atskirti smulkesnes nepageidaujamas priemaišas, Įtaisytas filtras 8. Biodujų, gautų deginant nuotekų dumblą, surinkimui įrengtas biodujų surinktuvas 9, sujungtas su tiekimo linija, tiekiančia biodujas kaip degalus vidaus degimo varikliui (brėžinyje neparodyta), su kuriuo sujungtas elektros generatorius 10. Pirmojoje degimo kameroje 2 deginant kietąjį kurą susidariusių degių dujų sudeginimui antrojoje degimo kameroje 6 sumontuotas pagrindinis dujinis degiklis 11. Patenkančio oro iš aplinkos į degiklį 11 pakaitinimui įrengtos erdvinės kanalinės paduodamo oro pakaitinimo grotelės 12. Be pagrindinio dujinio degiklio 11 antroje degimo kameroje 2 papildomai įrengtas universalus plazminis-dujinis degiklis 13, sujungtas su plazminiu šaltiniu ir dujų talpa 14. Plazminio-dujinio degiklio 13 įjungimas būtų reikalingas tuo atveju, jeigu neveiktų pagrindinis dujinis degiklis 11. Susidariusių pelenų, deginant nuotekų dumblą, transportavimui iš pelenų tiektuvo 15 į pelenų surinkimo dėžę 16 pelenų tiektuve 15 įtaisytas sraigtinis transporteris, varomas elektrine pavara, kurios mechaninės energijos šaltinis yra elektros variklis 17. Be to, pelenų surinkimo dėžėje 16 įtaisyti pelenų filtravimo elementai, (brėžinyje neparodyta). Degimo produktų pašalinimui ir išmetimui į aplinką įrengtas dūmtraukis 18 su traukos reguliatoriumi 19. Įrenginys prijungtas prie elektros maitinimo linijos 20. Nuotekų dumblo utilizavimo -perdirbimo į ekologišką produkciją procesas automatizuotas.A metal vessel 1 is used for loading sewage sludge and a screw conveyor 4 is provided for transporting and supplying sewage sludge to the sewage sludge boiler 3 in the first combustion chamber 2, which is driven by an electric drive powered by an electric motor 5. To transport it from sewage sludge a screw conveyor 4 located in the second combustion chamber 6 for separating particulates, a particulate trap 7 located beneath the screw conveyor 4, and a biogas hopper 9 for collecting biogas obtained from the incineration of sewage sludge and for separating the minor undesirable impurities a supply line supplying biogas as fuel for an internal combustion engine (not shown), to which an electrical generator is connected burner 11. For heating the incoming air from the ambient to the burner 11, there is provided a spatial ducted supply air heating grate 12. In addition to the main gas burner 11, the second combustion chamber 2 is additionally equipped with a universal plasma gas burner 13 connected to a plasma source and gas vessel 14. activation of the burner 13 would be required if the main gas burner 11 was not in operation. The ash from the ash feeder 15 to the ash bin 15 was transported in an ash feeder 15 with an electric drive powered by an electric motor. 17. In addition, the ash collection box 16 is equipped with ash filtering elements (not shown). Chimney 18 with draft regulator 19 is installed for removal and disposal of combustion products.
Įrenginys veikia sekančiai.The unit operates as follows.
Pirmiausia į metalinį indą 1 užkrauna nuotekų dumblą. Po to jį iš metalinio indo 1 sraigtiniu transporteriu 4 transportuoja į pirmąją degimo kamerą 2 per antrąją degimo kamerą 6. Transportuojamas nuotekų dumblas džiūsta ir išdžiuvęs patenka į nuotekų dumblo deginimo katilą 3, įrengtą pirmojoje degimo kameroje 2. Nuotekų dumblas, transportuojamas sraigtiniu transporteriu 4 ne tik džiūsta, bet ir išsivalo nuo kietųjų dalelių ir kitų smulkesnių nepageidaujamų priemaišų. Kietąsias daleles surenka surinktuvas 7, o smulkesnių priemaišų nepraleidžia filtras 8. Deginant kietąjį kurą gautos degios dujos pirmoje degimo kameroje 2 patenka į pagrindinį dujinį degiklį 11. Taip pat į pagrindinį degiklį 11 patenka oras iš aplinkos, kuris įkaista nuo įkaitusių erdvinių kanalinių oro pakaitinimo grotelių 12. Pagrindiniame degiklyje 11 susidaręs degus dujų mišinys dega aukštoje temperatūroje, siekiančioje net 2800 °C. Nuo susidariusios kaitros įkaista nuotekų dumblo deginimo katilas 3 su nuotekų dumblu. Tokiu būdu vyksta nuotekų dumblo terminis apdorojimas, kurio metu išsiskiria biodujos. Biodujas iš nuotekų dumblo deginimo katilo 3 surenka biodujų surinktuvas 9, kuris tiekimo linija jas kaip degalus tiekia vidaus degimo varikliui.First, sewage sludge is loaded into the metal vessel 1. It is then transported from the metal vessel 1 by screw conveyor 4 to the first combustion chamber 2 via the second combustion chamber 6. The transported sewage sludge dries and dries and enters the sewage sludge combustion boiler 3 located in the first combustion chamber 2. The sewage sludge transported by the screw conveyor 4 not only dries but also removes particulate matter and other minor impurities. The particulates are collected by the hopper 7 and the finer impurities are prevented by the filter 8. The combustible gas from the combustion of solid fuels in the first combustion chamber 2 enters the main gas burner 11. Also, the main burner 11 enters air from the heated 12. The flammable gas mixture formed in the main burner 11 burns at a high temperature up to 2800 ° C. Sewage sludge combustion boiler 3 with sewage sludge heats up from the resulting heat. In this way the heat treatment of sewage sludge takes place, whereby biogas is released. Biogas from the sewage sludge combustion boiler 3 is collected by a biogas collector 9, which feeds it as fuel to the internal combustion engine.
(brėžinyje neparodyta), kuris veikdamas suka elektros generatorių 18. Tokiu būdu mechaninę energiją paverčia elektrine. Sutrikus pagrindinio dujinio degiklio 11 darbui, įsijungia universalus plazminis-dujinis degiklis 13. Pelenus iš pelenų tiektuvo 15 išstumia sraigtinis transporteris ir paduoda į pelenų surinkimo dėžę 16. Nuotekų dumblo utilizavimas vyksta pagal proceso valdymo programą.(not shown in the drawing), which in turn drives an electric generator 18. In this way, mechanical energy is converted into electrical power. In the event of malfunction of the main gas burner 11, the universal plasma gas burner 13 is activated. The ash from the ash feeder 15 is pushed out by the screw conveyor and fed to the ash bin 16. The disposal of sewage sludge takes place according to a process control program.
Pareikšto išradimo svarbus privalumas tas, kad nuotekų dumblo utilizavimo perdirbimo j ekologišką produkciją įrenginys užtikrina ekonomišką, ekologišką ir efektyvų procesą. Ypač proceso efektyvumui įtakoja aukšta kaitros temperatūra, susidariusi degant degiam dujų mišiniui aukštoje (apie 2800 °C) temperatūroje. Utilizavimo proceso metu susidarę tokie produktai, kaip pelenai, biodujos, yra ekologiški ir tinkami tolimesniam panaudojimui. Būtent, pareikštu techniniu sprendimu išspręstas išsiskyrusių biodujų kaip degalų panaudojimas, sudarantis galimybę nesudėtingai, nereikalaujant papildomų išlaidų gauti pigią elektros energiją ir tenkinti vartotojų poreikius. Kadangi biodujos pagal šiluminę vertę nežymiai nusileidžia gamtinėms dujoms, jos gali būti panaudotos ir šilumos energijai gauti.An important advantage of the present invention is that the unit for recycling sewage sludge into organic production provides an economical, environmentally friendly and efficient process. Particularly the efficiency of the process is influenced by the high heat of combustion resulting from the combustion of the flammable gas mixture at high temperatures (about 2800 ° C). Products such as ash and biogas from the disposal process are environmentally friendly and suitable for further use. Namely, the claimed technical solution solves the use of the separated biogas as a fuel, which enables easy access to cheap electricity and meeting the needs of consumers without any additional costs. Because biogas has a low calorific value compared to natural gas, it can also be used to generate thermal energy.
Claims (3)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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LT2013073A LT6131B (en) | 2013-07-11 | 2013-07-11 | Installation for sewage sludge recovery and recycling into ecological products |
PCT/LT2014/000007 WO2015005755A1 (en) | 2013-07-11 | 2014-06-04 | Installation for sewage sludge recovery and recycling into ecological products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LT2013073A LT6131B (en) | 2013-07-11 | 2013-07-11 | Installation for sewage sludge recovery and recycling into ecological products |
Publications (2)
Publication Number | Publication Date |
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LT2013073A LT2013073A (en) | 2015-01-26 |
LT6131B true LT6131B (en) | 2015-03-25 |
Family
ID=51228465
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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LT2013073A LT6131B (en) | 2013-07-11 | 2013-07-11 | Installation for sewage sludge recovery and recycling into ecological products |
Country Status (2)
Country | Link |
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LT (1) | LT6131B (en) |
WO (1) | WO2015005755A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106082571A (en) * | 2016-08-04 | 2016-11-09 | 山东奥特高科环保科技有限公司 | Low heat value mud three change processes technique and device |
CN106594744B (en) * | 2017-01-13 | 2019-05-07 | 安徽未名鼎和环保有限公司 | A kind of incinerator for rubbish processing to be harmless |
CN109534653A (en) * | 2018-12-29 | 2019-03-29 | 重庆盎瑞悦科技有限公司 | A kind of front end sludge drying system in solid waste Thermal desorption accumulation of heat burning disposal |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2182884C1 (en) | 2000-11-16 | 2002-05-27 | Оао "Аммофос" | Method of treatment of wet-processing phosphoric acid used for production of liquid complex fertilizers |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2356294A1 (en) * | 1973-11-10 | 1975-05-15 | Air Preheater | Refuse incinerator with gasifier and burner - prevents oxidation of metallic refuse and uses afterburner heat for oxidation |
EP0360052B1 (en) * | 1988-09-05 | 1992-07-29 | Siemens Aktiengesellschaft | Pyrolysis reactor for the thermal disposal of waste |
DE4327953A1 (en) * | 1993-08-19 | 1995-02-23 | Siemens Ag | Plant for thermal waste disposal and method for operating such a plant |
DE19706757A1 (en) * | 1997-02-20 | 1998-09-03 | Siemens Ag | Thermic refuse processing plant |
CA2237414C (en) * | 1998-05-11 | 2004-10-19 | Hydro-Quebec | Treatment of moist residue containing pollutant and/or toxic substances |
AT408270B (en) * | 1999-12-27 | 2001-10-25 | Vogt Myrtha | COMBUSTION PLANT |
GB2359874B (en) * | 2000-02-29 | 2003-12-31 | Andrew William Webster | Gasification auger |
FR2810312A1 (en) * | 2000-06-16 | 2001-12-21 | Etienne Sennesael | System recovering heat and generating electricity from sludge recirculates charge with steel balls in screw conveyors equipped for drying, oxidation and heat exchange |
WO2011014094A1 (en) * | 2009-07-29 | 2011-02-03 | Shwarzman Alexander Jakovlevich | Method and device for recycling moist waste matter comprising organic materials |
JP5762713B2 (en) * | 2010-10-04 | 2015-08-12 | 株式会社キンセイ産業 | Dry distillation gasification incineration processing equipment |
-
2013
- 2013-07-11 LT LT2013073A patent/LT6131B/en not_active IP Right Cessation
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2014
- 2014-06-04 WO PCT/LT2014/000007 patent/WO2015005755A1/en active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2182884C1 (en) | 2000-11-16 | 2002-05-27 | Оао "Аммофос" | Method of treatment of wet-processing phosphoric acid used for production of liquid complex fertilizers |
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WO2015005755A1 (en) | 2015-01-15 |
LT2013073A (en) | 2015-01-26 |
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