KR980002081A - 하이솔리드계 아크릴 수지 조성물 - Google Patents

하이솔리드계 아크릴 수지 조성물 Download PDF

Info

Publication number
KR980002081A
KR980002081A KR1019960025712A KR19960025712A KR980002081A KR 980002081 A KR980002081 A KR 980002081A KR 1019960025712 A KR1019960025712 A KR 1019960025712A KR 19960025712 A KR19960025712 A KR 19960025712A KR 980002081 A KR980002081 A KR 980002081A
Authority
KR
South Korea
Prior art keywords
acrylic resin
resin composition
methacrylate
monomer
group
Prior art date
Application number
KR1019960025712A
Other languages
English (en)
Other versions
KR100220144B1 (ko
Inventor
강기준
한광영
김신국
Original Assignee
한영재
대한페인트 · 잉크 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 한영재, 대한페인트 · 잉크 주식회사 filed Critical 한영재
Priority to KR1019960025712A priority Critical patent/KR100220144B1/ko
Publication of KR980002081A publication Critical patent/KR980002081A/ko
Application granted granted Critical
Publication of KR100220144B1 publication Critical patent/KR100220144B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/44—Acrylonitrile

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

외관 품질이 뛰어나고 경도등의 기계적 물성과 작업성이 우수할 뿐만 아니라 저공해형인 하이솔리드(高固形)계 아크릴 수지 조성물이 개시되어 있다. 유기산기 함유 단량체, 적어도 2종 이상의 수산기 함유 단량체, 방향족계 비관능성 불포화 단량체 및 지방족계 비관능성 불포화 단량체로 구성된 단량체 혼합물로부터 수득된 아크릴 수지 공중합체 및 개시제로 구성된 아크릴 수지 조성물이 제공된다. 저분자량임에도 불구하고 외관품질, 경도, 내굴곡성 및 내산성등의 기계적, 화학적 물성이 뛰어나므로 냉장고나 자동판매기, 일반 가전기기 등의 금속을 도장하는데 사용하기에 매우 우수하다.

Description

하이솔리드계 아크릴 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 유기산기 함유 단량체,적어도 2종 이상의 수산기 함유 단량체, 방향족계 비관능성 불포화 단량체 및 지방족계 비관능성 불포화 단량체로 구성된 단량체 혼합물로부터 수득된 아크릴 수지 조성물.
  2. 제1항에 있어서, 상기 아크릴 수지 조성물은 산가 2∼25㎎ KOH/g, 수산기 함량 1∼5%, 유리 전이온도가 10∼60℃ 범위이고 불휘발분이 60% 이상인 것을 특징으로 하는 아크릴 수지 조성물.
  3. 제2항에 있어서 상기 아크릴 수지 조성물의 산가는 5∼9㎎ KOH/g이고, 유리 전이 온도는 15∼50℃인 것을 특징으로 하는 아크릴 수지 조성물
  4. 제1항에 있어서, 상기 아크릴 수지 조성물의 수평균 분자량이 1,000∼6,000이며 중량평균 분자량이 2,000∼15,000이고 분자량 분포도가 2.5 이하인 것을 특징으로하는 아크릴 수지 조성물.
  5. 제1항에 있어서, 상기 아크릴 수지 공중합체는, 총 단량체의 중량을 기준으로 상기 유기산기 함유 단량체 0.5∼5중량%, 상기 적어도 2종 이상의 수산기 함유 단량체 20∼50중량%, 상기 방향족계 비관능성 불포화 단량체 5∼40중량% 및 상기 지방족계 바관능성 불포화 단량체 10∼60중량%로 구성되는 것을 특징으로 하는 아크릴 수지 조성물.
  6. 제1항에 있어서, 상기 유기산기 함유 단량체로서는 아크릴산, 메타크릴산, 푸마르산, 이타곤산, 말레인산 및 이들의 무수물로 구성된 군에서 선택된 적어도 1종 이상의 단량체를 사용하고, 상기 방향족계 비관능성 불포화 단량체로서는 스티렌 또는 비닐 툴루엔을 적어도 1종 이상 사용하고, 상기 지방족계 비관능성 불포화 단량체로서는 메틸 메타크릴레이트, 에틸 아크릴레이트, 에틸 메타크릴레이트, 프로필 메타크렐레이트, 노르말 부틸 메타크릴레이트, 노르말 부틸 멕타크릴레이트, 이소 부틸 메타크릴레이트, 노르말 헥실 메타크릴레이트, 라우릴메타크릴레이트, 이소보닐 아크릴레이트, 이소보닐 메타크릴레이트, 싸이클로 헥실 아크릴레이트, 비닐 아세테이트 및 아크릴로 니트릴로 구성된 군에서 선택된 적어도 1종 이상을 사용하는 것을 특징으로 하는 아크릴 수지 조성물.
  7. 제1항에 있어서, 상기 수산기 함유 단량체로서는 2-하이드록시 에틸 아크릴레이트, 2-하이드록시 에틸 메타크릴레이트, 4-하이드록시 부틸 아크릴레이트 및 하이드록시프로필 메타크릴레이트로 구성된 군에서 선택된 하나 또는 입실본 카프로락톤의 개환 유도체를 포함하여 적어도 2종 이상의 수산기 함유 단량체 혼합물을 사용하는 것을 특징으로 하는 아크릴 수지 조성물.
  8. 제7항에 있어서, 상기 입실론 카프로락톤 개환 유도체는 5∼20%를 포함하는 것을 특징으로 하는 아크릴 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960025712A 1996-06-29 1996-06-29 하이솔리드계 아크릴 수지 조성물 KR100220144B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019960025712A KR100220144B1 (ko) 1996-06-29 1996-06-29 하이솔리드계 아크릴 수지 조성물

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019960025712A KR100220144B1 (ko) 1996-06-29 1996-06-29 하이솔리드계 아크릴 수지 조성물

Publications (2)

Publication Number Publication Date
KR980002081A true KR980002081A (ko) 1998-03-30
KR100220144B1 KR100220144B1 (ko) 1999-09-01

Family

ID=19464712

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960025712A KR100220144B1 (ko) 1996-06-29 1996-06-29 하이솔리드계 아크릴 수지 조성물

Country Status (1)

Country Link
KR (1) KR100220144B1 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030087234A (ko) * 2002-05-08 2003-11-14 박홍수 아크릴계 4원 공중합 수지와 그 제조방법 및 이를 주재로하는자동차용 하이솔리드 도료

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100335395B1 (ko) * 2000-02-25 2002-05-06 김장연 하이솔리드 아크릴수지 조성물 및 그 조성물을 함유하는도료
KR20040029556A (ko) * 2002-10-01 2004-04-08 주식회사 금강고려화학 하이솔리드 아크릴 수지
KR100518793B1 (ko) * 2002-10-01 2005-10-04 주식회사 케이씨씨 하이솔리드 폴리에스테르 수지 및 이의 제조방법

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030087234A (ko) * 2002-05-08 2003-11-14 박홍수 아크릴계 4원 공중합 수지와 그 제조방법 및 이를 주재로하는자동차용 하이솔리드 도료

Also Published As

Publication number Publication date
KR100220144B1 (ko) 1999-09-01

Similar Documents

Publication Publication Date Title
BR9901320A (pt) Composição modificadora de impacto núcleo-casca, mistura lìmpida, e, artigos produzidos a partir da mistura.
BR9908134A (pt) Copolìmero e composição de revestimento
EP1321481A4 (en) MODIFIED POLYOLEFIN RESIN, MODIFIED POLYOLEFIN RESIN COMPOSITION AND USE
EP1057866A3 (en) Curable resin composition
TW200504170A (en) Pressure-sensitive adhesive composition and pressure-sensitive adhesive product
DE69828630D1 (de) Verbesserte thermohärtbare antireflexionsbeschichtungen für tiefes ultraviolett
WO2002012402A3 (en) Colorant compounds containing copolymerizable vinyl groups
EP1792941A4 (en) RESIN COMPOSITION AND FORM BODY THEREOF
WO2002055620A3 (en) Powdered thermosetting composition for coatings
TW200420589A (en) Curable liquid resin composition
MY118728A (en) Resin composition containing graft polymer having multilayer structure
DE502006002387D1 (en) Verstärkte thermoplastische formmassen
CA2271685A1 (en) New polymers, process for making them and coating compositions containing them, especially thermosetting acrylic gel coat compositions
KR950702582A (ko) 폴리에스테르와 알킬하이드록시 (메트) 아크릴레이트 컴파운드의 블렌드(blends of polyesters and alkylhydroxy (meth)acrylate compounds)
DE60030113D1 (de) Vinyläther in ungesättigten polyesterharzen, vinylester und vinylesterurethane für konstruktionsteile
BR0004160A (pt) Composição de resina san, e, artigos
TR199501216A2 (tr) Belirli bir izomer dagilimina sahip siklik ya da polisiklik monomerleri iceren kopolimerler, ve bunlarin boya kompozisyonlarinda kullanimi.
CO5040147A1 (es) Composicion de recubrimiento curable
KR980002081A (ko) 하이솔리드계 아크릴 수지 조성물
CA2374756A1 (en) Vinyl chloride-base resin composition
KR970062000A (ko) 하이솔리드계 아크릴 폴리올 수지 조성물 및 이의 제조 방법
AU5655298A (en) (methyl)methacrylate maleic acid anhydride copolymers as polymer modifying agents for plastics and mixtures and polymer composites produced therewith
KR890003884A (ko) 폴리페닐렌 에테르, 폴리스티렌, 수소화블록 공중합체 및 폴리아크릴레이트의 열가소성 조성물
TW354327B (en) Thermoplastic resin composition
KR970027206A (ko) 유리섬유 강화 abs 수지 조성물

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
AMND Amendment
E601 Decision to refuse application
J201 Request for trial against refusal decision
B701 Decision to grant
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20130311

Year of fee payment: 15

FPAY Annual fee payment

Payment date: 20140304

Year of fee payment: 16

EXPY Expiration of term