KR970074824A - 잠재-가교결합성 폴리우레탄 수분산액 - Google Patents
잠재-가교결합성 폴리우레탄 수분산액 Download PDFInfo
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- 239000004814 polyurethane Substances 0.000 title claims abstract 29
- 229920002635 polyurethane Polymers 0.000 title claims abstract 15
- 239000006185 dispersion Substances 0.000 title claims abstract 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract 9
- 150000001875 compounds Chemical class 0.000 claims abstract 11
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract 7
- -1 I b) Substances 0.000 claims abstract 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims abstract 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract 2
- 229920003009 polyurethane dispersion Polymers 0.000 claims abstract 2
- 239000000178 monomer Substances 0.000 claims 9
- 150000003077 polyols Chemical class 0.000 claims 9
- 150000002009 diols Chemical class 0.000 claims 8
- 229920005862 polyol Polymers 0.000 claims 7
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 4
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims 3
- 239000012948 isocyanate Substances 0.000 claims 3
- 150000002513 isocyanates Chemical class 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 230000001476 alcoholic effect Effects 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 claims 2
- 239000010985 leather Substances 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 229920003023 plastic Polymers 0.000 claims 2
- 239000004033 plastic Substances 0.000 claims 2
- 239000004753 textile Substances 0.000 claims 2
- 239000002023 wood Substances 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 229920002873 Polyethylenimine Polymers 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000007598 dipping method Methods 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 231100000719 pollutant Toxicity 0.000 claims 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims 1
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Abstract
본 발명은 I) Ia) 폴리우레탄을 수중에 분산가능하게 기와 C-C 이중 결합에 직접 부착된 카르보닐에 의해 활성화 되는 C-C 이중 결합이 있는 기를 갖는 폴리우레탄(PUR, I a), 또는 I b)-폴리우레탄을 수중에 분산가능하게 하는 기를 갖으나 C-C 이중 결합에 직접 부착된 카르모닐에 의해 활성화되는 C-C 이중결합을 갖는 기가 없는 폴리 우레탄 (PUR, I b) 및-폴리우레탄 PUR, I a 및 PUR, I b와는 상이하고, C-C이중 결합에 직접 부착된 카르보닐에 의해 활성화되는 C-C 이중 결합이 있는 기를 갖는 화합물(V. I)의 혼합물을 포함하는 분산액 상(P. I), 및 Ⅱ)-아미노 관능기의 형태로 존재하는 평균 2개 이상의 수소, -1g/1(25℃) 이상의 물 중의 용해도 및 -200 내지 1,000,000(화합물(Ⅱ))의 수 평균 분자량(Mn)을 갖는 화합물을 포함하는, 잠재-가교결합성 폴리우레탄 수분산액에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- I) I a) 폴리우레탄을 수 중에 분산가능하게 기와 C-C 이중 결합에 직접 부착된 카르보닐에 의해 활성화되는 C-C 이중 결합이 있는 기를 갖는 폴리우레탄(PUR. I a), 또는I b)-폴리우레탄을 수 중에 분산가능하게 하는 기를 갖으나C-C 이중 결합에 직접 부착된 카르보닐에 의해 활성화되는 C-C 이중 결합을 갖는 기가 없는 폴리 우레탄(PUR. I b) 및 - 폴리우레탄PUR. Ia 및 PUR. Ib와는 상이하고, C-C이중 결합에 직접 부착된 카르보닐에 의해 활성화되는 C-C 이중 결합이 있는 기를 갖는 화합물(V. I)의 혼합물을 포함하는 분산액 상(P. I). 및 Ⅱ) - 아미노 관능기의 형태로 존재하는 평균 2개 이상의 수소, -1g/1(25℃) 이상의물 중의 용해도 및 -200 내지 1,000,000(화합물 (Ⅱ)의 수 평균 분자량(Mn)을 갖는 화합물을 포함하는, 잠재-가교결합성 폴리우레탄 수분산액.
- 제1항에 있어서, 상기 상(P.I)은 al) 4 내지 30개의 탄소의 다관능성 이소시아네이트, a2) a2.1) 디올(a2) 전량 기준으로 분자량 500 내지5000인 폴리올 10 내지 100몰%, 및 a2.2) 디올(a2) 전량 기준으로 분자량 60 내지 500g/몰인 폴리올 0 내지 90몰% a3) 단량체 (a1) 및 (a2)와 상이하고, 하나 이상의 이소시아네이트기 또는 하나 이상의 이소시아나네이트-반응성기를 갖고, 또한 하나 이상의 친수성기 또는 잠재적인 친수성기 (이는 폴리우레탄이 수 중에 분산가능하게 함)를 갖는 단량체, a4) 단량체 (a1), (a2) 및 (a3)과 상이하고, 하나 이상의 이소시아네이트기 또는 하나 이상의 이소이아네이토-반응성 기를 갖고, 또한 하나 이상의 아크릴로일기 및 메타크릴로일기를 갖는 단량체, 및 a5)필요하다면, 추가로 안량체(a2) 내지 (a4)와 상이하고, 알코올성히드록실기 또는 1금 아미노기 또는 2급 아미노기인 이소시아네이토-반응성기를 갖는 다관능성 화합물로 이루어진 폴리우레탄(PUR, Ia)을 포함하는 수분산액.
- 제1항에 또는 제2항에 있어서, 상기 상(P. I)이-폴리 우레탄(PUR. Ib) 및-화합물(V. I)로서 폴리우레탄 (PUR. Ic)의 혼합물이고, 폴리우레탄 (PUR. Ib)은 b1) 탄소 원자 4 내지 30개의 다관능성 이소시아네이트, b2) b2.1) 디올 (b2) 전량 기준으로 분자량 500 내지 5000인 폴리올 10 내지 100몰%, 및 b2.2)디올 (b2)전량 기준으로 분자량 60 내지 500g/몰인 폴리올 0 내지 90몰%, b3) 단량체 (b1) 및 (b2)와 상이하고, 하나 이상의 이소시아네이트기 또는 하나 이상의 이소시아네이토-반응성기를 갖고, 또한 이상의 친수성기 또는 잠재적 친수성기를 갖음으로서 폴리우레탄을 수 중에 분산가능하게 만드는 단량체, 밍 b4) 필요하다면, 추가로 폴리올 (b2) 및 안량체 (b3)과 상이하고, 알코올성 히드록실 또는 1급 아미노인 이소시아네이토-반응성기를 갖는 다관능성 화합물로 이루어지며, 폴리우레탄(PUR.Ic)은 c1) 탄소 원자 4 내지 30개의 다관능성 이소시아네이트, c2) c2.1) 디올 (c2) 전량 기준으로 분자량 500 내지 5000인 폴리올 10 재지 100몰%. 및 c2.2) 이올 (c2) 전량 기준으로 분자량 60 내지 500g/몰인 폴리올 0 내지 90몰%, c3) 단량체 (c1) 및 (c2)와 상이하고, 하나 이상의 이소시아네이트기 또는 하나 이상의 이소시아네이토-반응성기를 갖고, 또한 하나 이상의 아크릴로일기 또는 메타크릴로일기를 갖는 단량체로 이루어지는 수분산액.
- 제1항 내지 제3항 중 어느 한 항에 있어서, 상기 단량체(a4) 또는 (c3)은 C1-C6-히드록시알킬 아크릴레이트, C1-C6-히드록시알킬 메타크릴레이트 또는 아크릴산 및 (또는) 메타크릴산과 비스에폭시드의 이부가물인 수분산액.
- 제1항 내지 제4항 중 어느 한 항에 있어서, 분지된 또는 미분지된 폴리에틸렌이민의 화합물(Ⅱ)로서 사용되는 수분산액.
- 제1항 내지 제5항 중 어느 한 항에 있어서, 쇄말단에서 NH2기를 갖는 폴리 -C2-C4-알킬렌 산화물이 화합물(Ⅱ)로서 사용되는 수분산액.
- 제1항 내지 제6항 중 어느 한 항에 있어서, 카르보닐에 의해 활성화된 이중결합 대 아미노 형태로 존재하는 수소의 몰비가 0.1 : 1 내지 10 :1인 수분산액.
- 제1항 내지 제7항 중 어느 한 항에 있어서, 폴리우레탄 PUR,Ia 및 PUR.Ic가 보유하는, C-C 이중 결합에 직접 부착된 카르보닐에 의해 활성화된 C-C 이중 결합을 갖는 기가 아크릴로일인 잠재-가교결합성 폴링뤠탄 수분산액.
- 제1항 내지 제8항 중 어느 한 항에서 청구된 분산액을 사용하여 목재, 금속, 직물, 가죽 또는 플라스틱물품의 침지, 코팅 또는 접착 방법.
- 제1항 내지 제8항 중 어느 한 항에서 청구된 수분산액을 사용하여 코팅, 침지 또는 접착된 목재, 금속, 직물, 가죽 또는 플라스틱 물품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19619636.1 | 1996-05-15 | ||
| DE19619636A DE19619636A1 (de) | 1996-05-15 | 1996-05-15 | Latent vernetzende wässerige Polyurethandispersionen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR970074824A true KR970074824A (ko) | 1997-12-10 |
Family
ID=7794428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019970018392A KR970074824A (ko) | 1996-05-15 | 1997-05-13 | 잠재-가교결합성 폴리우레탄 수분산액 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5905113A (ko) |
| EP (1) | EP0807648B1 (ko) |
| JP (1) | JPH1060263A (ko) |
| KR (1) | KR970074824A (ko) |
| DE (2) | DE19619636A1 (ko) |
| ES (1) | ES2142642T3 (ko) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19731864A1 (de) * | 1997-07-24 | 1999-01-28 | Bayer Ag | Wäßrige PUR-Dispersionen mit verbesserten Eigenschaften |
| US6107436A (en) * | 1998-10-05 | 2000-08-22 | 3M Innovative Properties Company | Polyfunctional polymer |
| US6350823B1 (en) | 1998-10-05 | 2002-02-26 | 3M Innovative Properties Company | Pavement marking composition |
| US8076445B2 (en) * | 2000-01-11 | 2011-12-13 | Robert Shane Porzio | Oligocarbodiimides for the formation of crosslinked latex films |
| DE10002089A1 (de) | 2000-01-19 | 2001-07-26 | Basf Ag | Witterungsstabile, strahlungshärtbare Polyurethane |
| US6436540B1 (en) | 2000-02-18 | 2002-08-20 | Omnova Solutions Inc. | Co-mingled polyurethane-polyvinyl ester polymer compositions and laminates |
| US6541550B1 (en) | 2000-04-05 | 2003-04-01 | 3M Innovative Properties Company | Low temperature thermally activated water-dispersed adhesive compositions |
| US6310125B1 (en) | 2000-04-05 | 2001-10-30 | 3M Innovative Properties Company | Water-dispersed adhesive compositions |
| US6444737B1 (en) | 2000-04-05 | 2002-09-03 | 3M Innovative Properties Company | Water-dispersed polymer stabilizer |
| US6306942B1 (en) | 2000-04-05 | 2001-10-23 | 3M Innovative Properties Company | Low temperature thermally activated water-dispersed adhesives |
| AU2003287512A1 (en) * | 2002-11-04 | 2004-06-07 | Invista Technologies S.A.R.L. | Aqueous poly (urea/urethanes) dispersions using polyester glycol |
| SE528577C2 (sv) | 2005-03-23 | 2006-12-19 | Perstorp Specialty Chem Ab | Vattenburen polyuretandispersion samt användning därav |
| WO2008144535A2 (en) * | 2007-05-17 | 2008-11-27 | Johnsondiversey, Inc. | Surface coating system and method |
| EP2130846A1 (en) * | 2008-06-06 | 2009-12-09 | Cytec Surface Specialties, S.A. | Aqueous radiation curable polyurethane compositions |
| WO2012162640A2 (en) | 2011-05-25 | 2012-11-29 | Diversey, Inc. | Surface coating system and method of using surface coating system |
| US11035013B2 (en) | 2018-03-22 | 2021-06-15 | Lear Corporation | Use of hydroxy functional waterborne resins to create urethane crosslinking in leather finishes |
| TW202102573A (zh) * | 2019-07-12 | 2021-01-16 | 美商陶氏全球科技有限責任公司 | 基於水之組合物 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3586562T2 (de) * | 1984-11-05 | 1993-07-01 | Ici Plc | Bei raumtemperatur haertendes ueberzugsmittel, enthaltend ein kondensationspolymer mit einer aktivierten ungesaettigtheit und eine verbindung mit drei oder mehreren primaeren aminogruppen. |
| IT1177161B (it) * | 1984-11-12 | 1987-08-26 | Resem Spa | Polimeri di monomeri etilenicamente insaturi modificati con oligouretani e dispersioni acquose da essi ottenute |
| EP0443537A3 (en) * | 1990-02-20 | 1992-05-06 | Takeda Chemical Industries, Ltd. | Water soluble photocurable polyurethane poly(meth-)acrylate, adhesives containing the same, and production of laminated articles |
| JP3078859B2 (ja) * | 1990-02-23 | 2000-08-21 | 武田薬品工業株式会社 | 安定な放出制御性製剤用コーティング剤 |
| US5306764A (en) * | 1992-09-03 | 1994-04-26 | China Technical Consultants Inc. | Water dispersible polyurethane and process for preparation thereof |
| DE4434554A1 (de) * | 1994-09-28 | 1996-04-04 | Basf Ag | Strahlungshärtbare wäßrige Polyurethandispersionen |
| DE19608610A1 (de) * | 1996-03-06 | 1997-09-11 | Basf Ag | Latent vernetzende wässerige Polyurethandispersionen |
-
1996
- 1996-05-15 DE DE19619636A patent/DE19619636A1/de not_active Withdrawn
-
1997
- 1997-05-07 DE DE59700814T patent/DE59700814D1/de not_active Expired - Lifetime
- 1997-05-07 ES ES97107492T patent/ES2142642T3/es not_active Expired - Lifetime
- 1997-05-07 EP EP97107492A patent/EP0807648B1/de not_active Expired - Lifetime
- 1997-05-13 KR KR1019970018392A patent/KR970074824A/ko not_active Application Discontinuation
- 1997-05-14 US US08/855,948 patent/US5905113A/en not_active Expired - Lifetime
- 1997-05-15 JP JP9125130A patent/JPH1060263A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| DE59700814D1 (de) | 2000-01-13 |
| DE19619636A1 (de) | 1997-11-20 |
| EP0807648A3 (de) | 1998-04-22 |
| JPH1060263A (ja) | 1998-03-03 |
| US5905113A (en) | 1999-05-18 |
| ES2142642T3 (es) | 2000-04-16 |
| EP0807648A2 (de) | 1997-11-19 |
| EP0807648B1 (de) | 1999-12-08 |
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| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |