KR970073341A - Fungicidal and Insecticidal Compositions - Google Patents

Fungicidal and Insecticidal Compositions Download PDF

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KR970073341A
KR970073341A KR1019970020969A KR19970020969A KR970073341A KR 970073341 A KR970073341 A KR 970073341A KR 1019970020969 A KR1019970020969 A KR 1019970020969A KR 19970020969 A KR19970020969 A KR 19970020969A KR 970073341 A KR970073341 A KR 970073341A
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ethyl
methyl
group
dichloro
carboxamide
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KR1019970020969A
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Korean (ko)
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KR100478401B1 (en
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요시오 구라하시
유이치 오추
유미 하토리
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다테노 고이치
니혼 바이엘 아그로켐 케이. 케이
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/57—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C233/58—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/15—Saturated compounds containing halogen
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring

Abstract

본 발명은 살진균제 및 살충제로서 뛰어난 활성을 나타내는 활성 성분으로 Ⅰ) 적어도 하나의 일반식(Ⅰ)의 카복스아미드 및 Ⅱ) (E)-4,5-디하이드로-6-메틸-4-(3-피리딜메틸렌아미노)-1,2,4-트리아진-3(2H)-온, 5-아미노-1-(2,6-디클로로-4-트리플루오로메틸페닐)-4-(트리플루오로메틸설페닐)-1H-피라졸-3-카보니트릴, N-(6-클로로-3-피리딜메틸)-N-에틸-N′-메틸-2-니트로비닐리덴 디아민, 1-(2-클로로-티아졸-5-일메틸)-3-메틸-2-니트로구아니딘, 1-(2-클로로-티아졸-5-일메틸)-3,5-디메틸-2-니트로아미노-헥사하이드로-1,3,5-트리아진 및 비스아로일히드라지드 유도체로 구성된 그룹중에서 선택된 적어도 하나의 화합물을 함유하는 신규한 조성물에 관한 것이다 :The present invention relates to active ingredients exhibiting excellent activity as fungicides and insecticides, comprising: I) at least one carboxamide of formula (I) and II) (E) -4,5-dihydro-6-methyl-4- ( 3-pyridylmethyleneamino) -1,2,4-triazine-3 (2H) -one, 5-amino-1- (2,6-dichloro-4-trifluoromethylphenyl) -4- (trifluoro Rommethylsulphenyl) -1H-pyrazole-3-carbonitrile, N- (6-chloro-3-pyridylmethyl) -N-ethyl-N'-methyl-2-nitrovinylidene diamine, 1- (2 -Chloro-thiazol-5-ylmethyl) -3-methyl-2-nitroguanidine, 1- (2-chloro-thiazol-5-ylmethyl) -3,5-dimethyl-2-nitroamino-hexahydro A novel composition containing at least one compound selected from the group consisting of -1,3,5-triazine and bisaroylhydrazide derivatives:

상기 식에서, Z는 할로겐 원자를 나타내고, R1은 C1-4알킬 그룹을 나타내며, R2는 수소 원자, 메틸 그룹 또는 에틸 그룹을 나타내고, R3는 수소 원자 또는 메틸 그룹을 나타낸다.In the formula, Z represents a halogen atom, R 1 represents a C 1-4 alkyl group, R 2 represents a hydrogen atom, a methyl group or an ethyl group, and R 3 represents a hydrogen atom or a methyl group.

Description

살진균 및 살충 조성물Fungicidal and Insecticidal Compositions

내용없음No content

Claims (9)

Ⅰ)적어도 하나의 일반식(Ⅰ)의 카복스아미드 및 Ⅱ) (E)-4,5-디하이드로-6-메틸-4-(3-피리딜메틸렌아미노)-1,2,4-트리아진-3(2H)-온, 5-아미노-1-(2,6-디클로로-4-트리플루오로메틸페닐)-4-(트리플루오로메틸설피닐)-1H-피라졸-3-카보니트릴, N-(6-클로로-3-피리딜메틸)-N-에틸-N′-메틸-2-니트로비닐리덴 디아민, 1-(2-클로로-티아졸-5-일메틸)-3-메틸-2-니트로구아니딘, 1-(2-클로로-티아졸-5-일메틸)-3,5-디메틸-2-니트로이미노-헥사하이드로-1,3,5-트리아진 및 비스아로일히드라지드 유도체로 구성된 그룹중에서 선택된 적어도 하나의 화합물을 함유함을 특징으로 하는 살진균 및 살충 조성물 :I) at least one carboxamide of formula (I) and II) (E) -4,5-dihydro-6-methyl-4- (3-pyridylmethyleneamino) -1,2,4-tri Azine-3 (2H) -one, 5-amino-1- (2,6-dichloro-4-trifluoromethylphenyl) -4- (trifluoromethylsulfinyl) -1H-pyrazole-3-carbonitrile , N- (6-chloro-3-pyridylmethyl) -N-ethyl-N'-methyl-2-nitrovinylidene diamine, 1- (2-chloro-thiazol-5-ylmethyl) -3-methyl 2-nitroguanidine, 1- (2-chloro-thiazol-5-ylmethyl) -3,5-dimethyl-2-nitromino-hexahydro-1,3,5-triazine and bisaroylhydrazide Fungicidal and insecticidal compositions characterized by containing at least one compound selected from the group consisting of derivatives: 상기 식에서, Z는 할로겐 원자를 나타내고 R1은 C1-4알킬 그룹을 나타내며, R2는 수소 원자, 메틸 그룹 또는 에틸 그룹을 나타내고, R3는 수소 원자 또는 메틸 그룹을 나타낸다.In the formula, Z represents a halogen atom, R 1 represents a C 1-4 alkyl group, R 2 represents a hydrogen atom, a methyl group or an ethyl group, and R 3 represents a hydrogen atom or a methyl group. 제1항에 있어서, 카복스아미드가 Z가 염소 원자를 나타내고, R1은 에틸 또는 이소프로필 그룹을 나타내며, R2는 수소 원자 또는 메틸 그룹을 나타내고, R3는 수소 원자를 나타내는 일반식(Ⅰ)의 화합물인 조성물.2. The general formula (I) according to claim 1, wherein the carboxamide represents Z is a chlorine atom, R 1 represents an ethyl or isopropyl group, R 2 represents a hydrogen atom or a methyl group, and R 3 represents a hydrogen atom. A compound of formula (I). 제1항에 있어서, 카복스아미드가 N-[1-(4-클로로페닐)-에틸]-2,2-디클로로-1-에틸-3-메틸사이클로프로판 카복스아미드, N-[1-(4-클로로페닐)-에틸]-2,2-디클로로-1-이소프로필 사이클로프로판 카복스아미드, N-(R)-[1-(4-클로로페닐)-에틸]-2,2-디클로로-1-에틸-3t-메틸-1r-사이클로프로판 카복스아미드 디아스테레오머 혼합물, N-(R)-[1-(4-클로로페닐)-에틸]-2,2-디클로로-1-이소프로필 사이클로프로판 카복스아미드 디아스테레오머 혼합물, N-(R)-[1-(4-클로로페닐)-에틸]-(1S)-2,2-디클로로-1-에틸-3t-메틸-1r-사이클로프로판 카복스아미드 및 N-(R)-[1-(4-클로로페닐)-에틸]-(1S)-2,2-디클로로-1-이소프로필 사이클로프로판 카복스아미드로 구성된 그룹 중에서 선택된 화합물인 조성물.The compound of claim 1, wherein the carboxamide is N- [1- (4-chlorophenyl) -ethyl] -2,2-dichloro-1-ethyl-3-methylcyclopropane carboxamide, N- [1- ( 4-Chlorophenyl) -ethyl] -2,2-dichloro-1-isopropyl cyclopropane carboxamide, N- (R)-[1- (4-chlorophenyl) -ethyl] -2,2-dichloro- 1-ethyl-3t-methyl-1r-cyclopropane carboxamide diastereomer mixture, N- (R)-[1- (4-chlorophenyl) -ethyl] -2,2-dichloro-1-isopropyl cyclo Propane Carboxamide Diastereomeric Mixture, N- (R)-[1- (4-Chlorophenyl) -ethyl]-(1S) -2,2-dichloro-1-ethyl-3t-methyl-1r-cyclopropane A compound selected from the group consisting of carboxamide and N- (R)-[1- (4-chlorophenyl) -ethyl]-(1S) -2,2-dichloro-1-isopropyl cyclopropane carboxamide . 제1항에 있어서, 카복스아미드가 구조식The method of claim 1 wherein the carboxamide is of structural formula 의 N-(R)-[1-(4-클로로페닐)-에틸]-(1S)-2,2-디클로로-1-에틸-3t-메틸-1r-사이클로프로판 카복스아미드 또는 구조식.N- (R)-[1- (4-Chlorophenyl) -ethyl]-(1S) -2,2-dichloro-1-ethyl-3t-methyl-1r-cyclopropane carboxamide or a structural formula. 의 N-(R)-[1-(4-클로로페닐)-에틸]-(1S)-2,2-디클로로-1-에틸-3t-메틸-1r-사이클로프로판 카복스아미드 또는 이들의 혼합물인 조성물.N- (R)-[1- (4-chlorophenyl) -ethyl]-(1S) -2,2-dichloro-1-ethyl-3t-methyl-1r-cyclopropane carboxamide or mixtures thereof Composition. 제1항에 있어서, 그룹(Ⅱ)의 화합물이 5-아미노-1-(2,6-디클로로-4-트리플루오로메틸페닐)-4-(트리플루오로메틸설피닐)-1H-피라졸-3-카보니트릴, N-(6-클로로-3-피리딜메틸)-N-에틸-N′-메틸-2-니트로비닐리덴 디아민, 1-(2-클로로-티아졸-5-일메틸)-3-메틸-2-니트로구아니딘, 1-(2-클로로-티아졸-5-일메틸)-3,5-디메틸-2-니트로이미노-헥사하이드로-1,3,5-트리아진 및 N-(3-메톡시-2-메틸-벤조일)-N′-(3,5-디메틸벤조일)-N′-t-부틸히드라진으로 구성된 그룹 중에서 선택된 화합물인 조성물.The compound of claim 1, wherein the compound of Group (II) is 5-amino-1- (2,6-dichloro-4-trifluoromethylphenyl) -4- (trifluoromethylsulfinyl) -1H-pyrazole- 3-carbonitrile, N- (6-chloro-3-pyridylmethyl) -N-ethyl-N'-methyl-2-nitrovinylidene diamine, 1- (2-chloro-thiazol-5-ylmethyl) -3-methyl-2-nitroguanidine, 1- (2-chloro-thiazol-5-ylmethyl) -3,5-dimethyl-2-nitromino-hexahydro-1,3,5-triazine and N A composition selected from the group consisting of-(3-methoxy-2-methyl-benzoyl) -N '-(3,5-dimethylbenzoyl) -N'-t-butylhydrazine. 제1항에 있어서, 그룹(Ⅰ)의 활성 화합물 대 그룹(Ⅱ)의 활성 화합물의 중량비가 1 : 0.1 내지 1 : 10임을 특징으로 하는 조성물.The composition of claim 1, wherein the weight ratio of the active compound of group (I) to the active compound of group (II) is from 1: 0.1 to 1:10. 제1항에 따르는 활성 배합물을 진균 및/또는 곤충 및/또는 그들의 서식지에 적용시킴을 특징으로 하여, 진균 및 곤충을 구제하는 방법.A method for controlling fungi and insects, characterized in that the active combination according to claim 1 is applied to fungi and / or insects and / or their habitats. 진균 및 곤충을 구제하기 위한 제1항에 따르는 활성 배합물의 용도.Use of the active combination according to claim 1 for controlling fungi and insects. 제1항에 따르는 활성 배합물을 중량제 및/또는 계면활성제와 혼합시킴을 특징으로 하여, 살진균 및 살충 조성물을 제조하는 방법.A process for preparing fungicidal and pesticidal compositions, characterized in that the active formulation according to claim 1 is mixed with a weighting agent and / or a surfactant. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019970020969A 1996-05-30 1997-05-27 Fungicidal and insecticidal compositions KR100478401B1 (en)

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JP157408/1996 1996-05-30
JP15740896A JP3810480B2 (en) 1996-05-30 1996-05-30 Bactericidal insecticidal composition

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JP4387802B2 (en) * 2002-03-08 2009-12-24 ビーエーエスエフ ソシエタス・ヨーロピア Bactericidal mixture based on prothioconazole and containing an insecticide
JP6558488B1 (en) * 2018-10-23 2019-08-14 住友化学株式会社 Ester compounds and uses thereof

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JPS6317813A (en) * 1986-07-09 1988-01-25 Daicel Chem Ind Ltd Herbicide composition
JPH01180804A (en) * 1988-01-05 1989-07-18 Daicel Chem Ind Ltd Herbicide composition
DE3815728A1 (en) * 1988-05-07 1989-11-16 Bayer Ag STEREOISOMERS OF N- (R) - (1-ARYL-ETHYL) -1-ALKYL-2,2-DICHLORO-CYCLOPROPANCARBONIC ACID AMIDES
JP2546003B2 (en) * 1988-12-27 1996-10-23 武田薬品工業株式会社 Guanidine derivative, its production method and insecticide
JP2832482B2 (en) * 1990-03-19 1998-12-09 日本バイエルアグロケム株式会社 Insecticidal fungicide composition
JP2973370B2 (en) * 1990-10-15 1999-11-08 日本バイエルアグロケム株式会社 Combined fungicide
JP2990541B2 (en) * 1991-02-14 1999-12-13 日本バイエルアグロケム株式会社 Combined fungicide
JP3176418B2 (en) * 1991-06-29 2001-06-18 日本バイエルアグロケム株式会社 Agricultural and horticultural fungicides
MY121190A (en) * 1992-09-10 2006-01-28 Syngenta Participations Ag Control of pests using 1,2,4-triazine derivatives.
JP4004555B2 (en) * 1993-09-29 2007-11-07 ダウ アグロサイエンシィズ エルエルシー Insecticidal compound
JP3349566B2 (en) * 1993-11-25 2002-11-25 日本バイエルアグロケム株式会社 Agricultural and horticultural fungicide composition

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CN1192711C (en) 2005-03-16
CN1381175A (en) 2002-11-27
CN1166917A (en) 1997-12-10
JPH09315906A (en) 1997-12-09
JP3810480B2 (en) 2006-08-16
KR100478401B1 (en) 2005-07-18
CN1084591C (en) 2002-05-15
TW350759B (en) 1999-01-21
HK1051123A1 (en) 2003-07-25

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