KR970065545A - 알킬 또는 아실 디안히드로-1,4:3,6-d-글루시톨의 인산 에스테르화물, 그의 제조방법 및 온도 - Google Patents
알킬 또는 아실 디안히드로-1,4:3,6-d-글루시톨의 인산 에스테르화물, 그의 제조방법 및 온도 Download PDFInfo
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- KR970065545A KR970065545A KR1019970010954A KR19970010954A KR970065545A KR 970065545 A KR970065545 A KR 970065545A KR 1019970010954 A KR1019970010954 A KR 1019970010954A KR 19970010954 A KR19970010954 A KR 19970010954A KR 970065545 A KR970065545 A KR 970065545A
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- 238000000034 method Methods 0.000 title claims abstract 7
- 125000000217 alkyl group Chemical group 0.000 title claims abstract 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title abstract 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 title abstract 2
- 125000002252 acyl group Chemical group 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 17
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract 6
- 239000000203 mixture Substances 0.000 claims abstract 5
- 229920006395 saturated elastomer Polymers 0.000 claims abstract 5
- 239000002537 cosmetic Substances 0.000 claims abstract 4
- 229960002920 sorbitol Drugs 0.000 claims abstract 4
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 2
- 125000000539 amino acid group Chemical group 0.000 claims abstract 2
- 239000003054 catalyst Substances 0.000 claims abstract 2
- 229910052736 halogen Inorganic materials 0.000 claims abstract 2
- 150000002367 halogens Chemical class 0.000 claims abstract 2
- 229910052751 metal Inorganic materials 0.000 claims abstract 2
- 239000002184 metal Substances 0.000 claims abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract 2
- 239000010452 phosphate Substances 0.000 claims abstract 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract 2
- 239000002904 solvent Substances 0.000 claims abstract 2
- -1 alkyl radical Chemical class 0.000 claims 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 150000005840 aryl radicals Chemical class 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 239000006071 cream Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 238000005187 foaming Methods 0.000 claims 1
- 239000000499 gel Substances 0.000 claims 1
- 210000004080 milk Anatomy 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 239000002674 ointment Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000002453 shampoo Substances 0.000 claims 1
- 239000000344 soap Substances 0.000 claims 1
- 238000010557 suspension polymerization reaction Methods 0.000 claims 1
- 239000000271 synthetic detergent Substances 0.000 claims 1
- 150000003512 tertiary amines Chemical class 0.000 claims 1
- 239000003599 detergent Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6561—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing systems of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring or ring system, with or without other non-condensed hetero rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H11/00—Compounds containing saccharide radicals esterified by inorganic acids; Metal salts thereof
- C07H11/04—Phosphates; Phosphites; Polyphosphates
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- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
- C07H13/06—Fatty acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/16—Anti-static materials
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/78—Neutral esters of acids of phosphorus
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Abstract
본 발명은 하기 화학식(1) 또는 (2)의 신규 인산 에스테르화물에 관한 것이다:
〔식중, R은 탄소수 5 내지 21의 포화 또는 비포화 직쇄형 또는 측쇄형 알킬 라디칼을 나타내고, X는 CO또는 CH2를 나타내고, Z1및 Z2는, 동일하거나 상이하며, 수소원자, 알킬리 금속, 알킬리토금속 또는 식의 4차 암모늄을 나타낸다(식중, R1, R2,R3,및 R4는, 동일하거나 상이하며, 수소원자, 1 내지 6의 탄소원자를 함유하는 알킬 또는 히드록시알킬 라디칼, 또는 염기성 아미노산 잔기를 나타낸다)〕. 또한 본 발명은 화학식 (1) 또는 (2)의 화합물의 제조방법에 관한 것으로서, 이는 하기의 단계로 구성된다 a) 디안히드로-1,4:3,6-D-글루시톨을 촉매의 존재하에 식 RCOOR′또는 RCH2Y의 화합물과 반응시켜 하기 화학식(3) 및 (4)의 화합물을 형성시키고:
(삭중, Y는 할로겐 또는 알킬 또는 아릴술포닉 라디칼을 나타내고, R′는 수소원자 또는 1 내지 6개의 탄소원자를 갖는 알킬 라디칼을 나타내고, R은 탄소수 5 내지 21의 포화 또는 비포화된 직쇄형 또는 측쇄형 알킬 라디칼을 나타내고, X는 CO 또는 CH2을 나타낸다), b) 단계a)의 생성물을 인산옥시클로리드, 염기 및 무수용매와 반응시켜, 화학식(1) 및/또는 (2)의 화합물을 형성하고, 그들을 임의로 분리시키는 것, 본 발명의 과제를 형성하는 화합물들을 계면활성제, 특히 화장 및 세척제 조성물 분야에서 사용될 수 있다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (13)
- 하기 화학식(1) 또는 (2)의 화합물:〔식중, R은 탄소수 5 내지 21의 포화 또는 비포화 직쇄형 또는 측쇄형 알킬 라디칼을 나타내고, X는 CO 또는 CH2를 나타내고, Z1및 Z2는, 동일하거나 상이하며, 수소원자, 알칼리 금속, 알칼리토금속 또는 식의 4차 암모늄을 나타낸다(식중, R1,R2,R3,및 R4는, 동일하거나 상이하며, 수소원자, 1 내지 6개의 탄소원자를 함유하는 알킬 또는 히드록시알킬 라디칼, 또는 염기성 아미노산 잔기를 나타낸다.)〕
- 제1항에 있어서, R이 6 내지 17개의 탄소원자를 함유하는 화합물.
- 하기의 단계로 구성됨을 특징으로 하는, 제1항 또는 제2항에 따른 화합물의 제조방법: a) 디하이드로-1,4:3,6-D-글루시톨을 촉매의 존재하에 식 RCOOR′ 또는 RCH2Y의 화합물과 반응시켜 하기 화학식 (3) 및 (4)의 화합물을 형성시키고:(식중, Y는 할로겐 또는 알킬 또는 아릴술포닉 라디칼을 나타내고, R′는 수소원자 또는 1 내지 6개의 탄소원자를 갖는 아릴 라디칼을 나타내고, R은 탄소수 5 내지 21의 포화 또는 비포화된 직쇄형 또는 측쇄형 알킬 라디칼을 나타내고, X는 CO 또는 CH2을 나타낸다), b) 단계a) 의 생성물을 인산옥시클로리드, 염 및 무수용매와 반응시켜, 화학식 (1) 및/또는 (2)의 화합물을 형성하고, 그들을 임의로 분리시킨다.
- 제3항에 있어서, 디안히드로-1,4:3,6-D-글루시톨의 몰당량수 대 식 RCOOR′의 화합물의 몰당량수의 비율이 0.1 내지 20인 것을 특징으로 하는 방법.
- 제3항에 있어서, 디안히드로-1,4:3,6-D-글루시톨의 몰당량수 대 식 RCH2Y의 화합물의 몰당량수의 비율이 1 내지 20인 것을 특징으로 하는 방법.
- 제3항 내지 제5항 중 어느 한 항에 있어서,염기가 피리딘, N,N-디메틸-또는 -디메틸아미노-4-피리딘 및 3차 아민으로부터 선택되는 것을 특징으로 하는 방법.
- 제3항 내지 제6항 중 어느 한 항에 있어서, 포스포러스 옥시클로리드의 몰당량수 대 단계 a)의 생성물의 목당량수의 비율이 1 내지 5인 것을 특징으로 하는 방법.
- 위생용 조성물을 제조하기 위한 제1항 또는 제2항에 따른 화합물의 용도.
- 제8항에 있어서, 조성물이 샴푸 및 화장 또는 모발 조성물로부터 선택되는 것을 특징으로 하는 용도.
- 제9항에 있어서, 화장조성물이 연고, 크림, 미용밀크, 포밍 배쓰, 샤워겔 및 합성세제형 비누로 구성되는 군에 속하는 것을 특징으로 하는 용도.
- 직물의 대전방지처리를 위한 제1항 또는 제2항에 따른 화합물의 용도.
- 금속 처리를 위한 제1항 또는 제2항에 따른 화합물의 용도.
- 현탁중합화반응을 위한 제1항 또는 제2항에 따른 화합물의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9603813 | 1996-03-27 | ||
| FR9603813A FR2746801B1 (fr) | 1996-03-27 | 1996-03-27 | Esters phosphoriques d'alkyl ou d'acyl dianhydro-1,4:3,6-d- glucitol, procede de preparation et utilisations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR970065545A true KR970065545A (ko) | 1997-10-13 |
| KR100241566B1 KR100241566B1 (ko) | 2000-03-02 |
Family
ID=9490600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019970010954A KR100241566B1 (ko) | 1996-03-27 | 1997-03-27 | 알킬 또는 아실 디안히드로-1,4:3,6-d-글루시톨의 인산 에스테르화물, 그의 제조방법 및 용도 |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR100241566B1 (ko) |
| AU (1) | AU708838B2 (ko) |
| MX (1) | MX9702312A (ko) |
-
1997
- 1997-03-25 AU AU16518/97A patent/AU708838B2/en not_active Ceased
- 1997-03-26 MX MX9702312A patent/MX9702312A/es unknown
- 1997-03-27 KR KR1019970010954A patent/KR100241566B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| MX9702312A (es) | 1998-04-30 |
| KR100241566B1 (ko) | 2000-03-02 |
| AU1651897A (en) | 1997-10-02 |
| AU708838B2 (en) | 1999-08-12 |
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