KR970043338A - 밀 스케일을 이용한 산세 폐액 정제방법 - Google Patents

밀 스케일을 이용한 산세 폐액 정제방법 Download PDF

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Publication number
KR970043338A
KR970043338A KR1019950066202A KR19950066202A KR970043338A KR 970043338 A KR970043338 A KR 970043338A KR 1019950066202 A KR1019950066202 A KR 1019950066202A KR 19950066202 A KR19950066202 A KR 19950066202A KR 970043338 A KR970043338 A KR 970043338A
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KR
South Korea
Prior art keywords
waste liquid
mill scale
pickling
purification method
liquid purification
Prior art date
Application number
KR1019950066202A
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English (en)
Other versions
KR100368246B1 (ko
Inventor
이재영
변태봉
손진군
Original Assignee
김종진
포항종합제철주식회사
신창식
재단법인 산업과학기술연구소
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 김종진, 포항종합제철주식회사, 신창식, 재단법인 산업과학기술연구소 filed Critical 김종진
Priority to KR1019950066202A priority Critical patent/KR100368246B1/ko
Publication of KR970043338A publication Critical patent/KR970043338A/ko
Application granted granted Critical
Publication of KR100368246B1 publication Critical patent/KR100368246B1/ko

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/36Regeneration of waste pickling liquors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/02Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor with moving adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2215/00Separating processes involving the treatment of liquids with adsorbents
    • B01D2215/02Separating processes involving the treatment of liquids with adsorbents with moving adsorbents
    • B01D2215/021Physically moving or fluidising the adsorbent beads or particles or slurry, excluding the movement of the entire columns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Compounds Of Iron (AREA)

Abstract

철강 산세과정에서 밸출되는 산세 폐액중의 불순물을 제거하는 산세폐액 정제방법으로서, 특정 성분함량을 갖는 밀스케일을 이용한다. 밀스케일을 이용하여 흡착성이 강한 Fe(OH)3를 형성시킨 다음 Fe(OH)3가 폐액내의 불순물을 흡착 제거한다.

Description

밀 스케일을 이용한 산세 폐액 정제방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (1)

  1. 제철소의 철강산세공정에서 발생하는 산세폐액을 정제하는 방법에 있어서, α-Fe2O3함량이 10%이하이며, 금속 철(Fe)함량이 3.3%이상인 밀스케일을, 폐산내의 HCl몰비에 대하여 FeO로 환산한 밀스케일의 몰비가 0.5배이상되게 투입한후 30-90℃에서 20-80시간 용해하여 pH를 2.5-5되게 상승시켜 Fe(OH)3 스러지를 형성시킨 다음, 그 Fe(OH)3 스러지에 폐액내의 불순물이 흡착되게 하고, 불순물이 흡착된 상기 Fe(OH)3 스러지로 여과함을 특징으로 하는 산세폐액 정제방법
KR1019950066202A 1995-12-29 1995-12-29 밀스케일을이용한산세폐액정제방법 KR100368246B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019950066202A KR100368246B1 (ko) 1995-12-29 1995-12-29 밀스케일을이용한산세폐액정제방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019950066202A KR100368246B1 (ko) 1995-12-29 1995-12-29 밀스케일을이용한산세폐액정제방법

Publications (2)

Publication Number Publication Date
KR970043338A true KR970043338A (ko) 1997-07-26
KR100368246B1 KR100368246B1 (ko) 2003-05-12

Family

ID=37416299

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950066202A KR100368246B1 (ko) 1995-12-29 1995-12-29 밀스케일을이용한산세폐액정제방법

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KR (1) KR100368246B1 (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19990050174A (ko) * 1997-12-16 1999-07-05 이구택 산세폐액의 정제방법

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Publication number Publication date
KR100368246B1 (ko) 2003-05-12

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