KR960700287A - 발포 중합체 및 이를 제조하는 방법(foamed polymer and process for production thereof) - Google Patents

발포 중합체 및 이를 제조하는 방법(foamed polymer and process for production thereof)

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Publication number
KR960700287A
KR960700287A KR1019950702974A KR19950702974A KR960700287A KR 960700287 A KR960700287 A KR 960700287A KR 1019950702974 A KR1019950702974 A KR 1019950702974A KR 19950702974 A KR19950702974 A KR 19950702974A KR 960700287 A KR960700287 A KR 960700287A
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diisocyanate
polymer
isocyanate
mixture
group
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KR1019950702974A
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English (en)
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폴 브이. 파카스
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캐롤 에이. 딕슨
우드브리지 포옴 코오포레이숀
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Publication of KR960700287A publication Critical patent/KR960700287A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 충전물질을 포함하는 이소시아네이트계 발포 중합체에 관한 것으로서, 상기 충전물질은 중합체의 30 중량% 이상으로 존재하고, 비중은 2.0 미만이되, 단 충전물질은 멜라민이 아니어야 한다. 또한 본 발명은 이소시아네이트계 발포 중합체를 제조하는 방법에 관한 것이다. 이 방법은, 물, 촉매와, 물 및 촉매에 의해 표면이 습윤화되는 거의 불활성 충전물질로 구성된 제1혼합물을 제공하는 단계; 이소시아네이트와 활성 수소－포함 화합물을 포함하는 제2혼합물을 제공하는 단계로서; 상기 이소시아네이트와 활성 수소－포함 화합물이 거의 비반응된 상태인 단계; 제1혼합물과 제2혼합물을 혼합하므로써 반응 혼합물을 제공하는 단계; 반응혼합물을 팽창시키므로써 이소시아네이트계 발포 중합체를 제조하는 단계로 구성된다.

Description

발포 중합체 및 이를 제조하는 방법(FOAMED POLYMER AND PROCESS FOR PRODUSTION THEREOF)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (25)

  1. 물, 촉매와, 물 및 촉매를 위한 담체로서 작용하는 충전물질로 구성된 제1혼합물을 제공하는 단계; 이소시아네이트와 활성 수소－포함 화합물을 포함하는 제2혼합물을 제공하는 단계로서, 상기 이소시아네이트와 활성 수소－포함 화합물이 거의 비반응된 상태인 단계; 제1혼합물과 제2혼합물을 혼합하므로써 반응 혼합물을 제공하는 단계; 반응혼합물을 반응시키므로써 이소시아네이트계 발포 중합체를 제조하는 단계를 포함하는, 이소시아네이트계 발포 중합체를 제조하는 방법.
  2. 제1항에 있어서, 활성 수소－포함 화합물이 폴리올, 폴리아민, 폴리아미드, 폴리이민 및 폴리올아민으로 구성된 군중에서 선택되는 방법.
  3. 제1항에 있어서, 활성 수소－포함 화합물이 폴리올인 방법.
  4. 제3항에 있어서, 폴리올이 폴리에테르, 폴리에스테르, 폴리카보네이트, 폴리디엔 및 폴리카프롤락톤으로 구성된 군중에서 선택된 히드록실－말단 골조의 성분인 방법.
  5. 제3항에 있어서, 폴리올이 아디프산－에틸렌 글리콜 폴리에스테르, 폴리(부틸렌 글리콜), 폴리(프로필렌 글리콜) 및 히드록시－말단 폴리부타디엔으로 구성된 군중에서 선택되는 방법.
  6. 제3항에 있어서, 폴리올이 폴리에테르 폴리올인 방법.
  7. 제3항에 있어서, 폴리에테르 폴리올의 분자량이 약 200 내지 약 10,000인 방법.
  8. 제1항에 있어서, 활성 수소－포함 화합물이 폴리아민 또는 폴리알칼올아민인 방법.
  9. 제8항에 있어서, 폴리아민이 1급 및 2급 아민－말단 폴리에테르로 구성된 군중에서 선택되는 방법.
  10. 제1항에 있어서, 이소시아네이트가 하기 일반식으로 표시되는 방법:
  11. Q(NCO)i
  12. 상기식 중, i는 2 또는 그 이상의 정수이고, Q는 i기를 가진 유기 라디칼이다.
  13. 제1항에 있어서, 이소시아네이트가 1,6－헥사메틸렌 디이소시아네이트, 1,4－부틸렌 디이소시아네이트, 퍼푸릴리덴 디이소시아네이트, 2,4－톨루엔 디이소시아네이트, 2,6－톨루엔 디이소시아네이트, 2,4´－디페닐메탄 디이소시아네이트, 4,4´－디페닐메탄 디이소시아네이트, 4,4´－디페닐프로판 디이소시아네이트, 4,4´－디페닐－3,3´－디메틸 메탄 디이소시아네이트, 1,5－나프탈렌 디이소시아네이트, 1－메틸－2,4－디이소시아네이트－5－클로로벤젠, 2,4－디이소시아나토－s－트리아진, 1－메틸－2,4－디이소시아나토 시클로헥산, p－페닐렌 디이소시아네이트, m－페닐렌 디이소시아네이트, 1,4－나프탈렌 디이소시아네이트, 디아니시딘 디이소시아네이트, 비톨릴렌 디이소시아네이트, 1,4－크실릴렌 디이소시아네이트, 1,3－크실렌 디이소시아네이트, 비스－(4－이소시아나토페닐)메탄, 비스－(3－메틸－4－이소시아나토페닐)메탄, 폴리메틸렌 폴리페닐 폴리이소시아네이트 및 이들의 혼합물로 구성된 군중에서 선택되는 방법.
  14. 제1항에 있어서, 이소시아네이트가 2,4－톨루엔 디이소시아네이트, 2,6－톨루엔 디이소시아네이트 및 이들의 혼합물로 구성된 군중에서 선택되는 방법.
  15. 제1항에 있어서, 이소시아네이트가 (ⅰ) 2,4´－디페닐메탄 디이소시아네이트, 4,4´－디페닐메탄 디이소시아네이트 및 이들의 혼합물; 및 (ⅱ) 2,4－톨루엔 디이소시아네이트, 2,6－톨루엔 디이소시아네이트, 및 이들의 혼합물로 구성된 군중에서 선택된 이소시아네이트, 2,6－톨루엔 디이소시아네이트 및 이들의 혼합물로 구성된 군중에서 선택된 이소시아네이트와 상기 (ⅰ)의 혼합물로 주구성된 군중에서 선택되는 방법.
  16. 충전물질을 포함하는 이소시아네이트계 발포 중합체로서, 이 충전물질은 중합체의 약 30중량% 이상으로 존재하고, 비중은 약 2.0 미만이되, 단 충전물질이 멜라민이 아닌 중합체.
  17. 제14항에 있어서, 충전물질이 분쇄된 중합체로부터 유도된 중합체.
  18. 제14항에 있어서, 분쇄된 중합체가 충전된 중합체.
  19. 제14항에 있어서, 분쇄된 중합체가 비－충전된 중합체.
  20. 제14항에 있어서, 충전물질이 분쇄된 시트 성형 화합물인 중합체.
  21. 제14항에 있어서, 충전물질이 분쇄된 반응 사출성형된 중합체인 중합체.
  22. 제14항에 있어서, 충전물질이 재분쇄된 전체 타이어 또는 그 일부인 중합체.
  23. 제14항에 있어서, 충전물질이 분쇄된 이소시아네이트계 중합체 포말인 중합체.
  24. 제14항에 있어서, 충전물질이 재분쇄된 강화 반응 사출 성형된 탄성중합체인 중합체.
  25. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950702974A 1993-01-22 1994-01-21 발포 중합체 및 이를 제조하는 방법(foamed polymer and process for production thereof) KR960700287A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US799193A 1993-01-22 1993-01-22
US08/007,991 1993-01-22
US08/074,966 1993-06-11
US08/074,966 US5432204A (en) 1993-01-22 1993-06-11 Foamed polymer and process for production thereof
PCT/CA1994/000030 WO1994017117A1 (en) 1993-01-22 1994-01-21 Foamed polymer and process for production thereof

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US (3) US5432204A (ko)
EP (1) EP0680493A1 (ko)
JP (1) JPH08509249A (ko)
KR (1) KR960700287A (ko)
AU (1) AU5876894A (ko)
BR (1) BR9406071A (ko)
CA (2) CA2106453C (ko)
CZ (1) CZ188995A3 (ko)
PL (1) PL309946A1 (ko)
WO (1) WO1994017117A1 (ko)

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CA2106451A1 (en) 1994-07-23
JPH08509249A (ja) 1996-10-01
CA2106453A1 (en) 1994-07-23
US5668189A (en) 1997-09-16
US5422385A (en) 1995-06-06
BR9406071A (pt) 1995-12-12
WO1994017117A1 (en) 1994-08-04
CA2106453C (en) 2000-08-22
AU5876894A (en) 1994-08-15

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