KR960015165B1 - Soap compositions containing cosmetics - Google Patents

Soap compositions containing cosmetics Download PDF

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KR960015165B1
KR960015165B1 KR1019940020676A KR19940020676A KR960015165B1 KR 960015165 B1 KR960015165 B1 KR 960015165B1 KR 1019940020676 A KR1019940020676 A KR 1019940020676A KR 19940020676 A KR19940020676 A KR 19940020676A KR 960015165 B1 KR960015165 B1 KR 960015165B1
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soap
gold
coated
iron oxide
yellow
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KR1019940020676A
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Korean (ko)
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KR960007455A (en
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고종성
민선호
김광희
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주식회사 태평양
한동근
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/44Perfumes; Colouring materials; Brightening agents ; Bleaching agents
    • C11D9/444Dyes; Pigments
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/18Water-insoluble compounds
    • C11D9/20Fillers, abrasives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

This invention is provided to stabilize the material contained in a soap by decreasing activity of inorganic powders. The composite comprises sodium tallowate(65-85 wt %) and sodium cocoate(15-35 wt %), wherein the yellow pigments(0.01-10 wt %) made by doping inorganic powders with yellow iron oxide or doping yellow iron oxide with gold, are provided in the composite.

Description

금이 피복된 황색 안료를 함유하는 비누 조성물Soap Compositions Containing Gold-Coated Yellow Pigments

본 발명은 황색 산화철이 피복된 무기분체 또는 황색 산화철 표면에 금을 피복시킨 황색 안료에 관한 것으로, 더욱 상세하게는 상기 분체에 금을 피복시킴으로써 무기분체의 표면 활성을 소실시키고, 이렇게 활성이 소실된 안료를 함유함으로써 비누에 함유된 원료를 안정화시킬 수 있는 효과를 얻을 수 있는 금 피복된 황색 안료를 함유하는 비누 조성물에 관한 것이다.The present invention relates to an inorganic powder coated with yellow iron oxide or a yellow pigment coated with gold on a yellow iron oxide surface. More particularly, the surface activity of the inorganic powder is lost by coating gold on the powder, and thus the activity is lost. The present invention relates to a soap composition containing a gold-coated yellow pigment capable of obtaining the effect of stabilizing the raw material contained in the soap by containing the pigment.

종래 무기 분체를 함유하는 비누에 있어서, 무기 분체 외에도 각종 향료 및 약제가 함께 함유되어 있는데, 이러한 경우 무기 분체의 촉매 활성에 의해 향료 또는 약체의 분해가 촉진되며, 그 결과 변취, 변패를 일으켜 상품 가치를 저하시키는 문제가 있었다. 예를 들면, 리나롤 또는 리나릴아세테이트는 함께 함유된 산성 무기분체에 의해 쉽게 분해되어 본래의 방향(芳香)을 잃어버리게 되며, 또한 염기성 무기분체가 함유된 비누의 경우에는 α-피넨의 이성화 또는 벤즈알데히드의 불균화가 촉진되어 본래의 목적을 잃어버리는 문제가 있다.Conventionally, soaps containing inorganic powders contain various fragrances and drugs in addition to the inorganic powders. In this case, the decomposition of the perfumes or the drug is promoted by the catalytic activity of the inorganic powders, and as a result, deodorization and discoloration result in product value. There was a problem degrading. For example, linarol or linarylacetate is easily decomposed by the acidic inorganic powders contained therein and loses its original fragrance, and in the case of soaps containing basic inorganic powders, isomerization of α-pinene or There is a problem that the disproportionation of benzaldehyde is promoted and the original purpose is lost.

또한, 종래 금을 함유하는 비누에 있어서, 금은 금박의 형태로 함유되는데, 분산성이 불량하여 불균일하게 분산되고 기타 조성물과 혼합이 어려우며, 외관이 불량하여 상품가치를 저하기시키는 문제점이 있었다.In addition, in the soap containing gold in the prior art, gold is contained in the form of gold foil, it has a problem in that the dispersibility is poorly dispersed, it is difficult to mix with other compositions, poor appearance and lower the value of the product.

이에, 본 발명자들은 통상의 비누소지에 무기 분체가 함유되는 비누에 있어서, 무기 분체의 촉매 활성을 저하시키고, 이로써 비누에 함유된 그외 성분의 안정화를 도모할 수 있는 방법을 연구하던 중, 무기 분체를 금으로 피복시킴으로써 그의 촉매 활성을 현저히 억제할 수 있음을 발견하고 본 발명을 완성하기에 이르렀다.Therefore, the inventors of the present invention, while researching a method for reducing the catalytic activity of the inorganic powder in the soap containing the inorganic powder in the ordinary soap base, thereby achieving stabilization of the other components contained in the soap, inorganic powder It has been found that the catalyst activity can be remarkably suppressed by coating with gold, thus completing the present invention.

따라서, 본 발명의 목적은 무기분체의 촉매 활성을 현저히 억제시킬 수 있으며, 나아가 피부 신진대사를 촉진하여 피부의 건강을 유지할 수 있고, 또 금색에 의한 시각적 쾌감을 줄 수 있는 비누 조성물을 제공하는 것이다.Accordingly, an object of the present invention is to provide a soap composition that can significantly inhibit the catalytic activity of the inorganic powder, further promote skin metabolism, maintain the health of the skin, and give a visual pleasure by the golden color .

상기와 같은 본 발명의 목적은 황색 산화철이 피복된 무기 분체 또는 황색 산화철을 금으로 피복시킨 황색 안료를 함유함으로써 달성될 수 있다.The object of the present invention as described above can be achieved by containing an inorganic powder coated with yellow iron oxide or a yellow pigment coated with yellow iron oxide with gold.

본 원발명에서 사용하고 있는 비누소지는 본 기술분야에서 통상적으로 사용되는 비누소지로서 65~85중량%의 나트륨 탈로우에이트(sodium tallowate)와 15~35중량%의 나트륨 코코에이트(sodium cocoate)로 구성된 비누소지이다[참조; Soap Technology For The 1990's].Soap bases used in the present invention are soap bases commonly used in the art as 65 to 85% by weight of sodium tallowate and 15 to 35% by weight of sodium cocoate. Composed of soaps [see; Soap Technology For The 1990's.

본 발명에 따른 금이 피복된 황색 안료는 황색 산화철이 피복된 무기분체, 예를 들면, 운모, 실리카, 이산화티탄, 산화아연, 산화지르코늄, 탈크, 카오린, 산화철, 알루미나 등의 금속 산화물에 황색 산화철을 피복시킨 것; 또는 단일 황색 산화철에 금을 피복시킨 것이다. 이러한 황색 산화철이 피복된 무기 분체 또는 황색 산화철은 그들의 평균입경이 0.01~20㎛인 것이 바람직하다.The gold-coated yellow pigment according to the present invention is an inorganic powder coated with yellow iron oxide, for example, mica, silica, titanium dioxide, zinc oxide, zirconium oxide, talc, kaolin, iron oxide, alumina and the like, yellow iron oxide Coated; Or a single yellow iron oxide coated with gold. It is preferable that the inorganic powder or yellow iron oxide coated with such yellow iron oxide have an average particle diameter of 0.01 to 20 µm.

상기 황색 산화철이 피복된 무기분체 또는 황색 산화철에 금을 피복시키는 방법으로는, 상기 분체를 수금 희석액에 현탁, 분산시킨 후 450~600℃에서 소결시키는 수금법에 의해 행해진다. 이렇게 고온 소결된 수금은 순금으로 변하여 상기 분체에 피복되어 금계통의 금색 안료가 된다.As a method of coating gold with the said yellow iron oxide-coated inorganic powder or yellow iron oxide, it is performed by the collection method which suspends and disperse | distributes the said powder in dilution liquid of liquid, and sinters at 450-600 degreeC. The hot sintered molten metal is converted into pure gold and coated on the powder to become a gold pigment of the gold system.

상기에서 사용된 수금은 금, 터펜타인오일, 유황의 혼합물로서, 이를 희석액에 1~50%(w/w) 농도로 희석하여 사용한다.The collection used above is a mixture of gold, turpentine oil, and sulfur, which is diluted to a concentration of 1 to 50% (w / w) in a diluent.

본 발명의 비누 조성물은 상기의 방법으로 금을 피복시켜 얻은 황색 안료를 비누 조성물 총 중량에 대해 0.01~10중량%로 함유함을 특징으로 한다.The soap composition of the present invention is characterized in that it contains 0.01 to 10% by weight of the yellow pigment obtained by coating the gold by the above method with respect to the total weight of the soap composition.

이하, 본 발명의 보다 구체적인 이해를 위해 본 발명의 실시예를 들어 본 발명을 설명한다.Hereinafter, the present invention will be described with reference to embodiments of the present invention for a more specific understanding of the present invention.

[실시예 1]Example 1

황색 산화철이 피복된 입경 1~20㎛의 운모 50g을 수금 5g과 희석액 DH-92(DAGUSSA社) 100g을 넣어 30분간 교반시킨 후, 200℃에서 1차 소결 시킨 후, 550℃에서 2차 소결하여 금이 피복된 황색 안료(a)를 얻었다.50 g of mica having a particle size of 1-20 μm coated with yellow iron oxide was added with 5 g of gold and 100 g of diluent DH-92 (DAGUSSA), followed by stirring for 30 minutes. A yellow pigment (a) coated with gold was obtained.

[실시예 2]Example 2

실시예 1에서 운모 대신 실리카를 사용하는 것을 제외하고는 실시예 1과 동일한 방법으로 실시하여 금이 피복된 황색 안료(b)를 얻었다.A yellow pigment (b) coated with gold was obtained in the same manner as in Example 1 except that silica was used instead of mica in Example 1.

[실시예 3]Example 3

실시예 1에서 운모 대신 산화아연을 사용하는 것을 제외하고는 실시예 1과 동일한 방법으로 실시하여 금이 피복된 황색 안료(c)를 얻었다.A yellow pigment (c) coated with gold was obtained in the same manner as in Example 1 except that zinc oxide was used instead of mica in Example 1.

[실시예 4]Example 4

실시예 1에서 운모 대신 산화지르코늄을 사용하는 것을 제외하고는 실시예 1과 동일한 방법으로 실시하여 금이 피복된 황색 안료(d)를 얻었다.A yellow pigment (d) coated with gold was obtained in the same manner as in Example 1 except that zirconium oxide was used instead of mica in Example 1.

[실시예 5]Example 5

실시예 1에서 운모 대신 알루미나를 사용하는 것을 제외하고는 실시예 1과 동일한 방법으로 실시하여 금이 피복된 황색 안료(e)를 얻었다.A yellow pigment (e) coated with gold was obtained in the same manner as in Example 1 except that alumina was used instead of mica in Example 1.

[실시예 6]Example 6

실시예 1에서 황색 산화철이 피복된 운모 대신 단일 황색 산화철 50g을 사용하는 것을 제외하고는 실시예 1과 동일한 방법으로 실시하여 금이 피복된 황색 안료(f)를 얻었다.A yellow pigment (f) coated with gold was obtained in the same manner as in Example 1, except that 50 g of a single yellow iron oxide was used instead of mica coated with yellow iron oxide in Example 1.

[실시예 7~12]EXAMPLES 7-12

상기 실시예 1~6에서 얻은 황색 안료 1중량%를 함유하는 비누를 통상의 방법에 따라 제조하였다. 안료를 제외한 비누 조성물은 하기와 같았다.A soap containing 1% by weight of the yellow pigment obtained in Examples 1 to 6 was prepared according to a conventional method. The soap composition except the pigment was as follows.

[비교예 1~6][Comparative Examples 1-6]

황색 산화철이 피복된 입경 1~20㎛의 운모(비교예 1), 실리카(비교예 2), 산화아연(비교예 3), 산화지르코늄(비교예 4), 알루미나(비교예 5)를, 또는 단일 황색 산화철(비교예 6) 1중량%와, 금 박막 0.02중량%를 상기 실시예 7의 안료가 제외된 조성물에 혼합하여 통상의 방법으로 비누를 제조하였다.Mica having a particle size of 1 to 20 µm coated with yellow iron oxide (Comparative Example 1), silica (Comparative Example 2), zinc oxide (Comparative Example 3), zirconium oxide (Comparative Example 4), alumina (Comparative Example 5), or Soap was prepared in a conventional manner by mixing 1% by weight of a single yellow iron oxide (Comparative Example 6) and 0.02% by weight of a gold thin film to the composition without the pigment of Example 7.

[시험예 1][Test Example 1]

저장성 평가Hypotonic evaluation

상기 실시예 7~12 및 비교예 1~6에서 얻은 비누의 저장성을 비교하기 위하여 상온(25℃)에서 6개월 동안, 40℃에서 2개월 동안 보관한 후 변취정도와 변패정도를 19~40세의 전문 검사요원 남녀 50명에 의한 5점 평가법으로 비교하여 얻은 점수의 평균치를 얻었다. 그 결과는 표 2와 같았다.In order to compare the shelf life of the soaps obtained in Examples 7 to 12 and Comparative Examples 1 to 6 for 6 months at room temperature (25 ℃), after storing for 2 months at 40 ℃ for 19 to 40 years The average value of the scores obtained by comparing the five-point evaluation method by 50 male and female professional inspectors was obtained. The results were shown in Table 2.

1 : 심한 악취; 심하게 물러지는 등 심한 부패현상을 볼 수 있음.1: severe odor; Severe corruption can be seen, including severe retreat.

2 : 심한 악취; 부분적으로 물러지는 등 약간의 부패현상을 볼 수 있음.2: severe odor; Some corruption may be seen, such as partially receding.

3 : 약간의 악취; 부분적으로 물러지는 등 약간의 부패현상을 볼 수 있음.3: slight odor; Some corruption may be seen, such as partially receding.

4 : 약간의 악취; 부패현상이 관찰되지 않음.4: slight odor; No corruption was observed.

5 : 변취현상, 부패현상 관찰되지 않음.5: No odor, no corruption.

[시험예 2][Test Example 2]

비누의 전체적인 색감 비교Compare the overall color of the soap

상기 실시예 7~12 및 비교예 1~6에서 얻은 비누의 색감을 비교하기 위하여, 20~40대의 주부 50을 대상으로 하여 대조군[상기 비교예의 비누 조성에서 금박을 함유하지 않는 것을 제외하고 동일한 조성으로 비누 제조]의 비누에서 느끼는 색감을 1로 하고, 실시예 및 비교예에서 얻은 비누의 색감을 다음의 4점 채점 평가법으로 비교하여 평균값을 얻었다. 그 결과를 표 3에 나타내었다.In order to compare the color of the soap obtained in Examples 7 to 12 and Comparative Examples 1 to 6, the control group [the same composition except that the gold composition is not included in the soap composition of the Comparative Example, targeting a housewife 50 in their 20s and 40s. '' Soap color of the soap produced by Soap] was 1, and the color value of the soap obtained in Examples and Comparative Examples was compared by the following four-point scoring method to obtain an average value. The results are shown in Table 3.

-1 : 대조군에 비해 오히려 좋지 않음.-1: not good compared to the control.

0 : 대조군과 비슷한 정도.0: similar to control group.

1 : 대조군에 비해 금색으로 인한 화려한 색감을 느낄 수 있으나, 전체적으로 불균일한 색채 부여.1: Compared to the control group, you can feel the colorful color caused by gold, but it gives an uneven color overall.

2 : 대조군에 비해 전체적으로 균일한 금색, 화려한 색감 부여.2: Provides uniform gold and brilliant color overall compared to the control.

[시험예 3][Test Example 3]

피부 자극 정도 비교Skin irritation degree comparison

상기 실시예 7과 비교예 1에서 얻은 비누의 피부 자극 정도 및 전체적인 사용감을 비교하기 위하여, 20~40대의 주부 50을 대상으로 하여 14일 동안 아침, 저녁 하루 두차례의 세안시에 왼쪽 얼굴에는 실시예 7에서 얻은 비누를, 오른쪽 얼굴에는 비교예 1에서 얻은 비누를 사용하게 하여, 피부 자극 정도를 다음의 3점 채점법으로 비교하게 하여 그 평균값을 얻었다. 그 결과는 다음의 표 4와 같았다.In order to compare the skin irritation degree and overall feeling of use of the soap obtained in Example 7 and Comparative Example 1, a 50-year-old housewife 50 was carried out on the left face during two days of washing and washing for 14 days. The soap obtained in Example 7 was used as the soap obtained in Comparative Example 1 for the right face, the skin irritation degree was compared by the following three-point scoring method, and the average value was obtained. The results were as shown in Table 4 below.

-1 : 약간의 홍반이 생기는 등의 약간의 부작용, 사용후 화끈거림을 약간 느낌.-1: slight side effects, such as slight erythema, slightly burning after use.

0 : 부작용 거의 없음.0: Almost no side effects.

1 : 부작용 전혀 없으며, 사용후 촉촉함이 남고, 피부가 매끄러워짐, 전체적인 사용감 우수.1: No side effects, after use leave moisture, smooth skin, excellent overall feeling.

상기 시험예 1, 2 및 3에 알 수 있는 바와 같이, 본 발명에 따른 황색 안료를 함유하는 비누는 무기분체에 피복되어 있는 금이 무기분체의 표면 활성을 억제하기 때문에 무기분체를 그대로 함유하는 비누에 비해 변취, 변패 정도가 덜하고, 따라서 피부자극이 거의 없으며, 오히려 사용후 피부에 촉촉함을 주기 때문에 사용감이 개선된 효과를 얻을 수 있으며, 금색 분체가 균일하게 분산, 함유됨으로써 아름다운 금색의 외관에 의해 우수한 색감 효과를 얻을 수 있다.As can be seen in Test Examples 1, 2 and 3, the soap containing the yellow pigment according to the present invention is a soap containing the inorganic powder as it is because the gold coated on the inorganic powder inhibits the surface activity of the inorganic powder. Compared with less odor and deterioration, and there is almost no skin irritation, rather it gives moisture to the skin after use, improving the feeling of use, and the gold powder is uniformly dispersed and contained, resulting in a beautiful gold appearance. By this, excellent color effect can be obtained.

Claims (2)

65 내지 85중량%의 나트륨 탈로우에이트와 15내지 35중량%의 나트륨 코코에이트로 구성된 비누소지를 함유하는 조성물에 있어서, 조성물 총 중량을 기준으로 황색 산화철로 피복된 무기분체 또는 황색 산화철을 금으로 피복시켜서 얻은 황색 안료 0.01 내지 10중량%를 함유함을 특징으로 하는 비누 조성물.A composition comprising a soap body consisting of 65 to 85% by weight sodium tallowate and 15 to 35% by weight sodium cocoate, wherein the inorganic powder or yellow iron oxide coated with yellow iron oxide is coated with gold based on the total weight of the composition. A soap composition comprising 0.01 to 10% by weight of a yellow pigment obtained by coating. 제1항에 있어서, 상기 금이 피복된 황색 안료를 비누 조성물 총 중량에 대해 0.01~10중량%로 함유함을 특징으로 하는 비누 조성물.The soap composition according to claim 1, wherein the soap-containing yellow pigment is contained in an amount of 0.01 to 10% by weight based on the total weight of the soap composition.
KR1019940020676A 1994-08-22 1994-08-22 Soap compositions containing cosmetics KR960015165B1 (en)

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