KR960010757A - 내오염성이 우수한 광경화형 수지조성물 및 이의 제품 - Google Patents

내오염성이 우수한 광경화형 수지조성물 및 이의 제품 Download PDF

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Publication number
KR960010757A
KR960010757A KR1019940024336A KR19940024336A KR960010757A KR 960010757 A KR960010757 A KR 960010757A KR 1019940024336 A KR1019940024336 A KR 1019940024336A KR 19940024336 A KR19940024336 A KR 19940024336A KR 960010757 A KR960010757 A KR 960010757A
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South Korea
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weight
parts
resin composition
photocurable
photocurable resin
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KR1019940024336A
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English (en)
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KR0131008B1 (ko
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김상근
홍진후
김정득
김창수
김성호
황공현
최철규
이행우
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박원배
한화종합 주식회사
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Priority to KR1019940024336A priority Critical patent/KR0131008B1/ko
Priority to US08/534,719 priority patent/US5703139A/en
Priority to JP7249426A priority patent/JP2650880B2/ja
Publication of KR960010757A publication Critical patent/KR960010757A/ko
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Publication of KR0131008B1 publication Critical patent/KR0131008B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10—Esters
    • C08F22/1006—Esters of polyhydric alcohols or polyhydric phenols, e.g. ethylene glycol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/24—Homopolymers or copolymers of amides or imides
    • C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1668—Vinyl-type polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

본 발명은 각종 기재에 대하여 접착력이 있으면서도 대전방지성 및 내오염성을 나타내는 광경화형 수지 조성물 및 이의 제품에 관한 것이다. 특히 본 조성물은 염화비닐수지 바닥재의 피복물에 유용한 것이다. 본 발명의 조성물은 암모늄염을 함유하는 예비 중합체 100중량부, 상기 예비 중합체 100중량부에 대하여 광경화형 모노머(반응형 회석제) 50-400중량부, 최종 수지조성물 100중량부에 대하여 광개시제 2-40중량부 및 소량의 기타 첨가제로 이루어진다.

Description

내오염성이 우수한 광경화형 수지조성물 및 이의 제품
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 하기 식Ⅰ로 표시되는 암모늄염을 함유하는 예비 중합체 100중량부, 상기 예비 중합체 100중량부에 대하여 광경화형 모노머(반응형 회석제) 50-400중량부, 최종 수지조성물 100중량부에 대하여 광개시제 2-40중량부 및 소량의 기타 첨가제로 이루어지는 것을 특징으로 하는 광경화형 수지 조성물.
    (Ⅰ)
    상기식에서 R1은 -〔-O(CH2)1-〕-로 표시되는 알킬기로써 1은 2 내지 6의 정수이며, R2는으로 표시되며, m은 1 내지 6의 정수이며, R3는
    로 표시되며, 여기서 n,o 및 q는 1 내지 6의 정수이고, P는 0 내지 6의 정수이며, X는 Cl,Br 또는 SO3CH3이고, a+b+c=3이며, 이때 c는 필수성분이고, a 및 b는 선택적으로 사용되며, W는
  2. 제1항에 있어서, 상기 광경화형 모노머가 히드록시에틸 아크릴레이트, 히드록시프로필아크릴레이트, 헥산디올디아크릴레이트, 헥사메틸렌디아크릴레이트, 트리프로필렌글리콜디아크릴레이트 및 트리메틸올트리아크릴레이트로 구성된 군으로부터 둘 또는 그이상 선택됨을 특징으로 하는 광경화형 수지 조성물.
  3. 제1항에 있어서, 상기 광개시제가 1-하이드록시시클로헥실페닐 케톤 및/또는 2-하이드록시-2-메틸-1페닐프로판-1-온임을 특징으로 하는 광경화형 수지 조성물.
  4. 제1항 내지 제3항중 어느 한 항의 조성물을 메틸메타아크릴레이트 수지, 염화비닐수지 또는 카보네이트 수지로 제조된 제품의 표면에 도막 두께를 10~200㎛를 도포시키고, 이를 경화시켜 제조된 제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940024336A 1994-09-27 1994-09-27 대오염성이 우수한 광경화형 수지 조성물 및 이의 제품 KR0131008B1 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1019940024336A KR0131008B1 (ko) 1994-09-27 1994-09-27 대오염성이 우수한 광경화형 수지 조성물 및 이의 제품
US08/534,719 US5703139A (en) 1994-09-27 1995-09-27 Photo-curable resin composition and product coated therewith
JP7249426A JP2650880B2 (ja) 1994-09-27 1995-09-27 光硬化性樹脂組成物及び被覆製品

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019940024336A KR0131008B1 (ko) 1994-09-27 1994-09-27 대오염성이 우수한 광경화형 수지 조성물 및 이의 제품

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KR960010757A true KR960010757A (ko) 1996-04-20
KR0131008B1 KR0131008B1 (ko) 1998-04-13

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KR1019940024336A KR0131008B1 (ko) 1994-09-27 1994-09-27 대오염성이 우수한 광경화형 수지 조성물 및 이의 제품

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US (1) US5703139A (ko)
JP (1) JP2650880B2 (ko)
KR (1) KR0131008B1 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030011431A (ko) * 2001-08-02 2003-02-11 주식회사 큐시스 2,2,6,6-테트라메틸피페리딘 유도체가 도입된 반응형우레탄 아크릴레이트, 이의 제조방법 및 이를 함유한광경화형 수지 조성물

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19956483A1 (de) * 1999-11-24 2001-06-28 Basf Coatings Ag Lackierte Kunststoffformteile, Verfahren zu ihrer Herstellung und ihre Verwendung
JP2002069139A (ja) * 2000-08-30 2002-03-08 Dainippon Ink & Chem Inc 活性エネルギー線硬化型樹脂組成物
KR100887324B1 (ko) * 2000-11-21 2009-03-05 임페리알 케미칼 인더스트리즈 리미티드 에스테르화 촉매, 폴리에스테르 방법 및 폴리에스테르 물품
DE50105415D1 (de) * 2001-01-08 2005-03-31 Technoform Caprano Brunnhofer Verfahren zur Herstellung von pulverlackierten Kunststoffprofilen
JP4657584B2 (ja) * 2002-03-29 2011-03-23 三洋化成工業株式会社 酢酸セルロースフィルム用放射線硬化型樹脂組成物
GB0228267D0 (en) 2002-12-04 2003-01-08 Johnson Matthey Plc Catalyst and process
KR100579007B1 (ko) * 2003-08-13 2006-05-12 주식회사 루밴틱스 대전 방지 특성을 가진 광섬유 코팅용 광경화형 고분자수지 조성물
KR100650436B1 (ko) * 2004-11-22 2006-11-29 엘지마이크론 주식회사 대전방지 저중합체
WO2006083344A2 (en) * 2005-02-01 2006-08-10 Henkel Corporation Liquid stable thiol-acrylate/vinyl ether compositions
JP4993364B2 (ja) * 2007-08-07 2012-08-08 Ｄｉｃ株式会社 光学物品用活性エネルギー線硬化型樹脂組成物
KR101330784B1 (ko) * 2008-01-14 2013-11-18 엘지이노텍 주식회사 저중합체, 이의 제조방법, 이를 포함하는 광학 수지조성물, 및 이로부터 제조된 디스플레이용 광학 시이트
KR101053298B1 (ko) * 2008-05-16 2011-08-01 율촌화학 주식회사 라벨 및 그 제조 방법
US10000588B2 (en) * 2011-07-28 2018-06-19 Eastman Chemical Company Coating for the inner surface of plastic bottles for protection against degradation from volatile organic compounds
JP6010352B2 (ja) * 2012-06-07 2016-10-19 株式会社オートネットワーク技術研究所 硬化性増感剤、光硬化材料、硬化物及びワイヤーハーネス材料
CN103980215B (zh) * 2014-05-23 2016-07-06 中国科学院长春应用化学研究所 一种水性聚氨酯丙烯酸酯低聚体、其制备方法和水性紫外光固化涂料

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5235399B2 (ko) * 1973-07-31 1977-09-08
DE3941788A1 (de) * 1989-12-19 1991-06-20 Bayer Ag Verfahren zur herstellung von schaumstoffhaltigen polyurethan(harnstoff)-massen
ES2100302T3 (es) * 1991-11-01 1997-06-16 Witco Corp Procedimiento para la fabricacion de composiciones de poliuretano cationico y sales de amonio cuaternario.
KR950006945B1 (ko) * 1991-12-31 1995-06-26 고려화학주식회사 광경화형 도막 조성물 및 이를 이용한 바닥재

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030011431A (ko) * 2001-08-02 2003-02-11 주식회사 큐시스 2,2,6,6-테트라메틸피페리딘 유도체가 도입된 반응형우레탄 아크릴레이트, 이의 제조방법 및 이를 함유한광경화형 수지 조성물

Also Published As

Publication number Publication date
JP2650880B2 (ja) 1997-09-10
US5703139A (en) 1997-12-30
JPH08239541A (ja) 1996-09-17
KR0131008B1 (ko) 1998-04-13

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