KR950702591A - 투명도가 높은 중간색 제품 제조용 폴리에스테르 수지(polyester resin for the production of high-transparency, neutral-coloured articles) - Google Patents

투명도가 높은 중간색 제품 제조용 폴리에스테르 수지(polyester resin for the production of high-transparency, neutral-coloured articles) Download PDF

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Publication number
KR950702591A
KR950702591A KR1019950700037A KR19950700037A KR950702591A KR 950702591 A KR950702591 A KR 950702591A KR 1019950700037 A KR1019950700037 A KR 1019950700037A KR 19950700037 A KR19950700037 A KR 19950700037A KR 950702591 A KR950702591 A KR 950702591A
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KR
South Korea
Prior art keywords
polyester resin
compound
ppm
germanium
polyhydric alcohol
Prior art date
Application number
KR1019950700037A
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English (en)
Inventor
볼프강 크라메르
비헬름 뷜샤이트
테오도르 위르겐스
클라우스 클라이네크
루돌프 가이에르
Original Assignee
게랄트 베. 뮐러
존 브라운 도이취 엔지니어링 게엠베아(JOHN BROWN DEUTSCHE ENGINEERING GmbH)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 게랄트 베. 뮐러, 존 브라운 도이취 엔지니어링 게엠베아(JOHN BROWN DEUTSCHE ENGINEERING GmbH) filed Critical 게랄트 베. 뮐러
Publication of KR950702591A publication Critical patent/KR950702591A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)

Abstract

본 발명은 투명도가 높은 중간색의 벽이 두꺼운 병을 제조하는데 사용되는 폴리에스테르 수지에 관한 것이다. 상기 폴리에스테르 수지는 최소한 하나의 안티몬 화합물, 하나의 게리마늄 화합물 및 인 화합물을 함유하며 디카르복실산과 다가 알코올을 반응시키므로써 제조되고 또한 시클로헥산디메탄올을 추가로 함유한다. 상기 다가 알코올은 에틸렌 글리콜과 0.5% 이상의 시클로헥산 디메탄올의 혼합물이다. 본 발명에 의하면, 결정화 속도가 낮아서 벽이 두꺼운 중공형 부재를 제조할 수 있다.

Description

투명도가 높은 중간색 제품 제조용 폴리에스테르 수지(POLYESTER RESIN FOR THE PRODUCTION OF HIGH-TRANSPARENCY, NEUTRAL-COLOURED ARTICLES)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 투명도가 높은 중간색의 제품을 제조하는데 사용되며, 최소한 하나의 안티몬 화합물과 하나의 인 화합물의 형태로 된 하나 이상의 촉매를 함유하고, 디카르복실산과 다가 알코올을 반응시키므로써 제조되는 폴리에스테르 수지에 있어서, 게르마늄 화합물과 시클로헥산 디메탄올(CHDM)을 추가로 함유하며, 상기 다가 알코올이 에틸렌 글리콜과 0.5% 이상의 시클로헥산 디메탄올의 혼합물인 것을 특징으로 하는 폴리에스테르 수지.
  2. 제1항에 있어서, 주석 화합물을 추가로 함유하는 것을 특징으로 하는 폴리에스테르 수지.
  3. 제1항 또는 제2항에 있어서, 칼륨 화합물을 추가로 함유하는 것을 특징으로 하는 폴리에스테르 수지.
  4. 제1항 또는 제3항중 어느 한 항에 있어서, 코발트 화합물을 추가로 함유하는 것을 특징으로 하는 폴리에스테르 수지.
  5. 제1항 또는 제4항중 어느 한 항에 있어서, 반응에 사용된 디카르복실산이 테레프탈산 또는 이소프탈산 또는 이들 2가지 산의 혼합물인 것을 특징으로 하는 폴리에스테르 수지.
  6. 제1항 또는 제5항중 어느 한 항에 있어서, 활성 성분을 기준으로 하여, 0.5-15%의 CHDM, 50-350ppm의 안티몬화합물, 1-100ppm의 게르마늄 화합물, 및 1-125ppm의 인 화합물을 함유하는 것을 특징으로 하는 폴리에스테르 수지.
  7. 제1항 또는 제6항중 어느 한 항에 있어서, 게르마늄 원소로서 측정하여 10ppm의 게르마늄 화합물을 함유하는 것을 특징으로 하는 폴리에스테르 수지.
  8. 제1항 또는 제7항중 어느 한 항에 있어서, 정의한 폴리에스테르 수지로부터 제조된 중공형 부재, 특히 벽이 두꺼운 중공형(hollow) 용기.
  9. 제8항에 있어서, 벽이 두꺼운 병인 중공형 부재.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950700037A 1992-07-07 1993-06-25 투명도가 높은 중간색 제품 제조용 폴리에스테르 수지(polyester resin for the production of high-transparency, neutral-coloured articles) KR950702591A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DEP4222244.3 1992-07-07
DE4222244 1992-07-07
DEP4319008.1 1993-06-08
DE4319008A DE4319008A1 (de) 1992-07-07 1993-06-08 Polyesterharz zur Herstellung von Gegenständen mit hoher Klarheit und neutraler Farbe
PCT/DE1993/000565 WO1994001482A1 (de) 1992-07-07 1993-06-25 Polyesterharz zur herstellung von gegenständen mit hoher klarheit und neutraler farbe

Publications (1)

Publication Number Publication Date
KR950702591A true KR950702591A (ko) 1995-07-29

Family

ID=25916359

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950700037A KR950702591A (ko) 1992-07-07 1993-06-25 투명도가 높은 중간색 제품 제조용 폴리에스테르 수지(polyester resin for the production of high-transparency, neutral-coloured articles)

Country Status (7)

Country Link
US (1) US5596068A (ko)
EP (1) EP0649442A1 (ko)
KR (1) KR950702591A (ko)
CN (1) CN1039020C (ko)
DE (1) DE4319008A1 (ko)
MY (1) MY109201A (ko)
WO (1) WO1994001482A1 (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5608031A (en) * 1995-11-30 1997-03-04 Eastman Chemical Company Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system
TW381104B (en) * 1996-02-20 2000-02-01 Eastman Chem Co Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol
US6103857A (en) * 1997-06-19 2000-08-15 Eastman Chemical Company Poly(ethylene terephthalate) (PET) copolymers containing both 1,4-cyclohexanedimethanol and isophthalic acid moieties
US6197878B1 (en) 1997-08-28 2001-03-06 Eastman Chemical Company Diol latex compositions and modified condensation polymers
JP3634613B2 (ja) * 1998-02-09 2005-03-30 帝人株式会社 ポリエチレンナフタレンジカルボキシレート
US6246112B1 (en) * 1998-06-11 2001-06-12 Intel Corporation Interleaved signal trace routing
IT1306208B1 (it) * 1999-01-18 2001-05-30 Geogreen S P A Sistema di catalisi e correzione ottica per la produzione dipoliesteri termoplastici con elevate proprieta' ottiche.
WO2000052083A1 (en) 1999-03-03 2000-09-08 Eastman Chemical Company Silicone polymer diol compositions and condensation polymer/silicone polymer blends
EP1161497B1 (en) 1999-03-03 2003-05-07 Eastman Chemical Company Polyamide/emulsion polymer blends
BR0011676A (pt) 1999-06-18 2002-03-12 Eastman Chem Co Método de produção de uma mistura de polìmero de náilon 6/silicone, produto, mistura de polìmero de nãilon 6/silicone, e, método para produção de uma mistura de polìmero tipo amida/polìmero de silicone produto
JP2003503518A (ja) 1999-06-18 2003-01-28 イーストマン ケミカル カンパニー アミド型ポリマー／シリコーンポリマーブレンド及びその製造方法
US9777111B2 (en) * 2005-10-20 2017-10-03 Grupo Petrotemex, S.A. De C.V. PET polymer with improved properties
WO2014046519A1 (ko) 2012-09-24 2014-03-27 에스케이케미칼주식회사 색상이 우수한 폴리사이클로헥실렌디메틸렌테레프탈레이트 수지의 제조방법 및 이에 의해 제조된 폴리사이클로헥실렌디메틸렌테레프탈레이트 수지
WO2015128202A1 (en) * 2014-02-25 2015-09-03 Biochemtex S.P.A. Continuous process for producing an ethylene glycol stream

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440924A (en) * 1982-10-05 1984-04-03 Toyo Boseki Kabushiki Kaisha Process for production of polyester
JPS63139725A (ja) * 1986-12-02 1988-06-11 Diafoil Co Ltd ポリエステル系収縮フイルム
EP0501543B1 (en) * 1991-02-28 1998-05-20 Agfa-Gevaert N.V. Process for the production of polyesters with increased electroconductivity
JPH04304228A (ja) * 1991-04-01 1992-10-27 Teijin Ltd ボトル成形用ポリエステル

Also Published As

Publication number Publication date
MY109201A (en) 1996-12-31
EP0649442A1 (de) 1995-04-26
CN1083823A (zh) 1994-03-16
CN1039020C (zh) 1998-07-08
US5596068A (en) 1997-01-21
WO1994001482A1 (de) 1994-01-20
DE4319008A1 (de) 1994-01-13

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