KR950700259A - 아릴 인다졸 및 이를 이용한 제초제 조성물과 식물의 억제방법 - Google Patents

아릴 인다졸 및 이를 이용한 제초제 조성물과 식물의 억제방법

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KR950700259A
KR950700259A KR1019940703130A KR19940703130A KR950700259A KR 950700259 A KR950700259 A KR 950700259A KR 1019940703130 A KR1019940703130 A KR 1019940703130A KR 19940703130 A KR19940703130 A KR 19940703130A KR 950700259 A KR950700259 A KR 950700259A
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alkyl
hydrogen
halogen
amino
haloalkyl
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KR1019940703130A
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English (en)
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알. 제임스 도날드
알. 베이커 돈
디. 밀리치 스티븐
제이. 마이클리 윌리암
피츠존 스티븐
지. 크눗센 크리스토퍼
매튜스 크리스토퍼
엠. 거드스 존
Original Assignee
수잔 제인 젠틀
제네카 리미티드
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Priority claimed from PCT/US1993/001961 external-priority patent/WO1993018008A1/en
Publication of KR950700259A publication Critical patent/KR950700259A/ko

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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/54—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings condensed with carbocyclic rings or ring systems
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    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
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    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
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    • C07D—HETEROCYCLIC COMPOUNDS
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  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
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  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
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Abstract

본 발명은 치환된 아릴 인다졸, 그 제조방법 및 이를 이용한 제초제에 관한 것이다. 특히, 본 발명은 다음 식
식중, R1은 수소 또는 할로겐, R2은 수소, 니트로, 할로겐, 알킬, 시아노, 알킬타오, 알킬술피닐, 알킬술포닐, 알콕시, 아세틸아미노 또는 아미노, R3은 수소, 할로겐, 할로알킬, 할로알콕시, 시아노, 아미노 또는 SOyR13로서 R13은 알킬 또는 할로알킬, y는 0,1, 또는 2, R4,R5,R6은 각각 수소, 할로겐, 니트로, 아미노, 히드록시, 시아노, 알킬, 알콕시이미노알킬, 히드록시알킬, 알콕시알킬, 알킬술포닐아미노알킬, 할로알킬술포닐아미노알킬, (알킬)n아미노알킬, (알킬카르보닐옥시)z알킬, 할로알킬, 포르밀, 알킬카르보닐, 카르복시 및 그 염, COO알킬, 카르복스아미도, 치환된 카르복스아미도로서 수소, 알킬, 할로알킬술포닐 및 알킬술포닐에서 질소치환체가 선택될 수 있고, 술폰아미도로서 수소 및 알킬에서 질소치환체가 선택될 수 있고, (알킬술포닐)z아미노, (아세틸)z아미노,
로서 L,M,P 및 Q는 다음에 정의하는 바와 같고, YR9로서 Y는 0,NR12또는 S(0)n, R9은 -(R11)m-COR10, -(R11)m-SO2R10,, 알킬, 할로알킬, 히드록시알킬, 아랄킬, 시아노알킬, 아세톡시알킬, 알콕시알킬, 알케닐 또는 알키닐, R10은 알킬, 할로알킬, 수소, 히드록시, 알콕시, 알콕시알킬, 알콕시알콕시, 알콕시알킬아미노, 디알콕시알킬아미노, 아릴옥시, 아릴킬, 알콕시카르보닐, 히드록시카르복실, 알콕시카르보닐알킬, 히드록시카르보닐알킬, (알킬)n아미노, (알킬)n히드라지노, 알콕시카르보닐알킬아미노, 히드록시알킬아미노, (알킬)n)아미노알킬아미노, (알킬)n아미노카르보닐알킬아미노, 히드록시카르보닐알킬아미노, 알킬술포닐아미노, 아릴술포닐아미노, 아세틸아미노알킬아미노, N-알콕시-N-(알킬)m아미노, N-히드록시-N-(알킬)m아미노, 시아노알킬아미노, (알케닐)n아미노, 알콕시알킬아미노, (알키닐)n아미노, 알케닐옥시, 알키닐옥시, 세미카르바지도, 또는 CH,CH2,N,0 또는 S로 이루어지는 5 또는 6멤버복소환(複索環), R11은 알킬렌, R12은 수소, 알킬, 알케닐, 알키닐 또는 알킬카르보닐, M 또는 Q는 알콕시, 알킬, (알킬)n아미노, 히드륵시, 수소, 알케닐옥시, (알케닐)n)아미노, 알키닐옥시 또는 (알키닐)n)아미노, L은 산소 또는 황, P는 인, m은 0,1, n은 0,1,2, z는 1,2, 또는 R5및 R6은 이들이 결합되는 탄소원자와 함께 취해지는 것으로서 선택적으로 치환되고 탄소, 질소, 산소 및 황에서 선택되는 6멤버 이하를 가지는 포화 또는 불포화된 복소환으로서 복소환상의 치환체는 상기 R9로 정의되고,R7은 수소, 할로겐, 알킬 또는 니트로, R8은 수소 또는 할로겐, X는 질소 또는 CR14로서 R14은 수소, 할로겐, 할로알킬, 시아노, 니트로, 알킬티오, 알킬술포닐, 알킬술피닐 또는 알콕시의 치환된 아릴 인다졸 및 농업적으로 허용되는 그 염에 관한 것이다.

Description

아릴 인다졸 및 이를 이용한 제초제 조성물과 식물의 억제방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 다음 식
    식중, R1은 수소 또는 할로겐, R2은 수소, 니트로, 할로겐, 알킬, 시아노, 알킬타오, 알킬술피닐, 알킬술포닐, 알콕시, 아세틸아미노 또는 아미노, R3은 수소, 할로겐, 할로알킬, 할로알콕시, 시아노, 아미노 또는 SOyR13로서 R13은 알킬 또는 할로알킬, y는 0,1, 또는 2, R4,R5,R6은 각각 수소, 할로겐, 니트로, 히드록시, 시아노, 알킬, 알콕시이미노알킬, 히드록시알킬, 알콕시알킬, 알킬술포닐아미노알킬, 할로알킬술포닐아미노알킬, (알킬)n아미노알킬, (알킬카르보닐옥시)z알킬, 할로알킬, 포르밀, 알킬카르보닐, 카르복시 및 그 염, COO 알킬, 카르복스아미도, 치환된 카르복스아미도로서 수소, 알킬, 할로알킬술포닐 및 알킬술포닐에서 질소치환체가 선택될 수 있고, 술폰아미도로서 수소 및 알킬에서 질소치환체가 선택될 수 있고, (알킬술포닐)z아미노, (아세틸)z아미노,
    로서 L,M,P 및 Q는 다음에 정의하는 바와 같고, YR9로서 Y는 0,NR12또는 S(0)n, R9은 -(R11)m-COR10, -(R11)m-S02R10,, 알킬, 할로알킬, 히드록시알킬, 아랄킬, 시아노알킬, 아세톡시알킬, 알콕시알킬, 알케닐 또는 알키닐, R10은 알킬, 할로알킬, 수소, 히드록시, 알콕시, 알콕시알킬, 알콕시알콕시, 알콕시알킬아미노, 디알콕시알킬아미노, 아릴옥시, 아릴킬, 알콕시카르보닐, 히드록시카르복실, 알콕시카르보닐알킬, 히드록시카르보닐알킬, (알킬)n아미노, (알킬)n히드라지노, 알콕시카르보닐알킬아미노, 히드록시알킬아미노, (알킬)n)아미노알킬아미노, (알킬)n아미노카르보닐알킬아미노, 히드록시카르보닐알킬아미노, 알킬술포닐아미노, 아릴술포닐아미노, 아세틸아미노알킬아미노, N-알콕시-N-(알킬)m아미노, N-히드록시-N-(알킬)m아미노, 알케닐옥시, 알키닐옥시, 세미카르바지도, 또는 CH,CH2, N,0 또는 S로 이루어지는 5 또는 6멤버 복소환(複素環), R11은 알킬렌, R12은 수소, 알킬, 알케닐, 알키닐 또는 알킬카르보닐, M 또는 Q는 알콕시, 알킬, (알킬)n아미노, 히드록시, 수소, 알케닐옥시, (알케닐)n)아미노, 시아노알킬아미노, (알케닐)n아미노, 알콕시알킬아미노, (알키닐)n아미노,알키닐옥시 또는 (알키닐)n)아미노, L은 산소 또는 황, P는 인, m은 0,1, n은 0,1,2, z는 1,2, 또는 R5및 R6은 이들이 결합되는 탄소원자와 함께 취해지는 것으로서 선택적으로 치환되고 탄소, 질소, 산소 및 황에서 선택되는 6멤버 이하를 가지는 포화 또는 불포화된 복소환으로서 복소환상의 치환체는 상기 R9로 정의되고, R7은 수소, 할로겐, 알킬 또는 니트로, R8은 수소 또는 할로겐, X는 질소 또는 CR14로서 R14은 수소, 할로겐, 할로알킬, 시아노, 니트로, 알킬티오, 알킬술포닐, 알킬술피닐 또는 알콕시의 화합물 및 농업적으로 허용되는 그 염.
  2. 제1항에 있어서, R2은 수소, 할로겐, 알킬, 알킬티오 또는 알콕시, R3은 수소, 할로겐, SOyR13또는 할로알킬, R4,R5,R6은 각각 수소, 시아노, 할로겐, 알킬, 니트로, 알콕시, 할로알킬, 카르복시 및 그 염, COO 알킬, 치환된 카르복스아미도, 카르복스아미도, 술폰아미도, 치환된 술폰아미도 및 YR9로서 Y는 0,NR12또는 S(0)n, R9은 -(R11)m-COR10, -(R11)m-SO2R10,, 알킬, 할로알킬, 시아노알킬, 알콕시알킬, 알케닐 또는 알키닐, R7은 수소 또는 할로겐, X는 질소 또는 CR14로서 R14은 할로겐인 화합물.
  3. 제1항에 있어서, R4,R5,R6은 각각 수소, 할로겐, 알킬 및 YR9로서 Y는 0,R9은 -(R11)m-COR10, -(R11)m-SO2R10,, 알킬, 할로알킬, 히드록시알킬, 아랄킬, 시아노알킬, 아세톡시알킬, 알콕시알킬, 히드록시, 알케닐 또는 알키닐, R11은 -CH2-, -CH(CH3)- 및 -CH2CH2-인 화합물.
  4. 제3항에 있어서, X는 N인 화합물.
  5. 제3항에 있어서, X는 C-할로겐인 화합물.
  6. 제2항에 있어서, R2은 수소 또는 할로겐, R3은 할로알킬, R4은 수소, R4은 수소, R6은 YR9,R7은 수소, R8은 수소, X는 N 및 C-할로겐인 화합물.
  7. 제1항에 있어서, R1,R4,R5,R7및 R8은 수소, R2은 수소 또는 할로겐, R3은 CF3, X는 N 또는 C-클로로, R6은 OR9인 화합물.
  8. 제7항에 있어서, R9은, 알킬 및 알콕시알킬인 화합물.
  9. 제1항에 따른 화합물의 제초적 유효량을 바람직하지 않은 식물 또는 그 식물이 있는 곳에 투여하여 이루어지는 바람직하지 않은 식물의 억제방법.
  10. a) 제1항에 따른 제초적 유효량의 화합물과, b) 제초제에 사용하기에 적합한 희석제 또는 캐리어로 이루어지는 제초제 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940703130A 1992-03-09 1993-03-05 아릴 인다졸 및 이를 이용한 제초제 조성물과 식물의 억제방법 KR950700259A (ko)

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