KR950017792A - Hot wire reflective glass - Google Patents

Hot wire reflective glass Download PDF

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Publication number
KR950017792A
KR950017792A KR1019940037114A KR19940037114A KR950017792A KR 950017792 A KR950017792 A KR 950017792A KR 1019940037114 A KR1019940037114 A KR 1019940037114A KR 19940037114 A KR19940037114 A KR 19940037114A KR 950017792 A KR950017792 A KR 950017792A
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South Korea
Prior art keywords
coating film
oxide
per unit
unit area
weight
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KR1019940037114A
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Korean (ko)
Inventor
아키라 후지사와
호다카 노리마츠
쥰 야마구치
고이치 아타카
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마쓰무라 미노루
닛뽄이타가라스 가부시키가이샤
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Publication of KR950017792A publication Critical patent/KR950017792A/en

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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/25—Oxides by deposition from the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/217—FeOx, CoOx, NiOx
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/23—Mixtures
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C03C2218/112—Deposition methods from solutions or suspensions by spraying

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Glass Compositions (AREA)

Abstract

코발트 산화물과 니켈 산화물을 포함하는 피복 필름을 표면에 갖는 유리 지지체를 포함하는 열선 반사 유리가 기술되어 있다. 피복 필름은 다음의 특징을 갖는다: (1) 본 발명의 제1의 양태에 있어서, 피복 필름은 표면 저항률이 104 /square 이상이고, 두께가 10nm이상이며, 단위면적당 총 금속 함량을 기준으로 하여, 피복 필름의 코발트 함량이 60 내지 90중량%이고, 단위면적당 총 금속 함량을 기준으로하여, 피복 필름의 니켈 함량이 10 내지 40중량이다. (2) 본 발명의 제2의 양태에 있어서, 피복 필름은 티탄, 바나듐, 크롬, 망간, 구리 및 지르코늄으로부터 선택된 금속 하나 이상을 함유하는 금속 산화물을 추가로 포함하며, 표면 저항률이 104 /square이상이고, 두께가 10nm이상이고, 단위면적당 총 금속 함량을 기준으로 하여, 피복 필름의 코발트 함량이 10 내지 89중량%이고, 단위면적당 총 금속 함량을 기준으로 하여, 피복 필름의 니켈 함량이 10 내지 39중량%이고, 단위면적당 총 금속 함량을 기준으로 하여, 피복 필름의 티탄, 바나듐, 크롬, 망간, 구리 및 지르코늄으로부터 선택된 금속 하나 이상의 함량이 1 내지 30중량%이다. (3) 본 발명의 제3의 양태에 있어서, 피복 필름은 철 산화물을 추가로 포함하며, 표면 저항률이 104 /square이상이고, 두께가 10nm이상이며, 단위면적당 총 금속 함량을 기준으로 하여, 피복 필름의 철 함량이 1.0 내지 4.5중량%이다. (4) 본 발명의 제4의 양태에 있어서, 피복 필름은 표면 저항률이 104 /square이상이고, 두께가 10 내지 70nm이고, 필수적으로 코발트 산화물과 니켈 산화물을 포함하는 스피텔 구조를 갖는 산화물로 이루어지고, 피복 필름의 반대쪽 열선 반사 유리의 면에서 본 반사된 색조가 녹색 계열의 색이다.Heat-ray reflecting glass comprising a glass support having on its surface a coated film comprising cobalt oxide and nickel oxide is described. The coated film has the following characteristics: (1) In the first aspect of the present invention, the coated film has a surface resistivity of 10 4. / square or more, thickness is 10 nm or more, based on the total metal content per unit area, the cobalt content of the coating film is 60 to 90% by weight, and based on the total metal content per unit area, the nickel content of the coating film is 10 to 40 weight. (2) In the second aspect of the present invention, the coating film further comprises a metal oxide containing at least one metal selected from titanium, vanadium, chromium, manganese, copper and zirconium, the surface resistivity of 10 4 more than / square, thickness is 10 nm or more, based on the total metal content per unit area, the cobalt content of the coating film is 10 to 89% by weight, based on the total metal content per unit area, the nickel content of the coating film is 10 to 39% by weight and based on the total metal content per unit area, the content of at least one metal selected from titanium, vanadium, chromium, manganese, copper and zirconium is 1 to 30% by weight. (3) In the third aspect of the present invention, the coating film further contains iron oxide, and the surface resistivity is 10 4. / square or more, thickness is 10 nm or more, and the iron content of the coating film is 1.0 to 4.5% by weight based on the total metal content per unit area. (4) In the fourth aspect of the present invention, the coated film has a surface resistivity of 10 4 more than / square, 10 to 70 nm thick, essentially composed of an oxide having a spite structure comprising cobalt oxide and nickel oxide, and the reflected hue seen from the side of the hot-reflective glass opposite to the coating film is green-based. It is color.

Description

열선 반사 유리Hot wire reflective glass

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (11)

표면 저항류이 104 /square이상이고 두께가 10nm이상이며, 단위면적당 총 금속 함량을 기준으로 하여, 코발트 함량이 60 내지 90중량%이고, 단위면적당 총 금속 함량을 기준으로 하여, 니켈 함량이 10 내지 40중량%이며 코발트 산화물과 니켈 산화물을 포함하는 피복 필름이 표면 위에 있는 유리 지지체를 포함하는 열선 반사 유리.Surface resistivity is 10 4 cobalt content of 60 to 90% by weight, based on the total metal content per unit area, nickel content of 10 to 40% by weight, and cobalt based on the total metal content per unit area A heat ray reflecting glass comprising a glass support on which a coating film comprising oxide and nickel oxide is on a surface. 제1항에 있어서, 단위면적당 총 금속 함량을 기준으로 하여, 피복 필름의 코발트 함량이 68 내지 87중량%이고, 단위 면적당 총 금속 함량을 기준으로 하여, 피복 필름의 니켈 함량이 13 내지 32중량%인 열선 반사 유리.The coating film according to claim 1, wherein the coating film has a cobalt content of 68 to 87% by weight based on the total metal content per unit area, and the nickel content of the coating film is 13 to 32% by weight based on the total metal content per unit area. Heating wire reflective glass. 티탄, 바나듐, 크롬, 망간, 구리 및 지르코늄으로부터 선택된 금속을 하나 이상 함유하는 금속 산화물을 추가로 포함하며 표면 저항률이 104 /square이상이고 두께가 10nm이상이며, 단위면적당 총 금속 함량을 기준으로 하여, 코발트 함량이 60 내지 89중량%이고, 단위면적당 총 금속 함량을 기준으로 하여, 니켈 함량이 10 내지 39중량%이며, 단위면적당 총 금속 함량을 기준으로 하여, 티탄, 바나듐, 크롬, 망간, 구리 및 지르코늄으로부터 선택된 금속 하나 이상의 함량이 1내지 30중량%이고 코발트 산화물과 니켈 산화물을 포함하는 피복 필름이 표면 위에 있는 유리 지지체를 포함하는 열선 반사 유리.Further comprises a metal oxide containing at least one metal selected from titanium, vanadium, chromium, manganese, copper and zirconium and having a surface resistivity of 10 4 more than / square, more than 10nm thick, based on the total metal content per unit area, cobalt content is 60 to 89% by weight, based on the total metal content per unit area, nickel content is 10 to 39% by weight, A glass support having a coating film containing cobalt oxide and nickel oxide in an amount of 1 to 30% by weight and containing at least one metal selected from titanium, vanadium, chromium, manganese, copper and zirconium, based on the total metal content per unit area. Heat ray reflection glass comprising a. 제1항 내지 제3항 중의 어느 한 항에 있어서, 피복 필름의 두께가 130nm이하인 열선 반사 유리.The heat-ray reflecting glass of any one of Claims 1-3 whose thickness of a coating film is 130 nm or less. 철 산화물을 추가로 포함하며 표면 저항률이 104 /square이상이고 두께가 10 내지 70nm이며, 단위면적당 총 금속 함량을 기준으로 하여, 철 함량이 1.0 내지 4.5중량%이고 코발트 산화물과 니켈 산화물을 포함하는 피복 필름이 표면 위에 있는 유리 지지체를 포함하는 열선 반사 유리.Additionally contains iron oxide and has a surface resistivity of 10 4 a heat ray comprising a glass support on the surface of which the coating film comprising cobalt oxide and nickel oxide is 1.0 to 4.5% by weight, based on the total metal content per unit area, and the thickness is 10 to 70 nm or more. Reflective glass. 제5항에 있어서, 단위면적당 총 금속 함량을 기준으로 하여, 니켈 함량이 5 내지 40중량%인 열선 반사 유리.The heat ray reflecting glass of Claim 5 whose nickel content is 5-40 weight% based on the total metal content per unit area. 제1항 내지 제6항 중의 어느 한 항에 있어서, 피복 필름의 반대쪽 열선 반사 유리의 면에서 본 반사된 색조가 녹색 계열의 색인 열선 반사 유리.The index hot-ray reflecting glass according to any one of claims 1 to 6, wherein the reflected tint as viewed from the side of the heat-reflecting glass opposite to the coating film is green. 제1항 내지 제7항 중의 어느 한 항에 있어서, 피복 필름이 필수적으로 스피넬 구조를 갖는 산화물로 이루어진 열선 반사 유리.The heat ray reflecting glass according to any one of claims 1 to 7, wherein the coating film consists essentially of an oxide having a spinel structure. 제1항 내지 제8항 중의 어느 한 항에 있어서, 투과된 가시광이 다음 범위에 속하는 투과된 색조를 나타내는 열선 반사 유리.The heat ray reflecting glass according to any one of claims 1 to 8, wherein the transmitted visible light exhibits a transmitted color tone within the following range. -4.5a*4.5-4.5 a * 4.5 3.0b*12.53.0 b * 12.5 상기식에서, a* 및 b*는 색도 지수이다.Wherein a * and b * are chromaticity indices. 제1항 내지 제9항 중의 어느 한 항에 있어서, 피복 필름의 반대쪽 열선 반사 유리의 면에서 본 반사된 가시광이 다음의 범위에 속하는 반사된 색조를 나타내는 열선 반사 유리.The heat ray reflecting glass according to any one of claims 1 to 9, wherein the reflected visible light seen from the surface of the heat ray reflecting glass opposite to the coating film exhibits a reflected color tone within the following range. -7.0a*-3.0-7.0 a * -3.0 -5.0b*4.0-5.0 b * 4.0 상기식에서, a* 및 b*는 색도 지수이다.Wherein a * and b * are chromaticity indices. 필수적으로 코발트 산화물과 니켈 산화물을 포함하는 스피넬 구조를 갖는 산화물로 이루어지고 표면 저항률이 104 /square이상이며 두께가 10 내지 70nm이고, 피복 필름의 반대쪽 열선 반사 유리의 면에서 본 반사된 색조가 녹색 계열의 색이며 코발트 산화물과 니켈 산화물을 포함하는 피복 필름의 표면 위에 있는 유리 지지체를 포함하는 열선 반사 유리.It consists essentially of an oxide with a spinel structure containing cobalt oxide and nickel oxide and has a surface resistivity of 10 4 a glass support on the surface of the coated film comprising cobalt oxide and nickel oxide, having a thickness of 10 to 70 nm or more and having a thickness of 10 to 70 nm and the reflected hue as viewed from the side of the heat-reflective glass opposite to the coated film. Heat rays reflective glass. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940037114A 1993-12-28 1994-12-27 Hot wire reflective glass KR950017792A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP93-335123 1993-12-28
JP33586893 1993-12-28
JP33512393 1993-12-28
JP93-335868 1993-12-28

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KR950017792A true KR950017792A (en) 1995-07-20

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KR1019940037114A KR950017792A (en) 1993-12-28 1994-12-27 Hot wire reflective glass

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KR (1) KR950017792A (en)
CN (1) CN1101354C (en)
GB (1) GB2285634A (en)
SG (1) SG81880A1 (en)
TW (1) TW293005B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ID21079A (en) * 1997-05-22 1999-04-15 Nippon Electric Glass Co SUN LIGHT REFLECTION BLOCK AND PRODUCING METHODS
EP1288174A4 (en) 2000-04-28 2005-06-08 Asahi Glass Co Ltd Glass coated with heat reflecting colored film and method for manufacturing the same
CN102127326B (en) * 2010-12-28 2012-10-31 中国科学院上海硅酸盐研究所 Vanadium dioxide-based composite coating liquid and composite film and preparation methods and applications of coating liquid and composite film
CN107586039B (en) * 2017-11-02 2020-09-15 北京工业大学 Low-temperature lead-free sealing glass

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2688565A (en) * 1949-07-01 1954-09-07 Pittsburgh Plate Glass Co Refractory base containing a low reflection coating and method of making same
US2975076A (en) * 1957-11-12 1961-03-14 Pittsburgh Plate Glass Co Preparing glass coating compositions
GB1002024A (en) * 1961-02-14 1965-08-18 Libbey Owens Ford Glass Co Glazing closure
US3185586A (en) * 1961-02-28 1965-05-25 Pittsburgh Plate Glass Co Coated glass sheets
US3850665A (en) * 1971-07-08 1974-11-26 Glaverbel Process for forming a metal oxide coating on a substrate and resulting products
BE785764A (en) * 1971-07-08 1973-01-03 Glaverbel
US4160061A (en) * 1975-03-29 1979-07-03 Central Glass Company, Limited Heat-reflecting glass plate and method of producing same
US4204028A (en) * 1978-03-16 1980-05-20 Ppg Industries, Inc. Conductive metal oxide film for solar energy control
JPS57149848A (en) * 1981-03-06 1982-09-16 Asahi Glass Co Ltd Metallic oxide coated glass
CN1029734C (en) * 1992-04-07 1995-09-13 林启雄 Hot-line reflecting glass
JPH0859299A (en) * 1994-08-18 1996-03-05 Nippon Sheet Glass Co Ltd Heat radiation-reflecting glass and its production

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CN1101354C (en) 2003-02-12
GB2285634A (en) 1995-07-19
GB9426370D0 (en) 1995-03-01
CN1111216A (en) 1995-11-08
SG81880A1 (en) 2001-07-24
TW293005B (en) 1996-12-11

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