JPH0710609A - Heat-shielding glass and insulating glass produced by using the shielding glass - Google Patents

Heat-shielding glass and insulating glass produced by using the shielding glass

Info

Publication number
JPH0710609A
JPH0710609A JP5159614A JP15961493A JPH0710609A JP H0710609 A JPH0710609 A JP H0710609A JP 5159614 A JP5159614 A JP 5159614A JP 15961493 A JP15961493 A JP 15961493A JP H0710609 A JPH0710609 A JP H0710609A
Authority
JP
Japan
Prior art keywords
glass
heat
shielding
film
solar radiation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5159614A
Other languages
Japanese (ja)
Other versions
JP2882728B2 (en
Inventor
Yoshiaki Sugata
義敬 菅田
Iwai Inoue
祝 井上
Masanori Kurahashi
正則 倉橋
Masaji Onishi
正司 大西
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Glass Co Ltd
Original Assignee
Central Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Central Glass Co Ltd filed Critical Central Glass Co Ltd
Priority to JP5159614A priority Critical patent/JP2882728B2/en
Publication of JPH0710609A publication Critical patent/JPH0710609A/en
Application granted granted Critical
Publication of JP2882728B2 publication Critical patent/JP2882728B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a heat-shielding glass by using a heat ray absorbing and ultraviolet shielding glass exhibiting green color mild to the eye as a main material and forming a low-radiation film to shield far infrared rays on the glass and to obtain an insulating glass by using the heat-shielding glass having remarkably excellent heat-shielding property and heat-insulating property. CONSTITUTION:This heat-shielding glass is produced by forming a low-radiation film composed of a multilayer film containing a silver layer and having a vertical emissivity of <=0.2 on (one surface of) a green-colored glass capable of absorbing heat rays and ultraviolet rays. This insulating glass is formed by placing the heat-shielding glass to the outdoor side, a clear glass to the indoor side and the low-radiation film to the inner side face of the heat-shielding glass.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は建築物等において、夏季
には日射エネルギーの入射を抑制し冷房負荷を低減し、
冬季には屋内からの外部への熱放射を抑制し暖房負荷を
低減する、省エネルギー窓材として好適な熱遮断ガラス
およびそれを配した複層ガラスに関する。
BACKGROUND OF THE INVENTION The present invention relates to buildings and the like, which suppresses the incidence of solar energy in the summer to reduce the cooling load,
The present invention relates to a heat-shielding glass that is suitable as an energy-saving window material that suppresses heat radiation from the inside to the outside in the winter and reduces the heating load, and a double-layer glass having the heat-shielding glass.

【0002】[0002]

【従来技術とその問題点】従来、建築物、車両等におけ
る日射の入射を吸収・抑制し、高温時の冷房負荷を低減
するうえでいわゆる青色ガラス、ブロンズ色ガラス、灰
色ガラス等の着色熱線吸収ガラスを使用することは公知
であり、さらに、近年車両等に緑色系着色ガラスが採用
されつつある。しかしこれら熱線吸収ガラスは吸収され
た日射が熱に変換され、再度熱線(遠赤外線)として屋
外、車外はもとより、屋内、車内に放射される。
[Prior art and its problems] In the past, to absorb and suppress the incidence of solar radiation on buildings, vehicles, etc., and to reduce the cooling load at high temperatures, so-called blue glass, bronze colored glass, gray glass, etc. It is known to use glass, and in recent years, greenish colored glass has been adopted for vehicles and the like. However, in these heat ray absorbing glasses, the absorbed solar radiation is converted into heat, and is again radiated as heat rays (far infrared rays) not only outdoors but outside the vehicle as well as inside and inside the vehicle.

【0003】また、着色熱線吸収ガラスに熱遮断性の膜
を形成したガラスについてみれば、特開昭48−29815 号
には、可視光の少なくとも一部を透過するパネル、例え
ば着色熱線吸収ガラスに、周期律表の特定の族に属する
元素の硼化物、炭化物、窒化物、酸化物 (メタロイド)
膜を膜付けした日光フィルター熱絶縁ガラスが開示さ
れ、また、実開平3−55832 号には、グレー系熱線吸収
ガラスに窒化クロム膜、透明酸化物膜を順次積層し、あ
るいはブロンズ系熱線吸収ガラスに同様な膜を積層した
熱線遮蔽ガラスが開示される等、単に着色熱線吸収ガラ
スに熱遮断性の膜を形成することは公知である。
Further, regarding a glass having a heat-shielding film formed on a colored heat ray absorbing glass, Japanese Patent Laid-Open No. 4898/1985 discloses a panel which transmits at least a part of visible light, for example, a colored heat ray absorbing glass. , Borides, carbides, nitrides, oxides (metalloids) of elements belonging to a specific group of the Periodic Table
A sunlight filter heat insulating glass having a film formed thereon is disclosed, and in Japanese Utility Model Publication No. 3-55832, a gray heat absorbing glass is sequentially laminated with a chromium nitride film and a transparent oxide film, or a bronze heat absorbing glass. It is known that a heat-shielding film is simply formed on a colored heat-absorbing glass, such as the heat-shielding glass in which similar films are laminated.

【0004】しかし、日射を効果的に遮断する熱線・紫
外線吸収緑色系ガラスと、特に熱エネルギーの高い遠赤
外線を効果的に反射する低放射性膜との組合せについて
は開示しておらず、また前記メタロイド膜等は低放射性
という観点からすれば適当とは言いがたい。
However, it does not disclose a combination of a heat ray / ultraviolet ray absorbing green glass that effectively blocks solar radiation and a low emissivity film that effectively reflects far infrared rays having high heat energy. It is hard to say that metalloid films and the like are suitable from the viewpoint of low radiation.

【0005】なお、着色熱線吸収ガラスを用いた複層ガ
ラス (二重ガラス) についてみれば、屋外側に着色熱線
吸収ガラス、屋内側に通常のガラスを配する等、設計す
ることにより断熱性を向上せしめることは公知であり、
本出願人の先の発明にかかる特願平2−321465号、特願
平2−405840号等においても緑色系着色 (熱線吸収)ガ
ラスを提唱したなかで、該ガラスを用いた合せガラス、
複層ガラスについて開示示唆する等すでに公知の技術事
項である。
Regarding the multi-layer glass (double glass) using the colored heat ray absorbing glass, the heat insulating property is designed by designing the colored heat ray absorbing glass on the outdoor side and the ordinary glass on the indoor side. It is known to improve,
In the Japanese Patent Application No. 2-321465, Japanese Patent Application No. 2-405840, etc. according to the applicant's earlier invention, among others, a greenish colored (heat ray absorbing) glass is proposed, and a laminated glass using the glass,
It is already known technical matter such as disclosing and suggesting the double glazing.

【0006】さらに、少なくとも一方のガラスに熱遮断
性膜を形成した着色ガラス−ガラスの組合せからなる複
層ガラス (二重ガラス)についてみれば、アメリカ特許
第4069630 号には、屋外側には例えばブロンズ色ガラ
ス、灰色ガラス等の熱線吸収ガラスを配しその内側面に
は酸化錫よりなる赤外線反射膜を膜付けし、屋内側には
通常のガラスを配した熱線反射窓が開示され、また、ア
メリカ特許第4687687 号には、 2枚の被膜を組込んだ二
重ガラスユニットにおいて、一方の被膜はドープした酸
化錫および/ またはドープした酸化インジウムを有する
低輻射率被膜であり、他方の被膜は膜中に二酸化物換算
で少なくとも30wt%の錫、および少なくとも30wt%のチ
タンを含む熱反射性金属酸化物とすること、ガラス板の
一つはボディ着色ガラスとすることができることを提唱
し、例えば熱反射性金属酸化物被膜を外側面に有する外
側のブロンズ色ガラスと、低輻射率被膜を内面側に有す
る内側ガラスからなる二重ガラスユニットが開示されて
いる。
Further, regarding a double glazing composed of a colored glass-glass combination in which at least one of the glasses is provided with a heat-shielding film, US Pat. Bronze color glass, heat ray absorbing glass such as gray glass is arranged, an infrared reflection film made of tin oxide is filmed on the inner surface thereof, and a heat ray reflecting window in which ordinary glass is arranged on the indoor side is disclosed. U.S. Pat.No.4687687 discloses a double glazing unit incorporating two coatings, one coating being a low emissivity coating with doped tin oxide and / or doped indium oxide and the other coating. The film shall be a heat-reflecting metal oxide containing at least 30 wt% tin and at least 30 wt% titanium in terms of dioxide, and one of the glass plates shall be body colored glass. DOO proposed that can, for example, the outer bronze colored glass having a heat reflecting metal oxide coating on the outer surface, the double glazing unit consisting of an inner glass having a low emissivity coating on the inner surface side is disclosed.

【0007】しかし、本発明におけるような、外側ガラ
スに熱線・紫外線吸収緑色系ガラスを配し、その内側面
に銀層を含む低放射性膜を形成することは開示示唆して
いない。
However, it is not disclosed and suggested to dispose the heat ray / ultraviolet absorbing green glass on the outer glass and to form the low emissivity film including the silver layer on the inner surface as in the present invention.

【0008】特開平1−105895号には、外側の緑色、ブ
ロンズ色等の着色熱線吸収ガラスと、内側のアニールし
たガラスからなる二重ガラスで、内側ガラスの内面 (外
側ガラスに向いた面) に15〜40nmの銀層を含む被膜を有
することが開示されている。前記銀層を含む被膜は低放
射作用を呈するものではあるが、低放射性膜を内側ガラ
ス内面に配したものは、後段実施例の項で例示するよう
に外側ガラス内面に配したものより遮熱、断熱性に劣
る。
JP-A-1-105895 describes a double glass consisting of an outer colored glass for absorbing heat rays such as green and bronze and an inner annealed glass, and the inner surface of the inner glass (the surface facing the outer glass). It is disclosed to have a coating containing a silver layer of 15-40 nm. Although the coating including the silver layer exhibits a low radiation effect, the one having the low radiation film disposed on the inner surface of the inner glass has a heat shield more than the one disposed on the inner surface of the outer glass as exemplified in the section of the later-mentioned Examples. , Inferior in heat insulation.

【0009】すなわち、これら公知例は本発明における
ような構成を開示しておらず、構成はシンプルであるが
熱遮断、断熱作用において劣り、また有害な紫外線を有
効に遮断し難く、あるいは遮熱、断熱には相応の作用を
呈するが、構成が複雑で採光、透視性を損じ、コストが
きわめて高く汎く利用し難いという難点がある。本発明
はシンプルな構成で、視覚上穏やかで草木の緑色にマッ
チした色調を呈し、日射からの熱線を吸収し、有害な紫
外線を遮断する作用を呈する熱線・紫外線吸収緑色系ガ
ラスを基に、特に遠赤外域の熱線を遮断する低放射性膜
を被膜形成したことにより、熱遮断作用を向上させ、勿
論採光、透視性を損なうことのない熱遮断ガラス、およ
びそれを用いた複層ガラスを提供するものである。
That is, these known examples do not disclose the constitution as in the present invention, and although the constitution is simple, it is inferior in heat shield and heat insulation, and it is difficult to effectively shield harmful ultraviolet rays, or heat shield. Although the heat insulation has a proper function, it has a drawback that the structure is complicated, the lighting and the transparency are impaired, the cost is extremely high, and it is generally difficult to use. The present invention has a simple structure, has a color tone that is visually gentle and matches the green color of vegetation, absorbs heat rays from solar radiation, and is based on heat ray / ultraviolet ray absorbing green glass that acts to block harmful ultraviolet rays, In particular, by providing a low-emissivity film that blocks heat rays in the far infrared region, a heat-shielding glass that improves the heat-shielding effect without impairing daylighting and transparency, and a double-layer glass using the same are provided. To do.

【0010】[0010]

【問題点を解決するための手段】本発明は熱遮断ガラス
に関し、熱線・紫外線吸収緑色系ガラスの片面に、銀層
を含む多層膜からなり、垂直放射率0.2 以下の低放射性
膜を形成したこと、前記熱線・紫外線吸収緑色系ガラス
が、板厚5mmにおける可視光透過率 (A光源) 65%以
上、日射透過率35〜50%、紫外線透過率15%以下、主波
長500 〜530nm 、刺激純度5以下であること、さらに前
記熱遮断ガラスを屋外側、クリアー系ガラスを屋内側に
配した複層ガラスであって、低放射性膜を熱遮断ガラス
の内側面に形成してなる複層ガラス、からなる。
SUMMARY OF THE INVENTION The present invention relates to a heat-shielding glass, which is a heat-ray / ultraviolet-absorbing green glass formed on one surface with a multilayer film including a silver layer and having a low emissivity film having a vertical emissivity of 0.2 or less. The heat ray / ultraviolet absorbing green glass has a visible light transmittance of 65% or more (A light source) at a plate thickness of 5 mm, a solar radiation transmittance of 35 to 50%, an ultraviolet transmittance of 15% or less, a main wavelength of 500 to 530 nm, and a stimulus. It is a multi-layer glass having a purity of 5 or less, further, the heat-shielding glass is arranged on the outdoor side and a clear glass is arranged on the indoor side, and a low-emissivity film is formed on the inner surface of the heat-shielding glass. Consists of.

【0011】前記熱線・紫外線吸収緑色系ガラスの特性
に合致したガラスとして、本出願人の発明にかかる特願
平2−321465号、特願平2−405840号、特願平3−1449
27号等において提唱したガラスが好適に採用できる。こ
れらはいずれもソーダ石灰シリカ系ガラスであって、総
ずれば着色成分としてFe2O3 0.58〜0.75wt%、CeO2 0.1
0 〜0.50wt%、TiO2 0.10 〜0.40wt%の範囲で含み、か
つMnO を300ppm以下において適宜量含有させたものであ
り、この組成範囲のものがセントラル硝子株式会社製商
品名グリーンラルSPとして市販されている。
As a glass that matches the characteristics of the heat ray / ultraviolet absorbing green glass, Japanese Patent Application Nos. 2-321465, 2-405840, and 3-1449 according to the invention of the present applicant.
The glass proposed in No. 27, etc. can be preferably used. All of these are soda-lime-silica type glasses, and Fe 2 O 3 0.58 to 0.75 wt% and CeO 2 0.15% as coloring components in total.
0 to 0.50 wt%, TiO 2 0.10 to 0.40 wt% in the range, and MnO is contained in an appropriate amount at 300 ppm or less, those having this composition range as Central Glass Co., Ltd. product name Greenral SP It is commercially available.

【0012】なお、本出願人のさらに別の発明にかかる
特願平5−24456 号には、ソーダ石灰シリカ系ガラスに
おいて、着色成分としてFe2O3 ( 全鉄)0.1〜0.3 wt%、
CoO20〜50ppm およびCr2O3 200 〜400ppmを含み、還元
率 (Fe2+/ Fe3+) が20〜50%の緑色系ガラスを提唱した
が、これをベースとして前記色調を損なわない範囲で適
宜TiO2、CeO2等を添加したガラスも採用できる。
[0012] In addition, Japanese Patent Application No. 5-24456 of the applicant of the present invention discloses that in soda lime silica glass, Fe 2 O 3 (total iron) 0.1 to 0.3 wt% as a coloring component,
We proposed a greenish glass containing CoO 20 to 50 ppm and Cr 2 O 3 200 to 400 ppm and a reduction rate (Fe 2+ / Fe 3+ ) of 20 to 50%, but based on this, within the range that does not impair the color tone. Glass to which TiO 2 , CeO 2 or the like is appropriately added can also be used.

【0013】本発明における低放射性膜は、可視光は透
過し易いが、近赤外光〜遠赤外光、特に波長2100nm以上
の遠赤外域の光は反射する傾向を有するもので、例えば
屋内の人体、物体等の温熱体からの放射熱 (遠赤外線)
の逸散を抑制し、従って冬季は屋内の暖房負荷を軽減す
る。また、日射の赤外域の光の屋内への入射を抑制する
ので夏季の屋内の冷房負荷を軽減するものであるが、む
しろ熱線・紫外線吸収緑色系ガラスとの組合せによりそ
の作用を格段と向上するものである。
The low-emissivity film in the present invention has a tendency to easily transmit visible light, but to reflect near-infrared light to far-infrared light, particularly light in the far-infrared region having a wavelength of 2100 nm or more. Heat (far-infrared rays) from the human body and other objects
It reduces the heat dissipation in the room and thus reduces the indoor heating load in winter. Also, since it suppresses the incidence of sunlight in the infrared region into the indoor, it reduces the indoor cooling load in summer, but rather, its action is significantly improved by combining it with heat ray / ultraviolet absorbing green glass. It is a thing.

【0014】低放射性膜は金属層、特に銀層を含むもの
がコスト、性能面を勘案すれば最良であり、ただしガラ
スとの接着性や、雰囲気に対する安定性、耐食性を考慮
して、金属酸化物層−銀層−金属酸化物層を基本膜構成
とするのが好ましい。例示すれば、ZnO −Ag−ZnO 、あ
るいはこれにAu、Al、Pt、Crその他の金属層を適宜挟
み、TiO2、SiO2その他の金属酸化物層を適宜内側層、中
間層、または外郭層として配するのがよい。なお通常低
放射性膜はJIS R 3106に規定する測定方法により垂直放
射率が0.3 ないし0.4 以下のものをいうが、本発明にお
いては0.2 以下とすることによりその性能を充分発揮す
るもので、より好ましくは0.1 以下とするのが望まし
い。
The low-emissivity film is best if it includes a metal layer, especially a silver layer, in consideration of cost and performance, however, in consideration of adhesiveness with glass, stability to atmosphere, and corrosion resistance, metal oxide is used. It is preferable that the basic film structure is a physical layer-silver layer-metal oxide layer. By way of example, scissors ZnO -Ag-ZnO, or this Au, Al, Pt, Cr and other metal layers as appropriate, TiO 2, SiO 2 and other metal oxide layer as appropriate inner layer, intermediate layer, or outer layer It is good to arrange as. Note that the low emissivity film usually has a vertical emissivity of 0.3 to 0.4 or less according to the measurement method specified in JIS R 3106, but in the present invention, the emissivity is sufficiently exhibited by setting it to 0.2 or less, and it is more preferable. Is preferably 0.1 or less.

【0015】本発明における複層ガラスは、外側ガラス
に熱線・紫外線吸収緑色系ガラス、その内側に低放射性
膜を配すること、内側ガラスにクリアー系のガラスを配
することをベースとする。前記クリアー系のガラスとは
淡色系ガラス、線材入りガラス、非着色性透明膜付クリ
アーガラス等を包含するものである。なお内側ガラスに
外側ガラスと同様の、あるいは他の着色熱線吸収ガラス
を配した場合、透明性が損なわれる恐れがあるので好ま
しくない。また低放射性膜は外側ガラスの内側に配する
のが熱遮断上効果的である。
The double glazing in the present invention is based on arranging a heat ray / ultraviolet absorbing green glass on the outside glass, arranging a low emissive film on the inside thereof, and arranging a clear glass on the inside glass. The clear glass includes light-colored glass, glass with a wire rod, clear glass with a non-coloring transparent film, and the like. In addition, it is not preferable to dispose a colored heat ray absorbing glass similar to or different from the outer glass on the inner glass, because the transparency may be impaired. Also, it is effective for heat insulation to dispose the low emissivity film inside the outer glass.

【0016】なお、複層ガラスにおける各ガラスの厚み
や、ガラス間の空間厚み (幅) は特定するものではない
が、例えばガラス厚3mm−空間6mm−ガラス厚3mm、あ
るいはガラス厚3mm−空間12mm−ガラス厚3mmの配置構
成とするのが最も一般的である。勿論ガラス厚み、空間
の幅は適宜設計でき、また三層以上の多層ガラスとした
り、いずれか一方または双方のガラスを強化ガラスや半
強化ガラスとすること、内側ガラスの面に透視性等を著
しく損なわない範囲でさらに低放射性膜、熱線反射膜等
の機能性膜を膜付けすること、内部空間にエアー以外に
各種断熱性ガスを封入すること等も適宜設計事項であ
る。
The thickness of each glass and the space thickness (width) between the glasses in the double glazing are not specified, but for example, glass thickness 3 mm-space 6 mm-glass thickness 3 mm, or glass thickness 3 mm-space 12 mm. -The most common arrangement is a glass thickness of 3 mm. Of course, the thickness of the glass and the width of the space can be appropriately designed, and it is also possible to use multi-layered glass with three or more layers, to use one or both of the glasses as tempered glass or semi-tempered glass, and to see through the inner glass surface with remarkable transparency. It is also an appropriate design matter to coat a functional film such as a low-emissivity film or a heat ray reflective film within a range not impairing, and to enclose various adiabatic gases other than air in the internal space.

【0017】本発明の構成からなる熱遮断ガラス、特に
それを用いた複層ガラスは、熱遮断性、断熱性、紫外線
遮断性に富み、勿論適度な採光、透視性を備え、緑色系
としたので視覚上穏やかな感触を与える等多岐にわたる
効果を奏する。
The heat-shielding glass having the constitution of the present invention, in particular, the double glazing using the same is excellent in heat-shielding property, heat-insulating property, and ultraviolet-shielding property, and of course, has appropriate lighting and see-through properties, and is of a greenish type. Therefore, it has various effects such as giving a visually gentle feeling.

【0018】[0018]

【実施例】以下実施の数例を挙げて本発明を説明する。
図1Aは本実施例、比較例において採用したガラスの透
過率をあらわすグラフであり、分光光度計により測定し
たもので、図中aはセントラル硝子株式会社製紫外線・
赤外線吸収緑色系ガラス、商品名グリーンラルSP、bは
セントラル硝子株式会社製ブロンズ色ガラス、商品名ブ
ロンズラル、cはセントラル硝子株式会社製青色ガラ
ス、商品名ブルーラル、dはセントラル硝子株式会社製
クリアーガラス、品種名フロートガラス(FL)の、いずれ
も3mm厚における透過率曲線を示す。
EXAMPLES The present invention will be described below with reference to several examples.
FIG. 1A is a graph showing the transmittance of the glass used in this example and the comparative example, which is measured by a spectrophotometer, where a is an ultraviolet ray manufactured by Central Glass Co., Ltd.
Infrared absorbing green glass, trade name Green Ral SP, b is bronze glass manufactured by Central Glass Co., Ltd., product name Bronze Ral, c is blue glass manufactured by Central Glass Co., Ltd., product name Blue Ral, d is clear manufactured by Central Glass Co., Ltd. The transmittance curves of glass and float glass (FL) with a thickness of 3 mm are shown.

【0019】図1Bは本実施例、比較例において採用し
た低放射性膜、熱線反射性膜の反射率 (3mm厚クリアー
ガラスに膜付けしたものでガラス面側より測定) をあら
わすグラフであり、上記同様の手段で測定したもので、
図中eは垂直放射率0.07の低放射性膜、fは垂直放射率
0.16の低放射性膜、gは垂直放射率0.36の熱線反射膜の
反射率曲線を示す。なお、熱線反射膜は、図示のとおり
可視光〜近赤外域にかかる日射を反射する傾向を有し、
一方遠赤外域の熱線の反射は低放射性膜ほど強くなく、
他方低放射膜は可視光を透過し易く、遠赤外線を選択的
に強く反射する点で区別される。
FIG. 1B is a graph showing the reflectance (measured from the glass surface side of a film having a thickness of 3 mm clear glass) of the low-emissivity film and the heat ray reflective film used in this example and comparative examples. It was measured by similar means,
In the figure, e is a low emissivity film with a vertical emissivity of 0.07, and f is a vertical emissivity.
The low emissivity film of 0.16, g shows the reflectance curve of the heat ray reflective film having a vertical emissivity of 0.36. In addition, the heat ray reflective film has a tendency to reflect solar radiation in the visible light to near infrared region as shown in the figure,
On the other hand, the reflection of heat rays in the far infrared region is not as strong as that of the low emissivity film,
On the other hand, the low-emissivity film is distinguished by the fact that it easily transmits visible light and selectively reflects far infrared rays strongly.

【0020】〔I〕熱遮断ガラス 〔実施例A〕熱線・紫外線吸収緑色系ガラス (厚み3mm
)の片面に、スパッタリング法により、ZnO 、Agの互層
積層とし総膜厚880Aであって、JIS R 3106に規定する測
定方法による垂直放射率0.07からなる低放射性膜を膜付
けした。この膜付けガラスをJIS R 3106に規定する測定
方法により、A光源による可視光透過率、可視光反射
率、日射透過率、日射反射率 (外側ガラス面のみ) 、日
射吸収率、紫外線遮断率、熱貫流率、遮蔽係数、日射熱
取得率を測定した。結果を表1に示す。
[I] Heat-shielding glass [Example A] Heat ray / ultraviolet absorbing green glass (thickness: 3 mm)
On one surface of (1), a low-emissivity film having a total film thickness of 880 A and having a vertical emissivity of 0.07 according to the measuring method specified in JIS R 3106 was formed by alternately sputtering ZnO and Ag. This film-coated glass was measured according to JIS R 3106 by the visible light transmittance by A light source, visible light reflectance, solar radiation transmittance, solar radiation reflectance (outer glass surface only), solar radiation absorptivity, UV blocking rate, The heat transmission coefficient, the shielding coefficient, and the solar heat gain coefficient were measured. The results are shown in Table 1.

【0021】〔実施例B〕実施例A同様の熱線・紫外線
吸収緑色系ガラス (厚み3mm) の片面に、スパッタリン
グ法により、内、外郭層にSiNx、それに挟まれる金属層
にAgおよびNi−Crを配し、総膜厚920Aであって、垂直放
射率0.16からなる低放射性膜を膜付けした。実施例A同
様に、可視光透過率、可視光反射率、日射透過率、日射
反射率、日射吸収率、紫外線遮断率、熱貫流率、遮蔽係
数、日射熱取得率を測定した。結果を表1に示す。
[Example B] The same heat ray / ultraviolet absorbing green glass (thickness 3 mm) as in Example A was formed on one surface by sputtering, and the inner and outer layers were made of SiNx, and the metal layers sandwiched between them were made of Ag and Ni-Cr. And a low emissivity film having a total film thickness of 920 A and a vertical emissivity of 0.16 was applied. In the same manner as in Example A, the visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorptivity, ultraviolet ray blocking ratio, heat transmission coefficient, shielding coefficient, and solar heat gain coefficient were measured. The results are shown in Table 1.

【0022】〔比較例A〕ブロンズ色ガラス (厚み3m
m) に、Fe−Ni−Cr (ステンレススチール) およびTiNx
の2層積層とし、総膜厚480Aであって、垂直放射率0.36
からなる熱線反射膜をスパッタリング法により膜付けし
た。これを実施例A同様に、可視光透過率、可視光反射
率、日射透過率、日射反射率、日射吸収率、紫外線遮断
率、熱貫流率、遮蔽係数、日射熱取得率を測定した。結
果を表1に示す。
[Comparative Example A] Bronze glass (thickness 3 m
m), Fe-Ni-Cr (stainless steel) and TiNx
The total film thickness is 480A and the vertical emissivity is 0.36
The heat ray reflective film made of was deposited by the sputtering method. In the same manner as in Example A, the visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorptivity, ultraviolet ray blocking rate, heat transmission coefficient, shielding coefficient, and solar heat gain rate were measured. The results are shown in Table 1.

【0023】〔比較例B〕比較例A同様のブロンズ色ガ
ラス (厚み3mm) に、実施例Aと全く同様の垂直放射率
0.07の低放射性膜を膜付けした。これを実施例A同様
に、可視光透過率、可視光反射率、日射透過率、日射反
射率、日射吸収率、紫外線遮断率、熱貫流率、遮蔽係
数、日射熱取得率を測定した。結果を表1に示す。
Comparative Example B The same vertical emissivity as in Example A was applied to the same bronze colored glass (thickness 3 mm) as in Comparative Example A.
A 0.07 low emissivity film was applied. In the same manner as in Example A, the visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorptivity, ultraviolet ray blocking rate, heat transmission coefficient, shielding coefficient, and solar heat gain rate were measured. The results are shown in Table 1.

【0024】〔比較例C〕青色ガラス (厚み3mm) に、
実施例Aと全く同様の垂直放射率0.07の低放射性膜を膜
付けした。これを実施例A同様に、可視光透過率、可視
光反射率、日射透過率、日射反射率、日射吸収率、紫外
線遮断率、熱貫流率、遮蔽係数、日射熱取得率を測定し
た。結果を表1に示す。
[Comparative Example C] On a blue glass (thickness: 3 mm),
A low emissivity film having a vertical emissivity of 0.07, which is exactly the same as that of Example A, was applied. In the same manner as in Example A, the visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorptivity, ultraviolet ray blocking rate, heat transmission coefficient, shielding coefficient, and solar heat gain rate were measured. The results are shown in Table 1.

【0025】〔比較例D〕クリアーガラス (厚み3mm)
に、実施例Aと全く同様の垂直放射率0.07の低放射性膜
を膜付けした。これを実施例A同様に、可視光透過率、
可視光反射率、日射透過率、日射反射率、日射吸収率、
紫外線遮断率、熱貫流率、遮蔽係数、日射熱取得率を測
定した。結果を表1に示す。
[Comparative Example D] Clear glass (thickness 3 mm)
Then, a low-emissivity film having a vertical emissivity of 0.07, which is exactly the same as in Example A, was applied. Similar to Example A, this is the visible light transmittance,
Visible light reflectance, solar radiation transmittance, solar reflectance, solar absorption,
The ultraviolet ray blocking rate, heat transmission coefficient, shielding coefficient, and solar heat gain coefficient were measured. The results are shown in Table 1.

【0026】[0026]

【表1】 [Table 1]

【0027】表1の結果から明らかなとおり本発明にか
かる実施例A、実施例Bの熱遮断ガラスは可視光透過率
が66%以上、紫外線遮断率が85%以上であり、特に日射
熱取得率が0.50以下と、透視性が良好で、紫外線、日射
熱の遮断性に優れ、例えばガラスの板厚を3mmから6mm
に換えても可視光透過率が50%を優に越えるので透視性
が阻害されることはなく、勿論紫外線、日射熱遮断性は
向上するのでより好ましい態様であるといえる。なお低
放射性膜は垂直放射率が0.20以下であればよいが、好ま
しくは0.10以下とすれば、より日射熱の遮断性が向上す
るので推奨するものである。
As is clear from the results shown in Table 1, the heat-shielding glasses of Examples A and B according to the present invention have a visible light transmittance of 66% or more and an ultraviolet light shielding rate of 85% or more, and particularly, the solar heat acquisition. With a ratio of 0.50 or less, it has good transparency and excellent shielding from ultraviolet rays and solar heat. For example, the thickness of glass is 3 mm to 6 mm.
However, since the visible light transmittance is well above 50%, the transparency is not impaired, and the ultraviolet and solar heat shielding properties are improved, which is a more preferable embodiment. The low emissivity film may have a vertical emissivity of 0.20 or less, but a value of 0.10 or less is recommended because it further improves the solar heat shielding property.

【0028】比較例Aは可視光透過率が10%未満であっ
て、窓材としての機能を殆ど喪失しており、また比較例
B〜Dは日射熱取得率が0.52以上であって、実施例に比
べ明らかに劣る。
Comparative Example A had a visible light transmittance of less than 10% and almost no function as a window material, and Comparative Examples B to D had a solar heat gain of 0.52 or more. Obviously inferior to the example.

【0029】〔II〕複層ガラス 〔実施例1〕既述の実施例Aで用いた熱遮断ガラス (膜
付熱線・紫外線吸収緑色系ガラス:厚み3mm) を外側ガ
ラスとして垂直放射率0.07の低放射性膜を内側面に配
し、空気空間 (6mm) を介してクリアーガラス (厚み3
mm) を内側ガラスとして配設した複層ガラスを作製し、
実施例A同様に、可視光透過率、可視光反射率、日射透
過率、日射反射率、日射吸収率、紫外線遮断率、熱貫流
率、遮蔽係数、日射熱取得率を測定した。結果を表2に
示す。
[II] Double-layered glass [Example 1] The heat-shielding glass (heat ray with film / UV absorbing green-based glass: thickness 3 mm) used in the above-mentioned Example A was used as the outer glass and had a low vertical emissivity of 0.07. A radioactive film is placed on the inner surface, and clear glass (thickness 3
mm) as the inner glass,
In the same manner as in Example A, the visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorptivity, ultraviolet ray blocking ratio, heat transmission coefficient, shielding coefficient, and solar heat gain coefficient were measured. The results are shown in Table 2.

【0030】〔実施例2〕実施例1と同様で、ただし空
気空間を12mmとした複層ガラスを作製し、実施例1同様
に、可視光透過率、可視光反射率、日射透過率、日射反
射率、日射吸収率、紫外線遮断率、熱貫流率、遮蔽係
数、日射熱取得率を測定した。結果を表2に示す。
Example 2 The same as in Example 1, except that a double glazing having an air space of 12 mm was prepared, and in the same manner as in Example 1, visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation The reflectance, the solar radiation absorptance, the ultraviolet ray blocking rate, the heat transmission coefficient, the shielding coefficient, and the solar heat gain rate were measured. The results are shown in Table 2.

【0031】〔実施例3〕実施例1と同様で、ただし空
間 (6mm) 内にアルゴンガスを封入した複層ガラスを作
製し、実施例1同様に、可視光透過率、可視光反射率、
日射透過率、日射反射率、日射吸収率、紫外線遮断率、
熱貫流率、遮蔽係数、日射熱取得率を測定した。結果を
表2に示す。
Example 3 The same procedure as in Example 1 was repeated, except that a double-layer glass in which a space (6 mm) was filled with argon gas was prepared, and the visible light transmittance, visible light reflectance, and
Solar transmittance, solar reflectance, solar absorption, UV blocking rate,
The heat transmission coefficient, the shielding coefficient, and the solar heat gain coefficient were measured. The results are shown in Table 2.

【0032】〔実施例4〕既述の実施例Bで用いた熱遮
断ガラス (膜付熱線・紫外線吸収緑色系ガラス:厚み3
mm) を外側ガラスとして垂直放射率0.16の低放射性膜を
内側面に配し、空気空間(6mm) を介してクリアーガラス
(厚み3mm) を内側ガラスとして配設した複層ガラスを
作製し、実施例1同様に、可視光透過率、可視光反射
率、日射透過率、日射反射率、日射吸収率、紫外線遮断
率、熱貫流率、遮蔽係数、日射熱取得率を測定した。結
果を表2に示す。
[Embodiment 4] The heat-shielding glass used in the above-mentioned embodiment B (heat ray with film / green glass absorbing ultraviolet rays: thickness 3)
(mm) as the outer glass, a low emissivity film with a vertical emissivity of 0.16 is placed on the inner surface, and clear glass is provided through the air space (6 mm).
A multi-layer glass in which (thickness: 3 mm) was disposed as an inner glass was prepared, and in the same manner as in Example 1, visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorptivity, ultraviolet ray blocking rate, The heat transmission coefficient, the shielding coefficient, and the solar heat gain coefficient were measured. The results are shown in Table 2.

【0033】〔実施例5〕既述の実施例Aで用いた熱遮
断ガラス (膜付熱線・紫外線吸収緑色系ガラス:厚み3
mm) を外側ガラスとして垂直放射率0.07の低放射性膜を
内側面に配し、空気空間 (6mm) を介して比較例Dで用
いた熱遮断ガラス (膜付クリアーガラス:厚み3mm) を
内側ガラスとして垂直放射率0.07の低放射性膜を内側面
に配した複層ガラスを作製し、実施例1同様に、可視光
透過率、可視光反射率、日射透過率、日射反射率、日射
吸収率、紫外線遮断率、熱貫流率、遮蔽係数、日射熱取
得率を測定した。結果を表2に示す。
[Embodiment 5] The heat-shielding glass used in the above-mentioned Embodiment A (heat ray with film / UV absorbing green glass: thickness 3)
mm) as the outer glass and a low emissivity film with a vertical emissivity of 0.07 on the inner surface, and the heat-shielding glass (clear glass with film: thickness 3 mm) used in Comparative Example D through the air space (6 mm) as the inner glass As a double-layered glass having a low emissivity film with a vertical emissivity of 0.07 on its inner surface, as in Example 1, visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorptivity, The ultraviolet ray blocking rate, heat transmission coefficient, shielding coefficient, and solar heat gain coefficient were measured. The results are shown in Table 2.

【0034】〔比較例1〕既述の比較例Aで用いた熱遮
断ガラス (膜付ブロンズ色ガラス:厚み3mm) を外側ガ
ラスとして垂直放射率0.36の熱線反射膜を内側面に配
し、空気空間 (6mm) を介してクリアーガラス:厚み3
mm) を内側ガラスとして配設した複層ガラスを作製し、
実施例1同様に、可視光透過率、可視光反射率、日射透
過率、日射反射率、日射吸収率、紫外線遮断率、熱貫流
率、遮蔽係数、日射熱取得率を測定した。結果を表2に
示す。
Comparative Example 1 The heat-shielding glass (bronze colored glass with a film: thickness 3 mm) used in the above-mentioned Comparative Example A was used as an outer glass, and a heat-reflecting film having a vertical emissivity of 0.36 was arranged on the inner surface, and air was blown. Clear glass through the space (6 mm): thickness 3
mm) as the inner glass,
In the same manner as in Example 1, the visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorptivity, ultraviolet ray blocking rate, heat transmission coefficient, shielding coefficient, and solar heat gain rate were measured. The results are shown in Table 2.

【0035】〔比較例2〕比較例Bで用いた熱遮断ガラ
ス (膜付ブロンズ色ガラス:厚み3mm) を外側ガラスと
して垂直放射率0.07の低放射性膜を内側面に配し、空気
空間 (6mm) を介してクリアーガラス (厚み3mm) を内
側ガラスとして配設した複層ガラスを作製し、実施例1
同様に、可視光透過率、可視光反射率、日射透過率、日
射反射率、日射吸収率、紫外線遮断率、熱貫流率、遮蔽
係数、日射熱取得率を測定した。結果を表2に示す。
[Comparative Example 2] The heat-shielding glass (bronze colored glass with a film: thickness 3 mm) used in Comparative Example B was used as an outer glass, and a low emissivity film having a vertical emissivity of 0.07 was arranged on the inner surface, and an air space (6 mm ) And a clear glass (thickness: 3 mm) as an inner glass, a double-layer glass was prepared, and Example 1
Similarly, the visible light transmittance, the visible light reflectance, the solar radiation transmittance, the solar radiation reflectance, the solar radiation absorption rate, the ultraviolet ray blocking rate, the heat transmission coefficient, the shielding coefficient, and the solar heat gain rate were measured. The results are shown in Table 2.

【0036】〔比較例3〕比較例Cで用いた熱遮断ガラ
ス (膜付青色ガラス:厚み3mm) を外側ガラスとして、
垂直放射率0.07の低放射性膜を内側面に配し、空気空間
(6mm) を介してクリアーガラス (厚み3mm) を内側ガ
ラスとして配設した複層ガラスを作製し、実施例1同様
に、可視光透過率、可視光反射率、日射透過率、日射反
射率、日射吸収率、紫外線遮断率、熱貫流率、遮蔽係
数、日射熱取得率を測定した。結果を表2に示す。
Comparative Example 3 The heat-shielding glass (blue glass with film: thickness 3 mm) used in Comparative Example C was used as the outer glass.
A low emissivity film with a vertical emissivity of 0.07 is placed on the inner surface to create an air space.
A multilayer glass in which clear glass (thickness 3 mm) was provided as an inner glass via (6 mm) was prepared, and as in Example 1, visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, The solar absorptance, the UV blocking rate, the heat transmission rate, the screening coefficient, and the solar heat gain rate were measured. The results are shown in Table 2.

【0037】〔比較例4〕比較例Dで用いた熱遮断ガラ
ス (膜付クリアーガラス:厚み3mm) を外側ガラスとし
て垂直放射率0.07の低放射性膜を内側面に配し、空気空
間 (6mm) を介してクリアーガラス (厚み3mm) を内側
ガラスとして配設した複層ガラスを作製し、実施例1同
様に、可視光透過率、可視光反射率、日射透過率、日射
反射率、日射吸収率、紫外線遮断率、熱貫流率、遮蔽係
数、日射熱取得率を測定した。結果を表2に示す。
[Comparative Example 4] The heat-shielding glass (clear glass with a film: thickness 3 mm) used in Comparative Example D was used as an outer glass, and a low emissivity film having a vertical emissivity of 0.07 was arranged on the inner side surface to form an air space (6 mm). A multilayer glass in which clear glass (thickness: 3 mm) is disposed as an inner glass through the glass is prepared, and in the same manner as in Example 1, visible light transmittance, visible light reflectance, solar radiation transmittance, solar radiation reflectance, solar radiation absorption rate. The UV blocking rate, the heat transmission rate, the blocking coefficient, and the solar heat gain rate were measured. The results are shown in Table 2.

【0038】〔参考例1〕実施例Aに採用したガラスと
同様の熱線・紫外線吸収緑色系ガラス (厚み3mm) を膜
付けすることなく外側ガラスとし、空気空間 (6mm) を
介して比較例Dで用いた熱遮断ガラス (膜付クリアーガ
ラス:厚み3mm) を内側ガラスとし、垂直放射率0.07の
低放射性膜を内側面に配設して複層ガラスを作製し、実
施例1同様に、可視光透過率、可視光反射率、日射透過
率、日射反射率、日射吸収率、紫外線遮断率、熱貫流
率、遮蔽係数、日射熱取得率を測定した。結果を表2に
示す。
Reference Example 1 The same heat ray / ultraviolet absorbing green glass (thickness 3 mm) as the glass adopted in Example A was used as the outside glass without filming, and Comparative Example D was placed through the air space (6 mm). The heat-shielding glass (clear glass with film: thickness 3 mm) used in 1. was used as the inner glass, and a low-emissivity film with a vertical emissivity of 0.07 was arranged on the inner surface to prepare a double-layer glass. The light transmittance, the visible light reflectance, the solar radiation transmittance, the solar radiation reflectance, the solar radiation absorption rate, the ultraviolet ray blocking rate, the heat transmission coefficient, the shielding coefficient, and the solar heat gain rate were measured. The results are shown in Table 2.

【0039】〔参考例2〕参考例1と同様で、ただし空
気空間を12mmとした複層ガラスを作製し、実施例1同様
に、可視光透過率、可視光反射率、日射透過率、日射反
射率、日射吸収率、紫外線遮断率、熱貫流率、遮蔽係
数、日射熱取得率を測定した。結果を表2に示す。
[Reference Example 2] A multilayer glass similar to that of Reference Example 1 was prepared except that the air space was 12 mm, and the visible light transmittance, the visible light reflectance, the solar radiation transmittance and the solar radiation were the same as in Example 1. The reflectance, the solar radiation absorptance, the ultraviolet ray blocking rate, the heat transmission coefficient, the shielding coefficient, and the solar heat gain rate were measured. The results are shown in Table 2.

【0040】[0040]

【表2】 [Table 2]

【0041】結果は表2から明らかなとおり本発明にか
かる実施例1〜4の複層ガラスが可視光透過率60%以
上、紫外線遮断率90%以上、日射熱取得率0.45以下と好
適な可視光透過性、紫外線、日射熱遮断性を示し、就中
実施例1〜3におけるように垂直放射率0.10以下のもの
を採用すれば、日射熱取得率0.40前後と極めて望ましい
日射熱遮断性を示す。勿論熱遮断ガラスの板厚を実施例
1 〜3の3mmを6mm程度に換えれば、透視性を著しく損
ずることなく紫外線、日射遮断性を更に向上することが
できる。
As is clear from Table 2, the double glazings of Examples 1 to 4 according to the present invention have a visible light transmittance of 60% or more, an ultraviolet ray blocking ratio of 90% or more, and a solar heat gain ratio of 0.45 or less, which are suitable for visible light. Shows light transparency, ultraviolet rays, and solar heat shielding properties, and if the vertical emissivity of 0.10 or less is adopted as in Examples 1 to 3, it exhibits a solar radiation shielding property of around 0.40, which is extremely desirable. . Of course, the thickness of the heat-shielding glass is used as an example.
If 3 mm of 1 to 3 is changed to about 6 mm, the ability to block ultraviolet rays and solar radiation can be further improved without significantly impairing the transparency.

【0042】なお、実施例5は可視光透過率が50%台
と、実施例1〜4に劣るが透視性を著しく損ずるもので
はなく、紫外線遮断率97%以上、日射熱取得率0.40未満
と最良の値を示す。
The visible light transmittance of Example 5 is in the order of 50%, which is inferior to that of Examples 1 to 4, but does not significantly impair the transparency, and the ultraviolet ray blocking rate is 97% or more and the solar heat gain rate is less than 0.40. Shows the best value.

【0043】近年省エネルギーの観点から日射熱取得率
0.4 オーダーのものが奨用され、特に0.4 付近またはそ
れ以下のものを顧客から要求されるケースが多いが、本
発明にかかる実施例1〜5はそれを充分満足するもので
ある。
From the viewpoint of energy saving in recent years, the solar heat gain rate
0.4 order is recommended, and in particular, there are many cases where the customer demands a value around 0.4 or less, but Examples 1 to 5 according to the present invention sufficiently satisfy that.

【0044】比較例1は可視光透過率10%未満と、殆ど
窓材としての機能を喪失し、比較例2〜4は紫外線遮断
率が高くないうえに、日射熱取得率は0.45を越える等実
施例に対し劣ることが明白である。
In Comparative Example 1, the visible light transmittance was less than 10%, and the function as a window material was almost lost. In Comparative Examples 2 to 4, the ultraviolet ray blocking rate was not high, and the solar heat gain rate exceeded 0.45. Obviously, it is inferior to the examples.

【0045】なお、参考例1、2は実施例1、2に対比
し、低放射性膜の配置構成を替え、内側ガラスに配した
ものであるが、夫々日射熱遮断性が該実施例1、2より
やや劣り、本発明にかかる実施例が配置構成として最良
であることが明らかである。
The reference examples 1 and 2 are different from the examples 1 and 2 in that the arrangement of the low emissivity film is changed and the inner glass is arranged. Slightly inferior to No. 2, it is clear that the embodiment according to the present invention is the best arrangement configuration.

【0046】[0046]

【発明の効果】本発明によれば、熱遮断ガラスは視覚上
穏やかで草木の緑色にマッチした色調を呈し、日射から
の熱線を吸収し、有害な紫外線を遮断する作用を呈する
熱線・紫外線吸収緑色系ガラスを基に、遠赤外域の熱線
を遮断する低放射性膜を被膜形成したことにより、熱遮
断作用を向上させ、勿論採光、透視性を損なうことがな
い。また、それを用いた複層ガラスは紫外線遮断率が向
上し、熱遮断性、断熱性が格段に優れるという効果を奏
する。
EFFECTS OF THE INVENTION According to the present invention, the heat-shielding glass has a visually mild color tone that matches the green color of vegetation, absorbs heat rays from solar radiation, and has a function of blocking harmful ultraviolet rays. By forming a low-emissivity film that blocks heat rays in the far infrared region on the basis of greenish glass, the heat-shielding effect is improved and, of course, light and transparency are not impaired. In addition, the double glazing using the same has an effect of improving the ultraviolet ray blocking rate and being significantly excellent in heat blocking property and heat insulating property.

【図面の簡単な説明】[Brief description of drawings]

【図1】図1Aは紫外線・赤外線吸収緑色系ガラス、ブ
ロンズ色ガラス、青色ガラス、クリアーガラスの透過率
をあらわすグラフである。図1Bは低放射性膜、熱線反
射膜の反射率をあらわすグラフである。
FIG. 1A is a graph showing the transmittance of ultraviolet / infrared absorbing green glass, bronze glass, blue glass, and clear glass. FIG. 1B is a graph showing the reflectance of the low emissivity film and the heat ray reflective film.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 大西 正司 三重県松阪市大口町1510番地 セントラル 硝子株式会社テクニカルセンター内 ─────────────────────────────────────────────────── ─── Continuation of front page (72) Inventor Shoji Onishi 1510 Oguchi-cho, Matsusaka-shi, Mie Central Glass Co., Ltd. Technical Center

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】熱線・紫外線吸収緑色系ガラスの片面に、
銀層を含む多層膜からなり、垂直放射率0.2 以下の低放
射性膜を形成したことを特徴とする熱遮断ガラス。
1. A heat-ray / ultraviolet-absorbing green glass on one side,
A heat-shielding glass comprising a multi-layer film including a silver layer and having a low emissivity film having a vertical emissivity of 0.2 or less.
【請求項2】熱線・紫外線吸収緑色系ガラスが、板厚5
mmにおける可視光透過率 (A光源)65%以上、日射透過
率35〜50%、紫外線透過率15%以下、主波長500 〜530n
m 、刺激純度5以下であることを特徴とする請求項1記
載の熱遮断ガラス。
2. The heat ray / ultraviolet absorbing green glass has a plate thickness of 5
mm visible light transmittance (A light source) 65% or more, solar radiation transmittance 35 to 50%, ultraviolet light transmittance 15% or less, dominant wavelength 500 to 530n
The heat-shielding glass according to claim 1, wherein m 2 and stimulus purity are 5 or less.
【請求項3】請求項1または2記載の熱遮断ガラスを屋
外側、クリアー系ガラスを屋内側に配した複層ガラスで
あり、低放射性膜を熱遮断ガラスの内側面に形成してな
ることを特徴とする熱遮断ガラスを用いた複層ガラス。
3. A multi-layer glass comprising the heat-shielding glass according to claim 1 or 2 on the outdoor side and a clear glass on the indoor side, wherein the low emissivity film is formed on the inner surface of the heat-shielding glass. Multi-layer glass using a heat-shielding glass characterized by.
JP5159614A 1993-06-29 1993-06-29 Thermal barrier glass and double glazing using it Expired - Fee Related JP2882728B2 (en)

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JPH0710609A true JPH0710609A (en) 1995-01-13
JP2882728B2 JP2882728B2 (en) 1999-04-12

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