KR940018405A - 에틸렌계 불포화 카복실산과 에틸렌계 불포화 지방산 유도체의 공중합체의 염 - Google Patents

에틸렌계 불포화 카복실산과 에틸렌계 불포화 지방산 유도체의 공중합체의 염 Download PDF

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KR940018405A
KR940018405A KR1019940000091A KR19940000091A KR940018405A KR 940018405 A KR940018405 A KR 940018405A KR 1019940000091 A KR1019940000091 A KR 1019940000091A KR 19940000091 A KR19940000091 A KR 19940000091A KR 940018405 A KR940018405 A KR 940018405A
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프리이드리히 헤르베르트
메에스 베른하르트
그루버 리카르트
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엥겔하르트, 루츠
훽스트 아크티엔게젤샤프트
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Abstract

본 발명은 A) 일반식 (A)의 구조단위 1 내지 99중량%; B) 일반식(B)의 구조단위 99 내지 1중량%; C) 일반식(C)의 구조단위 0 내지 40중량%; 및 D) 일반식(D)의 구조단위 0 내지 40중량%를 포함하는, 에틸렌계 불포화 카복실산과 에틸렌계 불포화 지방산 유도체의 공중합체의 염에 관한 것이다.
상기식에서,R1, R2, R3, R4, X, M, Y, Z, W 및 V는 명세서내에서 정의한 바와 같다.
본 발명은 또한 상기한 물질의 제조방법 및 이의 용도에 관한 것이기도 하다.

Description

에틸렌계 불포화 카복실산과 에틸렌계 불포화 지방산 유도체의 공중합체의 염
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. A) 일반식 (A)의 구조단위 1 내지 99중량%; B) 일반식(B)의 구조단위 99 내지 1중량%; C) 일반식(C)의 구조단위 0 내지 40중량%; 및 D) 일반식(D)의 구조단위 0 내지 40중량%를 포함하는, 에틸렌계 불포화 카복실산과 에틸렌계 불포화 지방산 유도체의 공중합체의 염.
    상기식에서, R1및 R2는 각각 수소 또는 C1-C4알킬이고, R3은 수소 또는 C1-C4알킬, 바람직하게는 메틸이며, R4는 C2-C16알킬 또는 C2-C16알케닐이고, X는 -(CH2)0-10- 또는 C6-C18아릴, 바람직하게는 페닐이며, M은 알칼리 금속, 알칼리 토금속 또는 암모늄 이온이고, Y는 C1-C13알킬렌, -CH2-(CH=CH-CH2)1-5- 또는 -(CH=CH)1-3-이며, Z는 그룹 CN, C(O)N(R5)2(여기서, R5는 수소, C1-C18알킬, C1-C18알케닐 및/또는 (CH2)1-3OH이다), COCR6(여기서, R6은 C1-C36알킬, 바람직하게는 C1-C5알킬 또는 C16-C36알킬이다),
    (여기서, Y 및 R4는 상기한 바와 같다)이고, W는 그룹 CN, C(O)N(R5)2(여기서, R5는 상기와 같다) 또는 COOR7(여기서, R7은 C1-C18알킬, 바람직하게는 C1-C10알킬이다)이며,V는 C6-C18아릴, 바람직하게는 페닐, 또는 페녹시아세틸, C4-C6람탐(바람직하게는, N-피롤리딜), 그룹 O-R7, (O)C-R7또는 OOC-R7(여기서, R7은 C1-C18알킬, 바람직하게는 C1-C10알킬이다)이다.
  2. 다량체로서의 하나 이상의 에틸렌계 불포화 카복실산 및 공단량체로서의 하나 이상의 에틸렌계 불포화 지방산 유도체를 유리 래디칼 공여체의 존재하에서, 경우에 따라 조절제 및/ 또는 보조 개시제의 존재하에서 서로 중합반응시킨 다음, 염기 수용액을 가함을 특징으로 하여, 제 1 항의 공중합체를 제조하는 방법.
  3. 제 2 항에 있어서, 벌크 또는 용액 중합반응을 수행하는 방버.
  4. 제 2 항에 있어서, 중합반응을 교반 탱크, 교반 탱크들의 캐스캐이드(cascade), 교반 반응기 또는 고정식 혼합기 중에서 수행하는 방법.
  5. 제 2 항에 있어서, 중합반응을 유리 래디칼 공여체 0.1 내지 20중량%, 바람직하게는 0.2 내지 10중량%(단량체 함량기존)의 존재하에서 수행하는 방법.
  6. 제 2 항에 있어서, 중합반응을 조절제 0.1 내지 1중량%(단량체 함량 기준)의 존재하에서 수행하는 방법.
  7. 제 2 항에 있어서, 중합반응을 보조개시제 0.1 내지 2000ppm(중량), 바람직하게는 0.1 내지 1000ppm(중량) 존재하에서 수행하는 방법.
  8. 제 2 항에 있어서, 중합반응을 50 내지 200℃, 바람직하게는 100 내지 180℃의 온도에서 수행하는 방법.
  9. 제 2 항에 있어서, 중합반응을 수행한 후, 반응 혼합물을 100℃ 이하, 바람직하게는 20 내지 80℃, 특히 바람직하게는 20 내지 40℃의 온도로 냉각시키는 방법.
  10. 제 2 항에 있어서, 공중합체내에 함유된 유리 카복실 그룹에 대해 동몰량의 염기를 반응 혼합물에 가하는 방법.
  11. 제 10 항에 있어서, 20 내지 40% 농도(중량)의 알칼리 금속 수산화물 또는 수용성 질소 화합물의 수용액을 염기로서 사용하는 방법.
  12. 식물 및/또는 동물 지방, 오일 및/또는 왁스용 지방-리쿼링 유화제(fat-liquoring emulsifier)로서의 제 1 항의 공종합체의 용도.
  13. 하나 이상의 제 1 항의 공중합체를 포함하는 가죽 및 모피 펠트용 지방 리쿼링제.
  14. 제 13 항에 있어서, 하나 이상의 제 1 항의 공중합체, 포함되고/되거나 불포화된 지방산 유도체, 바람직하게는 지방산 에스테르, 특히 바람직하게는 지방산 트리글리세라이드, 물 및, 경우에 따라 부가제, 바람직하게는 중섬유를 포함하는 지방 리쿼링제.
  15. 제 2 항 내지 제10항중 어느 한 항의 방법을 포함하는 공정에 따라 제 1 항의 공중합체를 제조하고, 경우에 따라, 산을 가하고, 물 50 내지 80중량%(에멀젼의 총중량 기준)를 가함을 특징으로 하여, 제13항의 지방 리쿼링제를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940000091A 1993-01-06 1994-01-05 에틸렌계불포화카복실산과에틸렌계불포화지방산유도체의공중합체의염,이의제조방법,및이를포함하는가지제및이의제조방법 KR100292208B1 (ko)

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DE4300140 1993-01-06
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KR100292208B1 KR100292208B1 (ko) 2001-10-24

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DE4213283A1 (de) * 1992-04-23 1993-10-28 Basf Ag Verwendung von Copolymerisaten aus Carbonsäuren und langkettigen Verbindungen mit isolierten C-C-Mehrfachverbindungen als Verdickungs- oder Dispergiermittel
US5830957A (en) * 1997-06-23 1998-11-03 Morton International, Inc. Resins formed from alpha-beta-unsaturated monomers and unsaturated fatty acids
US6225402B1 (en) 1998-09-25 2001-05-01 Mcwhorter Technologies, Inc. Aqueous based dispersions for polyolefinic substrates
US6277953B1 (en) 1998-09-25 2001-08-21 Mcwhorter Technologies, Inc. Stable aqueous polymer dispersions and a process for their preparation
CN102241781B (zh) * 2011-05-06 2012-10-10 陕西科技大学 淀粉与磺甲基苯酚接枝共聚物皮革合成鞣剂的制备方法
JP7132316B2 (ja) * 2020-12-28 2022-09-06 高圧ガス工業株式会社 二液型硬化性組成物

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US3947399A (en) * 1972-06-01 1976-03-30 Desoto, Inc. Aqueous copolymer dispersions stable in the absence of emulsifying agent and method of producing the same by aqueous polymerization of unsaturated monomers in the presence of trihydric or tetrahydric alcohol
IT981903B (it) * 1973-04-09 1974-10-10 Duco Spa Resine acide oleo acriliche e procedimento per la loro prepa razione
US4653584A (en) * 1985-05-30 1987-03-31 The Standard Oil Company Maleimide-modified bioresistant polymers and enhanced oil recovery method employing same
DE4142318C2 (de) * 1991-12-20 1999-01-14 Zschimmer & Schwarz Gmbh & Co Verwendung von Fettsäure-Umsetzungsprodukten in Leder- und Pelzfettungsmitteln und Mittel zum Fetten von Leder und Pelzfellen

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ZA9449B (en) 1994-09-05
NO301334B1 (no) 1997-10-13
NO940041D0 (no) 1994-01-05
EP0606064A3 (de) 1994-11-30
KR100292208B1 (ko) 2001-10-24
ES2096957T3 (es) 1997-03-16
CA2112854A1 (en) 1994-07-07
AU667595B2 (en) 1996-03-28
EP0606064B1 (de) 1996-11-20
TR27325A (tr) 1995-01-12
NO940041L (ko) 1994-07-07
EP0606064A2 (de) 1994-07-13
BR9400022A (pt) 1994-07-26
DE59401050D1 (de) 1997-01-02
JPH06322033A (ja) 1994-11-22
US5504162A (en) 1996-04-02
CN1091437A (zh) 1994-08-31
AU5302894A (en) 1994-07-14

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