KR940003596A - 흡착막에 의한 수소 회수 - Google Patents

흡착막에 의한 수소 회수 Download PDF

Info

Publication number
KR940003596A
KR940003596A KR1019930014931A KR930014931A KR940003596A KR 940003596 A KR940003596 A KR 940003596A KR 1019930014931 A KR1019930014931 A KR 1019930014931A KR 930014931 A KR930014931 A KR 930014931A KR 940003596 A KR940003596 A KR 940003596A
Authority
KR
South Korea
Prior art keywords
component
stream
membrane
permeate
gas
Prior art date
Application number
KR1019930014931A
Other languages
English (en)
Other versions
KR0137440B1 (ko
Inventor
배스카라 라오 매드허카아
서어카아 쉬바지
마이클 애브라아도 조셉
프레드릭 바아드 윌리엄
Original Assignee
윌리암 에프. 마쉬
에어 프로덕츠 앤드 케미칼스, 인코오포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 윌리암 에프. 마쉬, 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 filed Critical 윌리암 에프. 마쉬
Publication of KR940003596A publication Critical patent/KR940003596A/ko
Priority to KR97042065A priority Critical patent/KR0136821B1/ko
Application granted granted Critical
Publication of KR0137440B1 publication Critical patent/KR0137440B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0046—Inorganic membrane manufacture by slurry techniques, e.g. die or slip-casting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/04—Tubular membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/028—Molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/028—Molecular sieves
    • B01D71/0281—Zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/045—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes using membranes, e.g. selective permeation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/081—Heating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound

Abstract

소공성 지지체에 의해 지된 미소공성 흡착 물질을 포함하는 복합 반투과성막은 압력 스웡 흡착(PSA) 시스템과 연속적으로 작동되며, PSA 거부 가스는 막성능을 항상시키기 위한 일소 가스로 사용된다. 통합 막-PSA 시스템은 수소와 탄화수소의 혼합물로부터 고순도의 수소를 회수하는데 특히 유용하며, 증기 -메탄 개질기차의 통합에 적합하다.

Description

흡착막에 의한 수소 회수
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도의 흡착막이 압력 스윙 흡착 시스템에 통합되어 있는 본 발명의 도식적 흐름도이다.
제2도는 흡착막이 압력 스윙 흡착 시스템 및 탄화수소 개질 시스템에 통합되어 있는 본 발명의 제2양태의 도식적 흐름도이다.
제3도는 흡착막이 압력 스윙 흡착 시스템 및 탄호수소 개질 시스템에 통합되어 있는 본 발명의 제3 양태의 도식적 흐름도이다.
제4도는 흡착막이 압력 스윙 흡착 시스템 및 분류기에 통합된 본 발명의 제4 양태의 도식적 흐름도이다.

Claims (17)

  1. 하나 이상의 제1성분 및 하나 이상의 제2성분을 포함하는 가스 피 이드 (feed) 혼합물로부터 상기 제1성분을 회수하는 방법으로서, 여기서, 상기 제2성분은 상기 제1성분보다흉착물질에 더 강하게 흡착되며, 상기 방법이 (a) 소공성 (porous) 지지체에 의해 지지된 미소공성(microporous) 흉착 물질을 포함하는 복합 반투과성 막(이 막은 피 이드쪽 및 투과물쪽을 가짐)을 함유하는 분리기 속으로 상기 피 이드 혼합물을 통과시키고, 상기 분리기로 부터 상기 제1 성분이 풍부한 불투과 중간 생성물 스트림(stream)을 회수하는 단계(여기서, 상기 제2 성분의 부분들은 상기 미소공성 홉착 물질에 의 해 선택적으로 흡착되며, 흡착된 유동상으로서 상기 막의 피이드쪽으로부터 투과물쪽으로 확산됨) : (b) 상긴 제2 성분을 포함하는 투과물을 상기 막의 투과물쪽으로부터 회수하는 단계 : (c) 상기 제1 성분을 포함하는 고순도의 생성물 스트림 및 상기 제2성분의 추가 부분을 포항하는 거부 스트림(rejectstream)으로 상기 불투과 중간 생성물 스트림을 분리하는 단계, 및 (d) 상기 막의 투과물 쪽을 가로질러 일소가스 (Sweep 9aS)로서 적어도 일부분의 상기 거부 스트림을 통과시키고, 상기 분리기로부터 일소 가스/투과 유출물 스트림을 회수하여 상기 제1 성분의 회수를 증가시키고, 상기 막을 통한 상기 제2 성분의 투과 속도를 증가시키는 단케를 포함하는 방법.
  2. 제1항에 있어서, 압력 스윙 흡착 시스템 속으로 스트림을 통과시키고(이 때, 잔존하는 제2성분들은 선택적으로 흡착됨), 상기 시스템으로부터 제1성분을 포함하는 고순도의 생성물 및 상기 제2성분의 추가부분을 포함하는 거부 스트림을 회수하므로써, 중간 생성물 스트림이 단계(C)에서 분리되는 것인 방법.
  3. 제2항에 있어서, 제1 성분이 적어도 수소를 포함하는 것인 방법.
  4. 제3항에 있어서, 제2성분이 메탄, 에탄, 에틸렌, 프로잔, 프로필렌, 부탄, 이소부탄, 부틸렌, 이소부틸렌, 및 이들의 혼합물로 이루어진 군으로부터 선택되는 탄화수소를 포함하는 것인 방법.
  5. 제4항에 있어서, 피이드 스트림의 압력이 20 내지 300 psig인 방법.
  6. 제5항에 있어서, 중간 생성물 스트림의 압력이 15 내지 295 psig인 방법.
  7. 제4항에 있어서, 일소 가스로서 사용된 거부 스트림의 압력이 2 내지 50 prig인 방법.
  8. 제4항에 있어서, 증기-메탄 개질기에서 메탄-함유 피이드 스트림을 개질시켜 수소, 탄소 산화물, 물 및 반응되지 않은 메탄을 포함하는 합성 가스를 생성시키고 압력 스윙 흡찰 시스템 앞의 중간 생성물 스트림과 상기 합성 가스를 합치는 단계를 추가로 포함하는 방법.
  9. 제8항에 있어서, 증기-메탄개질기에서 연료로서 적어도 일부의 일소 가스/투과유출물 스트림을 이용하는 것을 추가로 포항하는 방법.
  10. 제4항에 있어서, 적어도 일부의 일소 가스/투과 유출물 스트림을 분류기 (dephlegmator)속으로 통과시키는 단계, 상기 분류기로부터 C3와 보다 무거운 탄화수소를 함유하는 탄화수소 생성물 스트림을 회수하는 단계, 또한 상기 분류기로부터 C9 보다 가벼운 성분들을 함유하는 가벼운 중간 탄화수소 스트림을 회수하는 단계, 상기 가벼운 충간 탄화수소 스트림을 압력 스윙 흡착 시스템 앞의 상기 중간 생성물 스트림과 합치는 단계는 추가로 포함하는 방법.
  11. 메탄-함유 피이드 가스, 및 수소와 탄화수소를 함유하는 가스 혼합물로부터 수소를 생산하는 방법으로서, (a) 소공성 지지체에 의해 지지된 미소공서 흘착 물질을 포함하는 복합 반투과성 막(이 막은 피이드쪽 및 투과물 쪽을 가짐)을 함유하는 분리기 속으로 상기 가스 혼합물을 통과시키고. 상기 분리기로부터 수소가 풍부한 중간 생성물 스트림을 최수하는 단계(여기서, 상기 제2성분의 부분들은 상기 미소공성 흉착 물질에 의해 선택적으로 흉착되며, 흡착된 유동상으로서 상기 막의 피이드쪽으로부터 투과물쪽으로 확산됨): (b) 상기 탄화수소를 포함하는 투과물을 상기 막의 투과물쪽으로부터 회수하는 단계: (C) 중기-메탄 개질기에서 메탄-함유 피이드 스트림의 일부분을 개질시켜 수소, 탄소 산화물, 물 및 반응되지 않은 메탄을 포함하는 합성 가스를 생성시키고, 상기 중간 생성물 스트림과 상기 합성 가스를 합치는 단계: (d) 단계(c)의 결과로 생긴 합헉진 스트림을 탄화수소 및 탄소 산화물이 선택적으로 흡착되는 압력 스윙 흡착 시스텡 속으로 통과시키고, 상기 시스템으로부터 고순도의 수소 생 성물, 및 탄화수소와 탄소 산화물을 포함하는 거부 스트림을 회수하는 단계 : 및 (e) 상기 막의 투과물쪽을 가로질러 일소 가스로서 상기 메탄-함유 피이드 가스의 잔존부분을 통과시키고, 상기 분리기로부터 일소 가스/투과 유출물 스트림을 회수하여, 수소의 회수도를 증가시키고 상기 막을 통한 탄화수소의 투과속도를 증가시키는 단계를 포함하는 방법.
  12. 제11항에 있어서, 증기-메탄개질기에서 연료로서 적어도 일부의 일소 가스/투과 유출물 스트림을 이용하는 것을 추가로 포함하는 방법.
  13. 제11항에 있어서, 증기-메탄개질기에서 추가 피이드로서 적어도 일부의 일소 가스/투과 유출물 스트림을 이용하는 것을 추가로 포함하는 방법.
  14. 제11항에 있어서, 증기-메탄 개질기에서 적어도 일부의 거부 스트림을 압력 스윙 흡착시스뎀으로부터 이용하는 것을 추가로 포함하는 방법.
  15. 하나 이상의 제1 성분 및 하나 이상의 제2 성분을 포함하는 가스 피이드 혼합물로부터 상기 제1 성분을 회수하는 방법으로서, 여기서, 상기 제2성분은상기 제1성분 보다흡착물질에 더 강하게 흡착되며, 상기 방법이 (a) 소공성 지지테에 의해 지지된 미소공성 흡착 물질을 포함하는 복합 반투과성막(이 막은 피이드쪽 및 투과물 쪽을 가짐)을 함유하는 분리기 속으로 상기 피이드 혼합물을 통과시키고, 상기 분리기로부터 상기 제1 성분이 풍부한 불투과 중간 릉성물 스트림을 회수하는 단계 (여기서, 상기 제2성분의 부분들은 상기 미소공성 흡착 물질 에 의해 선택적으로 흡착되며, 흡착된 유동상으로서 상기 막의 피이드쪽으로 부터 투과물쪽으로 확산됨) ; (b)상기 제2성분을 포함하는 투과물을 상기 막의 투과물쪽으로부터 회수하는 단계; (c) 상기 막의 투과물쪽을 가로 질러 일소 가스를 통과시키고, 상기 분리기로부터 일소 가스/투과 유출물 스트림을 회수시켜 (일소 가스는 상기 피이드 혼합물내에 존재하는 하나 이상의 동일한 제2성분을 포함함), 상기 제1 성분의 회수를 증가시키고 상기 막을 통한 상기 제2 성분의 투과 속도를 증가시키는 단계를 포함하는 방법.
  16. 하나 이상의 제1 성분 및 하나 이상의 제2 성분을 포함하는 가스 피이드 혼합물로부터 상기 제1 성분을 회수하기 위한 통합 분리 시스템으로서, 여기서, 상기 제2성분은 상기 제1성분보다 흡착 물질에 더 강하게 흡착되며, 상기 시스템이 (a) 소공성 지지테에 의해 지지된 미소공성 흉착 물질(이 물질은 상기 제2성분을 선택적으로 흡착할 수 있고 투과할 수 있음)을 포함하는 복합 반투과성 막(각각의 막은 피이드쪽 및 투과물쪽을 가짐)을 각각 함유하는 하나 이상의 분리기 모듀울(modules) ; (b) 상기 제2 성분을 선택적으로 흡착할 수 있는 알갱이 흡착 물질을 함유하는 복수의 흡착 용기를 포함하는 압력 스윙 흡착 시스템; (c) 상기 막의 피이드쪽의 각각의 상기 분리기 모듀을 속으로 상기 가스 피이드 혼합물을 주입하는 수단; (d) 각각의 상기 분리기 모듈울로부터 상기 막의 피 이드쪽의 불투과 중간 생성물 스트림을 제거하는 수단 및 상기 스트림을 상기 압력 스윙 흡착 시스템 속으로 주입하는 수단; (e) 상기 제1 성분을 포함하는 고순도의 생성물 스트림을 제거하는 수단 및 상기 제2 성분을 포항하는 거부 스트림을 상기 압력 스윙 흡착 시스템으로부터 제거하는 수단, (f) 적어도 일부의 상기 거부 스트림을 각각의 상기 분리기 모듀을 속으로 주입하고 상기 거부 스트림의 일부를 일소 가스로서 각각의 막의 투과물 쪽을 지나 통과시키는 수단: 및 (g) 상기 분리기 모듀울로부터 혼합 일소 가스/투과물 스트림을 회수하는 수단을 포함하는 통합 분리 시스템.
  17. 제16항에 있어서, 분리기 모듀울내에 소공성 지지체가 평평한 시이트, 실린더형 관, 공동(空洞) 섬유 또는 단일체(monolith)로 이루어진 군으로부터 선택되는 모양으로 제조되는 것인 시스템.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930014931A 1992-08-03 1993-08-02 흡착막에 의한 수소 회수 방법 및 장치 KR0137440B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR97042065A KR0136821B1 (en) 1992-08-03 1997-08-25 Hydrogen recovery by absorbent membranes

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/923,768 US5354547A (en) 1989-11-14 1992-08-03 Hydrogen recovery by adsorbent membranes
US07/923768 1992-08-03
US7/923768 1992-08-03

Publications (2)

Publication Number Publication Date
KR940003596A true KR940003596A (ko) 1994-03-12
KR0137440B1 KR0137440B1 (ko) 1998-04-27

Family

ID=25449239

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930014931A KR0137440B1 (ko) 1992-08-03 1993-08-02 흡착막에 의한 수소 회수 방법 및 장치

Country Status (6)

Country Link
US (2) US5354547A (ko)
EP (1) EP0582184A1 (ko)
KR (1) KR0137440B1 (ko)
CA (1) CA2101373A1 (ko)
SG (1) SG41934A1 (ko)
TW (1) TW235250B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150091501A (ko) * 2012-12-06 2015-08-11 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 기체 분리용 흡착제의 선택화 방법

Families Citing this family (151)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5354547A (en) * 1989-11-14 1994-10-11 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
US5507856A (en) * 1989-11-14 1996-04-16 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
DE4214551C2 (de) * 1992-04-27 1996-06-20 Geesthacht Gkss Forschung Verfahren und Vorrichtung zur Trennung von über Flüsssigkeiten entstehenden Gasgemischen
US5332424A (en) * 1993-07-28 1994-07-26 Air Products And Chemicals, Inc. Hydrocarbon fractionation by adsorbent membranes
US5435836A (en) * 1993-12-23 1995-07-25 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
US5912048A (en) * 1994-08-25 1999-06-15 Air Products And Chemicals, Inc. Passivation carbonaceous adsorptive membranes
AU690723B2 (en) * 1994-09-14 1998-04-30 Bend Research, Inc. Organic and inorganic vapor permeation by countercurrent condensable sweep
US5792239A (en) * 1994-10-21 1998-08-11 Nitrotec Corporation Separation of gases by pressure swing adsorption
US5632803A (en) * 1994-10-21 1997-05-27 Nitrotec Corporation Enhanced helium recovery
US5707425A (en) * 1994-10-21 1998-01-13 Nitrotec Corporation Helium recovery from higher helium content streams
FR2730790B1 (fr) * 1995-02-17 1997-05-23 Air Liquide Procede d'introduction d'un gaz de remplissage dans une enceinte et installation de mise en oeuvre
FR2731163B1 (fr) * 1995-03-03 1997-06-20 Air Liquide Procede et installation de separation d'un melange gazeux par permeation
CA2170190A1 (en) * 1995-03-07 1996-09-08 Dwayne T. Friesen Volatile organic component removal by membrane separation using countercurrent sweep gas
EP0747108B1 (en) * 1995-06-07 2002-02-20 Air Products And Chemicals, Inc. Oxygen production by ion transport membranes with work recovery
FR2740444B1 (fr) * 1995-10-26 1997-12-26 Air Liquide Procede et installation de production d'hydrogene et d'energie
US5637259A (en) * 1995-12-04 1997-06-10 Natural Resources Canada Process for producing syngas and hydrogen from natural gas using a membrane reactor
JP3868000B2 (ja) * 1996-01-25 2007-01-17 エクソン・リサーチ・アンド・エンジニアリング・カンパニー 膜を用いる分離法
US5634354A (en) * 1996-05-08 1997-06-03 Air Products And Chemicals, Inc. Olefin recovery from olefin-hydrogen mixtures
US5669959A (en) * 1996-05-16 1997-09-23 Uop Process for safe membrane operation
US5843209C1 (en) * 1996-08-14 2001-05-15 Bend Res Inc Vapor permeation system
US6059857A (en) * 1996-08-14 2000-05-09 Bend Research, Inc. Ultrapurification of organic solvents
US5753010A (en) * 1996-10-28 1998-05-19 Air Products And Chemicals, Inc. Hydrogen recovery by pressure swing adsorption integrated with adsorbent membranes
US6783741B2 (en) 1996-10-30 2004-08-31 Idatech, Llc Fuel processing system
US6319306B1 (en) 2000-03-23 2001-11-20 Idatech, Llc Hydrogen-selective metal membrane modules and method of forming the same
US6494937B1 (en) 2001-09-27 2002-12-17 Idatech, Llc Hydrogen purification devices, components and fuel processing systems containing the same
US6376113B1 (en) 1998-11-12 2002-04-23 Idatech, Llc Integrated fuel cell system
US6547858B1 (en) 1999-03-22 2003-04-15 Idatech, Llc Hydrogen-permeable metal membrane and hydrogen purification assemblies containing the same
US6537352B2 (en) 1996-10-30 2003-03-25 Idatech, Llc Hydrogen purification membranes, components and fuel processing systems containing the same
US5997594A (en) * 1996-10-30 1999-12-07 Northwest Power Systems, Llc Steam reformer with internal hydrogen purification
US5861137A (en) * 1996-10-30 1999-01-19 Edlund; David J. Steam reformer with internal hydrogen purification
US6152995A (en) * 1999-03-22 2000-11-28 Idatech Llc Hydrogen-permeable metal membrane and method for producing the same
US6221117B1 (en) 1996-10-30 2001-04-24 Idatech, Llc Hydrogen producing fuel processing system
US7195663B2 (en) 1996-10-30 2007-03-27 Idatech, Llc Hydrogen purification membranes, components and fuel processing systems containing the same
US5753011A (en) * 1997-01-17 1998-05-19 Air Products And Chemicals, Inc. Operation of staged adsorbent membranes
JP2001510395A (ja) * 1997-01-23 2001-07-31 カーボン メンブレインズ リミテッド モレキュラーシーブ膜を用いる過フッ化化合物およびヒドロフルオロカーボンガスの回収
US6159272A (en) * 1997-01-24 2000-12-12 Membrane Technology And Research, Inc. Hydrogen recovery process
US5980609A (en) * 1997-01-24 1999-11-09 Membrane Technology And Research, Inc. Hydrogen recovery process
US5827351A (en) * 1997-02-14 1998-10-27 Praxair Technology, Inc. Air separation system and method
EP0860194A1 (en) * 1997-02-21 1998-08-26 Aquilo Gas Separation B.V. A process for drying compressed air
US6117210A (en) * 1997-04-29 2000-09-12 Praxair Technology, Inc. Solid electrolyte systems for producing controlled purity oxygen
US5906673A (en) * 1997-05-15 1999-05-25 Nitrotec Corporation Pressure swing system with auxiliary adsorbent bed
US6149714A (en) * 1997-06-05 2000-11-21 Praxair Technology, Inc. Process for enriched combustion using solid electrolyte ionic conductor systems
US5888272A (en) * 1997-06-05 1999-03-30 Praxair Technology, Inc. Process for enriched combustion using solid electrolyte ionic conductor systems
US5944874A (en) * 1997-06-23 1999-08-31 Praxair Technology, Inc. Solid electrolyte ionic conductor systems for the production of high purity nitrogen
US5837034A (en) * 1997-06-23 1998-11-17 Praxair Technology, Inc. Process for reducing carbon production in solid electrolyte ionic conductor systems
US6106591A (en) * 1997-06-23 2000-08-22 Praxair Technology, Inc. Process for reducing carbon production in solid electrolyte ionic conductor systems
US5900031A (en) * 1997-07-15 1999-05-04 Niagara Mohawk Power Corporation Electrochemical hydrogen compressor with electrochemical autothermal reformer
US6179900B1 (en) * 1997-10-09 2001-01-30 Gkss Forschungszentrum Geesthacht Gmbh Process for the separation/recovery of gases
EP0908219B1 (en) * 1997-10-09 1999-12-08 Gkss-Forschungszentrum Geesthacht Gmbh Multi-stage process for the separation/recovery of gases
US5976223A (en) * 1997-11-18 1999-11-02 Praxair Technology, Inc. Solid electrolyte ionic conductor systems for oxygen, nitrogen, and/or carbon dioxide production with gas turbine
US5964922A (en) * 1997-11-18 1999-10-12 Praxair Technology, Inc. Solid electrolyte ionic conductor with adjustable steam-to-oxygen production
US5954859A (en) * 1997-11-18 1999-09-21 Praxair Technology, Inc. Solid electrolyte ionic conductor oxygen production with power generation
US5935298A (en) * 1997-11-18 1999-08-10 Praxair Technology, Inc. Solid electrolyte ionic conductor oxygen production with steam purge
FR2778581B1 (fr) * 1998-05-12 2000-06-09 Commissariat Energie Atomique Procede de purification, et de concentration en un constituant minoritaire, d'un melange gazeux, procede de detection de ce constituant, et installation
US6190540B1 (en) 1998-05-22 2001-02-20 Membrane Technology And Research, Inc. Selective purging for hydroprocessing reactor loop
US6165350A (en) * 1998-05-22 2000-12-26 Membrane Technology And Research, Inc. Selective purge for catalytic reformer recycle loop
US6179996B1 (en) 1998-05-22 2001-01-30 Membrane Technology And Research, Inc. Selective purge for hydrogenation reactor recycle loop
US6190536B1 (en) 1998-05-22 2001-02-20 Membrane Technology And Research, Inc. Catalytic cracking process
US6011192A (en) * 1998-05-22 2000-01-04 Membrane Technology And Research, Inc. Membrane-based conditioning for adsorption system feed gases
US6171472B1 (en) 1998-05-22 2001-01-09 Membrane Technology And Research, Inc. Selective purge for reactor recycle loop
US6264828B1 (en) 1998-05-22 2001-07-24 Membrane Tehnology And Research, Inc. Process, including membrane separation, for separating hydrogen from hydrocarbons
US6616909B1 (en) * 1998-07-27 2003-09-09 Battelle Memorial Institute Method and apparatus for obtaining enhanced production rate of thermal chemical reactions
US6440895B1 (en) * 1998-07-27 2002-08-27 Battelle Memorial Institute Catalyst, method of making, and reactions using the catalyst
DE19849216A1 (de) 1998-10-26 2000-04-27 Andreas Noack Verfahren und Vorrichtung zur Trennung von Fluidgemischen (Thermomembranverfahren)
US6419726B1 (en) 1999-10-21 2002-07-16 Ati Properties, Inc. Fluid separation assembly and fluid separation module
US6602325B1 (en) 1999-10-21 2003-08-05 Ati Properties, Inc. Fluid separation assembly
CA2351191C (en) * 1998-11-10 2005-02-22 Ati Properties, Inc. Hydrogen separation membrane
US6835232B2 (en) * 1998-11-10 2004-12-28 Frost Chester B Fluid separation assembly and fluid separation module
US6183628B1 (en) 1999-03-19 2001-02-06 Membrane Technology And Research, Inc. Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons
US6592749B1 (en) 1999-03-19 2003-07-15 Membrane Technology And Research, Inc. Hydrogen/hydrocarbon separation process, including PSA and membranes
US6596057B2 (en) 1999-03-22 2003-07-22 Idatech, Llc Hydrogen-selective metal membranes, membrane modules, purification assemblies and methods of forming the same
US6767389B2 (en) * 1999-03-22 2004-07-27 Idatech, Llc Hydrogen-selective metal membranes, membrane modules, purification assemblies and methods of forming the same
US6979507B2 (en) * 2000-07-26 2005-12-27 Idatech, Llc Fuel cell system controller
MXPA02000712A (es) 1999-07-27 2002-07-22 Idatech Llc Controlador de sistema de celda de combustible.
US7135048B1 (en) 1999-08-12 2006-11-14 Idatech, Llc Volatile feedstock delivery system and fuel processing system incorporating the same
US6375906B1 (en) * 1999-08-12 2002-04-23 Idatech, Llc Steam reforming method and apparatus incorporating a hydrocarbon feedstock
FR2800725B1 (fr) * 1999-11-08 2001-12-28 Air Liquide Procede et installation pour la production d'hydrogene pur a partir d'un gaz contenant de l'helium
US6589303B1 (en) 1999-12-23 2003-07-08 Membrane Technology And Research, Inc. Hydrogen production by process including membrane gas separation
DE60116298T2 (de) * 2000-06-22 2006-08-31 E.I. Dupont De Nemours And Co., Wilmington Nanopröse kohlenstoffmebran mt zusammengesetzter matrix
US6569227B2 (en) 2001-09-27 2003-05-27 Idatech, Llc Hydrogen purification devices, components and fuel processing systems containing the same
DE10119721A1 (de) * 2001-04-21 2002-10-31 Bayer Cropscience Gmbh Herbizide Mittel enthaltend Benzoylcyclohexandione und Safener
US6967063B2 (en) 2001-05-18 2005-11-22 The University Of Chicago Autothermal hydrodesulfurizing reforming method and catalyst
DE60230149D1 (de) * 2001-07-31 2009-01-15 Praxair Technology Inc Steuersystem zur rückgewinnung von helium
US6569226B1 (en) 2001-09-28 2003-05-27 The United States Of America As Represented By The United States Department Of Energy Metal/ceramic composites with high hydrogen permeability
US6946016B2 (en) * 2001-12-18 2005-09-20 Fluor Technologies Corporation PSA sharing
US7619012B2 (en) * 2006-07-18 2009-11-17 The Regents Of The University Of California Method and apparatus for steam hydro-gasification in a fluidized bed reactor
US20080016770A1 (en) * 2006-07-18 2008-01-24 Norbeck Joseph M Method for high energy density biomass-water slurry
US20080021119A1 (en) * 2006-07-18 2008-01-24 Norbeck Joseph M Operation of a steam methane reformer by direct feeding of steam rich producer gas from steam hydro-gasification
US7500997B2 (en) * 2002-02-05 2009-03-10 The Regents Of The University Of California Steam pyrolysis as a process to enhance the hydro-gasification of carbonaceous materials
AU2003215059B2 (en) * 2002-02-05 2007-03-22 The Regents Of The University Of California Production of synthetic transportation fuels from carbonaceous materials using self-sustained hydro-gasification
US8143319B2 (en) * 2006-07-18 2012-03-27 The Regents Of The University Of California Method and apparatus for steam hydro-gasification with increased conversion times
US8118894B2 (en) * 2006-07-18 2012-02-21 The Regents Of The University Of California Commingled coal and biomass slurries
US8349288B2 (en) * 2006-12-06 2013-01-08 The Regents Of The University Of California Process for enhancing the operability of hot gas cleanup for the production of synthesis gas from steam-hydrogasification producer gas
US8603430B2 (en) * 2002-02-05 2013-12-10 The Regents Of The University Of California Controlling the synthesis gas composition of a steam methane reformer
US20080031809A1 (en) * 2006-07-18 2008-02-07 Norbeck Joseph M Controlling the synthesis gas composition of a steam methane reformer
US6755975B2 (en) * 2002-06-12 2004-06-29 Membrane Technology And Research, Inc. Separation process using pervaporation and dephlegmation
US7087211B2 (en) * 2002-09-17 2006-08-08 The University Of Chicago Hydrogen production by high temperature water splitting using electron conducting membranes
US6726893B2 (en) * 2002-09-17 2004-04-27 The University Of Chicago Hydrogen production by high-temperature water splitting using electron-conducting membranes
US7025803B2 (en) * 2002-12-02 2006-04-11 L'Air Liquide Societe Anonyme A Directoire et Counsel de Surveillance Pour L'Etude et L'Exploration des Procedes Georges Claude Methane recovery process
US6881242B2 (en) * 2003-01-13 2005-04-19 Ati Properties, Inc. Hydrogen reclamation apparatus and method
US20040197616A1 (en) * 2003-04-01 2004-10-07 Edlund David J. Oxidant-enriched fuel cell system
FR2853899B1 (fr) * 2003-04-18 2007-12-28 Air Liquide Procede de traitement d'un melange gazeux comprenant du propane et du propylene
US7252702B2 (en) * 2003-07-25 2007-08-07 Saudi Arabian Oil Company Hydrogen purification optimization system
US7329791B2 (en) * 2004-03-31 2008-02-12 Uchicago Argonne, Llc Hydrogen transport membranes for dehydrogenation reactions
US8277997B2 (en) * 2004-07-29 2012-10-02 Idatech, Llc Shared variable-based fuel cell system control
US7842428B2 (en) 2004-05-28 2010-11-30 Idatech, Llc Consumption-based fuel cell monitoring and control
US7297183B2 (en) * 2004-09-20 2007-11-20 Idatech, Llc Hydrogen purification devices, components, and fuel processing systems containing the same
US7470293B2 (en) 2004-10-29 2008-12-30 Idatech, Llc Feedstock delivery systems, fuel processing systems, and hydrogen generation assemblies including the same
US7666383B2 (en) * 2005-04-06 2010-02-23 Cabot Corporation Method to produce hydrogen or synthesis gas and carbon black
US7708810B2 (en) * 2005-07-19 2010-05-04 The Penn State Research Foundation Carbon nanocomposite membranes and methods for their fabrication
US20070044663A1 (en) * 2005-08-25 2007-03-01 The University Of Chicago Method for fabricating a hydrogen separation membrane on a porous substrate
US20070044662A1 (en) * 2005-08-25 2007-03-01 The University Of Chicago Method for fabricating dense thin film cermet hydrogen separation membrane
US7604771B2 (en) * 2005-08-25 2009-10-20 Uchicago Argonne, Llc Thermal method for fabricating a hydrogen separation membrane on a porous substrate
US7601302B2 (en) 2005-09-16 2009-10-13 Idatech, Llc Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same
TWI328898B (en) 2005-09-16 2010-08-11 Idatech L L C Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same
US7754491B2 (en) * 2005-12-09 2010-07-13 The Regents Of The University Of Calif. Sensor for measuring syngas ratios under high temperature and pressure conditions
US7485173B1 (en) * 2005-12-15 2009-02-03 Uop Llc Cross-linkable and cross-linked mixed matrix membranes and methods of making the same
US20070209505A1 (en) * 2006-03-10 2007-09-13 Chunqing Liu High Flux Mixed Matrix Membranes for Separations
US7897207B2 (en) * 2006-03-10 2011-03-01 Uop Llc Nano-molecular sieve-polymer mixed matrix membranes with significantly improved gas separation performance
US7846496B2 (en) * 2006-03-10 2010-12-07 Uop Llc Mixed matrix membranes incorporating surface-functionalized molecular sieve nanoparticles and methods for making the same
US8083833B2 (en) * 2006-03-10 2011-12-27 Uop Llc Flexible template-directed microporous partially pyrolyzed polymeric membranes
US7799964B2 (en) * 2006-04-04 2010-09-21 Exxonmobil Research And Engineering Company Membrane process for LPG recovery
US7887958B2 (en) 2006-05-15 2011-02-15 Idatech, Llc Hydrogen-producing fuel cell systems with load-responsive feedstock delivery systems
US7972420B2 (en) 2006-05-22 2011-07-05 Idatech, Llc Hydrogen-processing assemblies and hydrogen-producing systems and fuel cell systems including the same
US7939051B2 (en) 2006-05-23 2011-05-10 Idatech, Llc Hydrogen-producing fuel processing assemblies, heating assemblies, and methods of operating the same
US7637983B1 (en) 2006-06-30 2009-12-29 Uop Llc Metal organic framework—polymer mixed matrix membranes
FR2904821B1 (fr) * 2006-08-09 2009-02-20 Air Liquide Procede de purification d'hydrogene
US7943543B1 (en) 2006-09-29 2011-05-17 Uop Llc Ionic liquid-solid-polymer mixed matrix membranes for gas separations
US7758751B1 (en) 2006-11-29 2010-07-20 Uop Llc UV-cross-linked membranes from polymers of intrinsic microporosity for liquid separations
US7998246B2 (en) * 2006-12-18 2011-08-16 Uop Llc Gas separations using high performance mixed matrix membranes
US7815712B2 (en) * 2006-12-18 2010-10-19 Uop Llc Method of making high performance mixed matrix membranes using suspensions containing polymers and polymer stabilized molecular sieves
US20080142440A1 (en) * 2006-12-18 2008-06-19 Chunqing Liu Liquid Separations Using High Performance Mixed Matrix Membranes
US20080143014A1 (en) * 2006-12-18 2008-06-19 Man-Wing Tang Asymmetric Gas Separation Membranes with Superior Capabilities for Gas Separation
NO328522B1 (no) * 2007-03-19 2010-03-08 Statoil Asa Fremgangsmate for produksjon av hydrogen, hydrogenproduksjonsanlegg, en vann-gassskift-reaktor samt en fremgangsmate for fremstilling av hydrogen fra syngass.
EP2141119B1 (en) * 2007-03-29 2014-01-22 Nippon Oil Corporation Method of hydrogen production and carbon dioxide recovery and apparatus therefor
US7815713B2 (en) * 2007-07-10 2010-10-19 Manufactured Methane Corp. Landfill gas purification method and system
US8480789B2 (en) * 2007-07-10 2013-07-09 Manufactured Methane Corporation Landfill gas purification method and system
US8262752B2 (en) 2007-12-17 2012-09-11 Idatech, Llc Systems and methods for reliable feedstock delivery at variable delivery rates
EP2296784B1 (en) * 2008-05-12 2013-09-04 Membrane Technology And Research, Inc. Gas-separation process using membranes with permeate sweep to remove co2 from combustion gases
US7790803B2 (en) * 2008-06-02 2010-09-07 Uop Llc Crosslinked organic-inorganic hybrid membranes and their use in gas separation
US7972415B2 (en) * 2008-12-11 2011-07-05 Spx Corporation Membrane-based compressed air breathing system
US20110061376A1 (en) * 2009-02-17 2011-03-17 Mcalister Technologies, Llc Energy conversion assemblies and associated methods of use and manufacture
US20110138999A1 (en) * 2009-12-15 2011-06-16 Uop Llc Metal organic framework polymer mixed matrix membranes
US20110185891A1 (en) * 2010-02-02 2011-08-04 Generon Igs, Inc. Sweep gas for membrane-based dehydration modules
WO2016020042A1 (de) * 2014-08-07 2016-02-11 Linde Aktiengesellschaft Rückgewinnung von gasen, insbesondere permanentgasen, aus stoffströmen, insbesondere aus abgasströmen von polymerisationen
WO2016079542A1 (en) * 2014-11-21 2016-05-26 Fit For Keeps Ltd Exercise system and method of use thereof
US10476093B2 (en) 2016-04-15 2019-11-12 Chung-Hsin Electric & Machinery Mfg. Corp. Membrane modules for hydrogen separation and fuel processors and fuel cell systems including the same
US11439948B2 (en) * 2019-12-09 2022-09-13 Mahle International Gmbh Membrane module for mitigating evaporative fuel emissions of automobiles
US11712655B2 (en) 2020-11-30 2023-08-01 H2 Powertech, Llc Membrane-based hydrogen purifiers
TWI797749B (zh) * 2021-09-16 2023-04-01 鐙鋒綠能科技股份有限公司 變壓吸附氣體回沖系統以及變壓吸附氣體回沖方法
TWI804994B (zh) * 2021-09-23 2023-06-11 華懋科技股份有限公司 具催化燃燒爐之中空纖維管式膜油氣處理系統及其方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4002042A (en) * 1974-11-27 1977-01-11 Air Products And Chemicals, Inc. Recovery of C2 + hydrocarbons by plural stage rectification and first stage dephlegmation
US4077779A (en) * 1976-10-15 1978-03-07 Air Products And Chemicals, Inc. Hydrogen purification by selective adsorption
JPS58120502A (ja) * 1982-01-13 1983-07-18 Nippon Steel Corp 製鉄ガスよりの高純度水素の製造法
US4398926A (en) * 1982-04-23 1983-08-16 Union Carbide Corporation Enhanced hydrogen recovery from low purity gas streams
DE3315930A1 (de) * 1982-07-29 1984-03-01 Linde Ag, 6200 Wiesbaden Verfahren und vorrichtung zur zerlegung eines gasgemisches
US4732583B1 (en) * 1984-12-03 1990-05-15 Gas separation
US4654063A (en) * 1984-12-21 1987-03-31 Air Products And Chemicals, Inc. Process for recovering hydrogen from a multi-component gas stream
JPS62153390A (ja) * 1985-12-27 1987-07-08 Toho Gas Co Ltd メタンの濃縮分離方法
JPS62153389A (ja) * 1985-12-27 1987-07-08 Toho Gas Co Ltd メタンの濃縮方法
US4690695A (en) * 1986-04-10 1987-09-01 Union Carbide Corporation Enhanced gas separation process
US4765804A (en) * 1986-10-01 1988-08-23 The Boc Group, Inc. PSA process and apparatus employing gaseous diffusion barriers
US4701187A (en) * 1986-11-03 1987-10-20 Air Products And Chemicals, Inc. Process for separating components of a gas stream
US4836833A (en) * 1988-02-17 1989-06-06 Air Products And Chemicals, Inc. Production and recovery of hydrogen and carbon monoxide
FR2636341A1 (fr) * 1988-09-12 1990-03-16 Air Liquide Procede et installation de recuperation des hydrocarbures les plus lourds d'un melange gazeux
FR2636250B1 (fr) * 1988-09-12 1992-01-17 Air Liquide Procede et installation de recuperation d'hydrogene et de monoxyde de carbone
US5116396A (en) * 1989-05-12 1992-05-26 Union Carbide Industrial Gases Technology Corporation Hybrid prepurifier for cryogenic air separation plants
US4934148A (en) * 1989-05-12 1990-06-19 Union Carbide Corporation Dry, high purity nitrogen production process and system
JPH0312307A (ja) * 1989-06-08 1991-01-21 Nippon Sanso Kk 空気分離方法
US4952219A (en) * 1989-09-29 1990-08-28 Air Products And Chemicals, Inc. Membrane drying of gas feeds to low temperature units
US4981676A (en) * 1989-11-13 1991-01-01 Minet Ronald G Catalytic ceramic membrane steam/hydrocarbon reformer
US5354547A (en) * 1989-11-14 1994-10-11 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
US5104425A (en) * 1989-11-14 1992-04-14 Air Products And Chemicals, Inc. Gas separation by adsorbent membranes
US5131930A (en) * 1991-05-06 1992-07-21 Air Products And Chemicals, Inc. Process for mixing gas streams having different pressures
JP3012307U (ja) 1994-12-12 1995-06-13 手嶋 清和 釣用仕掛巻

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150091501A (ko) * 2012-12-06 2015-08-11 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 기체 분리용 흡착제의 선택화 방법

Also Published As

Publication number Publication date
TW235250B (ko) 1994-12-01
KR0137440B1 (ko) 1998-04-27
EP0582184A1 (en) 1994-02-09
US5447559A (en) 1995-09-05
CA2101373A1 (en) 1994-02-04
US5354547A (en) 1994-10-11
SG41934A1 (en) 1997-08-15

Similar Documents

Publication Publication Date Title
KR940003596A (ko) 흡착막에 의한 수소 회수
US5435836A (en) Hydrogen recovery by adsorbent membranes
US5753010A (en) Hydrogen recovery by pressure swing adsorption integrated with adsorbent membranes
US4229188A (en) Selective adsorption process
US5507856A (en) Hydrogen recovery by adsorbent membranes
US4645516A (en) Enhanced gas separation process
US6572679B2 (en) Gas separation using organic-vapor-resistant membranes in conjunction with organic-vapor-selective membranes
EP0021756A1 (en) Selective adsorption process and system
CA2124601C (en) Hydrogen fractionation by adsorbent membranes
CA1314491C (en) Integrated pressure swing adsorption/membrane separation
US5073356A (en) Integrated processes for the production of carbon monoxide
US6179900B1 (en) Process for the separation/recovery of gases
ES2388918T3 (es) Procedimientos que utilizan membranas de permeabilidad selectiva de sólidos en múltiples grupos para la recuperación simultánea de productos específicos a partir de una mezcla de fluidos
US5753011A (en) Operation of staged adsorbent membranes
EP0945163A1 (en) A process for the separation/recovery of gases
US20160115029A1 (en) Helium recovery process and apparatus
US6183628B1 (en) Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons
JPH06504949A (ja) ハイブリッド膜分離システムを用いる酸性ガスの処理
US6592749B1 (en) Hydrogen/hydrocarbon separation process, including PSA and membranes
CA1128316A (en) Process for synthesis gas mixtures

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20020116

Year of fee payment: 5

LAPS Lapse due to unpaid annual fee