KR930019684A - 아인산염, 퀴논 및 이소시아네이트의 반응 생성물을 포함하는 조성물 - Google Patents
아인산염, 퀴논 및 이소시아네이트의 반응 생성물을 포함하는 조성물 Download PDFInfo
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- KR930019684A KR930019684A KR1019930003713A KR930003713A KR930019684A KR 930019684 A KR930019684 A KR 930019684A KR 1019930003713 A KR1019930003713 A KR 1019930003713A KR 930003713 A KR930003713 A KR 930003713A KR 930019684 A KR930019684 A KR 930019684A
- Authority
- KR
- South Korea
- Prior art keywords
- radical
- composition
- compound
- formula
- mixture
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract 13
- 239000012948 isocyanate Substances 0.000 title claims 3
- 150000002513 isocyanates Chemical class 0.000 title claims 3
- 239000007795 chemical reaction product Substances 0.000 title claims 2
- 150000004053 quinones Chemical class 0.000 title claims 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 title 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000002657 fibrous material Substances 0.000 claims abstract 4
- 239000005056 polyisocyanate Substances 0.000 claims abstract 4
- 229920001228 polyisocyanate Polymers 0.000 claims abstract 4
- 239000006185 dispersion Substances 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims abstract 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract 2
- 229920000728 polyester Polymers 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims 6
- 150000004057 1,4-benzoquinones Chemical class 0.000 claims 2
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 claims 2
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims 2
- 150000004056 anthraquinones Chemical class 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000000047 product Substances 0.000 claims 2
- 239000005058 Isophorone diisocyanate Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000005442 diisocyanate group Chemical group 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 150000005846 sugar alcohols Polymers 0.000 claims 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Materials For Medical Uses (AREA)
Abstract
본 발명은 유기 아인산염과 퀴논을 반응시킨 다음 모노-, 디- 또는 폴리이소시아네이트와 반응시킴으로써 수득될 수 있는, 섬유재료를 유기 용매 중의 수성 분산액 또는 용액 형태로 허리하기에 적합한 조성물에 관한 것이다. 당해 조성물을 사용하는 방법에 의해 폴리에스테르 섬유를 포함하는 직물에 양호한 성능을 갖는 방염 특성이 부여된다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (13)
- a) 일반식 (I)의 아인산염 또는 이의 혼합물을 벤조퀴논, 치환된 벤조퀴논, 나프트퀴논, 치환된 나프트퀴논, 안트라퀴논 또는 치환된 안트라퀴논 또는 이들 퀴논의 혼합물과 반응시키고, b) 단계 a)에서 수득된 생성물을 모노-, 디- 또는 폴리이소시아네이트 또는 이들 이소시아네이트의 혼합물과 반응시킴으로써 수득된 조성물.
-
- 상기식에서, R1및 R2는 각각 독립적으로 탄소수 1내지 8의 알킬 라디칼 또는 페닐 라디칼〔여기서, 알킬 라디칼 또는 페닐 라디칼은 각각 하나 이상의 할로겐 원자에 의해 치환될 수 있다〕이다.
- 제1항에 있어서, 치환되지 않은 p-벤조퀴논 또는 1, 2- 또는 1, 4-나프토퀴논이 단계 a)에서 사용되는 조성물.
- 제1항 또는 제2항에 있어서, 단계 a)가 개시시의 반응 혼합물의 pH가 7 내지 8인 조성물.
- 제1항에 있어서, 단계 a)가 용매로서 일반식 R3OR5의 화합물, 일반식 R5OR|5의 화합물, 일반식 R5COOR5의 화합물, 일반식 (R3O)x(R4O)|3-xP=O의 화합물 또는 이러한 화합물 〔여기서, 존재하는 각각의 라디칼 R3은 임의 치환된 페닐 또는 나프틸 라디칼이고, 존재하는 각각의 라디칼 R4는 탄소수 1 내지 18의 비측쇄 또는 측쇄 알킬 라디칼이고, 존재하는 각각의 라디칼 R5는 탄소수 1 내지 6의 알킬 라디칼이며, X는 0, 1, 2 또는 3이다〕 중에서 수행되는 조성물.
- 제1항에 있어서, 단계 b)에서 일반식 (Ⅱ)의 디이소시아네이트 또는 이의 혼합물이 사용되거나, 단계 b)에서 이소포론 디이소시아네이트가 사용되는 조성물.
-
- 상기식에서, X는 -(CH2)n은 3 내지 8의 수이다〕,
- 제1항에 있어서, 단계 a)에서 수득된 생성물을 단계 a)로부터의 반응 생성물의 하이드록실 그룹 당량당 1.3 내지 3.0 당량의 이소시아네이트가 존재하도록 단계 b)에서 디- 또는 폴리이소시아네이트와 반응시킨 다음, 단계 b)를 수행한 후에, 디- 또는 폴리이소시아네이트로부터 유도되는 과량의 이소시아네이트 그룹을 다가 알콜과 반응시킨 조성물.
- 조성물을 용액 또는 분산액 형태로 섬유재료에 적용시킴을 포함하는, 섬유재료를 처리하기 위한 제1항 내지 제6항 중의 어느 한 항에 따르는 조성물의 용도.
- 제7항에 있어서, 섬유재료가 70 내지 100중량%의 폴리에스테르를 포함하는 직포, 편포 또는 부직포인 용도.
- ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP4208235.8 | 1992-03-14 | ||
| DE4208235A DE4208235A1 (de) | 1992-03-14 | 1992-03-14 | Umsetzungsprodukte von phosphiten, chinonen und isocyanaten enthaltende zusammensetzungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR930019684A true KR930019684A (ko) | 1993-10-18 |
Family
ID=6454092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930003713A KR930019684A (ko) | 1992-03-14 | 1993-03-12 | 아인산염, 퀴논 및 이소시아네이트의 반응 생성물을 포함하는 조성물 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5498740A (ko) |
| EP (1) | EP0561223B1 (ko) |
| JP (1) | JPH069665A (ko) |
| KR (1) | KR930019684A (ko) |
| AT (1) | ATE142218T1 (ko) |
| AU (1) | AU669348B2 (ko) |
| BR (1) | BR9301139A (ko) |
| DE (2) | DE4208235A1 (ko) |
| ES (1) | ES2094395T3 (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101140173B1 (ko) * | 2009-09-21 | 2012-04-24 | 우석대학교 산학협력단 | 이륜차 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19914291A1 (de) * | 1999-03-30 | 2000-10-05 | Bayer Ag | Verfahren zur Absenkung des Chlorgehaltes von niedermolekularen Isocyanaten |
| US6446734B1 (en) | 1999-11-11 | 2002-09-10 | Black & Decker Inc. | Motor/handle housing and gear case mounting for portable power tool |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2733229A (en) * | 1956-01-31 | Dialkyi polyvinyl phosphate | ||
| US2577281A (en) * | 1948-10-15 | 1951-12-04 | Lockheed Aircraft Corp | Flame retardant cellular plastic material |
| US2691567A (en) * | 1951-10-23 | 1954-10-12 | Du Pont | Polymeric organic phosphorus compounds for increasing flame resistance of textiles and method of using same |
| US2691566A (en) * | 1951-10-23 | 1954-10-12 | Du Pont | Organic phosphorus compounds for increasing the flame resistance of textiles and method of applying the same |
| DE937956C (de) * | 1953-04-09 | 1956-01-19 | Anorgana G M B H | Verfahren zur Herstellung von Oxyaryl-dialkylphosphorsaeureestern |
| US2926145A (en) * | 1957-09-11 | 1960-02-23 | Eastman Kodak Co | Phosphono-polyesters from 1,4-cyclohexanedimethanol and polyester-urethanes therefrom |
| CH473937A (de) * | 1966-06-01 | 1969-07-31 | Ciba Geigy | Verfahren zum Flammfestmachen von cellulosehaltigen Textilmaterialien |
| CH1923668A4 (ko) * | 1968-12-24 | 1970-07-15 | ||
| US3725510A (en) * | 1970-02-05 | 1973-04-03 | Borg Warner | Phosphite-phosphates |
| DE2312090A1 (de) * | 1973-03-10 | 1974-09-12 | Basf Ag | Poly-dialkylphosphonoalkylcarbonate und ihre verwendung zur flammschutzausruestung von cellulosehaltigem textilgut |
| DE3109352A1 (de) * | 1981-03-12 | 1982-09-23 | Bayer Ag, 5090 Leverkusen | Gegebenenfalls geschaeumte intumeszenzmassen und ihre verwendung |
| SU1147713A1 (ru) * | 1982-07-09 | 1985-03-30 | Казанский Ордена Трудового Красного Знамени Химико-Технологический Институт Им.С.М.Кирова | Способ получени диалкил-(3,5-дитрет.-бутил-4-оксифенил) фосфатов |
-
1992
- 1992-03-14 DE DE4208235A patent/DE4208235A1/de not_active Withdrawn
-
1993
- 1993-02-17 AU AU33105/93A patent/AU669348B2/en not_active Ceased
- 1993-03-03 AT AT93103410T patent/ATE142218T1/de not_active IP Right Cessation
- 1993-03-03 EP EP93103410A patent/EP0561223B1/de not_active Expired - Lifetime
- 1993-03-03 ES ES93103410T patent/ES2094395T3/es not_active Expired - Lifetime
- 1993-03-03 DE DE59303610T patent/DE59303610D1/de not_active Expired - Fee Related
- 1993-03-05 US US08/026,963 patent/US5498740A/en not_active Expired - Fee Related
- 1993-03-11 BR BR9301139A patent/BR9301139A/pt not_active Application Discontinuation
- 1993-03-12 KR KR1019930003713A patent/KR930019684A/ko not_active Application Discontinuation
- 1993-03-12 JP JP5052420A patent/JPH069665A/ja not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101140173B1 (ko) * | 2009-09-21 | 2012-04-24 | 우석대학교 산학협력단 | 이륜차 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0561223A2 (de) | 1993-09-22 |
| EP0561223A3 (en) | 1994-05-25 |
| BR9301139A (pt) | 1993-09-21 |
| DE4208235A1 (de) | 1993-09-16 |
| ATE142218T1 (de) | 1996-09-15 |
| AU669348B2 (en) | 1996-06-06 |
| DE59303610D1 (de) | 1996-10-10 |
| ES2094395T3 (es) | 1997-01-16 |
| AU3310593A (en) | 1993-09-16 |
| US5498740A (en) | 1996-03-12 |
| JPH069665A (ja) | 1994-01-18 |
| EP0561223B1 (de) | 1996-09-04 |
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| Date | Code | Title | Description |
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| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E601 | Decision to refuse application |