KR930012950A - 광택성이 우수한 열가소성 수지 조성물 - Google Patents

광택성이 우수한 열가소성 수지 조성물 Download PDF

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KR930012950A
KR930012950A KR1019910025073A KR910025073A KR930012950A KR 930012950 A KR930012950 A KR 930012950A KR 1019910025073 A KR1019910025073 A KR 1019910025073A KR 910025073 A KR910025073 A KR 910025073A KR 930012950 A KR930012950 A KR 930012950A
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South Korea
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weight
group
thermoplastic resin
resin composition
monomer
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KR1019910025073A
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KR950010122B1 (ko
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박홍섭
이정훈
이필웅
한종순
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이덕림
한남화학 주식회사
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/02Polymerisation in bulk
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/01Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5415Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 광택성이 우수한 열가소성 수지 조성물에 관한 것으로서, 본 발명에 따른 수지 조성물은 중량평균입자경이 0.10-0.25㎛인 입자 70-80중량% 및 0.25-0.3㎛인 입자20-30중량%로 구성된 공액디엔계고무30-70중량%, 방향족 비닐계 단량체20-50중량%및 시안화비닐게 단량체5-30중량%를 그라프트 공중합시킨 공중합체(A)30-60중량%, 시안화비닐계 단량체25-35중량%, 방향족비닐 단량체65-75중량%를 괴상 중합한 공중합체(B)40-70중량% 및 유기 규소화합물(C)0.01-0.10중량%와 활제(D)1.0-3.0중량%로 이루어지고 공액디엔계 고무 함유량이10-25중량%임을 특징으로 하는 열가소성 수지 조성물로 이루어져 있다.

Description

광택성이 우수한 열가소성 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 중량평균입자경이 0.10~0.25㎛인 입자70~80중량% 및 0.25~0.3㎛인 입자20~30중량%로 구성된 공액디엔계고무30~70중량%, 방향족 비닐계 단량체20~50중량% 및 시안화비닐게 단량체5~30중량%를 그라프트 공중합시킨 공중합체(A) 30~60중량%, 시안화비닐계 단량체25-35중량%, 방향족비닐 단량체65~75중량%를 괴상 중합한 공중합체(B) 40~70중량 및 유기 규소화합물(C) 0.01~0.10중량%와 활제(D) 1.0~3.0중량%로 이루어지고 공액디엔계 고무 함유량이 10~25중량%임을 특징으로 하는 열가소성 수지 조성물.
  2. 제1항에 있어서, 유기 규소화합물은 하기의 일반식으로 표시되고 카르복실기, 에폭시기, 저급 알킬기 또는 아미노기로 부터 선택된 적어도 1조의 치환기를 가지며 점도의 범위가 0.65~10-6I.V.임을 특징으로 하는 열가소성 수지 조성물.
    식중, R은 저급알킬기, 알킬아릴기, 아릴기, 아크릴릭기, 알킬렌기, 에폭시기 또는 아미노알킬기를 나타낸다.
  3. 제1항에 있어서, 활제는 탄화수소계 화합물, 지방산계 화합물, 지방산 아미드계 화합물, 에스테르계 화합물, 지방산 알코올, 다가 알코올 및 지방산과 다가 알코올의 부분 에스테르로 된 군에서 선택되는 1종이나 2종이상의 혼합물임을 특징으로 하는 열가소성 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910025073A 1991-12-30 1991-12-30 광택성이 우수한 열가소성 수지 조성물 KR950010122B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019910025073A KR950010122B1 (ko) 1991-12-30 1991-12-30 광택성이 우수한 열가소성 수지 조성물

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KR1019910025073A KR950010122B1 (ko) 1991-12-30 1991-12-30 광택성이 우수한 열가소성 수지 조성물

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KR930012950A true KR930012950A (ko) 1993-07-21
KR950010122B1 KR950010122B1 (ko) 1995-09-07

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Publication number Priority date Publication date Assignee Title
KR101503115B1 (ko) * 2011-08-11 2015-03-18 주식회사 엘지화학 알킬 〔메트〕아크릴레이트계 열가소성 수지 조성물, 및 내스크래치성과 황색도가 조절된 열가소성 수지

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