KR930010107A - 블럭 공중합체 조성물 및 그로 부터 제조된 조형품 - Google Patents

블럭 공중합체 조성물 및 그로 부터 제조된 조형품 Download PDF

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KR930010107A
KR930010107A KR1019920020385A KR920020385A KR930010107A KR 930010107 A KR930010107 A KR 930010107A KR 1019920020385 A KR1019920020385 A KR 1019920020385A KR 920020385 A KR920020385 A KR 920020385A KR 930010107 A KR930010107 A KR 930010107A
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block copolymer
parts
weight
copolymer composition
amount
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KR1019920020385A
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페르디난드 베르마이르 한스
로저 헨리 덴두우벤 한스
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알베르투스 빌헬무스·요아네스 쩨스트 라텐
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
요아네스 째스트 라텐
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Publication of KR930010107A publication Critical patent/KR930010107A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof

Abstract

하기 (a)-(e)로 구성되는 블럭 공중합체 조성물을 제공한다. (a)우세하게 공역 티엔으로부터 유래된 적어도 하나의 선택적으로 수소첨가된 엘라스토머 블럭 및 우세하게 비닐 방향족 화합물로 부터 유래된 적어도 하나의 블럭을 함유하는 블럭 공중합체, (b)블럭 공중합체 100중량부 당 5 중량부 내지 500 중량부의 양으로 폴리알킬렌, 폴리(비닐 방향족), 폴리페닐렌 에테르 및 그의 혼합물로부터 선택되는 열가소성 중합체, (c)블럭 공중합체 100중량 부당 5 내지 200중량부 양의 Mw/Mnql\\비율 1.0 내지 3.0, 바람직하게 1.3 내지 2.4의 범위를 갖고 수평균 분자량 1100 내지 6000 및 바람직하게 1200 내지 4500 및 보다 바람직하게 2000 내지 3500의 범위를 갖는 폴리(알킬렌)으로 구성되는 가소제, (d)블럭 공중합체 100 중량부 당 0내지 500중량부, 바람직하게 50 내지 250의 양의 충전제, 및 (e)첨가제, 예컨대 난연제, 항산화제, 안정화제, 유동촉진수지, 염료등 이때 각각의 첨가제의 양은 블럭 공중합체 100중량부 당 0 내지 50중량부이다.
상기 블럭 공중합체는 특히 열숙성에 의해 영향 받지 않는 성질을 보이므로, 보다 고급인 응용물, 예컨대 의료영역에서 매우 유용하다.

Description

블럭 공중합체 조성물 및 그로 부터 제조된 조형품
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 120℃ 가열 속성 중의 중량 손실 %를 나타낸다. 제2도는 120℃ 가열 속성 중의 수축 %를 나타낸다.

Claims (12)

  1. 하기 (a)-(e)로 구성되는 블럭 공중합체 조성물을：(a)우세하게 공역 티엔으로부터 유래된 적어도 하나의 선택적으로 수소첨가된 엘라스토머 블럭 및 우세하게 비닐 방향족 화합물로 부터 유래된 적어도 하나의 블럭을 함유하는 블럭 공중합체, (b)블럭 공중합체 100중량부 당 5 중량부 내지 500 중량부의 양으로 폴리알킬렌, 폴리(비닐 방향족), 폴리페닐렌 에테르 및 그의 혼합물로부터 선택되는 열가소성 중합체, (c)블럭 공중합체 100중량부당 5 내지 200중량부 양의, Mw/M비율 1.0 내지 3.0, 바람직하게 1.3 내지 2.4의 범위를 갖고 수평균 분자량 1100 내지 6000 범위를 갖는 폴리(알킬렌)으로 구성되는 가소제, (d) 블록 공중합체 100 중량부 당 0 내지 500중량부, 양의 충전제, 및 (e) 첨가제, 예컨대 난연제, 항산화제, 안정화제, 유동촉진수지, 염료등 이때 각각의 첨가제의 양은 블럭 공중합체 100중량부 당 0 내지 50중량부이다.
  2. 제1항에 있어서, 블럭 공중합체 100중량부 당 25중량부 내지 250중량부의 양의 성분(b)를 함유하는 블럭 공중합체 조성물.
  3. 제1항에 있어서, 1.3 내지 2.4 범위의 Mw/Mn 비율을 갖는 성분(c)를 함유하는 블럭 공중합체 조성물.
  4. 제1 내지 3항에 있어서, 1200 내지 4500의 범위인 수평균 분자량을 갖는 성분(c)를 함유하는 블럭 공중합체 조성물.
  5. 제4항에 있어서, 1200 내지 3500의 범위인 수평균 분자량을 갖는 성분(c)를 함유하는 블럭 공중합체 조성물.
  6. 제1항에 있어서, 블럭 공중합체 100중량부 당 50 내지 150중량부의 양의 성분(c)를 함유하는 블럭 공중합체 조성물.
  7. 제1항에 있어서, 블럭 공중합체 100중량부 당 50 내지 150중량부의 양의 성분(c)를 함유하는 블럭 공중합체 조성물.
  8. 제1 내지 7항에 있어서, 성분(c)의 폴리(알킬렌)이 폴리프로필렌, 폴리부틸렌 및 폴리이소부틸렌으로 구성된 군으로부터 선택되는 것을 특징으로 하는 블럭 공중합체 조성물.
  9. 제8항에 있어서, 성분(c)가 폴리부틸렌 또는 폴리이소부틸렌인 것을 특징으로 하는 블럭 공중합체 조성물.
  10. 제1 내지 9항에 있어서, 선택적으로 수소첨가된 블록 공중합체 스티렌 및 부타디엔 또는 이소프렌 또는 그의 혼합물로 부터 유래되는 것을 특징으로 하는 블록 공중합체 조성물.
  11. 제10항에 있어서, 선택적으로 수소첨가된 블럭 공중합체가 스티렌 및 부타디엔으로 부터 유래되는 것을 특징으로 하는 블럭 공중합체 조성물.
  12. 제1 내지 9항에 따른 블럭 공중합체 조성물로부터 제조된 조형품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019920020385A 1991-11-04 1992-10-31 블럭 공중합체 조성물 및 그로 부터 제조된 조형품 KR930010107A (ko)

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EP91202860 1991-11-04
EP91202860.2 1991-11-04

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US (1) US5278220A (ko)
EP (1) EP0541174A1 (ko)
JP (1) JPH05214208A (ko)
KR (1) KR930010107A (ko)
AU (1) AU661055B2 (ko)
BR (1) BR9204220A (ko)
CA (1) CA2081922A1 (ko)
TW (1) TW209877B (ko)

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EP0541174A1 (en) 1993-05-12
AU2748392A (en) 1993-05-06
US5278220A (en) 1994-01-11
BR9204220A (pt) 1993-05-11
TW209877B (ko) 1993-07-21
AU661055B2 (en) 1995-07-13
CA2081922A1 (en) 1993-05-05

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