KR930006106A - 열가소성 엘라스토머 및 그의 제조방법 - Google Patents

열가소성 엘라스토머 및 그의 제조방법 Download PDF

Info

Publication number
KR930006106A
KR930006106A KR1019920017765A KR920017765A KR930006106A KR 930006106 A KR930006106 A KR 930006106A KR 1019920017765 A KR1019920017765 A KR 1019920017765A KR 920017765 A KR920017765 A KR 920017765A KR 930006106 A KR930006106 A KR 930006106A
Authority
KR
South Korea
Prior art keywords
functionalized
weight
epdm rubber
thermoplastic elastomer
epdm
Prior art date
Application number
KR1019920017765A
Other languages
English (en)
Other versions
KR960005083B1 (ko
Inventor
주넬르 모페트 안드라
엠마누엘 조하네스 데커스 매리너스
존 쉬아 티모시
로버트 캠프벨 존
Original Assignee
아더 엠. 킹
제너럴 일렉트릭 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 아더 엠. 킹, 제너럴 일렉트릭 캄파니 filed Critical 아더 엠. 킹
Publication of KR930006106A publication Critical patent/KR930006106A/ko
Application granted granted Critical
Publication of KR960005083B1 publication Critical patent/KR960005083B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Abstract

본 발명은 폴리알킬렌 테레프탈레이트와 같은 방향족 폴리에스테르와 관능화 EPDM 반응성 고무쌍의 혼합물을 용융 압축시킴으로써 제공되는 EPDM 고무와 방향족 폴리에스테르의 가황화 혼합물에 관한 것이다. 에폭시기로 관능화된 EPDM은 에폭시 반응성 카르복실산을 생성할 수 있는 열에 불안정한 에스테르기로 관능화된 EPDM 고무로 가황화될 수 있다.

Description

열가소성 엘라스토머 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. (A) 방향족 폴리에스테르 45 내지 70중량% 및 (B) (a) 탄소원자 1000개당 약 0.1 내지 약 16개의 에폭시기로 관능화되고, 약 0.1 내지 약 20중량%의 에폭시 함유 그라프트화 물질을 함유하는 EPDM 고무 1 내지 99중량% 및 (b) 탄소원자 1000개 당 약 0.1 내지 약 16개의 열에 불안정한 카르복실산 생성 에스테르기로 관능화되고, 약 0.01 내지 약 20중량%의 에스테르 함유 그라프트화 물질을 함유하는 EPDM 고무 99 내지 1중량%로 필수적으로 구성된 관능화 EPDM 고무 30 내지 55중량%로 이루어진 용융 압출된 혼합물의 압출물로 이루어진 열가소성 엘라스토머.
  2. 제1항에 있어서, 방향족 폴리에스테르가 폴리부틸렌 테레프탈레이트인 열가소성 엘라스토머.
  3. 제1항에 있어서, EPDM 고무가 글리시딜 메타크릴레이트기로 관능화된 열가소성 엘라스토머.
  4. 제1항에 있어서, EPDM 고무가 t-부틸메타크릴레이트기로 관능화된 열가소성 엘라스토머.
  5. 방향족 열가소성 폴리에스테르, 탄소원자 1000개 당 약 0.1 내지 약 16개의 에폭시기로 관능화되고 약 0.01 내지 약 20중량%의 에폭시기 함유 그라프트화 물질을 함유하는 EPDM 고무 및 탄소원자 1000개 당 약 0.1 내지 약 16개의 열에 불안정한 카르복실산 생성 에스테르기로 관능화된 EPDM 고무의 혼합물을 150℃ 내지 350℃의 온도에서 용융 압출시키는 것을 특징으로 하는 동적 가황화 열가소성 엘라스토머의 제조방법.
  6. 제5항에 있어서, 방향족 열가소성 폴리에스테르가 폴리알킬렌 테레프탈레이트인 방법.
  7. 제5항에 있어서, 에폭시기로 관능화된 EPDM 고무가 글리시딜 메타크릴레이트기로 관능화된 방법.
  8. 제5항에 있어서, EPDM 고무가 열에 불안정한 t-부틸메타크릴레이트기로 관능화된 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920017765A 1991-09-30 1992-09-29 열가소성 엘라스토머 및 그의 제조 방법 KR960005083B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US76770191A 1991-09-30 1991-09-30
US767,701 1991-09-30

Publications (2)

Publication Number Publication Date
KR930006106A true KR930006106A (ko) 1993-04-20
KR960005083B1 KR960005083B1 (ko) 1996-04-20

Family

ID=25080284

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920017765A KR960005083B1 (ko) 1991-09-30 1992-09-29 열가소성 엘라스토머 및 그의 제조 방법

Country Status (6)

Country Link
US (1) US5322893A (ko)
EP (1) EP0535849A3 (ko)
JP (1) JPH0768440B2 (ko)
KR (1) KR960005083B1 (ko)
CA (1) CA2076116A1 (ko)
TW (1) TW215449B (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4343586A1 (de) * 1993-12-21 1995-06-22 Huels Chemische Werke Ag Haftvermittlerfreie Verbunde zwischen thermoplastischen Polyesterelastomeren und thermoplastischen Polyesterformmassen
GB9617507D0 (en) 1996-08-21 1996-10-02 Exxon Chemical Patents Inc Chemically modified elastomeres and blends thereof
US5733628A (en) 1996-10-10 1998-03-31 Tredegar Industries, Inc. Breathable elastic polymeric film laminates
US6277905B1 (en) 1999-09-23 2001-08-21 Eastman Chemical Company Process for improving the toughness of PCT formulations by adding rubber impact modifiers
US6855738B2 (en) * 2003-06-06 2005-02-15 Dow Global Technologies Inc. Nanoporous laminates
CN109721863A (zh) * 2019-01-23 2019-05-07 保定华月胶带有限公司 阻燃再生胶在阻燃输送带中的应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2902468A1 (de) * 1979-01-23 1980-07-31 Bayer Ag Thermoplastische polyesterformmassen mit hoher zaehigkeit
KR960014563B1 (ko) * 1987-10-01 1996-10-16 코폴리머 루버 앤드 케미칼 코포레이숀 개량된 충격 강도를 가지는 폴리에스테르 조성물의 제조방법
EP0340566B1 (en) * 1988-05-02 1994-09-21 General Electric Company Reactive graft polymers
US5208287A (en) * 1990-06-18 1993-05-04 General Electric Company Thermoplastic elastomers and method for making

Also Published As

Publication number Publication date
KR960005083B1 (ko) 1996-04-20
TW215449B (ko) 1993-11-01
EP0535849A2 (en) 1993-04-07
CA2076116A1 (en) 1993-03-31
JPH05239327A (ja) 1993-09-17
EP0535849A3 (en) 1993-05-19
JPH0768440B2 (ja) 1995-07-26
US5322893A (en) 1994-06-21

Similar Documents

Publication Publication Date Title
KR880011274A (ko) 열가소성 수지 조성물의 제조법
CN111154243B (zh) 一种生物基可堆肥降解耐热型薄膜复合材料及其制备方法
JPS55131049A (en) Novel thermoplastic resin composition
KR880014028A (ko) 방음성을 갖는 단단하고 재성형 가능한 판넬, 그 제조방법 및 그에 적합한 압출 가능한 조성물
SE8404625L (sv) Polyesterkomposition
KR860000334A (ko) 수지조성물
FR2255346A1 (en) Uprated polyester moulding matls. - with improved hardness and elasticity
KR930006106A (ko) 열가소성 엘라스토머 및 그의 제조방법
KR890006736A (ko) 열접착성이 우수한 열가소성 엘라스토머(Elastomer)조성물
DE69024918D1 (de) Thermoplastisches Elastomer auf Basis von Polynorbornen und Polyvinylchlorid
KR920016206A (ko) 내부 이형제, 내부 이형제를 함유하는 활성수소-함유 혼합물 및 성형품 생산 공정에서의 이 혼합물의 용도
KR920006439A (ko) 폴리에틸렌 테레프탈레이트 조성물 및 이의 사용방법
KR880000508A (ko) 열가소성 수지 조성물
KR920009924A (ko) 난연성 폴리에스테르수지 조성물
KR920006424A (ko) 고 인성, 고 모듈러스 및 우수한 절상 생장(cut growth) 저항성을 가진 고무 조성물
KR900004859A (ko) 반응성 처리에 의한 폴리 아미드 배합물
KR880005193A (ko) 열가소성 엘라스토머 조성물
KR920702392A (ko) 열가소성 탄성중합체 및 그의 제조방법
KR930701540A (ko) 열가소성 탄성중합체 및 epdm 고무의 가황된 블렌드 및 그의 제조방법
KR890014616A (ko) 변성에폭시수지 및 그의 제조방법
ATE59197T1 (de) Mit funktionalisierten polymeren schlagzaeh modifizierte thermoplaste und deren verwendung zur herstellung von formteilen.
KR870008953A (ko) 유동성이 증진된 폴리에스테르조성물
KR870004919A (ko) 저수축성을 갖는 중합체 콘크리트의 제조방법
JPS6463135A (en) Manufacture of joint sheet gasket
KR850001257A (ko) 내 충격성이 강한 폴리아미드 조성물

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
NORF Unpaid initial registration fee