KR930002421A - 폴리우레탄 조성물 - Google Patents

폴리우레탄 조성물 Download PDF

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KR930002421A
KR930002421A KR1019920012718A KR920012718A KR930002421A KR 930002421 A KR930002421 A KR 930002421A KR 1019920012718 A KR1019920012718 A KR 1019920012718A KR 920012718 A KR920012718 A KR 920012718A KR 930002421 A KR930002421 A KR 930002421A
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acid
tetramethyl
bis
piperidyl
phosphate
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KR1019920012718A
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마사히코 야스다
시게오 호소카와
요로즈 요코모리
유키요시 이토
고지 히사무라
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원본미기재
교와학코코교 가부시키가이샤
더 비. 에프. 굿리치 캄파니
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Publication of KR930002421A publication Critical patent/KR930002421A/ko

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    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62—Record carriers characterised by the selection of the material
    • G11B5/68—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent
    • G11B5/70—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer
    • G11B5/702—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the bonding agent
    • G11B5/7021—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the bonding agent containing a polyurethane or a polyisocyanate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
    • C08G71/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3462—Six-membered rings

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음.

Description

폴리우레탄 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하나 이상의 산성 친수성 그룹을 함유하는 폴리우레탄 분자 또는 폴리우레탄과 하나 이상의 산성 친수성 그룹을 갖는 하나 이상의 화합물과의 혼합물 또는 이의 배합물을 포함하고 하나 이상의 피페리딘 유도체 또는 하나 이상의 피페라지논 유도체 또는 이들의 배합물에 의해 중화된 폴리우레탄 조성물을 포함하는 중합체성 조성물.
  2. 제1항에 있어서, 하나 이상의 산성 친수성 그룹이 하나 이상의 산성 친수성 그룹 함유 화합물인 카복실 그룹 함유 화합물, 설포네이트 그룹 함유 화합물, 포스페이트 그룹 함유 화합물, 카복실 그룹 및 하이드록실 그룹 함유 화합물, 설포네이트 그룹 하이드록실 그룹 함유 화합물 또는 포스페이트 그룹 및 하이드록실 그룹 함유 화합물로부터 유도되는 중합체성 조성물.
  3. 제1항에 있어서, 피페리딘 유도체가 4-아세톡시-2,3,6,6-테트라메틸피페리딘, 4-스테아로일옥시-2,2,6,6-테트라메틸피페리딘, 4-벤조일옥시-2,2,6,6-4-아크릴로일-2,2,6,6-테트라메틸피페리딘, 4-(페닐카바모일옥시)-2,2,6,6-테트라메틸피페리딘, 4-펜옥시-2,2,6,6-테트라메틸피페리딘, 4-벤질옥시-2,2,6,6-테트라메틸피페리딘, 4-사이클로헥실옥시-2,2,6,6-테트라메틸피페리딘, 4-메톡시-2,2,6,6-테트라메틸피페리딘, , 4-(q-클로로벤조일옥시)-2,2,6,6-테트라메틸피페리딘, 비스(2,2,6,6-테트라메틸-4-피페리딜)옥살레이트, 비스(2,2,6,6-테트라메틸-4-피페리딜)세바케이트, 비스(2,2,6,6-테트라메틸-4-피페리딜)아디페이트, 비스(2,2,6,6-테트라메틸-4-피페리딜)말로페이트, 비스(2,2,6,6-테트라메틸-4-피페리딜)테레프탈레이트, 비스(2,2,6,6-테트라메틸-4-피페리딜)헥살메틸렌-1,6-디카바메이트, 1,2-비스(2,2,6,6-테트라메틸-4-피페리딜옥시)에탄, α,α-비스(2,2,6,6-테트라메틸-4-피페리딜옥시)-p-크실렌, 트리스(2,2,6,6-테트라메틸-4-피페리딜)벤젠-1,3,5-트리카복실레이트, 테트라(2,2,6,6-테트라메틸-4-피페리딜옥시)부탄-1,2,3,4-트라카복실레이트, 폴리[{6-(1,1,3,3-테트라메틸부틸)이미노-1,3,5-트리아진-2,4-디일}-{(2,2,6,6-테트라메틸-4-피페리딜)이미노}헥사메틸렌-{(2,2,6,6-테트라메틸-4-피페리딜이미노}비스(1,2,2,6,6-펜타메틸-4-피페리딜)세바케이트, 2-(3,5-t-부틸-4-하이드록실벤질)-2-n-부틸 말로네이트 비스(1,2,2,6,6-테트라메틸-4-피페리딜)또는 N,N-비스-(3-아미노프로필)에틸렌디아민-2,4-[1,2,2,6,6-펜타메틸-4-피페리딜)아미노)]-6-클로로-1,3,5-트리아진 혼합물이며, 피페라지논 유도체가 N1-프로필-3,3,5,5-테트라메틸-2-피페라지논, N1-이소프로필-3,3,5,5-테트라메틸-2-피페라지논, N1-도데실-3,3,5,5-테트라메틸-2-피페라지논, N1-t-옥틸-3,3,5,5-테트라메틸-2-피페라지논, 1,2-에탄-비스-(N1-t-3,3,5,5,-테트라메틸-2-피페라지논), N4-t-옥틸-3,3,6,6-테트라메틸-2-피페라지논, N1-페닐--3,3,5,5-테트라메틸-2-피페라지논, N1-t-부틸-3,3-디메틸-5,5-펜타메틸렌-2-피페라지논 또는 2,4,6-트리스(사이클로헥실[2-(3,3,5,5-테트라메틸-2-옥소-1-피페라지닐)에틸]아미노}-1,3,5-트리아진인 중합체성 조성물.
  4. 제2항에 있어서, 카복실 그룹 함유 화합물이 아세트산, 프로피온산, 부티르산, 팔미트산, 스테아르산, 미리스트산, 올레산, 카프릴산, 라우르산, 코코낫산, 카프로산, 리놀레산, 우지산, 아디프산, 말레산, 벤조산, 프탈산, 테레프탈산 도는 이소프탈산이고; 설포네이트 그룹 함유 화합물이 황산, 파라톨루엔설폰산, 나프탈렌설폰산, 벤젠설폰산, 5-설포이소프탈산, 2-설포프탈산, 5-설포벤조산, N,N-비스(2-하이드록시에틸)-2-아미노에탄설폰산, 설포프탈산, 도데실벤젠설폰산, 올레일 메틸 타우르산, 라우릴메틸 타우르산 또는 설포석시네이트이며; 포스페이트 그룹 함유 화합물이 인산, 아인산, 부틸 산포스페이트, 부톡시에틸 산 포스페이트, 2-에틸헥실 산 포스페이트, 디(2-에틸헥실)포스페이트, 이소데실 산 포스페이트, 모노이소데실 포스페이트, 폴리옥시에틸렌 알킬페닐에테르 포스페이트 또는 레시틴이고; 카복실 그룹 및 하이드록실 그룹 함유 화합물이 2,2-디메틸롤프로피온산; 타르타르산; 에틸렌 글리콜, 아디프산 및 2,2-디메틸롤프로피온산의 반응생성물; 1,4-부틸렌 글리콜, 아디프산 및 2,2-디메틸롤프로피온산의 반응생성물; 1,4-사이클로헥산디메탄올, 아디프산 및 2,2-디메틸롤프로피온의 반응 생성물; 또는 1,4-부틸렌 글리콜, 이소프탈산 및 디메틸롤프로피온산의 반응생성물이고, 설포네이트 그룹 및 하이드록실 그룹 함유 화합물이 N,N-비스(2-하이드록시에틸)-2-아미노에탄설폰산; 1,4-부틸렌 글리콜, 아디프산 및 N,N-비스(2-하이드록시에틸)-2-아미노에탄설폰산의 반응생성물; 또는 1,4-사이클로헥산디메탄올, 아디프산 및 N,N-비스(하이드록시에틸)-2-아미노에탄설폰산의 반응생성물이며; 포스페이트 그룹 및 하이드록실 그룹 함유 화합물이 2,3-디하이드록시프로필페닐포스페이트, 2,3-에폭시프로판올 및 인산의 반응 혼합물; 2,3-에폭시프로판올과 페닐포스폰산과의 반응 생성물; 또는 2,3-에폭시프로판올과 모노인산 에스테르와의 반응 혼합물인 중합체성 조성물.
  5. 제1항에 있어서, 중합 화합물이 비스(2,2,6,6-테트라메틸-4-피페리딜)세바케이트, 2-(3,5-t-부틸-4-하이드록시벤질)-2-n-부틸-말로네이트 비스(1,2,2,6,6-펜타메틸-4-피페리딜)또는 1,2-에탄-비스(N1-t-3,3,5,5,-테트라메틸-3-피페라지논)이고, 산성 그룹 함유 화합물이 2,2-디메틸롤프로피온산, N,N-비스(2-하이드록시에틸)-2-아미노에탄설폰산, 페닐포스폰산, 팔미트산 또는 폴리옥시에틸렌 알킬페닐에테르 포스페이트인 중합체성 조성물.
  6. 제1항에 있어서, 50℃ 및 상대습도 96%에서 1주일간 정치시킨 후의 파단강도 보유율이 70%이상인 중합체성 조성물.
  7. 제5항에 있어서, 50℃ 및 상대습도 96%에서 1주일간 정치시킨 후의 파단강도 보유율이 80%이상인 중합체성 조성물.
  8. 제1항에 있어서, 50℃ 및 상대습도 96%에서 1주일간 정치시킨 후의 당해 폴리우레탄의 분자량 보유율이 85%이상인 중합체성 조성물.
  9. 제5항에 있어서, 50℃ 및 상대습도 96%에서 1주일간 정치시킨 후의 당해 폴리우레탄의 분자량 보유율이 95%이상인 중합체성 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019920012718A 1991-07-17 1992-07-16 폴리우레탄 조성물 KR930002421A (ko)

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JP91-268,093 1991-07-17
JP26809391 1991-07-17

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US4501852A (en) * 1983-06-20 1985-02-26 Mobay Chemical Corporation Stable, aqueous dispersions of polyurethane-ureas
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US4729925A (en) * 1986-12-22 1988-03-08 Eastman Kodak Company Polyurethane elastomers comprising a charge-control agent and shaped elements therefrom

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