KR930001974A - Method for preparing metal element adsorbent and method for adsorptive separation of metal elements by the adsorbent - Google Patents

Method for preparing metal element adsorbent and method for adsorptive separation of metal elements by the adsorbent Download PDF

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KR930001974A
KR930001974A KR1019920012242A KR920012242A KR930001974A KR 930001974 A KR930001974 A KR 930001974A KR 1019920012242 A KR1019920012242 A KR 1019920012242A KR 920012242 A KR920012242 A KR 920012242A KR 930001974 A KR930001974 A KR 930001974A
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metal element
adsorbent
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gel composition
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와타루 시라토
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나가노 타케시
미쯔비시겐시넨료오 카부시키가이샤
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/18—Macromolecular compounds
    • B01J39/22—Cellulose or wood; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Sorption (AREA)
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Abstract

내용 없음.No content.

Description

금속원소 흡착제의 제조방법 및 그 흡착제에 의한 금속 원소의 흡착 분리 방법Method for preparing metal element adsorbent and method for adsorptive separation of metal elements by the adsorbent

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 본 발명에 의한 흡착성능시험예1의 결과를 나타내는 그래프,1 is a graph showing the results of the adsorption performance test example 1 according to the present invention,

제2도는 본 발명에 의한 흡착성능시험예2의 결과를 나타내는 그래프,2 is a graph showing the results of the adsorption performance test example 2 according to the present invention;

제3도는 본 발명에 의한 흡착성능시험예3에서 사용한 컬럼의 단면도.3 is a cross-sectional view of the column used in the adsorption performance test example 3 according to the present invention.

Claims (26)

암모니아수에 축합형타닌 분말을 용해하고, 이 용액에 알데히드 수용액을 혼합해서 겔상조성물을 생성하고, 이 겔상조성물을 숙성하여서 안정화하는 것을 특징으로 하는 금속원소 흡착제의 제조방법.A method for producing a metal element adsorbent, wherein condensed tannin powder is dissolved in ammonia water, an aldehyde aqueous solution is mixed with this solution to form a gel composition, and the gel composition is matured and stabilized. 제1항에 있어서, 겔상조성물이 안정화하기에 충분한 시간동안 실온하에 겔상조성물을 방치하여 숙성을 행하는 것을 특징으로 금속원소흡착제의 제조방법.The method for producing a metal element adsorbent according to claim 1, wherein the gel composition is left to mature at room temperature for a time sufficient to stabilize the gel composition. 제2항에 있어서, 겔상조성물이 안정화하기에 충분한 시간동안 실온 이상의 온도에서 겔상조성물을 가열하여서 숙성을 행하는 것을 특징으로 하는 금속원소흡착제의 제조방법.The method for producing a metal element adsorbent according to claim 2, wherein the gel composition is aged by heating at a temperature of room temperature or more for a time sufficient to stabilize the gel composition. 암모니아수와 알데히드수용액을 혼합하고, 이 혼합액에 축합형타닌 분말을 용해해서, 이 용액을 안정화한 겔상조성물을 생성하기에 충분한 시간동안 실온 이상의 온도에서 가열하는 것을 특징으로 하는 금속원소흡착제의 제조방법.A method for producing a metal element adsorbent, characterized by mixing ammonia water and an aldehyde aqueous solution, dissolving condensed tannin powder in the mixed solution and heating at a temperature above room temperature for a time sufficient to produce a gel composition having stabilized the solution. pH 8이상의 암모니아수에 축합형타닌분말을 용해하고, 이 용액에 헥사메틸렌테트라민을 혼합해서, 이 혼합액을 안정화한 겔상조성물을 생성하기에 충분한 시간동안 실온 이상의 온도에서 가열하는 것을 특징으로 하는 금속원소흡착제의 제조방법.A metal element characterized by dissolving a condensed tannin powder in ammonia water having a pH of 8 or higher, and mixing hexamethylenetetramine in this solution and heating at a temperature above room temperature for a time sufficient to produce a gel composition having stabilized the mixture. Process for preparing adsorbent. 헥사메틸렌테트라민 수용액에 축합형타닌분말을 혼합하고, 이 혼합액에 암모니아수를 첨가하여 pH 8이상으로 하는 것에 의해 전기한 타닌분말을 용해하고, 이 용액을 안정화한 겔살조성물을 생성하기에 충분한 시간동안 실온 이상의 온도에서 가열하는 것을 특징으로 하는 금속원소흡착제의 제조방법.Condensed tannin powder is mixed with an aqueous solution of hexamethylenetetramine, and ammonia water is added to the mixed solution to pH 8 or above to dissolve the tannin powder as described above, and for a time sufficient to produce a gel alkaloid composition having stabilized the solution. A method for producing a metal element adsorbent, characterized by heating at a temperature above room temperature. pH7-10인 알칼리금속수산화물의 수용액에 축합형탄니분말을 용해하고, 이 용액에 알데히드 수용액을 혼합해서, 이 혼합액을 안정화한 겔상조성물을 생성하기에 충분한 시간동안 실온 이상의 온도에서 가열하는 것을 특징으로 하는 금속원소 흡착제의 제조방법.A condensed tannic powder is dissolved in an aqueous solution of an alkali metal hydroxide having a pH of 7-10, and an aqueous aldehyde solution is mixed with the solution, and the mixture is heated at a temperature above room temperature for a time sufficient to produce a stabilized gel composition. Method for producing a metal element adsorbent to. pH7-10인 알칼리금속수산화물의 수용액에 축합형타닌분말을 용해하고, 이 용액에 헥사메틸렌테트라민을 혼합해서, 이 혼합액을 안정화한 겔상조성물을 생성하기에 충분한 시간동안 실온 이상의 온도에서 가열하는 것을 특징으로 하는 금속원소 흡착제의 제조방법.Condensed tannin powder is dissolved in an aqueous solution of an alkali metal hydroxide having a pH of 7-10, and hexamethylenetetramine is mixed with the solution, and heated at a temperature of room temperature or more for a time sufficient to produce a gel composition having stabilized the mixture. Method for producing a metal element adsorbent characterized in that. 헥사메틸렌테트라민 수용액에 축합형타닌분말을 혼합하고, 이 혼합액에 알칼리 금속수산화물의 수용액을 첨가해서 pH7-10으로 하는 것에 의해 전기한 타닌분말을 용해하고, 이 용액을 안정화한 겔상조성물을 생성하기에 충분한 시간동안 실온 이상의 온도에서 가열하는 것을 특징으로 하는 금속원소흡착제의 제조방법.Condensed tannin powder is mixed with an aqueous solution of hexamethylenetetramine, an aqueous solution of an alkali metal hydroxide is added to the mixed solution to pH 7-10 to dissolve the tannin powder as described above, and a gel composition obtained by stabilizing this solution is produced. A method for producing a metal element adsorbent, characterized in that heating at a temperature above room temperature for a sufficient time. 제7항 또는 제8항에 있어서, 전기한 알칼리금속수산화물이 수산화나트륨, 수산화칼륨 또는 수산화리튬인 것을 특징으로 하는 금속원소흡착제의 제조방법.The method for producing a metal element adsorbent according to claim 7 or 8, wherein the alkali metal hydroxide described above is sodium hydroxide, potassium hydroxide or lithium hydroxide. 청구범위 제1항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.It is obtained by the manufacturing method of Claim 1, The metal element adsorption agent characterized by the above-mentioned. 청구범위 제2항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.It is obtained by the manufacturing method of Claim 2, The metal element adsorption agent characterized by the above-mentioned. 청구범위 제3항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.It is obtained by the manufacturing method of Claim 3, The metal element adsorption agent characterized by the above-mentioned. 청구범위 제4항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.It is obtained by the manufacturing method of Claim 4, The metal element adsorption agent characterized by the above-mentioned. 청구범위 제5항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.A metal element adsorbent obtained by the production method according to claim 5. 청구범위 제6항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.It is obtained by the manufacturing method of Claim 6. The metal element adsorption agent characterized by the above-mentioned. 청구범위 제7항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.It is obtained by the manufacturing method of Claim 7, The metal element adsorption agent characterized by the above-mentioned. 청구범위 제8항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.It is obtained by the manufacturing method of Claim 8. The metal element adsorption agent characterized by the above-mentioned. 청구범위 제9항에 기재된 제조방법에 의해 얻어지는 것을 특징으로 하는 금속원소흡착제.It is obtained by the manufacturing method of Claim 9. The metal element adsorption agent characterized by the above-mentioned. 금속원소를 함유하는 용액과 청구범위 제11항 내지 제19항에 기재된 금속원소흡착제를 용액내의 금속이 전기한 흡착제에 흡착되도록 충분한 시간동안 접촉시키고, 그 용액으로부터 전기한 흡착제를 분리시키는, 것으로 이루어지는 것을 특징으로 하는 금속원소의 흡착분리방법.A solution containing a metal element and the metal element adsorbent according to claims 11 to 19 are brought into contact with each other for a sufficient time to adsorb the metal in the solution to the adsorbent described above, and the adsorbent separated from the solution is separated. Adsorption separation method of a metal element, characterized in that. 제20항에 있어서, 전기한 흡착제를 전기한 용액과의 접촉 이전에 세분화하는 것을 특징으로 하는 금속원소의 흡착분리방법.21. The method of claim 20 wherein the adsorbent described above is subdivided prior to contact with the electrolytic solution. 제20항에 있어서, 전기한 흡착제의 용액과의 접속은, 전기한 흡착제를 관형상 컬럼내에 충전하고, 그 컬럼에 전기한 용액을 통과시켜서 행해지는 것을 특징으로 하는 금속원소의 흡착분리방법.The method for adsorbing and separating metal elements according to claim 20, wherein the connecting of the adsorbent with the solution is performed by filling the adsorbent with a tubular column and passing the solution through the column. 제20항에 있어서, 전기한 금속원소는 악티늄족원소인 것을 특징으로 하는 금속 원소의 흡착분리방법.21. The method of claim 20, wherein the metal element described above is an actinium element. 제20항에 있어서 전기한 금속원소는 카드뮴, 납, 크롬, 수은 및 철로 이루어지는 군에서 선택된 원소인 것을 특징으로 하는 금속원소의 흡착분리방법.21. The method of claim 20, wherein the metal element described above is an element selected from the group consisting of cadmium, lead, chromium, mercury, and iron. 제20항에 있어서, 전기한 금속원소는 코발트, 세슘 및 스트론쥼으로 이루어지는 군에서 선택된 원소인 것을 특징으로 하는 금속원소의 흡착분리방법.21. The method of claim 20, wherein the metal element described above is an element selected from the group consisting of cobalt, cesium, and strontium. 제20항에 있어서, 분리된 흡착제를 희광산과 접촉시켜서 전기한 흡착제로부터 금속원소를 용리하는 것을 특징으로 하는 금속원소의 흡착분리방법.21. The method of claim 20, wherein the separated adsorbent is contacted with a dilute acid to elute the metal element from the adsorbent. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920012242A 1991-07-09 1992-07-09 Method of preparing metal element adsorbent and method of adsorbing and separating metal KR950009706B1 (en)

Applications Claiming Priority (5)

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JP91-194960 1991-07-09
JP19496091 1991-07-09
JP91-351676 1991-12-12
JP91-351678 1991-12-12
JP35167691A JP3033796B2 (en) 1991-07-09 1991-12-12 Method for producing metal element adsorbent and method for adsorbing and separating metal element by the adsorbent

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JP3037178B2 (en) * 1997-02-04 2000-04-24 核燃料サイクル開発機構 Equipment for treating plutonium-containing waste liquid using tannin
JP4124382B2 (en) * 1997-12-12 2008-07-23 三菱マテリアル株式会社 Adsorbent adsorbent combustion equipment
WO2007023521A1 (en) * 2005-08-22 2007-03-01 Saga University Method of separating gold
JP2009254971A (en) * 2008-04-16 2009-11-05 Doshisha Method for removing metal complex
JP5858223B2 (en) * 2011-10-18 2016-02-10 センカ株式会社 Noble metal recovery agent and method for recovering noble metal from liquid containing noble metal
JP6044978B2 (en) * 2012-07-05 2016-12-14 一般財団法人電力中央研究所 Manufacturing method of underwater metal collector
JP6236608B2 (en) * 2012-11-16 2017-11-29 国立大学法人佐賀大学 Adsorption and removal of cesium from water
JP2016047505A (en) * 2014-08-28 2016-04-07 元基 井上 Noble metal adsorbent using polyphenol derived from grape seeds as raw material
CN114906914A (en) * 2022-05-09 2022-08-16 河海大学 Environment-friendly plant tannin-based flocculant and preparation method thereof

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