KR930000557A - 선형 중합체 제조 방법 - Google Patents

선형 중합체 제조 방법 Download PDF

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Publication number
KR930000557A
KR930000557A KR1019920009406A KR920009406A KR930000557A KR 930000557 A KR930000557 A KR 930000557A KR 1019920009406 A KR1019920009406 A KR 1019920009406A KR 920009406 A KR920009406 A KR 920009406A KR 930000557 A KR930000557 A KR 930000557A
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compound
group
range
aromatic
phenylphosphonite
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KR1019920009406A
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English (en)
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가레사 요한나 카에실리아 마리아 코페스 마르
아드리아누스 반 도오른 요하네스
요한나 베렌디나 발호프 쥬디스
Original Assignee
알베르투스 빌헬무스 요아네스 째스트 라텐
셀 인터나쵸 나아레 레사아치 마아츠 샤피 비이부이
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Publication of KR930000557A publication Critical patent/KR930000557A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
    • C07F9/4841—Aromatic acids or derivatives (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

선형 중합체 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 유기알칼리 금속 개시제 화합물 및 적어도 탄화수소 희석제의 존재하에서 적어도 공역디엔 및/또는 모노알킬렌 방향족 화합물을 중합반응시키고, 연속해서 리빙 중합체 사슬을 하기 일반식(Ⅰ)의 화합물과 접촉시킴으로 구성되는 선형 중합체의 제조 방법 :
    RP(X)n(OR1)2(Ⅰ)
    상기 식에서 R은 인원자에 연결된 탄소 원자가 이차 또는 삼차 탄소 원자인 히드로카르빌기이고; R1은 임의적으로 치환된 히드로카르빌기이고; X는 0 또는 s 원자를 나타내며; n은 0 또는 1이다.
  2. 제1항에 있어서, R이 방향족 히드로카르빌기, 및 바람직하게 페닐인 방법.
  3. 제1 또는 2항에 있어서, R1이 방향족기, 및 바람직하게 페닐기인 방법.
  4. 제3항에 있어서, 방향족기 R1이 극성 치환기를 운반하는 방법.
  5. 제4항에 있어서, 극성 치환기는 알콕시기 또는 할로겐인 방법.
  6. 제1-5항 중 어느 한 항에 있어서, n이 0인 방법.
  7. 제1-5항 중 어느 한 항에 있어서, n이 1인 경우 x가 0원자를 나타내는 방법.
  8. 제1-7항 중 어느 한 항에 있어서, R 및 R1이 동시에 방향족기 및 바람직하게는 페닐기를 나타내는 방법.
  9. 제1-3항 중 어느 한 항에 있어서, 일반식 Ⅰ의 화합물은 디페닐 페닐포스포나이트, 버스(4-메톡시페닐) 페닐포스포나이트 및 비스(3-클로로페닐) 페닐포스포나이트로 구성된 군으로부터 선택되는 방법.
  10. 제1-3항 중 어느 한 항에 있어서, 일반식 Ⅰ의 화합물은 디페닐 페닐포스포네이트인 방법.
  11. 제1-10항 중 어느 한 항에 있어서, 일반식 Ⅰ의 화합물은 개시제의 몰당 0.3-0.7몰의 범위내의 양으로 사용되는 방법.
  12. 제11항에 있어서, 화합물의 양이 개시제의 몰 당 0.4-0.6몰의 범위내 및 보다 바람직하게는 0.45-0.55의 범위내인 방법.
  13. 제1-12항 중 어느 한 항에 있어서, 공역디엔은 1, 3-부타디엔, 이소프렌 또는 이들의 혼합물인 방법.
  14. 제1-12항 중 어느 한 항에 있어서, 모노알킬렌 방향족 화합물은 스티렌인 방법.
  15. 제1-14항 중 어느 한 항에 있어서, 탄화수소 희석제는 시클로헥산인 방법.
  16. 제1-15항 중 어느 한 항에 있어서, -20 내지 150℃범위내 및 바람직하게는 30 내지 90℃범위내의 온도에서 수행되는 방법.
  17. 화합물 버스(4-메톡시페닐) 페닐포스포나이트 및 버스(3-클로로페닐) 페닐포스포나이트.
  18. 실온에서 디클로로 페닐포스핀을 4-메톡시페놀 또는 3-클로로페놀의 몰 초과량과 혼합시키고, 연속해서 상기 혼합물을 180-200℃범위의 온도로 서서히 가열시키고, 원하는 생성물이 형성되도록 충분히 오랜 시간 동안 반응혼합물을 유지시키는 한편, 부산물 HCl은 반응기로부터 누출되도록 하며, 마지막으로 감압하에서 잔류물을 증류시킴으로 구성된 제17항에 청구된 화합물의 제조 방법.
  19. 제1-16항 중 어느 한 항에서 청구한 방법에 따라 제조된 적어도 공역 디엔 및/또는 모노 알킬렌 방향족 화합물로부터 유도된 선형 중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920009406A 1991-06-03 1992-05-30 선형 중합체 제조 방법 KR930000557A (ko)

Applications Claiming Priority (2)

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GB919111872A GB9111872D0 (en) 1991-06-03 1991-06-03 Polymer process
GB9111872.9 1991-06-03

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US (1) US5268429A (ko)
EP (1) EP0517317B1 (ko)
JP (1) JPH05209003A (ko)
KR (1) KR930000557A (ko)
CN (1) CN1067434A (ko)
BR (1) BR9202096A (ko)
DE (1) DE69207486T2 (ko)
ES (1) ES2082343T3 (ko)
GB (1) GB9111872D0 (ko)
MX (1) MX9202605A (ko)
RU (1) RU2073691C1 (ko)
TW (1) TW224977B (ko)

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DE69510477T2 (de) * 1994-03-14 2000-03-16 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von hoch verstreuten Metall-Kolloiden und von auf einem Substrat gebundenen Metall-Clusters durch elektrochemische Reduktion von Metallsalzen
CN1271103C (zh) 2001-01-18 2006-08-23 克拉通聚合物研究有限公司 粘合剂组合物
JP4560998B2 (ja) 2001-02-05 2010-10-13 味の素株式会社 発酵法によるｌ−グルタミンの製造法及びｌ−グルタミン生産菌
ES2643078T3 (es) 2003-12-22 2017-11-21 Kraton Polymers U.S. Llc Formulaciones adhesivas de los polímeros (S-I/B)X radiales
CN101306249B (zh) * 2008-05-30 2011-09-14 北京中星微电子有限公司 动作分析装置和方法
CN103254231B (zh) * 2013-06-05 2016-02-24 苏州科技学院 苯基亚膦酸二异丙酯化合物及其制备方法

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JPH05209003A (ja) 1993-08-20
US5268429A (en) 1993-12-07
EP0517317B1 (en) 1996-01-10
MX9202605A (es) 1992-12-01
EP0517317A1 (en) 1992-12-09
BR9202096A (pt) 1993-02-02
ES2082343T3 (es) 1996-03-16
DE69207486D1 (de) 1996-02-22
TW224977B (ko) 1994-06-11
CN1067434A (zh) 1992-12-30
GB9111872D0 (en) 1991-07-24
RU2073691C1 (ru) 1997-02-20
DE69207486T2 (de) 1996-06-27

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