KR920019671A - 휘발성 알칼리 토금속 착물 및 이의 용도 - Google Patents
휘발성 알칼리 토금속 착물 및 이의 용도 Download PDFInfo
- Publication number
- KR920019671A KR920019671A KR1019920005880A KR920005880A KR920019671A KR 920019671 A KR920019671 A KR 920019671A KR 1019920005880 A KR1019920005880 A KR 1019920005880A KR 920005880 A KR920005880 A KR 920005880A KR 920019671 A KR920019671 A KR 920019671A
- Authority
- KR
- South Korea
- Prior art keywords
- substrate
- ether
- alkaline earth
- earth metal
- oxygen
- Prior art date
Links
- 229910052784 alkaline earth metal Inorganic materials 0.000 title claims 4
- 150000001342 alkaline earth metals Chemical class 0.000 title claims 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 11
- 239000000758 substrate Substances 0.000 claims 7
- 125000001931 aliphatic group Chemical group 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 4
- 239000001301 oxygen Substances 0.000 claims 4
- 229910052760 oxygen Inorganic materials 0.000 claims 4
- 239000002887 superconductor Substances 0.000 claims 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- 229910052788 barium Chemical group 0.000 claims 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 3
- 239000007789 gas Substances 0.000 claims 3
- 238000000197 pyrolysis Methods 0.000 claims 3
- 239000003039 volatile agent Substances 0.000 claims 3
- YRAJNWYBUCUFBD-UHFFFAOYSA-N 2,2,6,6-tetramethylheptane-3,5-dione Chemical compound CC(C)(C)C(=O)CC(=O)C(C)(C)C YRAJNWYBUCUFBD-UHFFFAOYSA-N 0.000 claims 2
- -1 alkaline earth metal chelate complex Chemical class 0.000 claims 2
- 239000012159 carrier gas Substances 0.000 claims 2
- 150000004697 chelate complex Chemical class 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N methyl monoether Natural products COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 239000013522 chelant Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical group [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/455—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application the coating or impregnating process including a chemical conversion or reaction
- C04B41/4554—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application the coating or impregnating process including a chemical conversion or reaction the coating or impregnating material being an organic or organo-metallic precursor of an inorganic material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/92—Ketonic chelates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/40—Oxides
- C23C16/408—Oxides of copper or solid solutions thereof
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N60/00—Superconducting devices
- H10N60/01—Manufacture or treatment
- H10N60/0268—Manufacture or treatment of devices comprising copper oxide
- H10N60/0772—Processes including the use of non-gaseous precursors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical Vapour Deposition (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 물, 1,2-디메톡시에탄(DME)및 디에틸렌 글리콜 디메틸 에티르(Dgl)중의 Ba(thd)2용매화합물의 아레니우스 슬롯 및 직선 기울기로부터 계산된 증발에 대한 활성화 에너지를 도시한 것이다,
제2도는 화합물의 핵자기 공명 스펙트럼(100 MHz에서1H NMR스펙트럼, 용미 CDCl3/TMS)을 도시한 것이다.
Claims (6)
- 수화수를 함유하지 않는 일반식(Ⅰ)의 2,2,6,6-테트라메틸헵탄디온의 알칼리 토금속 킬레이트 착물.M2+(C11H19O2)- 2·LK(Ⅰ)상기식에서, M은 칼슘, 스트론튬 또는 바륨이고, L은 분자내에 2개 이상의 산소원자를 갖는 지방족에테르인 리간드이며, k는 1내지 3이다.
- 제1항에 있어서, 지방족 에테르가 비스(메틸)에테르 또는 비스(에틸)에테르인 킬레이트 착물.
- 제2항에 있어서, 지방족 에테르가 에틸렌 글리콜 또는 디에틸렌 글리콜의 비스 에테르인 킬레이트 착물.
- 분자내에 2개 이상의 산소원자를 갖는 지방족 에테르로부터 수화수를 함유하는 2,2,6,6-테트라메틸헵탄디온의 알칼리 토금속 킬레이트 착물을 재결정시킴을 특징으로 하여, 제1항에서 청구한 알칼리 토금속 킬레이트 착물을 제조하는 방법.
- 제1항에서 청구한 킬레이트 착물을 휘발성 화합물로서 사용함을 특징으로 하여, 분리된 증발기에서, 고온 초전도체를 구성하는 각각의 금속의 휘발성 화합물을 상이한 온도로 가열하고 불활성 담체 가스와 함께 형성된 증기를 산소 스트림과 합하고, 가스 혼합물을 약 850℃에서 열분해에 적용시키고, 고온 열분해 가스를 냉각된 기질상에 침착시키고, 경우에 따라, 피복된 기질을 산소-함유 대기중에서 연장된 시간 동안 연속적으로 가열함으로써, CVD방법에 의해 불활성 기질을 바륨을 함유하는 고온 초전도체로 피복시키는 방법.
- 제1항에서 청구한 킬레이트 착물을 휘발성 화합물로서 사용함을 특징으로 하여, 분리된 증발기에서 고온 초전도체를 구성하는 각각의 금속의 휘발성 화합물을 상이한 온도로 가열하고 불활성 담체 가스와 함께 형성된 증기를 산소 스트림과 합하고, 가스 혼합물을 약 850℃의 고온 기질 표면에서 열분해에 적용시켜, 기질상에서 금속 산화물을 침착시키고, 경우에 따라, 피복된 기질을 연장된 시간 동안 산소-함유대기중에서 연속적으로 가열함으로써, CVD방법에 의해 불활성 기질을 바륨을 함유하는 고온 초전도체로 피복시키는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4111460 | 1991-04-09 | ||
| DEP4111460.4 | 1991-04-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR920019671A true KR920019671A (ko) | 1992-11-19 |
Family
ID=6429146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019920005880A KR920019671A (ko) | 1991-04-09 | 1992-04-09 | 휘발성 알칼리 토금속 착물 및 이의 용도 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5264634A (ko) |
| EP (1) | EP0508345A3 (ko) |
| JP (1) | JPH0597762A (ko) |
| KR (1) | KR920019671A (ko) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2274456A (en) * | 1993-01-22 | 1994-07-27 | Timothy John Leedham | Volatile rare earth beta-diketone complexes |
| US6361759B1 (en) | 1998-05-26 | 2002-03-26 | Wisconsin Alumni Research Foundation | MR signal-emitting coatings |
| US6896874B2 (en) * | 1998-05-26 | 2005-05-24 | Wisconsin Alumni Research Foundation | MR-signal emitting coatings |
| WO2002020695A1 (de) * | 2000-09-08 | 2002-03-14 | Nanosolutions Gmbh | Dotierte nanopartikel |
| US20040253292A1 (en) * | 2003-04-23 | 2004-12-16 | Wisconsin Alumni Research Foundation | MR-signal emitting coatings |
| US7175888B2 (en) | 2004-03-03 | 2007-02-13 | General Electric Company | Mischmetal oxide TBC |
| US20070156042A1 (en) * | 2005-12-30 | 2007-07-05 | Orhan Unal | Medical device system and method for tracking and visualizing a medical device system under MR guidance |
| US8457712B2 (en) * | 2005-12-30 | 2013-06-04 | Wisconsin Alumni Research Foundation | Multi-mode medical device system and methods of manufacturing and using same |
| US8532742B2 (en) * | 2006-11-15 | 2013-09-10 | Wisconsin Alumni Research Foundation | System and method for simultaneous 3DPR device tracking and imaging under MR-guidance for therapeutic endovascular interventions |
| US20080183070A1 (en) * | 2007-01-29 | 2008-07-31 | Wisconsin Alumni Research Foundation | Multi-mode medical device system with thermal ablation capability and methods of using same |
| US8412306B2 (en) * | 2007-02-28 | 2013-04-02 | Wisconsin Alumni Research Foundation | Voltage standing wave suppression for MR-guided therapeutic interventions |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4558144A (en) * | 1984-10-19 | 1985-12-10 | Corning Glass Works | Volatile metal complexes |
| DE3827069A1 (de) * | 1987-11-21 | 1989-06-08 | Asea Brown Boveri | Verfahren zur herstellung eines supraleiters |
| ATE112512T1 (de) * | 1987-12-17 | 1994-10-15 | Univ Colorado Foundation | Chemischer dampf-niederschlag von gemischten oxidfilmen. |
| WO1989007666A1 (en) * | 1988-02-19 | 1989-08-24 | Northwestern University | Method of forming superconducting materials |
| US5140003A (en) * | 1989-03-22 | 1992-08-18 | Siemens Aktiengesellschaft | Method for manufacturing layers from an oxide-ceramic superconductor material on a substrate using a cvd-process |
| DE4006489A1 (de) * | 1990-03-02 | 1991-09-05 | Hoechst Ag | Vorrichtung zum herstellen duenner schichten aus metallmischoxiden aus organischen metallverbindungen auf einem substrat |
-
1992
- 1992-04-06 EP EP19920105916 patent/EP0508345A3/de not_active Withdrawn
- 1992-04-07 US US07/864,513 patent/US5264634A/en not_active Expired - Fee Related
- 1992-04-09 JP JP4088504A patent/JPH0597762A/ja active Pending
- 1992-04-09 KR KR1019920005880A patent/KR920019671A/ko not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US5264634A (en) | 1993-11-23 |
| EP0508345A3 (en) | 1994-06-01 |
| EP0508345A2 (de) | 1992-10-14 |
| JPH0597762A (ja) | 1993-04-20 |
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| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |