KR920009963A - Concentrated liquid dishwashing detergent composition containing alkyl benzene sulfonate and magnesium - Google Patents

Concentrated liquid dishwashing detergent composition containing alkyl benzene sulfonate and magnesium Download PDF

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Publication number
KR920009963A
KR920009963A KR1019910020749A KR910020749A KR920009963A KR 920009963 A KR920009963 A KR 920009963A KR 1019910020749 A KR1019910020749 A KR 1019910020749A KR 910020749 A KR910020749 A KR 910020749A KR 920009963 A KR920009963 A KR 920009963A
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weight percent
water
weight
alkyl
magnesium
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KR1019910020749A
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Korean (ko)
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조오지프 야쿠빅키 게리
바르슈스키 더어크
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로버어트 시이 설리반
콜 게이트-파아므올리브 캄파니
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Publication of KR920009963A publication Critical patent/KR920009963A/en

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/655—Mixtures of sulfonated products with alkylolamides of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Steroid Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Cosmetics (AREA)

Abstract

A concentrated light duty liquid detergent composition is described. The composition, which offers superior grease cutting and foam mileage, contains a surfactant mixture of magnesium alkylbenzene sulfonate, alkyl ethoxy sulfate and optionally, alkyl sulfate. The composition also contains a magnesium ion source in an amount such that the molar ratio of total magnesium ion to alkylbenzene sulfonate ranges from about 0.65:1.0 to 1.0:1.0.

Description

알킬 벤젠 설포네이트 및 마그네슘을 함유하는 농축 액체 식기세척 세제 조성물Concentrated liquid dishwashing detergent composition containing alkyl benzene sulfonate and magnesium

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (6)

하기(A)~(F)로 구성되는, 그리스 오염물 제거에 특히 효과적인, 안정한 거품형성 특성을 제공하는 액체 식기세척 세제 조성물 : (A)(a) C18-C18알 벤젠 설폰산 음이온 계면활성제의 마그네슘 염 약 15-약 35중량%; (b)총 마그네슘 이온 대 알킬벤젠 설로네이트의 몰비가 약0.65:1.0-1.0:1.0일 정도의 양으로, 수용성 마그네슘 염 약 1-약 5중량%, (c)알킬 에테르 설페이트내 알킬기 당평균 약 1-약 6개 산화에틸렌기를 함유하는 수용성 C18-C18일차 알킬에톡시 설페이트 약 1-약 20중량%, 및 (d)일차, 이차 또는 삼차 아민 또는 C18-C18알킬 설페이트의 알킬리 금속 염 약 0-약 20중량%, 로 구성되는 계면활성제 시스템 약 20-약 70중량%; (B)아미드 몰당 산화에틸렌 약 15몰 이하로 축합된, C18-C18에톡시화 및 비에톡시화 모노-또는 디-C1-C5알카놀아미드 및 C12-C14알킬 아미드로 구성되는 군으로부터 선택된 거품 촉진제 약 0.5-약 8중량%; (C)저 자극성 유기 용매 약 0-약 10중량%; (D)히드로트로프 약 0-약 10중량%; 및 (E)킬레이팅제, 착색제, 염료, 향료, 살균제, 살진균제, 방부제, 일광차단제, pH변경제, pH완충제, 불투명제, 항산화제, 단백질로부터 선택된 하나 이상의 임의 첨가제 약 0-약 10중량%, (F)나머지, 물.A liquid dishwashing detergent composition, comprising (A)-(F), which provides stable foaming properties, particularly effective in removing grease contaminants: (A) (a) C 18 -C 18 al benzene sulfonic acid anionic surfactant Magnesium salt of about 15-about 35% by weight; (b) about 1- about 5% by weight of the water-soluble magnesium salt in an amount of about 0.65: 1.0-1.0: 1.0, and (c) an average of about an alkyl group in the alkyl ether sulfate About 1 to about 20 weight percent of water-soluble C 18 -C 18 primary alkylethoxy sulfates containing 1 to about 6 ethylene oxide groups, and (d) alkyli of primary, secondary or tertiary amines or C 18 -C 18 alkyl sulfates From about 0 to about 20 weight percent of a metal salt, from about 20 to about 70 weight percent of a surfactant system; (B) consisting of C 18 -C 18 ethoxylated and nonethoxylated mono- or di-C 1 -C 5 alkanolamides and C 12 -C 14 alkyl amides condensed up to about 15 moles of ethylene oxide per mole amide About 0.5 to about 8 weight percent of a foam promoter selected from the group consisting of: (C) about 0 to about 10 weight percent of a low irritant organic solvent; (D) about 0- about 10 weight percent of hydrotropes; And (E) at least one optional additive selected from chelating agents, colorants, dyes, flavorings, fungicides, fungicides, preservatives, sunscreens, pH changing agents, pH buffers, opacifiers, antioxidants, proteins %, (F) remaining, water. 제1항에 있어서, 하기(A)~(F)로 구성되는 조성물 : (A)약 30-55%; (B)약 1-6%; (C)약 5-8%; (D)약 0-6%; (E)0-약3%; 및 (F)나머지, 물.The composition of claim 1 comprising the following compositions (A)-(F): (A) about 30-55%; (B) about 1-6%; (C) about 5-8%; (D) about 0-6%; (E) 0-about 3%; And (F) the rest, water. 제1항에 있어서, 계면활성제 시스템(A)가, (a)C10-C18알킬벤젠 설폰산의 마그네슘 염 약 19-21중량%; (b)마그네슘 이온 대 알킬벤젠 설포에이트 몰비가 0.65:1.0 내지0.8:1.0일 정도의 양의 수용성 마그네슘 염; (c)알콕 몰당 산화에틸렌기 3개를 가진 C10-C16알킬 에톡시 설페이트 약 10-13중량%; 및 (d)C10-C16알킬 설페이트 약 10-15중량%로 구성되는 조성물.The process of claim 1, wherein the surfactant system (A) comprises: (a) about 19-21 weight percent magnesium salt of C 10 -C 18 alkylbenzene sulfonic acid; (b) water-soluble magnesium salts in an amount of magnesium ion to alkylbenzene sulfoate molar ratio of about 0.65: 1.0 to 0.8: 1.0; (c) about 10-13% by weight of C 10 -C 16 alkyl ethoxy sulfate having three ethylene oxide groups per mole of alkoxy; And (d) about 10-15% by weight of C 10 -C 16 alkyl sulfate. 하기 (A)~(E)로 구성되는, 물리적으로 안정한 액체 식기세척 세제 염기 조성물; (A))(a)C10-C18알킬벤젠 설폰산의 마그네슘 염 약 10-약 50중량%; (b)총 마그네슘 이온 대 알킬벤젠 설포네이트 몰비가 약 0.65:1.0내지 1.0:1.0범위일 정도의 양으로, 수용성 마그네슘 염 약 1-약 5중량%; (c)알킬기당 평균 약-약 6개 산화에틸렌기를 함유하는 수용성 C10-C18일차 알킬에톡시 설페이트 염 약 1-약 27중량%; (d)일차아민 또는 C10-C16알킬 설페이트의 알킬리 금속염 약 0-약 27중량%, 로 구성되는 세제 활성 성분들 약 30- 약 70중량%; (B)아미드 몰당 산화에틸렌 15몰 이하로 축합된, C10-C16모노- 및 디-C1-C5알카놀아미드 및 C12-C14알킬아미드로 구성되는 군으로부터 선택된 거품 촉진제 약 0.6-약 11중량%; (C)저 자극성 유기용매 약 0-약 10중량; (D)히드로트로프 약 0-약 8중량%; 및 (E)나머지, 물.A physically stable liquid dishwashing detergent base composition composed of the following (A) to (E); (A)) about 10-about 50 weight percent of a magnesium salt of (a) C 10 -C 18 alkylbenzene sulfonic acid; (b) about 1 to about 5 weight percent of the water soluble magnesium salt in an amount ranging from about 0.65: 1.0 to 1.0: 1.0 molar ratio of total magnesium ion to alkylbenzene sulfonate; (c) about 1 to about 27 weight percent of a water-soluble C 10 -C 18 primary alkylethoxy sulfate salt containing an average of about-about 6 ethylene oxide groups per alkyl group; (d) about 0-about 27% by weight of an alkyl metal salt of primary amine or C 10 -C 16 alkyl sulfate, about 30- about 70% by weight of detergent active ingredients; (B) about 0.6 foam inhibitors selected from the group consisting of C 10 -C 16 mono- and di-C 1 -C 5 alkanolamides and C 12 -C 14 alkylamides condensed up to 15 moles of ethylene oxide per mole of amide About 11% by weight; (C) about 0 to about 10 weight percent low irritant organic solvent; (D) about 0% to about 8% hydrotrope; And (E) the rest, water. 제4항에 있어서, 하기 (A)~(E)로 구성되는 조성물 ; (A)약 60-65%; (B)약 1-약 8%; (C)약 2.5-약3.5%; (D)약 1-약 5%; 및 (E)나머지 물.The composition of Claim 4 which consists of following (A)-(E); (A) about 60-65%; (B) about 1- about 8%; (C) about 2.5-about 3.5%; (D) about 1- about 5%; And (E) remaining water. 제4항에 있어서, 계면활성제 시스템(A)이, 총 마그네슘 이온 대 마그네슘 알킬벤젠 설포네이트 몰비 0.65:1.0내지 0.8:1.0범위를 제공하기에 충분한 양의 수용성 마그네슘 염을 포함하는 조성물.The composition of claim 4, wherein the surfactant system (A) comprises an amount of water-soluble magnesium salt sufficient to provide a total magnesium ion to magnesium alkylbenzene sulfonate molar ratio ranging from 0.65: 1.0 to 0.8: 1.0. ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.※ Note: This is to be disclosed by the original application.
KR1019910020749A 1990-11-21 1991-11-20 Concentrated liquid dishwashing detergent composition containing alkyl benzene sulfonate and magnesium KR920009963A (en)

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US61649690A 1990-11-21 1990-11-21
US616,496 1990-11-21

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KR (1) KR920009963A (en)
CN (1) CN1061993A (en)
AT (1) ATE141638T1 (en)
AU (1) AU654508B2 (en)
BR (1) BR9105056A (en)
CA (1) CA2055340A1 (en)
DE (1) DE69121524T2 (en)
DK (1) DK0487169T3 (en)
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GR (1) GR1001194B (en)
HU (1) HU211779B (en)
IE (1) IE914032A1 (en)
MW (1) MW7091A1 (en)
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KR100317948B1 (en) * 1999-06-01 2001-12-22 손 경 식 Alkali liquid detergent composition containing alkyl benzene sulfonate magnesium salt
KR100340230B1 (en) * 1999-04-10 2002-06-12 (주)한국자원재활유지 a process for preparing cleanser soap

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KR100340230B1 (en) * 1999-04-10 2002-06-12 (주)한국자원재활유지 a process for preparing cleanser soap
KR100317948B1 (en) * 1999-06-01 2001-12-22 손 경 식 Alkali liquid detergent composition containing alkyl benzene sulfonate magnesium salt

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NO179796C (en) 1996-12-18
YU181191A (en) 1994-01-20
ZA918752B (en) 1992-05-04
YU47539B (en) 1995-10-03
AU8770691A (en) 1992-05-28
NO914544L (en) 1992-05-22
CA2055340A1 (en) 1992-05-22
HU913627D0 (en) 1992-02-28
HUT59720A (en) 1992-06-29
DE69121524D1 (en) 1996-09-26
ZW15191A1 (en) 1993-03-03
FI915473A (en) 1992-05-22
PT99542B (en) 1999-04-30
PL292456A1 (en) 1992-08-10
ZM4391A1 (en) 1992-05-29
GR1001194B (en) 1993-06-07
NO179796B (en) 1996-09-09
DK0487169T3 (en) 1997-02-10
MX9102048A (en) 1992-07-08
FI915473A0 (en) 1991-11-20
AU654508B2 (en) 1994-11-10
EP0487169A1 (en) 1992-05-27
EP0487169B1 (en) 1996-08-21
GR910100471A (en) 1992-10-08
MW7091A1 (en) 1993-08-11
NZ240394A (en) 1994-01-26
CN1061993A (en) 1992-06-17
BR9105056A (en) 1992-06-23
NO914544D0 (en) 1991-11-20
ATE141638T1 (en) 1996-09-15
IE914032A1 (en) 1992-06-03
HU211779B (en) 1995-12-28
PT99542A (en) 1992-09-30
DE69121524T2 (en) 1997-03-27

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