KR910021441A - 개선된 인성을 갖는 열가소성 성형재료 - Google Patents

개선된 인성을 갖는 열가소성 성형재료 Download PDF

Info

Publication number
KR910021441A
KR910021441A KR1019910002675A KR910002675A KR910021441A KR 910021441 A KR910021441 A KR 910021441A KR 1019910002675 A KR1019910002675 A KR 1019910002675A KR 910002675 A KR910002675 A KR 910002675A KR 910021441 A KR910021441 A KR 910021441A
Authority
KR
South Korea
Prior art keywords
thermoplastic molding
monomer
following components
molding material
alkyl group
Prior art date
Application number
KR1019910002675A
Other languages
English (en)
Other versions
KR0161290B1 (ko
Inventor
자이츠 프리드리히
루프미히 카를
Original Assignee
바르츠, 비텐베르크
바스프 악티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바르츠, 비텐베르크, 바스프 악티엔게젤샤프트 filed Critical 바르츠, 비텐베르크
Publication of KR910021441A publication Critical patent/KR910021441A/ko
Application granted granted Critical
Publication of KR0161290B1 publication Critical patent/KR0161290B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

개선된 인성을 갖는 열가소성 성형재료
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. (A+B+C의 합에 근거하여) 그래프트 베이스로서 하기성분A와, 하기성분B 및 C를 함유하는 열가소성 성형재로, A : A에 근거하여 하기성분 A1, A2 및 A3를 함유하고, 30 내지 1000㎚의 평균 입자 크기를 갖는 1 내지 30wt.%의 하나이상의 엘라스토머성 중합체 A, A1 : 알킬기에 1 내지 8개의 탄소원자를 갖는 50 내지 99.9wt.%의 하나 이상의 알킬 아크릴레이트 A1, A2 : 0.1 내지 5wt.%의 하나이상의 다중작용기성 가교 단량체 A2, A3 : 50wt.%이하의 하나 이상의 모노 에틸렌적으로 불포화된 단량체 A3, B : B에 근거하여 하기성분 B1, B2 및 B3 를 포함하고 엘라스토머성 중합체 A에 그래프팅된 5 내지 40wt.%의 쉘 B, B1 : 30 내지 90wt.%의 하나 이상의 비닐-방향족 단량체 B1, B2 : 5 내지 40wt.%의 하나 이상의 극성이며, 공중합 가능하고 에틸렌 적으로 불포화된 단량체 B2, B3 : 알킬기에서 7 내지 20개의 탄소원자를 갖는 5 내지 30wt.%의 하나 이상의 알킬 아크릴레이트, C : 하기성분 C1 및 C2를 포함하는 30 내지 94wt.%의 공중합체 C, C1 : 하나 이상의 비닐-방향족 단량체 C1, C2 : 하나 이상의 극성이고 공중합 가능하며 에틸렌적으로 불포화된 단량체 C2.
  2. 제1항에 있어서, 그래프트 쉘 B 가 45 내지 80wt.%의 단량체 B1, 10 내지 30wt.%의 단량체 B2 및 10 내지 25wt.%의 알킬 아크릴레이트 B3로 이루어진 열가소성 성형재료.
  3. 제1항에 있어서, 알킬기에서 8 내지 12개의 탄소원자를 갖는 알킬 아크릴레이트 B3를 갖는 열가소성 성형재료.
  4. 제1항에 있어서, 단량체 C2로서 아크릴로니트릴을 갖는 열가소성 성형재료.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910002675A 1990-02-20 1991-02-20 개선된 인성을 갖는 열가소성 성형재료 KR0161290B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4005210A DE4005210A1 (de) 1990-02-20 1990-02-20 Thermoplastische formmasse mit verbesserter zaehigkeit
DEP4005210.9 1990-02-20
DE40052109 1990-02-20

Publications (2)

Publication Number Publication Date
KR910021441A true KR910021441A (ko) 1991-12-20
KR0161290B1 KR0161290B1 (ko) 1999-01-15

Family

ID=6400510

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910002675A KR0161290B1 (ko) 1990-02-20 1991-02-20 개선된 인성을 갖는 열가소성 성형재료

Country Status (6)

Country Link
US (1) US5120788A (ko)
EP (1) EP0444468B1 (ko)
JP (1) JP2960559B2 (ko)
KR (1) KR0161290B1 (ko)
DE (2) DE4005210A1 (ko)
ES (1) ES2063387T3 (ko)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4011163A1 (de) * 1990-04-06 1991-10-10 Basf Ag Teilchenfoermiges pfropfpolymerisat und daraus hergestellte thermoplastische formmasse mit verbesserter zaehigkeit
DE4235976A1 (de) * 1992-10-24 1994-04-28 Basf Ag Thermoplastische Formmasse
DE4407069A1 (de) * 1994-03-03 1995-09-07 Basf Ag Formmasse
DE19536892A1 (de) * 1995-10-04 1997-04-10 Basf Ag Formteile aus thermoplastischen Formmassen
US5784197A (en) * 1996-04-01 1998-07-21 Minnesota Mining And Manufacturing Company Ultra-flexible retroreflective sheeting with coated back surface
US5754338A (en) * 1996-04-01 1998-05-19 Minnesota Mining And Manufacturing Company Structured retroreflective sheeting having a rivet-like connection
US5882796A (en) * 1996-04-01 1999-03-16 Minnesota Mining And Manufacturing Company Bonded structured retroreflective sheeting
US5910858A (en) * 1996-04-01 1999-06-08 Minnesota Mining And Manufacturing Company Retroreflective sheeting with coated back surface
US5840803A (en) * 1997-02-26 1998-11-24 Bayer Corporation Thermoplastic composition containing a grafted copolymeric acrylate rubber
US5990239A (en) * 1997-04-16 1999-11-23 Bayer Corporation Weatherable ASA composition
KR100260375B1 (ko) * 1997-12-16 2000-07-01 성재갑 내후성 수지 조성물 및 그 제조 방법
KR100417062B1 (ko) 2001-01-11 2004-02-05 주식회사 엘지화학 바이모달 입자분포로 이루어진 아크릴계 고무라텍스의제조방법
JP2003064231A (ja) * 2001-08-29 2003-03-05 Asahi Kasei Corp 耐候・耐衝撃性スチレン系樹脂組成物
US7317043B2 (en) * 2002-02-27 2008-01-08 Mitsubishi Rayon Co., Ltd. Impact modifier, process for producing the same, and thermoplastic resin composition
EP1486518B2 (en) * 2002-02-27 2015-10-14 Mitsubishi Rayon Co., Ltd. Impact modifier, process for producing the same, and thermoplastic resin composition
US6720386B2 (en) * 2002-02-28 2004-04-13 General Electric Company Weatherable styrenic blends with improved translucency
US9982123B2 (en) * 2014-04-02 2018-05-29 Ineos Styrolution Group Gmbh Process for producing thermoplastic moulding compositions with improved mechanical properties
KR20240012450A (ko) 2021-05-25 2024-01-29 이네오스 스티롤루션 그룹 게엠베하 우수한 저온 충격 강도를 갖는 열가소성 물질을 위한 아크릴 고무

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL221084A (ko) * 1956-09-28
US3041307A (en) * 1959-04-24 1962-06-26 Monsanto Chemicals Blend of styrene copolymer with a graft-copolymer of styrene and a nitrile upon an alkyl acrylate polymer
DE1260135B (de) * 1965-01-05 1968-02-01 Basf Ag Schlagfeste thermoplastische Formmassen
DE1911882B2 (de) * 1969-03-08 1975-04-17 Basf Ag, 6700 Ludwigshafen Schlagfeste thermoplastische Massen
DE2212928C3 (de) * 1972-03-17 1974-12-19 Th. Goldschmidt Ag, 4300 Essen Wärmehärtbare Folie
DE2536312C3 (de) * 1975-08-14 1980-02-28 Th. Goldschmidt Ag, 4300 Essen Verfahren zur Herstellung einer wärmehärtbaren Folie
DE2826925A1 (de) * 1978-06-20 1980-01-17 Basf Ag Witterungsbestaendige, schlagzaehe thermoplastische massen mit guter einfaerbbarkeit
US4351923A (en) * 1980-04-14 1982-09-28 Monsanto Company Process for terpolymer polyblends having high gloss and ductility
US4308355A (en) * 1980-04-14 1981-12-29 Monsanto Company Process for terpolymer polyblends having high gloss and ductility
DE3129378A1 (de) * 1981-07-25 1983-02-10 Basf Ag, 6700 Ludwigshafen Thermoplastische formmasse
DE3129472A1 (de) * 1981-07-25 1983-02-10 Basf Ag, 6700 Ludwigshafen Thermoplastische formmasse
DE3134103A1 (de) * 1981-08-28 1983-03-17 Basf Ag, 6700 Ludwigshafen Thermoplastische formmasse
DE3149358A1 (de) * 1981-12-12 1983-06-16 Basf Ag, 6700 Ludwigshafen Thermoplastische formmasse
DE3227555A1 (de) * 1982-07-23 1984-01-26 Basf Ag, 6700 Ludwigshafen Thermoplastische formmasse
JPS59227941A (ja) * 1983-06-10 1984-12-21 Kureha Chem Ind Co Ltd 熱可塑性樹脂組成物
DE3641991A1 (de) * 1986-12-09 1988-06-16 Bayer Ag Verfahren zur herstellung von pfropfpolymerisaten in pulverform

Also Published As

Publication number Publication date
EP0444468A3 (en) 1992-04-08
JP2960559B2 (ja) 1999-10-06
KR0161290B1 (ko) 1999-01-15
DE59103305D1 (de) 1994-12-01
DE4005210A1 (de) 1991-08-22
US5120788A (en) 1992-06-09
EP0444468A2 (de) 1991-09-04
ES2063387T3 (es) 1995-01-01
JPH05331334A (ja) 1993-12-14
EP0444468B1 (de) 1994-10-26

Similar Documents

Publication Publication Date Title
KR910021441A (ko) 개선된 인성을 갖는 열가소성 성형재료
KR910016793A (ko) 그라프팅 베이스 및 그라프트 시쓰사이의 개선된 부착성을 갖는 미립자 그라프트 중합체
KR910018428A (ko) 입자그래프트 중합체 및 이들로부터 제조된 개선된 인성을 갖는 열가소성 성형재료
JPS56118446A (en) Antistatic resin composition
GB972229A (en) Compositions comprising graft copolymers
KR910018481A (ko) 무광 표면 외관을 갖는, 방향족 폴리카보네이트 수지, abs 중합체 및 san 공중합체의 성형 조성물
KR840007098A (ko) 열가소성 수지 조성물
KR890000576A (ko) 폴리머 블랜드 조성물
ATE36343T1 (de) Pfropfcopolymere aus alkylmethacrylaten alkylacrylaten auf dien alkylacrylatcopolymeren und deren anwendung in schlagfestigkeitsmitteln.
NO158026C (no) Polymerblanding.
ATE36341T1 (de) Pfropfcopolymere aus alkylmethacrylaten auf vernetzten dien-alkylacrylat-copolymeren und deren verwendung als schlagfestigkeitsmodifiziermittel.
KR910021442A (ko) 저온 강화된 열가소성 중합체 블렌드 조성물
KR900016369A (ko) 폴리에스테르 및 그라프트 중합체를 기제로 하는 유리 섬유-강화 열가소성 성형 재료
KR960004431A (ko) 헤테로상 올레핀 중합체 물질로 내충격성 개질된 프로필렌 중합체 물질의 그래프트 공중 합체
KR920701353A (ko) 열가소성 수지 조성물
KR880005156A (ko) 가교결합 및 그라프트 오우버폴리머 아크릴레이트 고무
KR920009865A (ko) 내충격성 그라프트 공중합체 및 이것을 함유하는 열가소성 수지조성물
KR930000556A (ko) Abs 그라프트 공중합체 및 그를 함유하는 조성물
JPS55112252A (en) Impact-resistant, thermoplastic resin composition
KR930017976A (ko) 하이드록시 작용화 그라프트 공중합체에 의해 수득된 저 광택 폴리카보네이트/에이비에스(abs) 블렌드
KR900016351A (ko) 열가소성 성형물질
JPS5494547A (en) Thermoplastic resin composition
KR900014499A (ko) 스티렌계수지 조성물
DE69023609D1 (de) Thermoplastische Zusammensetzungen basierend auf vinylaromatischen Copolymeren und Polyamid-Harzmassen.
KR910002998A (ko) 그래프트 수준이 조절된 epdm과 아크릴 고무를 포함하는 블렌드

Legal Events

Date Code Title Description
A201 Request for examination
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee