KR910020138A - 산부식 방지성 코우팅조성물 및 그 용도 - Google Patents

산부식 방지성 코우팅조성물 및 그 용도 Download PDF

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KR910020138A
KR910020138A KR1019910007159A KR910007159A KR910020138A KR 910020138 A KR910020138 A KR 910020138A KR 1019910007159 A KR1019910007159 A KR 1019910007159A KR 910007159 A KR910007159 A KR 910007159A KR 910020138 A KR910020138 A KR 910020138A
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coating composition
range
component
polyurethane polyol
polyol
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KR1019910007159A
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KR960006086B1 (en
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허버트 워커 프레데릭
레슬리 가아돈 존
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원본미기재
아크조 엔. 브이.
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/64Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6415Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/3831Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing urethane groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01FMEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
    • G01F1/00Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
    • G01F1/68Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow by using thermal effects
    • G01F1/684Structural arrangements; Mounting of elements, e.g. in relation to fluid flow
    • G01F1/688Structural arrangements; Mounting of elements, e.g. in relation to fluid flow using a particular type of heating, cooling or sensing element
    • G01F1/69Structural arrangements; Mounting of elements, e.g. in relation to fluid flow using a particular type of heating, cooling or sensing element of resistive type
    • G01F1/692Thin-film arrangements

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Physics & Mathematics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음

Description

산부식 방지성 코우팅조성물 및 그 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (26)

  1. (1) (A) 적어도 네 개의 탄소원자로 구성되는 실질적으로 단량체인 대칭적인 1,3-디올로부터 선택되는 디올성분과, (b) n-관능성 폴리이소시아네이트 (n은2내지 5범위의 수임)로부터 선택된, 이소시아네이트 성분의 반응 생성물로 구성되는 약 1.1 내지 3.5 범위내의 분산도 및 약 600 내지 약 3000범위내의 수평균 분자량을 가지는 폴리우레탄 폴리올 및 ; (2) 히드록실기-활성 가교재로 구정된 것을 특징으로 하는 코우팅 조성물.
  2. 제1항에 있어서, 25℃에서 약 25mPa.s 내지 약 300mPa.s 범위내의 용액 점성도에서 40중량% 내지 약 80중량% 범위내의 비-휘발성 물질 함량을 가진 것을 특징으로 하는 코우팅 조성물.
  3. 제2항에 있어서, 25℃에서 약 50mPa.s 내지 약 200mPa.s 범위내의 용액 점성도에서 40중량% 내지 약 80중량%범위내의 비-휘발성 물질 함량을 가지는 것을 특징으로 하는 코우팅 조성물.
  4. 제1항에 있어서, 폴리우레탄 폴리올리 (A) 0.8n 내지 1.2n 몰의 디올성분 및 (B) 1몰의 이소시아네이트 성분의 반응 생성물로 구성되는 것을 특징으로 하는 코우팅 조성물.
  5. 제4항에 있어서, 폴리우레탄 폴리올이 (A) 0.9n 내지 1.1n 몰의 폴리올성분 및(B) 1몰의 이소시아네이트 성분으로 구성되는 것을 특징으로 하는 코우팅 조성물.
  6. 제5항에 있어서, 폴리우레탄 폴리올이 (A) 0.95n 내지 1.05n 몰의 폴리올성분, 및(B) 1몰의 이소시아네이트 성분인 것을 특징으로 하는 조성물.
  7. 제6항에 있어서, 폴리우레탄 폴리올이 (A) 0.98n 내지 1.02n 몰의 폴리올 성분 및 (B) 1 몰의 이소시아네이트 성분의 반응 생성물로 구성되는 것을 특징으로 하는 코우팅 조성물.
  8. 제1항에 있어서, n이 2 내지 4범위내의 수인 것을 특징으로 하는 코우팅 조성물.
  9. 제8 항에 있어서, n이 3 내지 4범위내의 수인 것을 특징으로 하는 코우팅 조성물.
  10. 제9항에 있어서, 폴리우레탄 폴리올의 폴리이소시아네이트 성분이 단량체인 디이소시아네이트의 이소시아누레이트, 단랑체인 디이소시아네이트의 비우레트 및 약 0.45 내지 0.55의 히드록실 대 이소시아네이트 기의 비로 2 내지 4개의 히드록실 기를 가진 다-관능성 알콜과 단량체 디이소시아네이트의 반응생성물로부터 선택되는 것을 특징으로 하는 코우팅 조성물.
  11. 제1항에 있어서, 폴리우레탄 폴리올의 디올 성분이 실질적으로 적어도 다섯 개의 탄소원자로 구성되는 단량체인 대칭성 1.3-디올로부터 선택되는 것을 특징으로 하는 코우팅 조성물.
  12. 제11항에 있어서, 폴리우레탄 폴리올의 디올 성분이 네오펜틸 글리콜, 2-부틸-2-에틸-1.3-프로판디올 및 2.2-디에틸-1.3-프로판 디올로부터 선택되는 것을 특징으로 하는 코우팅 조성물.
  13. 제1항에 있어서, 폴리우레탄 폴리올이 약 2500이하의 수평균 분자량을 가진 것을 특징으로 하는 코우팅 조성물.
  14. 제1항에 있어서, 폴리우레탄 폴리올이 약 1000보다 더큰 수평균 분자량을 가진 것을 특징으로 하는 코우팅 조성물.
  15. 제1항에 있어서, 폴리우레탄 폴리올이 약 2.5이하의 분산도를 가지는 것을 특징으로 하는 코우팅 조성물.
  16. 제15항에 있어서, 폴리우레탄 폴리올이 약 2.0이하의 분산도를 가지는 것을 특징으로 하는 코우팅 조성물.
  17. 제1항에 있어서, 히드록시기-활성 가교제가 포리이소시아네이트, 블록된 폴리이소시아네이트 및 아미노 플라스트 수지로부터 선택되는 것을 특징으로 하는 코우팅 조성물.
  18. 제17 항에 있어서, 히드록시기-활성 가교제가 아미노플라스트 수지로 구성되는 것을 특징으로 하는 코우팅 조성물.
  19. 제18항에 있어서, 히드록시기-활성 가교제가 약 90/10 내지 50/50범위내의 폴리우레탄 폴리올 대 아미노플라스트 수지의 중량비인 아미노플라스트 수지로 구성되는 것을 특징으로 하는 코우팅 조성물.
  20. 제19항에 있어서, 아미노플라스트 수지가 1 내지 4 개의 탄소원자를 가진 알콜로 에테르화된 헥사메톡시 멜라민으로 구성되는 것을 특징으로 하는 코우팅 조성물.
  21. 제17항에 있어서, 히드록시기-활성 가교제가 블록된 폴리이소시아네이트로 구성된 것을 특징으로 하는 코우팅 조성물.
  22. 제21항에 있어서, 히드록시기-활성 가교제가 약 0.4 내지 2.2 범위내의 히드록실 대 이소시아네이트기의 당량비로 블록된 폴리이소시아네이트로 구성되는 것을 특징으로 하는 코우팅 조성물.
  23. 제21항에 있어서, 폴리이소시아네이트가 말로네이트로 블록된 것을 특징으로 하는 코우팅 조성물.
  24. 제1항 내지 23 항중 어느 하나에 있어서, 원-팩 시스템으로 배합된 것을 특징으로 하는 코우팅 조성물.
  25. (A) 적어도 네 개의 탄소원자로 구성되는 실질적으로 단량체인 대칭성 1,3-디올로부터 선택되는 디올성분 및, (B) n-관능성 폴리이소시아네이트 (상기 식내의 n 이 2 내지 5 범위내의 수임)로부터 선택되는 이소시아네이트 성분의 반응 생성물로 구성되며 약 600 내지 약 3000범위내의 수평균 분자량 및 약 1.1 내지 약 3.5 범위내의 분산도를 가진 폴리우레탄 폴리올의 (1) 폴리올 및 (2) 히드록시기-활성 가교제로 구성된 코우팅 조성물들로부터 필름의 산부식 방지성을 개선하기 위한 용도 폴리우레탄 폴리올의 이용.
  26. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR91007159A 1990-05-01 1991-05-01 Acid etch resistant coatings and polyurethane polyol therefrom KR960006086B1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US640,655 1975-12-15
US517,086 1983-07-22
US07/517,086 US5155201A (en) 1989-07-13 1990-05-01 Polyurethane polyols and high solids coatings therefrom
US07/640,655 US5130405A (en) 1989-07-13 1991-01-14 Acid etch resistant coatings

Publications (2)

Publication Number Publication Date
KR910020138A true KR910020138A (ko) 1991-12-19
KR960006086B1 KR960006086B1 (en) 1996-05-08

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US (1) US5130405A (ko)
EP (1) EP0455291B1 (ko)
JP (1) JP3188284B2 (ko)
KR (1) KR960006086B1 (ko)
BR (1) BR9101767A (ko)
CA (1) CA2041522C (ko)
DE (1) DE69101872T2 (ko)
ES (1) ES2052323T3 (ko)

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DE69101872T2 (de) 1994-11-10
CA2041522A1 (en) 1991-11-02
JP3188284B2 (ja) 2001-07-16
EP0455291B1 (en) 1994-05-04
KR960006086B1 (en) 1996-05-08
BR9101767A (pt) 1991-12-17
ES2052323T3 (es) 1994-07-01
EP0455291A1 (en) 1991-11-06
JPH04227776A (ja) 1992-08-17
CA2041522C (en) 2002-12-24
US5130405A (en) 1992-07-14
DE69101872D1 (de) 1994-06-09

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