KR910020050A - 발포성 스티렌 중합체 - Google Patents

발포성 스티렌 중합체 Download PDF

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Publication number
KR910020050A
KR910020050A KR1019910007171A KR910007171A KR910020050A KR 910020050 A KR910020050 A KR 910020050A KR 1019910007171 A KR1019910007171 A KR 1019910007171A KR 910007171 A KR910007171 A KR 910007171A KR 910020050 A KR910020050 A KR 910020050A
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KR
South Korea
Prior art keywords
styrene polymer
component
expandable styrene
weight
expandable
Prior art date
Application number
KR1019910007171A
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English (en)
Inventor
비텐베르크 디트마르
한 클라우스
구르 우베
힌츠 한스
피. 오캘러건 마이클
리트휘스 미하엘
Original Assignee
바르츠, 비텐베르크
바스프 악티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 바르츠, 비텐베르크, 바스프 악티엔게젤샤프트 filed Critical 바르츠, 비텐베르크
Publication of KR910020050A publication Critical patent/KR910020050A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/91—Plural blowing agents for producing nonpolyurethane cellular products

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  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

발포성 스티렌 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (a) 스티렌 중합체, (b) (a)에 대해, 0.05 내지 3중량%의 수분, (c) (a)에 대해 0.001 내지 1중량%의, 10g/g 이상의 수분 흡수용량을 갖는 미립 유기 중합체, (d) (a)에 대해, 0.5 내지 8중량%의 C3-C6-탄화수소, 및, 필요하다면, (e) 유효량의 통상적인 첨가제를 함유하는 발포성 스티렌 중합체.
  2. 제1항에 있어서, 전부 또는 약간이 염 생성에 의해 중화될 수 있는, 40 내지 62중량%의 카르복실기를 함유하는 교차 결합되거나 또는 부분적으로 교차 결합된 유기 중합체를 성분 (c)로서 함유함을 특징으로 하는 발포성 스티렌 중합체.
  3. 제2항에 있어서, 50% 이상의 카르복실기가 알카리 금속염의 형태로 존재하는 교차 결합되거나 또는 부분적으로 교차 결합된 폴리아크릴산을 성분(c)로서 함유하는 것을 특징으로 하는 발포성 스티렌 중합체.
  4. 제1항 내지 3항중 어느 한 항에 있어서, 성분(c)가 1내지 50㎛의 평균 입자 크기를 갖는 것을 특징으로 하는 발포성 스티렌 중합체.
  5. 제1항 내지 4항중 어느 한 항에 있어서, 성분(c)중 최소한 약간이 성분(a)에 균일하게 분포하는 것을 특징으로 하는 발포성 스티렌 중합체.
  6. 제1항 내지 제4항중 어느 한 항에 있어서, 성분(c)중 최소한 약간이 표면 피복은 형태로 존재하는 것을 특징으로하는 발포성 스티렌 중합체.
  7. 스티렌 및, 필요하다면, 그밖의 공단량체 및 성분(c)의 혼합물을 수성 현탁액중에서 중합시키고, 사용된다면, 성분(d)를 중합전, 도중 또는 후에 첨가하는 것으로 이루어지는, 제1항 내지 5항중 어느 한항에 따르는 발포성 스티렌 중합체의 제조방법.
  8. 현탁 중합에 의해 제조된 비드-형 발포성 스티렌 중합체의 표면에 성분(c)를 피복하고, 성분 (a), (b), (d) 및, 필요하다면, (c) 및/또는 (e)를 함유하는 것으로 이루어지는, 제6항에 따르는 발포성 스티렌 중합체의 제조방법.
  9. 제10g/g이상의 수분 흡수 용량을 갖는 0.001 내지 1중량%의 미립 유기 중합체를 함유하고 0.01 내지 0.1g/㎤의 밀도를 갖는 스티렌 중합체 포움.
  10. 제1항 내지 6항중 어느 한항에 따르는 스티렌 중합체를 통상적인 방법으로 연화점 이상의 온도를 가열함으로써 발포시키고, 생성된 포움 입자들을 기밀 방법으로 밀폐하지 않은 모울드에서 가열함으로써 서로 용융 결합시키는 것으로 이루어지는, 제9항에 따르는 스티렌 중합체 포움의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910007171A 1990-05-04 1991-05-03 발포성 스티렌 중합체 KR910020050A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4014261A DE4014261A1 (de) 1990-05-04 1990-05-04 Expandierbare styrolpolymerisate
DEP4014261.2 1990-05-04

Publications (1)

Publication Number Publication Date
KR910020050A true KR910020050A (ko) 1991-12-19

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ID=6405667

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910007171A KR910020050A (ko) 1990-05-04 1991-05-03 발포성 스티렌 중합체

Country Status (9)

Country Link
US (1) US5096931A (ko)
EP (1) EP0459147B1 (ko)
JP (1) JPH04227704A (ko)
KR (1) KR910020050A (ko)
AT (1) ATE130332T1 (ko)
AU (1) AU635637B2 (ko)
CA (1) CA2041756A1 (ko)
DE (2) DE4014261A1 (ko)
ES (1) ES2078988T3 (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5239007A (en) * 1991-10-22 1993-08-24 Arco Chemical Technology, L.P. Oil-absorbent compositions
MY117649A (en) * 1996-07-04 2004-07-31 Shell Int Research Process for the preparation of polymer particles
MY116407A (en) * 1996-07-04 2004-01-31 Shell Int Research Process for the preparation of polymer particles
DE10101402A1 (de) * 2001-01-13 2002-07-18 Basf Ag Verfahren zur Herstellung wasserexpandierbarer Styrolpolymerisate
DE10101432A1 (de) * 2001-01-13 2002-07-18 Basf Ag Kohlenstoffpartikel enthaltende expandierbare Styrolpolymerisate
EP1837172A1 (de) * 2006-03-22 2007-09-26 Basf Aktiengesellschaft Wärmedämmverbundsystem zur Innendämmung von Gebäuden
MX2009002243A (es) * 2006-09-08 2009-04-16 Nova Chem Inc Particulas polimericas y articulos relacionados.
EP2199325A1 (de) * 2008-12-22 2010-06-23 Basf Se Schaumstoffpartikel aus Styrolpolymeren
US9850361B2 (en) 2014-12-02 2017-12-26 Sabic Global Technologies B.V. Water expandable polymer beads containing latex particles
MX2018007750A (es) 2016-01-07 2018-11-14 Topsoe Haldor As Proceso para la preparacion de etilenglicol a partir de azucares.

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2115859A5 (en) * 1970-11-24 1972-07-07 Basf Ag Styrene polymn waste water - clarification - by flocculation with acrylic acid-contg polymers or their salts
US4307202A (en) * 1980-01-04 1981-12-22 The Dow Chemical Company Thermoplastic foam and process for the preparation thereof
US4306036A (en) * 1980-03-24 1981-12-15 The Dow Chemical Company Thermoplastic foam and process for the preparation thereof
US4312910A (en) * 1980-04-04 1982-01-26 The Dow Chemical Company Styrene-acrylic acid copolymer foam
US4323655A (en) * 1980-05-07 1982-04-06 Atlantic Richfield Company Rubber-modified fire-retardant anhydride copolymers
US4278768A (en) * 1980-05-07 1981-07-14 Arco Polymers, Inc. Rubber-modified fire-retardant anhydride copolymers
JPS59109532A (ja) * 1982-12-15 1984-06-25 Sekisui Plastics Co Ltd 二次成形性の改良されたポリスチレン系押出発泡シ−ト及びその製造法
JP2598656B2 (ja) * 1987-12-24 1997-04-09 三菱レイヨン株式会社 懸濁重合方法
AU622024B2 (en) * 1989-05-12 1992-03-26 Basf Aktiengesellschaft Expandable styrene polymers
DE3936596A1 (de) * 1989-11-03 1991-05-08 Basf Ag Expandierbare styrolpolymerisate und daraus hergestellte aromatenbestaendige schaumstoffe

Also Published As

Publication number Publication date
AU7622991A (en) 1991-11-07
CA2041756A1 (en) 1991-11-05
ATE130332T1 (de) 1995-12-15
EP0459147A3 (en) 1992-04-29
DE59106887D1 (de) 1995-12-21
JPH04227704A (ja) 1992-08-17
EP0459147B1 (de) 1995-11-15
US5096931A (en) 1992-03-17
AU635637B2 (en) 1993-03-25
EP0459147A2 (de) 1991-12-04
DE4014261A1 (de) 1991-11-07
ES2078988T3 (es) 1996-01-01

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