KR910015531A - 아미드의 제조방법 - Google Patents

아미드의 제조방법 Download PDF

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Publication number
KR910015531A
KR910015531A KR1019910001901A KR910001901A KR910015531A KR 910015531 A KR910015531 A KR 910015531A KR 1019910001901 A KR1019910001901 A KR 1019910001901A KR 910001901 A KR910001901 A KR 910001901A KR 910015531 A KR910015531 A KR 910015531A
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KR
South Korea
Prior art keywords
phosphine
compound
range
atom
unsaturated compound
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KR1019910001901A
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English (en)
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KR100211224B1 (ko
Inventor
드렌트 아이트
Original Assignee
오노 알버어스
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
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Publication of KR910015531A publication Critical patent/KR910015531A/ko
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Publication of KR100211224B1 publication Critical patent/KR100211224B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/57—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/10—Preparation of carboxylic acid amides from compounds not provided for in groups C07C231/02 - C07C231/08
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/58—Pyridine rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/62—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing three- or four-membered rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyrrole Compounds (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)

Abstract

내용 없음

Description

아미드의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. a) VIII족 금속원, b) 이미노 질소원자를 함유하는 방향족 치환체를 갖는 포스핀, 및 c) 양성자산으로 구성된 촉매계의 존재하에, 일산화탄소 및 암모니아 및 일차 또는 이차 아민 또는 아미드로 부터 선택된 질소화합물과 아세틸렌형 또는 올레핀형불포화 화합물을 반응시키는 것으로 구성되는 아미드의 제조방법.
  2. 제1항에 있어서, VIII족 금속원이 팔라듐 화합물인 방법.
  3. 제1항 또는 제2항에 있어서, 이미노 질소원자가 단일 브릿징 탄소원자를 통해 인원자와 연결되는 방법.
  4. 제3항에 있어서, 포스핀이 2-피리딜 포스핀 또는 2-피리미디닐 포스핀인 방법.
  5. 제1항 내지 제4항중 어느 한항에 있어서, 양성자산이 황산, 설폰산, 포스폰산, 카르복실산, 피할산 또는 설폰화 이온 교환수지인 방법.
  6. 제1항 내지 제5항중 어느 한항에 있어서, VIII족 금속의 그램 원자당 포스핀의 몰수비가 2내지 500의 범위에 있고, 양성자산의 몰당 포스핀의 몰수비가 0.5내지 25의 범위에 있는 방법.
  7. 제1항 내지 제6항중 어느 한항에 있어서, 온도가 20내지 130°의 범위에 있고, 압력이 1내지 70바아의 범위에 있는 방법.
  8. 제1항 내지 재7항중 어느 한항에 있어서, 아세틸렌형 또는 올레핀형 불포화 화합물이 2내지 10개 탄소원자를 갖는 치환 비치환 알켄, 시클로알켄 또는 알킨인 방법.
  9. 제1항 내지 제8항중 어느 한항에 있어서, 질소화합물이 하기 일반식(III)인의 화합물인 방법.
    HNR5R6(III)
    (상기식에서, 각 R5및 R6은 독립적으로 수소원자, 또는 임의로 치환된 알킬, 시클로알킬, 아릴, 방향족 헤테로시클릭, 또는 아실기를 나타내거나, 또는 R5및 R6은 이들이 부착된 질소원자와 함께 고리를 형성한다.)
  10. 제1항 내지 제9항중 어느 한항에 있어서, 불포화 화합물이 아세틸렌형 불포화 화합물이고, 질소 화합물이 방향족 아민인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910001901A 1990-02-05 1991-02-04 아미드의 제조방법 KR100211224B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB909002522A GB9002522D0 (en) 1990-02-05 1990-02-05 Preparation of amides
GB90025222 1990-02-05

Publications (2)

Publication Number Publication Date
KR910015531A true KR910015531A (ko) 1991-09-30
KR100211224B1 KR100211224B1 (ko) 1999-07-15

Family

ID=10670440

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910001901A KR100211224B1 (ko) 1990-02-05 1991-02-04 아미드의 제조방법

Country Status (12)

Country Link
US (1) US5128475A (ko)
EP (1) EP0441445B1 (ko)
JP (1) JP2949602B2 (ko)
KR (1) KR100211224B1 (ko)
CN (1) CN1029957C (ko)
AU (1) AU637452B2 (ko)
BR (1) BR9100446A (ko)
CA (1) CA2034972A1 (ko)
DE (1) DE69101849T2 (ko)
ES (1) ES2053269T3 (ko)
GB (1) GB9002522D0 (ko)
RU (1) RU1833367C (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2646847B1 (fr) * 1989-05-12 1991-07-12 Rhone Poulenc Sante N-phenyl amides, leurs procedes de preparation et les medicaments les contenant
US6194529B1 (en) * 1999-03-19 2001-02-27 Board Of Trustees Operating Michigan State University Ordered polyacetylenes and process for the preparation thereof
CN107935878A (zh) * 2017-11-20 2018-04-20 华东师范大学 一种由烯烃、一氧化碳和氨气制备一级酰胺的方法
CN115304505B (zh) * 2021-05-08 2023-06-27 西北大学 烯烃羰基化合成酰胺的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2113210B (en) * 1981-12-15 1985-10-23 Mitsubishi Petrochemical Co Catalytic process for preparing alkyl tertiary amines
DE3664632D1 (en) * 1985-04-05 1989-08-31 Texaco Development Corp Process for the synthesis of n-acetyl amino acids from olefins, acetamide and syngas
GB2216036A (en) * 1988-03-31 1989-10-04 Shell Int Research Process and catalyst for the carbo-amination or carbo-amidation of olefins

Also Published As

Publication number Publication date
AU637452B2 (en) 1993-05-27
US5128475A (en) 1992-07-07
JP2949602B2 (ja) 1999-09-20
ES2053269T3 (es) 1994-07-16
CN1029957C (zh) 1995-10-11
DE69101849T2 (de) 1994-09-08
RU1833367C (ru) 1993-08-07
DE69101849D1 (de) 1994-06-09
AU7023591A (en) 1991-08-08
EP0441445A2 (en) 1991-08-14
CN1053785A (zh) 1991-08-14
GB9002522D0 (en) 1990-04-04
EP0441445A3 (en) 1991-11-27
EP0441445B1 (en) 1994-05-04
KR100211224B1 (ko) 1999-07-15
JPH04211042A (ja) 1992-08-03
CA2034972A1 (en) 1991-08-06
BR9100446A (pt) 1991-10-22

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