KR900701974A - 옥시-알킬렌 하이드록시 연결그룹을 갖는 긴 사슬의 지방족 하이드로 카빌 아민 첨가제 - Google Patents

옥시-알킬렌 하이드록시 연결그룹을 갖는 긴 사슬의 지방족 하이드로 카빌 아민 첨가제

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KR900701974A
KR900701974A KR1019900700964A KR900700964A KR900701974A KR 900701974 A KR900701974 A KR 900701974A KR 1019900700964 A KR1019900700964 A KR 1019900700964A KR 900700964 A KR900700964 A KR 900700964A KR 900701974 A KR900701974 A KR 900701974A
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additive
component
aliphatic hydrocarbyl
range
amine
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에프·버클리 3세 토마스
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원본미기재
셰브런 리써취 캄파니
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Abstract

내용 없음

Description

옥시-알킬렌 하이드록시 연결그룹을 갖는 긴 사슬의 지방족 하이드로 카빌 아민 첨가제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (45)

  1. 긴 사슬의 지방족 하이드로카밀 성분, 아민성분 및 상기 지방족 하이드로카밀 성분과 상기 아민성분을 연결시켜 주는 옥시-알킬렌 하이드록시 연결그룹으로 구성되며, 그 연결그룹은 적어도 두개의 산소원자, 연결 산소 및 연결그룹의 연결산소원자가 상기 긴 사슬의 지방족 하이드로카빌 성분 중 탄소원자와 그 연결그룹중 나머지의 탄소원자에 공유로 결합되는 하이드록실 산소를 가지며, 상기 긴 사슬의 지방족 하이도록카빌 성분은 상기 첨가제가 가솔린이나 디젤범위에서 끓는 탄소수소에 가용성인 충분한 분자량과 사슬길이로 된 것으로 구성되는 긴 사슬의 지방족 하이드록카빌 아민 첨가제.
  2. 제1항에 있어서, 상기 아민성분이 강산에 의하여 적정가능한 적어도 1개의 염기성 질소원자인 첨가제.
  3. 제2항에 있어서, 상기 긴-사슬 지방족 하이드로카빌 성분이 적어도 약 50개 탄소원자들을 가지는 첨가제.
  4. 제3항에 있어서, 상기 아민성분 중에서 적어도 한개의 염기성 질소원자가 일급이나 이급 아민그룹으로 된 첨가제.
  5. 제3항에 있어서, 아민성분이, 1 : 1과 10 : 1사이의 탄소 : 질소 비율로 2개 내지 12개 아민 질소원자를 가지는 폴리아민과 2개 내지 40개 탄소원자로부터 얻어지는 첨가제.
  6. 제65항에 있어서, 상기 폴리아민이(A)수소, (B)1개 내지 약 10개 탄소원자의 하이드로 카빌그룹, (C)2개 내지 약10개 탄소 원자의 아실그룹과 (D), (B)와 (C)의 모노케토, 모노하이드록시, 모노니트로, 모노시아노, 저급알킬과 저급알콕시 유도체들로부터 선택된 치한체들에 의해서 치환된 폴리아민인 첨가제.
  7. 제5항에 있어서, 상기 폴리아민이 알킬렌 그룹은 2내지 6개 탄소원자를 함유하고 폴리아민은 2내지 12개 아민 질소원자와 2내지 24개 탄소원자를 함유하는 폴리알킬렌 폴리아민인 첨가제.
  8. 제7항에 있어서, 상기 폴리 알킬렌 폴리아민이 에틸렌디아민, 프로필렌디아민, 부틸렌디아민, 펜틸렌디아민, 헥실렌디아민, 디에틸 트리아민, 디프로필렌 트리아민, 트리에틸렌 테트라민, 테트라에틸렌 펜타민과 1,3-디아미노 프로판으로 구성되는 그룹으로부터 선택되는 첨가제.
  9. 제8항에 있어서, 상기 지방족 하이드로 카빌 성분이 약 700내지 약 3,000의 평균 분자량을 갖는 중합탄화수소로 구성되는 첨가제.
  10. 제9항에 있어서, 상기 지방족 하이드로카빌 성분이 평균 분자량 약 900내지 2,000을 갖는 폴리이소부틸렌으로 구성되는 첨가제.
  11. 제10항에 있어서, 상기 폴리아민이 에틸렌디아민, 디에틸렌 트리아민, 트리에틸렌 테트라민, 테트파에틸렌 펜타민, 또는 1,3-디아미노 프로판인 첨가제.
  12. 제11항에 있어서, 상기 연결그룹이 -OCH2CHOHCH2-이거나또는 이것들의 혼합물인 첨가제.
  13. 제12항에 있어서, 상기 지방족 하이드로카빌 성분이 평균 분자량 약 950내지 약 1,600을 갖는 폴리이소부틴렌으로 구성되는 첨가제.
  14. 제13항에 있어서, 상기 폴리아민이 에틸렌디아민이나 디에틸렌 트리아민인 첨가제.
  15. 제14항에 있어서, 상기 지방족 하이드로카빌 성분이 평균분자량 약 950을 갖는 첨가제.
  16. 제14항에 있어서, 상기 지방족 하이드로카빌 성분이 약 1300의 평균 분자량을 갖는 첨가제.
  17. 일반식 R-X-Am의 긴 사슬의 지방족 하이드로카빌 아민 첨가제: 이 식에서, R은 적어도 50개 탄소원자의 사슬길이를 갖는 지방족 하이드로카빌 성분이고: Am은 적어도 한개의 염기성 질소원자를 갖는 아민성분이며, X는 -OCH2CHOHCH2-와또는 이것들의 혼합물에서 선택되는 일반식의 연결그룹이다.
  18. 제17항에 있어서, X가 주로 -OCH2CHOHCH2-인 첨가제.
  19. 제18항에 있어서, R이 폴리이소부틸렌이나 폴리프로필렌인 첨가제.
  20. 제19항에 있어서, Am이 에틸렌디아민, 디에틸렌 트리아민, 트리에틸렌 테트라민, 테트라에틸렌펜타민, 또는 1,3-디아미노 프로판으로부터 선택되는 첨가제.
  21. 제20항에 있어서, R이 평균 분자량 약 900내지 약 2000을 갖는 폴리이소부틸렌인 첨가제.
  22. 제21항에 있어서, Am이 에틸렌 디아민이나 디에틸렌 트리아민인 첨가제.
  23. 제22항에 있어서, R이 폴리이소부틸-24나 폴리이소부틸-32인 첨가제.
  24. 다음일반식 R-O-CH2CHOHCH2-NHpH와또는 이것들의 혼합물로부터 선택되는 긴 사슬의 지방족 하이드로카빌 아민 첨가제, 상기식에서, R은 적어도 50개 탄소원자의 평균사슬 길이를 갖는 지방족 하이드로카빌 성분이고 : R1은 2내지 6개 탄소원자의 알킬렌이고 p는 1내지 6의 정수이다.
  25. 제24항에 있어서, R이 폴리프로필, 폴리부틸 또는 폴리이소부틸인 화합물.
  26. 제25항에 있어서, R이 평균분자량의 약 700내지 약3000을 갖는 폴리이소부틸렌인 화합물.
  27. 제26항에 있어서, R1이 에틸렌인 첨가제.
  28. 제27항에 있어서, p는 1이거나 2인 첨가제.
  29. 제28항에 있어서, R이 폴리이소부틸-24이거나 폴리이소부틸-32인 첨가제.
  30. 가솔린이나 디젤범위의 비점의 탄화수소와 제1항에 따른 첨가제 약 30내지 약 5000ppm으로 구성되는 원료 조성물.
  31. 가솔린이나 디젤범위의 타화수소와 약 30내지 약5000ppm의 제17항에 의한 첨가제로 구성되는 연료조성물.
  32. 가솔린이나 디젤범위의 탄화수소와 약 30내지 약5000ppm의 제24항에 의한 첨가제로 구성되는 연료조성물.
  33. 가솔린이나 디젤범위의 탄화수소와 약 30내지 약5000ppm의 제29항에 의한 첨가제로 구성되는 연료조성물.
  34. 150℉ 내지 400℉범위의 불활성의 안정한 친유성 유기용매와 약5내지 약50%중량의 제1항에 의한 첨가제로 구성되는 연료농축물.
  35. 150℉ 내지 400℉범위의 불활성의 안정한 친유성 유기용매와 약5내지 약50%중량의 제17항에 의한 첨가제로 구성되는 연료농축물.
  36. 150℉ 내지 400℉범위의 불활성의 안정한 친유성 유기용매와 약5내지 약50%중량의 제24항에 의한 첨가제로 구성되는 연료농축물.
  37. 150℉ 내지 400℉범위의 불활성의 안정한 친유성 유기용매와 약5내지 약50%중량의 제36항에 의한 첨가제로 구성되는 연료농축물.
  38. 윤활점성의 오일과 제1항에 의한 분산에 효과적인 양의 첨가제로 구성되는 윤활유 조성물.
  39. 윤활점성의 오일과 제17항에 의한 분산에 효과적인 양의 첨가제로 구성되는 윤활유 조성물.
  40. 윤활점성의 오일과 제24항에 의한 분산에 효과적인 양의 첨가제로 구성되는 윤활유 조성물.
  41. 윤활점성의 오일과 제27항에 의한 분산에 효과적인 양의 첨가제로 구성되는 윤활유 조성물.
  42. 약 90내지 약50중량퍼센트의 윤활점성의 오일과 약 10내지 약 50중량%의 제1항에 의한 첨가제로 구성되는 윤활유 농축물.
  43. 약 90내지 약50중량퍼센트의 윤활점성의 오일과 약 10내지 약 50중량%의 제17항에 의한 첨가제로 구성되는 윤활유 농축물.
  44. 약 90내지 약50중량퍼센트의 윤활점성의 오일과 약 10내지 약 50중량%의 제24항에 의한 첨가제로 구성되는 윤활유 농축물.
  45. 약 90내지 약50중량퍼센트의 윤활점성의 오일과 약 10내지 약 50중량%의 제29항에 의한 첨가제로 구성되는 윤활유 농축물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900700964A 1988-09-09 1989-09-08 옥시-알킬렌 하이드록시 연결그룹을 갖는 긴 사슬의 지방족 하이드로카빌 아민 첨가제 KR0143779B1 (ko)

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US242,756 1988-09-09
US242.756 1988-09-09
US07/242,756 US4975096A (en) 1988-09-09 1988-09-09 Long chain aliphatic hydrocarbyl amine additives having an oxyalkylene hydroxy connecting group
PCT/US1989/003902 WO1990002784A1 (en) 1988-09-09 1989-09-08 Long chain aliphatic hydrocarbyl amine additives having an oxy-alkylene hydroxy connecting group

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KR0143779B1 (ko) 1998-07-01
ATE163034T1 (de) 1998-02-15
EP0406343A4 (en) 1991-05-08
EP0406343B1 (en) 1998-02-04
WO1990002784A1 (en) 1990-03-22
JP2854906B2 (ja) 1999-02-10
US4975096A (en) 1990-12-04
DE68928577D1 (de) 1998-03-12

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