KR900016386A - 개선된 열 안정성을 갖는 아크릴아미드 폴리실옥산 조성물 - Google Patents

개선된 열 안정성을 갖는 아크릴아미드 폴리실옥산 조성물 Download PDF

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Publication number
KR900016386A
KR900016386A KR1019900004887A KR900004887A KR900016386A KR 900016386 A KR900016386 A KR 900016386A KR 1019900004887 A KR1019900004887 A KR 1019900004887A KR 900004887 A KR900004887 A KR 900004887A KR 900016386 A KR900016386 A KR 900016386A
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South Korea
Prior art keywords
thermal stability
polydiorganosiloxane
acrylamide
acrylamide functional
stability additive
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KR1019900004887A
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English (en)
Inventor
앤드류 루츠 마이클
안드리아 슈베르트 크리스텐
Original Assignee
노만 에드워드 루이스
다우 코닝 코포레이션
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Application filed by 노만 에드워드 루이스, 다우 코닝 코포레이션 filed Critical 노만 에드워드 루이스
Publication of KR900016386A publication Critical patent/KR900016386A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/057—Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Silicon Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymerisation Methods In General (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음.

Description

개선된 열 안정성을 갖는 아크릴아미드 폴리실옥산 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 분자당 아크릴아미드 작용기를 평균 약 0.4이상 함유하고 감광화 시스템의 존재하에 자외선 방사시켜 가교걸합 가능한 폴리오가노실옥산, 및 나프텐산 아연, 옥토산 제1주석 및 테트라오가노티탄산염 중에서 선택된 열 안정성 첨가제 유효량 및 감광화 시스템 유효량을 포함하는 조성물.
  2. 제1항에 있어서, 폴리디오가노실옥산이 (A) 일반식(a)의 아크릴아미드 작용성 말단차단된 폴리디오가노실옥산 4 내지 90몰%, (B) 일반식(b)의 모노아크릴아미드 작용성 말단 차단된 폴리디오가노실옥산 9 내지 50몰% 및 (C) 일반식(c)의 비작용성 폴리디오가노실옥산 0 내지 65몰%의 배합물(배합물의 폴리디오가노실옥산은 아크릴아미드 작용기로서 말단차단제 20 내지 95% 및 비작용기로서 말단차단제 5 내지 80%를 제공하는 양으로 존재한다)인 조성물.
    상기식에서, R은 알킬, 아릴 및 플루오르화 알킬중에서 선택된 1가 라디칼이고; R′는 각각 독립적으로 R, 하이드록실 및 가수분해 가능한 그룹중에서 선택되며; Y는 아크릴아미드 작용기가 하기 일반식을 갖는, 실리콘-탄소 결합을 통해 실리콘 원자에 결합된 아크릴아미드 작용성 라디칼이고, n은 총 배합몰 100몰%를 기준으로 하여 30 내지 3000몰% 값이다.
    (여기에서, R″는 수소원자 또는 메틸이며; R2는 수소원자 또는 탄소수 1 내지 4의 알킬이고; R3은 라디칼당 탄소수가 1 내지 10인 2가 탄화수소 라디칼이며; R*은 2가 탄화수소 라디칼 또는 에테르 결합을 함유하는 2가 탄화수소 라디칼이다.)
  3. 제1항에 있어서, 열 안정성 첨가제가 나프텐산 아연인 조성물.
  4. 제1항에 있어서, 열 안정성 첨가제가 오가노티탄산 염인 조성물.
  5. 제1항에 있어서, 열 안정성 첨가제가 옥토산 제1주석인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900004887A 1989-04-10 1990-04-10 개선된 열 안정성을 갖는 아크릴아미드 폴리실옥산 조성물 KR900016386A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/335,639 US5036114A (en) 1989-04-10 1989-04-10 Acrylamide polysiloxane composition with improved heat stability
US335639 1989-04-10

Publications (1)

Publication Number Publication Date
KR900016386A true KR900016386A (ko) 1990-11-13

Family

ID=23312636

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900004887A KR900016386A (ko) 1989-04-10 1990-04-10 개선된 열 안정성을 갖는 아크릴아미드 폴리실옥산 조성물

Country Status (7)

Country Link
US (1) US5036114A (ko)
EP (1) EP0400786B1 (ko)
JP (1) JP2518952B2 (ko)
KR (1) KR900016386A (ko)
AU (1) AU623761B2 (ko)
CA (1) CA2013472A1 (ko)
DE (1) DE69022483T2 (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2013012A1 (en) * 1989-04-10 1990-10-10 Michael A. Lutz Ultraviolet cured gels with controlled modulus and viscosity
CA2013020A1 (en) * 1989-04-10 1990-10-10 Michael A. Lutz Ultraviolet curable phenyl containing acrylamide compositions
US5237082A (en) * 1989-09-22 1993-08-17 Minnesota Mining And Manufacturing Company Radiation-curable silicone elastomers and pressure sensitive adhesives
AU630732B2 (en) * 1989-09-22 1992-11-05 Minnesota Mining And Manufacturing Company Radiation-curable silicone elastomers and pressure sensitive adhesives
DE69131694T2 (de) 1990-12-28 2000-11-30 Dow Corning Verfahren zur Sichtbarmachung der Härtung einer UV-härtbaren Zusammensetzung durch Farbänderung
US5246979A (en) * 1991-05-31 1993-09-21 Dow Corning Corporation Heat stable acrylamide polysiloxane composition
EP0678542B1 (en) * 1994-04-20 1999-07-07 Three Bond Co., Ltd. Photocurable silicone composition
US5502144A (en) * 1994-07-15 1996-03-26 University Of Cincinnati Composition and method for preparing silicone elastomers
JP3177410B2 (ja) * 1995-07-17 2001-06-18 信越化学工業株式会社 放射線硬化性オルガノポリシロキサン組成物
KR20130064733A (ko) * 2010-03-26 2013-06-18 이 아이 듀폰 디 네모아 앤드 캄파니 폴리아릴렌 설파이드-함유 중합체 용융물

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2929829A (en) * 1956-10-12 1960-03-22 Union Carbide Corp Organosilicon acylamino compounds and process for producing the same
JPS5124377B2 (ko) * 1972-12-18 1976-07-23
US4070343A (en) * 1975-09-26 1978-01-24 Toray Silicone Company, Ltd. Heat stable organopolysiloxane composition
DE2917754A1 (de) * 1979-05-02 1980-11-13 Wacker Chemie Gmbh Hydrophile, vernetzte, modifizierte organopolysiloxane verfahren zu ihrer herstellung und ihre verwendung
EP0117360A1 (en) * 1982-12-27 1984-09-05 Dow Corning Corporation Aqueous compositions containing siloxane and a metallorganic additive
US4507384A (en) * 1983-04-18 1985-03-26 Nippon Telegraph & Telephone Public Corporation Pattern forming material and method for forming pattern therewith
US4608270A (en) * 1985-10-25 1986-08-26 Dow Corning Corporation Acylamino silicon compounds, their use and preparation
US4697026A (en) * 1986-01-06 1987-09-29 Dow Corning Corporation Acryl functional silicone compounds
JPS62197453A (ja) * 1986-02-25 1987-09-01 Shin Etsu Chem Co Ltd シリコ−ン組成物
US4831064A (en) * 1986-12-22 1989-05-16 Dow Corning Corporation Organopolysiloxane compositions curable by ultraviolet radiation
US4824875A (en) * 1987-11-06 1989-04-25 Dow Corning Corporation UV curable conformal coating with moisture shadow cure
US5008301A (en) * 1989-02-21 1991-04-16 Dow Corning Corporation Ultraviolet curing conformal coating with dual shadow cure
CA2013012A1 (en) * 1989-04-10 1990-10-10 Michael A. Lutz Ultraviolet cured gels with controlled modulus and viscosity
CA2013020A1 (en) * 1989-04-10 1990-10-10 Michael A. Lutz Ultraviolet curable phenyl containing acrylamide compositions

Also Published As

Publication number Publication date
EP0400786A3 (en) 1991-09-25
JP2518952B2 (ja) 1996-07-31
DE69022483D1 (de) 1995-10-26
CA2013472A1 (en) 1990-10-10
AU623761B2 (en) 1992-05-21
DE69022483T2 (de) 1996-05-09
EP0400786A2 (en) 1990-12-05
JPH02294315A (ja) 1990-12-05
AU5299690A (en) 1990-10-11
US5036114A (en) 1991-07-30
EP0400786B1 (en) 1995-09-20

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