KR900009674A - 유기 금속 화합물을 및/또는 금속 카르보닐을 그들의 유기 매체 용액으로부터 분리하는 방법 - Google Patents

유기 금속 화합물을 및/또는 금속 카르보닐을 그들의 유기 매체 용액으로부터 분리하는 방법 Download PDF

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KR900009674A
KR900009674A KR1019890018377A KR890018377A KR900009674A KR 900009674 A KR900009674 A KR 900009674A KR 1019890018377 A KR1019890018377 A KR 1019890018377A KR 890018377 A KR890018377 A KR 890018377A KR 900009674 A KR900009674 A KR 900009674A
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membrane
organic medium
polyaramid
organometallic compounds
solution
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KR930002965B1 (ko
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바흐르만 헬무트
하웁스 미카엘
크로이디 빌리
뮐레 토마스
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콘콜, 라이첼트
훽스트 악치엔 게젤샤프트
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Abstract

내용 없음

Description

유기 금속 화합물을 및/또는 금속 카르보닐을 그들의 유기 매체 용액으로부터 분리하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 용액을 방향족 폴리아미드(폴리아라미드)로 제조된 반투과성막과 접촉시키는 것을 특징으로 하는, 유기 금속화합물 및/또는 금속 카르보닐을 그들의 유기매체용액으로부터 분리하는 방법.
  2. 청구범위 제 1항에 있어서, 가압하에 용액을 반투과성막과 접촉시키는 것을 특징으로 하는 방법.
  3. 청구범위 제 1항에 있어서, 유기금속화합물 및/또는 금속 카르보닐의 분리를 반투과성막을 이용하여 투석으로써 하는 방법.
  4. 청구범위 제 1항 내지 제 3항중 어느 한 항에 있어서, 막이 랜덤 또는 블록 코폴리아라미드로 이루어짐을 특징으로 하는 방법.
  5. 청구범위 제 1항 내지 제 4항중 어느 한 항에 있어서, 단량체 성분으로서 테레프탈산, P-페닐렌디아민, 1. 4-비스(4-아미노페녹시)벤젠 및 3, 31-디메틸벤지딘으로부터 폴리아라미드가 합성됨을 특징으로 하는 방법.
  6. 청구범위 제 1항 내지 제 5항 중 어느 한 항에 있어서, 폴리아라미드의 평균중량으로서 주어진 분자량이 5,000 내지 200,000, 바람직하게는 10,000 내지 50,000임을 특징으로 하는 방법.
  7. 청구범위 제 1항 내지 제 6항 중 어느 한 항에 있어서, 막이 모세관 또는 중공섬유형태를 가짐을 특징으로 하는 방법.
  8. 청구범위 제 1항 내지 제 7항 중 어느 한 항에 있어서, 막의 분리층의 두께가 0.05 내지 5μ임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890018377A 1988-12-20 1989-12-12 유기 금속 화합물 및/또는 금속 카르보닐을 그들의 유기 매체 용액으로부터 분리하는 방법 KR930002965B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3842819A DE3842819A1 (de) 1988-12-20 1988-12-20 Verfahren zur abtrennung von metallorganischen verbindungen und/oder metallcarbonylen aus ihren loesungen in organischen medien
DEP3842819.9 1988-12-20
DE3842819 1988-12-20

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KR930002965B1 KR930002965B1 (ko) 1993-04-16

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EP (1) EP0374615B1 (ko)
JP (1) JPH02231435A (ko)
KR (1) KR930002965B1 (ko)
AT (1) ATE141923T1 (ko)
AU (1) AU621968B2 (ko)
BR (1) BR8906575A (ko)
CA (1) CA2006021C (ko)
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Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5288818A (en) * 1991-08-20 1994-02-22 Exxon Chemical Patents Inc. Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5215667A (en) * 1991-08-20 1993-06-01 Exxon Chemical Patents Inc. Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
GB9119955D0 (en) * 1991-09-18 1991-10-30 Imperial College Treatment of aqueous supplies containing organic material
EP0539870B1 (de) * 1991-10-26 1996-08-28 Hoechst Aktiengesellschaft Hydrophile, asymmetrische, chemikalienbeständige Polyaramidmembran
IT1256360B (it) * 1992-09-01 1995-12-01 Enichem Spa Processo per la separazione di catalizzatori in soluzioni organiche per mezzo di membrane semipermeabili
US5395979A (en) * 1993-02-25 1995-03-07 Exxon Chemical Patents Inc. Method for separating catalyst from a hydroformylation reaction product using alkylated ligands
US5298669A (en) * 1993-03-23 1994-03-29 Exxon Chemical Patent Inc. Perstraction sweep stream for a membrane reactor
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
DE19619527A1 (de) * 1996-05-15 1997-11-20 Hoechst Ag Katalysatorsysteme auf der Basis von Rhodium-Komplexverbindungen mit Diphosphin-Liganden und ihre Verwendung bei der Herstellung von Aldehyden
US5618436A (en) * 1996-02-16 1997-04-08 Condea Vista Company Process for clarifying metal alkyls
DE19609337C2 (de) * 1996-03-11 1998-11-19 Hoechst Ag Verfahren zur Herstellung von Aldehyden mittels eines Rhodium und substituierte Diphenyldiphosphane enthaltenden Katalysatorsystems
EP0810029B1 (de) * 1996-05-15 2001-11-14 Celanese Chemicals Europe GmbH Verfahren zur Herstellung von Aldehyden
DE19619528A1 (de) * 1996-05-15 1997-11-20 Hoechst Ag Substituierte Diphosphine und ein Verfahren zu ihrer Herstellung
EP0823282B1 (de) * 1996-05-15 2001-11-14 Celanese Chemicals Europe GmbH Verfahren zur Herstellung von Aldehyden
EP1065194B2 (en) 1999-07-02 2007-03-28 Mitsubishi Gas Chemical Company, Inc. Production of tricyclodecane dicarbaldehyde, pentacyclopentadecane dicarbaldehyde and corresponding dimethanols
EP1532094A1 (de) 2002-08-31 2005-05-25 Oxeno Olefinchemie GmbH Verfahren zur hydroformylierung von olefinisch ungesättigten verbindungen, insbesondere olefinen in gegenwart cyclischer kohlensäureester
DE102006003618A1 (de) * 2006-01-26 2007-08-02 Oxeno Olefinchemie Gmbh Verfahren zur Abtrennung von Metall-Komplexkatalysatoren aus Telomerisationsgemischen
GB2437519B (en) * 2006-04-28 2010-04-21 Imp Innovations Ltd Method for separation
GB201012083D0 (en) 2010-07-19 2010-09-01 Imp Innovations Ltd Thin film composite membranes for separation
GB201012080D0 (en) 2010-07-19 2010-09-01 Imp Innovations Ltd Asymmetric membranes for use in nanofiltration
GB201117950D0 (en) 2011-10-18 2011-11-30 Imp Innovations Ltd Membranes for separation
DE102012223572A1 (de) * 2012-12-18 2014-06-18 Evonik Industries Ag Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren
DE102013215004A1 (de) * 2013-07-31 2015-02-05 Evonik Industries Ag Membrankaskade mit sinkender Trenntemperatur
TWI669317B (zh) 2014-09-22 2019-08-21 德商贏創德固賽有限責任公司 反應性單體的改良製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1266180A (ko) * 1969-12-19 1972-03-08
US3853754A (en) * 1972-07-20 1974-12-10 Du Pont Membrane separation of homogeneous catalysts from nitrile solutions
US3966595A (en) * 1972-07-20 1976-06-29 E. I. Du Pont De Nemours And Company Method of making group VIII metal complex compounds
US3957504A (en) * 1974-11-11 1976-05-18 Allied Chemical Corporation Membrane hydro-metallurgical extraction process
US4544484A (en) * 1983-06-24 1985-10-01 E. I. Du Pont De Nemours And Company Reverse osmosis membrane quenching
DE3802030A1 (de) * 1988-01-25 1989-07-27 Hoechst Ag Makroporoese, asymmetrische, hydrophile membran aus polyaramid

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AU4685889A (en) 1990-06-28
USRE35292E (en) 1996-07-09
DE58909716D1 (de) 1996-10-02
HUT52709A (en) 1990-08-28
CA2006021A1 (en) 1990-06-20
JPH02231435A (ja) 1990-09-13
EP0374615A3 (de) 1991-05-02
CA2006021C (en) 1996-06-11
EP0374615B1 (de) 1996-08-28
ATE141923T1 (de) 1996-09-15
EP0374615A2 (de) 1990-06-27
BR8906575A (pt) 1990-09-04
HU202771B (en) 1991-04-29
ES2092471T3 (es) 1996-12-01
KR930002965B1 (ko) 1993-04-16
DE3842819A1 (de) 1990-06-21
JPH0480013B2 (ko) 1992-12-17
HU896491D0 (en) 1990-03-28
US5174899A (en) 1992-12-29
AU621968B2 (en) 1992-03-26

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