KR900006450A - 작용화된 에틸렌-알파-올레핀 공중합체와 폴리프로필렌의 그래프트 중합체 그의 제조방법 및 폴리프로필렌 조성물에서의 그의 용도 - Google Patents
작용화된 에틸렌-알파-올레핀 공중합체와 폴리프로필렌의 그래프트 중합체 그의 제조방법 및 폴리프로필렌 조성물에서의 그의 용도 Download PDFInfo
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- KR900006450A KR900006450A KR1019890015550A KR890015550A KR900006450A KR 900006450 A KR900006450 A KR 900006450A KR 1019890015550 A KR1019890015550 A KR 1019890015550A KR 890015550 A KR890015550 A KR 890015550A KR 900006450 A KR900006450 A KR 900006450A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (18)
- 하나 또는 그 이상의 작용성 결합을 통해 폴리프로필렌이 그래프트된, 작용화된 에틸렌-α-올레핀 공중합체를 포함하는 그래프트 공중합체 조성물.
- 제1항에 있어서, 상기 작용화된 에틸렌-α-올레핀 공중합체가 에틸렌, 프로필렌 및 적어도 하나의 작용기 함유 단량체를 포함하며, 상기 작용기가 하이드록시, 1차 아미노 및 2차 아미노로 이루어진 그룹으로부터 선택되는 조성물.
- 제2항에 있어서, 상기 작용화된 에틸렌-α-올레핀 공중합체가 적어도 하나의 디엔 단량체를 추가로 포함하는 조성물.
- 제1항에 있어서, 상기 폴리프로필렌이 이소택틱 폴리프로필렌을 포함하는 조성물.
- 제3항에 있어서, 상기 폴리프로필렌이 이소택틱 폴리프로필렌을 포함하는 조성물.
- 작용화된 중합체 적어도 일부를 폴리프로필렌으로 그래프트시키기에 충분한 조건하에서, 작용화된 에틸렌-α-올레핀 공중합체를 말리에이트화된 폴리프로필렌과 배합함을 포함하는 그래프트 공중합체 조성물의 제조방법.
- 제6항에 있어서, 상기 작용화된 공중합체가 에틸렌, 프로필렌 및 적어도 하나의 작용기 함유 단량체를 포함하는 방법.
- 제6항에 있어서, (A) 상기 작용화된 에틸렌-α-올레핀 공중합체를 생성하기에 충분한 중합조건하에, 랜덤 공중합체를 생성하는 능력면에서 선택한 비-입체특이성 지글러-나타(Ziegler-Natta)촉매 시스템의 존재하에서, 에틸렌, 적어도 하나의 α-올레핀 단량체 및 적어도 하나의 작용기 함유 단량체를 배합하는 단계; 및 (B) 작용화된 공중합체 적어도 일부를 말리에이트화된 폴리프로필렌으로 그래프트시키기에 충분한 조건하에서, 상기 단계(A)에 따라 제조한 중합체 조성물을 말리에이트화된 폴리프로필렌 조성물과 배합하는 단계를 포함하는 방법.
- 제8항에 있어서, 적어도 하나의 디엔 단량체를 사기 단계(A)에 따라 추가로 배합하여 상기 작용화된 에틸렌-α-올레핀 공중합체를 생성하는 방법.
- 제8항에 있어서, 상기 비-입체특이성 지글러-나타 촉매 시스템이 탄화수소 가용성 바나듐염 및 알루미늄 알킬을 포함하는 방법.
- 제9항에 있어서, 상기 비-입체특이성 지글러-나타 촉매 시스템이 탄화수소 가용성 바나듐염 및 알루미늄 알킬을 포함하는 방법.
- 제10항에 있어서, 상기 배합단계(A)를 실질적으로 혼합이 자유로운 관형 반응기에서 수행하는 방법.
- 제11항에 있어서, 상기 배합단계(A)를 실질적으로 혼합이 자유로운 관형 반응기에서 수행하는 방법.
- 하나 또는 그 이상의 작용성 결합을 통해 폴리프로필렌이 그래프트된, 작용화된 에틸렌-α-올레핀 공중합체를 포함하는 그래프트 공중합체 조성물 및 이소택틱 폴리프로필렌을 포함하는 폴리프로필렌 블랜드 조성물.
- 제14항에 있어서, 에틸렌-프로필렌 고무를 추가로 포함하는 폴리프로필렌 블렌드 조성물.
- 제14항에 있어서, 상기 작용화된 에틸렌-α-올레핀 공중합체가 에틸렌 20 내지 90중량%, α-올레핀 10 내지 80중량%, 디엔 단량체 0 내지 15중량% 및 극성 작용기 함유 단량체 0.01 내지 15중량%를 포함하며, 상기 그래프트 하기전의 상기 그래프트 폴리프로필렌이 말리에이트화된 폴리프로필렌인 폴리프로필렌 블렌드 조성물.
- 제15항에 있어서, 상기 작용화된 에틸렌-α-올레핀 공중합체가 에틸렌 20 내지 90중량%, α-올레핀 10 내지 80중량%, 디엔 단량체 0 내지 15중량% 및 극성 작용기 함유 단량체 0.01 내지 15중량%를 포함하며, 상기 그래프트 하기전의 상기 그래프트 폴리프로필렌이 말리에이트화된 폴리프로필렌인 폴리프로필렌 블렌드 조성물.
- 제16항 또는 17항에 있어서, 상기 이소택틱 폴리프로필렌이 45 내지 98중량%의 양으로 존재하고, 상기 에틸렌-프로필렌 고무가 0 내지 50중량%의 양으로 존재하며, 상기 그래프트 공중합체 조성물이 0.1 내지 25중량%의 양으로 존재하는 폴리프로필렌 블렌드 조성물(상기 모든 중량%는 폴리프로필렌 블렌드조성물의 총 중량을 기준으로 함).※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US264,484 | 1988-10-28 | ||
US07/264,484 US4999403A (en) | 1988-10-28 | 1988-10-28 | Graft polymers of functionalized ethylene-alpha-olefin copolymer with polypropylene, methods of preparation, and use in polypropylene compositions |
Publications (1)
Publication Number | Publication Date |
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KR900006450A true KR900006450A (ko) | 1990-05-08 |
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Application Number | Title | Priority Date | Filing Date |
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KR1019890015550A KR900006450A (ko) | 1988-10-28 | 1989-10-27 | 작용화된 에틸렌-알파-올레핀 공중합체와 폴리프로필렌의 그래프트 중합체 그의 제조방법 및 폴리프로필렌 조성물에서의 그의 용도 |
Country Status (7)
Country | Link |
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US (1) | US4999403A (ko) |
EP (1) | EP0366412A3 (ko) |
JP (1) | JPH02170826A (ko) |
KR (1) | KR900006450A (ko) |
AU (1) | AU4383189A (ko) |
BR (1) | BR8905504A (ko) |
CA (1) | CA2000655A1 (ko) |
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JPS5847402B2 (ja) * | 1976-02-13 | 1983-10-22 | 三井化学株式会社 | 成形用重合体組成物およびその製法 |
NL267816A (ko) * | 1960-08-04 | |||
NL290711A (ko) * | 1962-03-28 | 1900-01-01 | Shell Int Research | |
US3268624A (en) * | 1962-11-29 | 1966-08-23 | Avisun Corp | Block copolymers of ethylene and propylene |
US3318976A (en) * | 1965-12-03 | 1967-05-09 | Shell Oil Co | Production of modified polyolefin |
US3454675A (en) * | 1966-03-21 | 1969-07-08 | Phillips Petroleum Co | Process for preparing block copolymers of olefins |
US3483273A (en) * | 1966-03-31 | 1969-12-09 | Ppg Industries Inc | Graft copolymers of unsaturated hydrocarbon interpolymers |
GB1222860A (en) * | 1967-12-15 | 1971-02-17 | Allied Chem | Grafted block copolymers of synthetic rubbers and polyolefins |
NL7001827A (ko) * | 1970-02-10 | 1971-08-12 | ||
US3879494A (en) * | 1971-02-22 | 1975-04-22 | Cpc International Inc | Polyblends of chemically joined, phase separated thermoplastic graft copolymers |
US4113802A (en) * | 1974-11-14 | 1978-09-12 | Montedison S.P.A. | Process for preparing polypropylene compositions having high impact strength at low temperatures |
NL8200049A (nl) * | 1982-01-08 | 1983-08-01 | Stamicarbon | Thermoplastisch propeenblokcopolymeer. |
US4540753A (en) * | 1983-06-15 | 1985-09-10 | Exxon Research & Engineering Co. | Narrow MWD alpha-olefin copolymers |
US4806581A (en) * | 1983-10-12 | 1989-02-21 | Occidental Chemical Corporation | Graft polymers of polymerizable monomers and olefin polymers |
-
1988
- 1988-10-28 US US07/264,484 patent/US4999403A/en not_active Expired - Fee Related
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1989
- 1989-10-13 CA CA002000655A patent/CA2000655A1/en not_active Abandoned
- 1989-10-24 EP EP19890310946 patent/EP0366412A3/en not_active Withdrawn
- 1989-10-27 BR BR898905504A patent/BR8905504A/pt unknown
- 1989-10-27 AU AU43831/89A patent/AU4383189A/en not_active Abandoned
- 1989-10-27 KR KR1019890015550A patent/KR900006450A/ko not_active Application Discontinuation
- 1989-10-30 JP JP1280034A patent/JPH02170826A/ja active Pending
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EP0366412A3 (en) | 1992-01-29 |
EP0366412A2 (en) | 1990-05-02 |
JPH02170826A (ja) | 1990-07-02 |
US4999403A (en) | 1991-03-12 |
CA2000655A1 (en) | 1990-04-28 |
BR8905504A (pt) | 1990-05-29 |
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