KR900005975B1 - Method for producing kaolin-bricks - Google Patents

Method for producing kaolin-bricks

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Publication number
KR900005975B1
KR900005975B1 KR1019880005560A KR880005560A KR900005975B1 KR 900005975 B1 KR900005975 B1 KR 900005975B1 KR 1019880005560 A KR1019880005560 A KR 1019880005560A KR 880005560 A KR880005560 A KR 880005560A KR 900005975 B1 KR900005975 B1 KR 900005975B1
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Prior art keywords
kaolin
agent
cement
bricks
brick
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KR1019880005560A
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Korean (ko)
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KR890017195A (en
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남상채
남기만
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남상채
남기만
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Publication of KR900005975B1 publication Critical patent/KR900005975B1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The kaolin bricks are prepared by the stages of mixing 80 wt.% admixture and 20 wt.% mixing solution, moulding and drying. The admixture consists of 85-90 wt.% kaolin powder of no more than 0.01-1 mm particle size, 4-6 wt.% cement having C3S of at least 50% and 0.01-0.02 wt.% at least one of Al, Zn and CaC2. The mixing solution contains 0.03-0.06 wt.% air-entraining agent e.g. Na2SiO3, 0.03 wt.% Na2SiF6 and 0.06 wt.% CaCl2 as waterproofing agent to the weight of cement.

Description

고령토벽돌 제조방법Kaolin Brick Manufacturing Method

본 발명은 건축용 단열벽돌로 이용되는 고령토벽돌 제조방법에 관한 것이다.The present invention relates to a kaolin brick manufacturing method used as a building insulation brick.

지금까지 벽돌의 제조를 위해 대한민국 특허공보 제201,244, 336,429, 480, 510, 1014,1190 및 1210호 등에 제시된 바와 같이 여러가지 방법이 알려졌으나 포졸란(pozzolan)으로 고령토를 사용한 방법은 제시된바 없으며 특히 이를 이용한 단열성의 개량은 더욱더 언급된 바와 없다.Until now, various methods have been known as shown in Korean Patent Publication Nos. 201,244, 336,429, 480, 510, 1014,1190 and 1210 for the manufacture of bricks, but the method of using kaolin as pozzolan has not been proposed, No improvement in thermal insulation is mentioned.

본 발명은 이상 각각의 특허공보에 제시한 제조방법과는 상이하며 고령토성분을 포졸란으로 사용하였고 여기에 기포를 분산시켜서 분리 존재할 수 있도록 하기 위한 AE제로서 계면활성제, 빈졸레진, 다렉스 푸로렉스 뉴-레스 등의 20%수용액을 시멘트중량에 대해서 0.03-0.06%정도 가하고 발포제로서는 Al, PE발포제, CaC2등의 분말을 시멘트에 대해서 0.01-0.02와 경화제로서 1% Na2SiO3수용액 적당량과 방수제로서 Na2SiF6을 시멘트에 대해 0.03%와 CaCl20.06%를 첨가하여 단열성 방수성이 우수한 고령토벽돌을 제조하는데 있다.The present invention is different from the manufacturing method described in each of the above patent publications, and the kaolin component is used as pozzolanic, and as an AE agent for dispersing and dispersing bubbles therein, surfactants, vinzolesine, and Darex Furex New -Add 20% aqueous solution such as LES to 0.03-0.06% by weight of cement.As a foaming agent, Al, PE foaming agent, CaC 2 and other powders are 0.01-0.02 to cement and 1% Na 2 SiO 3 aqueous solution as hardener and waterproofing agent. Na 2 SiF 6 is added to 0.03% of CaCl 2 and 0.06% of cement to prepare kaolin brick with excellent heat insulation and waterproofness.

포졸란은 석회의 존재로 물과 반응하여 경화하는 규산질 또는 알루미노실리케이트질 물질을 말한다. 다른 시멘트 질성분으로 규조토, 알로펜, 할로사이트, 벤토나이트 등도 반응성을 갖지만 반죽수량을 증가하므로 보통 사용치 않는다. 인공포졸란으로서는 연소성점토, 롤라이애쉬 등이 있다.Pozzolane refers to a siliceous or aluminosilicate material which reacts with water and cures in the presence of lime. Diatomaceous earth, allophene, halosite, bentonite, etc. are also reactive as other cement materials, but they are not usually used because they increase the amount of dough. Artificial pozzolans include combustible clay, roll ash, and the like.

알루미나 함유량이 높은 포졸란은 시멘트를 급결시켜 화학저항성을 해치는 경향이 있다.Pozzolans with a high alumina content tend to quench the cement and impair chemical resistance.

본 발명의 목적은 포졸란으로서 고령토를 사용하여 여기에 C3S가 50%이상인 시멘트를 소량 충분히 혼합하고, Na2SiO3수용액 A,E. 제, 발포제, 조강제, 방수제, 등을 적절히 첨가하여 단열성과 방수성이 우수하고, 특히 탈취성질을 가진 고강도 고령토 벽돌을 제조하는데 있다.It is an object of the present invention to use a kaolin as pozzolanic and sufficiently mix a small amount of cement having a C 3 S of 50% or more thereto, and to provide an aqueous solution of Na 2 SiO 3 solution A, E. It is to prepare a high-strength kaolin brick having excellent heat insulation and waterproofing properties, in particular, deodorizing properties by appropriately adding a blowing agent, a roughening agent, a waterproofing agent, and the like.

더욱더 본 발명은 이러한 고령토를 사용하여 건축자재로 사용하는 벽돌 및 판넬의 제조에 관한 것이다.The present invention further relates to the manufacture of bricks and panels for use as building materials using such kaolin.

본 발명은 상세히 설명하면 다음과 같고, 이러한 구현으로 본 발명의 범위는 제한되지 않는다.The present invention will be described in detail as follows, and the scope of the present invention is not limited to such an implementation.

1.입경이 0.01-0.1㎜이하고 분쇄된 고령토분85-90%와 C3S 50%정도의 시멘트 4-6%를 혼합하고 여기에 Al이나 Zn또는 CaC2분말을 0.01-0.02%첨가하고 충분히 혼합한다.1.The particle size should be 0.01-0.1mm, mix 85-90% of the ground kaolin powder and 4-6% of cement of C 3 S 50%, and add 0.01-0.02% of Al, Zn or CaC 2 powder to it. Mix enough.

2.A.E.WP중 한 성분과 CaCL2, NA2SiF6등을 시멘트에 대해서 각각 0.03-0.06%가 되도록 혼합하고 여기에 Na2SiO31%수용액을 가하여 완전히 혼합한다.2. Mix one component of AEWP with CaCl 2 , NA 2 SiF 6 to 0.03-0.06% with respect to cement, add 1% aqueous solution of Na 2 SiO 3, and mix thoroughly.

3.1공정의 혼합물80%에, 2공정의 혼합용액20%를 가하며 충분히 혼련하여 성형 후 건조한다. 본 발명에 의한 고령토벽돌 제조방법은 2실시예에 의하여 기술하면 다음과 같다.To 80% of the mixture in step 3.1, 20% of the mixed solution in two steps is added, kneaded sufficiently and dried after molding. Kaolin brick manufacturing method according to the present invention is described as follows by the second embodiment.

[실시예 1]Example 1

고령토를 분쇄하여 이의 85-90%와 C3S50%정도의 시멘트 4-6%를 첨가혼합하고 여기에 발포제로서 CaC2분말 0.01-0.02%를 가하여 충분히 혼합하고 분산제로서 빈존레진과 방수제로는 CaC2와 Na2SiF6와 경화제 Na2SiO3수용액등을 각각 첨가하여 충분히 혼련한 후 성형하며 양생시킨 고령토벽돌은 다음과 같은 결과를 보였다.Grind the kaolin and add and mix 85-90% of it and 4-6% of cement of C 3 S50%, add CaC 2 powder 0.01-0.02% as a blowing agent, and mix it sufficiently. The kaolin bricks cured by adding 2 and Na 2 SiF 6 and a curing agent Na 2 SiO 3 aqueous solution, respectively, were sufficiently kneaded and molded. The results were as follows.

Figure kpo00001
Figure kpo00001

상기 표 1에서 알수 있듯이 본 발명의 고령토벽돌은 종래의 모래벽돌보다 방수 및 단열효과가 우수하다.As can be seen in Table 1, the kaolin brick of the present invention has an excellent waterproofing and insulating effect than conventional sand brick.

그 이유로는 종래의 점토를 이용한 벽돌과 같이 굽지않고, 방수제 등을 첨가하여 직접 성형건조하므로서 방수 및 단열효과가 우수하고, 실험결과 특히 탈취효과 또한 우수한 것으로 밝혀졌다.The reason is that it does not bend like a brick using a conventional clay, and by direct molding and drying by adding a waterproofing agent and the like, the waterproofing and heat insulating effect is excellent, and the experimental results have been found to be particularly excellent in deodorizing effect.

또한, 본 발명의 고령토벽돌은 깨어짐이 없고, 구멍뚫기가 용이하며 색상조절이 가능하다는 장점을 갖고 있다.In addition, the kaolin brick of the present invention has the advantage that it is not broken, easy to perforate and the color can be adjusted.

특히 주목할만한 점은 종래의 모래벽돌의 수명이 20내지 30년 정도이지만, 본 발명의 고령토벽돌은 수명이 거의 반영구적이라는 점이다. 그러므로 앞으로 건축용 재료로서 그 용도가 기대되고 있다.In particular, although the life of the conventional sand brick is about 20 to 30 years, the kaolin brick of the present invention is almost semi-permanent life. Therefore, its use as a building material is expected in the future.

Claims (2)

고령토와 C3S 50%이상을 함유하는 시멘트를 90:5로 혼합하고, 분산제, 발표제, 방수제, 및 경화제를 적절하게 첨가 혼련하여 성형 양생함을 특징으로 하는 고령토벽돌 제조방법.A kaolin brick manufacturing method characterized by mixing kaolin and cement containing 50% or more of C 3 S at 90: 5, and curing by appropriately adding and kneading a dispersant, a release agent, a waterproofing agent, and a curing agent. 제1항에 있어서, 고령토와 C3S 50%이상을 함유하는 시멘트를 90:5로 혼합하고 분산제, 발포제, 방수제 및 경화제를 적절하게 첨가 혼련하여 성형 양생함을 특징으로 하는 고령토 패널 제조방법.The method of manufacturing kaolin panel according to claim 1, wherein the kaolin and cement containing 50% or more of C 3 S are mixed at 90: 5, and curing is performed by appropriately kneading a dispersant, a foaming agent, a waterproofing agent and a curing agent.
KR1019880005560A 1988-05-13 1988-05-13 Method for producing kaolin-bricks KR900005975B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100867963B1 (en) * 2006-11-20 2008-11-10 조현문 Construction method for arch type sweating bathroom
KR101292801B1 (en) * 2011-08-30 2013-08-02 이은희 kaoline block and manufacturing method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100331705B1 (en) * 1999-03-02 2002-04-09 임정근 Method of manufacture of high functional lining building materials using SOKPIRE minerals

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100867963B1 (en) * 2006-11-20 2008-11-10 조현문 Construction method for arch type sweating bathroom
KR101292801B1 (en) * 2011-08-30 2013-08-02 이은희 kaoline block and manufacturing method thereof

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KR890017195A (en) 1989-12-15

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