KR900004807A - 비선형 광학 활성 중합체, 그를 포함하는 재료, 상기 중합체 및 재료의 제조 방법 및 그를 포함하는 전기 광학 장치 - Google Patents

비선형 광학 활성 중합체, 그를 포함하는 재료, 상기 중합체 및 재료의 제조 방법 및 그를 포함하는 전기 광학 장치 Download PDF

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KR900004807A
KR900004807A KR1019890013301A KR890013301A KR900004807A KR 900004807 A KR900004807 A KR 900004807A KR 1019890013301 A KR1019890013301 A KR 1019890013301A KR 890013301 A KR890013301 A KR 890013301A KR 900004807 A KR900004807 A KR 900004807A
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polymer
group
compound
electron
optically active
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KR1019890013301A
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미냐니 제라르
바르뗄르미 빠스깔
메이뤼이 레미
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쟝-삐에르 에송
롱-쁠랑 쉬미
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/35—Non-linear optics
    • G02F1/355—Non-linear optics characterised by the materials used
    • G02F1/361—Organic materials
    • G02F1/3615—Organic materials containing polymers
    • G02F1/3617—Organic materials containing polymers having the non-linear optical group in a side chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/675—Low-molecular-weight compounds
    • C08G18/676—Low-molecular-weight compounds containing the unsaturation at least partially in a non-aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/675—Low-molecular-weight compounds
    • C08G18/677—Low-molecular-weight compounds containing heteroatoms other than oxygen and the nitrogen of primary or secondary amino groups
    • C08G18/678—Low-molecular-weight compounds containing heteroatoms other than oxygen and the nitrogen of primary or secondary amino groups containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • C09K19/3833—Polymers with mesogenic groups in the side chain
    • C09K19/3885—Polyurethanes
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/35—Non-linear optics

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Light Receiving Elements (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Organic Insulating Materials (AREA)
  • Optical Modulation, Optical Deflection, Nonlinear Optics, Optical Demodulation, Optical Logic Elements (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

비선형광학 활성중합체, 그를 포함하는 재료, 상기 중합체 및 재료의 제조방법 및 그를 포함하는 전기광학장치.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 하나이상의 이작용성 화합물이 하나이상의 전자 수용기와 하나이상의 전자공여기를 함유하는 전하이동극성기를 포함하는 첫번째 이작용성 화합물과 두번째 이작용성 화합물의 반응에 의해 수득되며, 중합반응 작용이 상기 하나이상의 전자공여기에 의해 실시됨을 특징으로 하는 비선형광학 활성 중합체.
  2. 제1항에 있어서, 하기식(I)의 구조를 가진 전하 이동극성기를 포함하는 이작용성 화합물이며, 중합용 반응기가 전자공여기 D에 의해 전달됨을 특징으로 하는 중합체.
    D-(π전자비편재화 라디칼)-A
  3. 제1 또는 2항에 있어서, 이작용성 화합물의 중합용 반응기가 알콜, 아민, 이소시아네이트, 알릴, 비닐, 산기를 포함하는 군중에서 선택됨을 특징으로 하는 중합체.
  4. 제1 내지 3항중 어느 한 항에 있어서, 첫번째 및 두번째 작용성 화합물이 동일한 중합용 반응기를 전달함을 특징으로 하는 중합체.
  5. 제1 내지 3항중 어느 한 항에 있어서, 첫번째 이 작용성 화합물의 중합용 반응기가 두번째 이작용성 화합물에 의해 전달되는 기와는 상이함을 특징으로 하는 중합체.
  6. 제1 내지 5항중 어느 한 항에 있어서, 이작용성 화합물의 혼합물에 삼작용성 화합물을 첨가하여 망상화시킴을 특징으로 하는 중합체.
  7. 제2 내지 6항중 어느 한 항에 있어서, π전자 비편재화 라디칼이 하기 구조의 라디칼을 포함하는 군중에서 선택됨을 특징으로 하는 중합체.
    (식중, R3,R4및 R6은 동일 또는 상이하며, 수소 또는 내부 알킬라디칼을 나타낸다).
  8. 제1 내지 7항중 어느 한 항에 있어서, 전자수용 라디칼(A)이 하기 라디칼중에서 선택됨을 특징으로 하는 중합체. 니트로, 시아노, -CO2R5,PO3(R5)2(R5는 저급알킬 라디칼이다).
  9. 제1 내지 8항중 어느 한 항에 있어서, 전자공여 라디칼(D)이 다음식
    (식중, R7및 R8은 동일 또는 상이하며, 중합용 반응기를 포함하는 라디칼이다)의 라디칼이며, 바람직하게는 다음의 구조
    -(CH2)m-OH; -(CH2)p-CH=CH2
    (식중, m 및 p는 정수이며, m은 1 내지 6, p는 0 내지 6이다)를 가짐을 특징으로 하는 중합체.
  10. 전기장 효과에 의해 편향되어 비중심대칭의 전하가 수득되는 제1 내지 9항중 어느 한 항에 따른 중합체를 포함함을 특징으로 하는 비선형 광학활성 재료.
  11. 재료를 중합체의 유리전이 온도 이상의 온도로 가열하고, 가열된 재료를 전기장으로 처리한후, 냉각 시키는 것으로 구성됨을 특징으로 하는 제10항에 따른 비선형 광학 활성재료의 제조방법.
  12. 이작용성 화합물과 다작용성 화합물을 포함하는 혼합물을 부분적으로 중합시키고, 이렇게 수득된 예비중합체를 그의 연화온도 또는 그의 유리전이온도를 초과하는 온도로 가열하고, 가열된 예비중합체를 전기장으로 처리한후, 중합체로 완전 중합하는 것으로 구성됨을 특징으로 하는 제10항에 따른 비선형 광학 활성 재료의 제조방법.
  13. 제11 또는 12항에 있어서, 중합체 또는 재료의 중합 또는 예비중합이 열, 라디칼, 이온에 의해, 또는 복사에 의한 충격에 의해 실시됨을 특징으로 하는 제조방법.
  14. 제10항에 따른 재료를 포함함을 특징으로 하는 광학장치.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890013301A 1988-09-16 1989-09-12 비선형 광학 활성 중합체, 그를 포함하는 재료, 상기 중합체 및 재료의 제조 방법 및 그를 포함하는 전기 광학 장치 KR900004807A (ko)

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FR8812080A FR2636745B1 (fr) 1988-09-16 1988-09-16 Polymeres et materiaux les contenant, actifs en optique non lineaire, procedes de fabrication de ces polymeres et materiaux et dispositif optoelectrique les contenant
FR88-12080 1988-09-16

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KR900004807A true KR900004807A (ko) 1990-04-13

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US (1) US5189134A (ko)
EP (1) EP0363237B2 (ko)
JP (1) JPH071361B2 (ko)
KR (1) KR900004807A (ko)
CN (1) CN1042164A (ko)
AT (1) ATE98382T1 (ko)
AU (1) AU4149589A (ko)
DE (1) DE68911258T3 (ko)
DK (1) DK456189A (ko)
FI (1) FI894375A (ko)
FR (1) FR2636745B1 (ko)
IL (1) IL91645A0 (ko)
NO (1) NO893694L (ko)
PT (1) PT91729A (ko)
ZA (1) ZA897046B (ko)

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FR2678613B1 (fr) * 1991-07-02 1993-09-17 Thomson Csf Materiaux reticulables thermiquement pour application en optique non lineaire.
JPH06509188A (ja) * 1991-07-19 1994-10-13 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー 非線形光学要素の製造
US5594093A (en) * 1992-07-13 1997-01-14 Fujitsu Limited Nonlinear optical material and nonlinear optical device and directional coupling type optical switch using same
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US5288816A (en) * 1992-08-10 1994-02-22 The Dow Chemical Company Nonlinear optical aminoaryl hydrazones and nonlinear optical polymers thereof
DE4244195A1 (de) * 1992-12-24 1994-06-30 Basf Ag Verfahren zur Herstellung von strukturierten Polymerschichten mit nichtlinear optischen Eigenschaften
US5670603A (en) * 1993-03-08 1997-09-23 Alliedsignal Inc. Polymers exhibiting nonlinear optical properties
EP0647874A1 (en) * 1993-10-06 1995-04-12 ENICHEM S.p.A. Highly efficient nonlinear optical polyimides
DE4335541A1 (de) * 1993-10-19 1995-04-20 Basf Ag Azo- oder Stilbenfarbstoffgruppierungen und Urethangruppen enthaltendes Polyaddukt und dessen Verwendung in der nicht-linearen Optik
TW243501B (en) * 1994-07-22 1995-03-21 Akzo Nobel Nv Bleachable optical waveguide component
US5688896A (en) * 1994-09-26 1997-11-18 Akzo Nobel N.V. Non-linear optically active polycarbonate
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CN102482504B (zh) 2009-08-24 2016-01-20 独立行政法人情报通信研究机构 二阶非线性光学化合物及含有它的非线性光学元件

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US5001209A (en) * 1988-07-04 1991-03-19 Akzo N.V. Non-linear optical active diols and polyurethanes prepared therefrom
FR2636634B1 (fr) * 1988-09-16 1992-11-27 Rhone Poulenc Chimie Polyurethannes, actifs en optique non lineaire et materiaux les contenant, dispositif optique les contenant et procedes de fabrication de ces composes et materiaux

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EP0363237B2 (fr) 1997-06-18
NO893694L (no) 1990-03-19
DE68911258T3 (de) 1998-01-15
DE68911258T2 (de) 1994-06-30
DE68911258D1 (de) 1994-01-20
FR2636745A1 (fr) 1990-03-23
FI894375A0 (fi) 1989-09-15
IL91645A0 (en) 1990-04-29
EP0363237A2 (fr) 1990-04-11
ZA897046B (en) 1990-06-27
EP0363237A3 (en) 1990-05-16
US5189134A (en) 1993-02-23
FI894375A (fi) 1990-03-17
DK456189D0 (da) 1989-09-15
AU4149589A (en) 1990-03-22
JPH02115827A (ja) 1990-04-27
DK456189A (da) 1990-03-17
FR2636745B1 (fr) 1990-11-09
CN1042164A (zh) 1990-05-16
JPH071361B2 (ja) 1995-01-11
PT91729A (pt) 1990-03-30
EP0363237B1 (fr) 1993-12-08
NO893694D0 (no) 1989-09-15
ATE98382T1 (de) 1993-12-15

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