KR890003652A - 갈륨-활성 제올라이트를 이용하여 지방족을 방향족으로 전환시키는 방법 - Google Patents

갈륨-활성 제올라이트를 이용하여 지방족을 방향족으로 전환시키는 방법 Download PDF

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KR890003652A
KR890003652A KR1019880010827A KR880010827A KR890003652A KR 890003652 A KR890003652 A KR 890003652A KR 1019880010827 A KR1019880010827 A KR 1019880010827A KR 880010827 A KR880010827 A KR 880010827A KR 890003652 A KR890003652 A KR 890003652A
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aromatic compound
producing
compound according
zeolite
weight
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KR1019880010827A
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이오시프 네메트 마가레트
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에드워드 에이취.바란스
모빌오일 코퍼레이션
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Publication of KR890003652A publication Critical patent/KR890003652A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

갈륨-활성 제올라이트를 이용하여 지방족을 방향족으로 전환시키는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 450-700℃의 온도, 0.5-70bar의 압력 및 0.05-50hr-1의 무게 시간당 공간속도를 포함하여 탄소수가 최고 12인 파라핀, 올레핀 및 나프텐의 최소한 80%가 전환될 수 있도록 하는 시비어리티의 전환조건에서, 최소한 50무게 %가 탄소수 최고 12인 파라핀, 올레핀 및 나프텐으로 이루어져 있는 C3+ 공급원료를, 갈륨으로 교환하거나 함침시킨후 최소한700℃의 온도롤 하소시킨 것으로 컨스트레인트 인덱스가 1-12이고 실리카/알루미나 몰비가 25-1000인 제올라이트로 이루어진 촉매와 접촉시킴을 특징으로 하는 방향족 화합울의 제조방법.
  2. 제 1항에서, 압력이 1-70bar이며 공간속도가 0.1-50hr-1인 방향족 화합물의 제조방법.
  3. 제 1항 또는 2항에서, 온도가 500-650℃이고, 압력이 1-35bar이며 공간속도가 0.1-20hr-1인 방향족 화합물의 제조방법.
  4. 제 1항-3항중의 어느 하나에서, 온도가 525-600℃이고, 압력이 1-7bar이며 공간속도가 0.5-5hr-1인 방향족 화합물의 제조방법.
  5. 제 1항-4항중에의 어느 하나에서, 상기 조건의 시비어리티가 상기 파라핀, 올레핀 및 나프텐의 최소한 85%가 전환될 수 있도록 야기하는 방향족 화합물의 제조방법.
  6. 제 1항-5항중의 어느 하나에서, 촉매가 고정상의 형태인 방향족 화합물의 제조방법.
  7. 제 1항-6항중의 어느 하나에서, C3+ 공급원료의 최소한 75무게 %가 C5-C8파라핀으로 이루어진 방향족 화합물의 제조방법.
  8. 제 1항-7항중 어느 하나에서, 갈륨의 양이 교환되거나 함침된 제올라이트의 0.5-5무게 %를 차지하는 방향족 화합물의 제조방법.
  9. 제 1항-8항중의 어느 하나에서, 제올라이트의 하소온도가 최소한 775℃인 방향족 화합물의 제조방법.
  10. 제 9항에서, 800-825℃의 온도에서, 1-1.5시간 하소를 진행시키는 방향족 화합물의 제조방법.
  11. 제 1항-10항중의 어느 하나에서, 제올라이트가 ZSM-5, -11, -12, -23, -35, -38 또는 -48인 방향족 화합물의 제조방법.
  12. 제 1항 -11항중의 어느 하나에서, 제올라이트의 양이 제올아이트와 무기 산화물 매트릭스와의 복합체의 1-99무게 %를 차지하는 방향족 화합물의 제조방법.
  13. 제 12항에서, 제올라이트의 양이 복합체의 29-65무게 %를 차지하는 방향족 화합물의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880010827A 1987-08-25 1988-08-25 갈륨-활성 제올라이트를 이용하여 지방족을 방향족으로 전환시키는 방법 KR890003652A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8919487A 1987-08-25 1987-08-25
US089,194 1987-08-25

Publications (1)

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KR890003652A true KR890003652A (ko) 1989-04-17

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EP (1) EP0309089B1 (ko)
JP (1) JPH01125332A (ko)
KR (1) KR890003652A (ko)
AU (1) AU610214B2 (ko)
CA (1) CA1304417C (ko)
DE (1) DE3868374D1 (ko)
NO (1) NO883767L (ko)
NZ (1) NZ225639A (ko)
ZA (1) ZA886335B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2655038B1 (fr) * 1989-11-28 1993-05-14 Inst Francais Du Petrole Procede de production d'hydrocarbures alkylaromatiques a partir de gaz naturel. invention de mm. bernard juguin, jean-claude collin, joseph larue et christian busson.
GB9011106D0 (en) * 1990-05-17 1990-07-04 British Petroleum Co Plc Catalyst
RU2043148C1 (ru) * 1993-07-23 1995-09-10 Мельников Вячеслав Борисович Катализатор для облагораживания бензинов
EP1063013B1 (en) * 1999-06-24 2005-10-12 ENI S.p.A. Catalytic composition for the aromatization of hydrocarbons
US11439991B2 (en) * 2019-12-19 2022-09-13 King Fahd University Of Petroleum & Minerals Catalyst compositions for aromatizing hydrocarbons and processes for producing aromatic compounds using the catalyst compositions

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4180689A (en) * 1976-12-20 1979-12-25 The British Petroleum Company Limited Process for converting C3 -C12 hydrocarbons to aromatics over gallia-activated zeolite
IN154515B (ko) * 1979-08-07 1984-11-03 British Petroleum Co
US4350835A (en) * 1981-02-19 1982-09-21 Mobil Oil Corporation Process for converting ethane to aromatics over gallium-activated zeolite
GB8520977D0 (en) * 1985-08-21 1985-09-25 British Petroleum Co Plc Production of aromatics
EP0252705B1 (en) * 1986-07-07 1991-10-23 Mobil Oil Corporation Aromatisation of aliphatics over gallium-containing zeolites

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NO883767D0 (no) 1988-08-23
JPH01125332A (ja) 1989-05-17
AU610214B2 (en) 1991-05-16
ZA886335B (en) 1990-04-25
NZ225639A (en) 1989-09-27
NO883767L (no) 1989-02-27
CA1304417C (en) 1992-06-30
DE3868374D1 (de) 1992-03-26
EP0309089A1 (en) 1989-03-29
EP0309089B1 (en) 1992-02-12
AU2035388A (en) 1989-03-02

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