KR890002566B1 - Method for preparing architectural material by using burned paper slurry - Google Patents

Method for preparing architectural material by using burned paper slurry Download PDF

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KR890002566B1
KR890002566B1 KR1019860010053A KR860010053A KR890002566B1 KR 890002566 B1 KR890002566 B1 KR 890002566B1 KR 1019860010053 A KR1019860010053 A KR 1019860010053A KR 860010053 A KR860010053 A KR 860010053A KR 890002566 B1 KR890002566 B1 KR 890002566B1
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Prior art keywords
parts
paper sludge
paper slurry
asbestos
sludge
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KR1019860010053A
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Korean (ko)
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KR880006422A (en
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조태철
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전주제지 주식회사
김인호
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21JFIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
    • D21J1/00Fibreboard
    • D21J1/08Impregnated or coated fibreboard

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  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A method comprises (i) mixing 100-200 mesh burned paper slurry ashes 30-80 wt.%, slaked lime 10-30 wt.%, asbestos 10-20 wt.%, paper slurry and sodium silicate 10-30 wt.%, (ii) adding an appropriate amt. water to the mixt. and pre-reacting at room temp. and (iii) steam solidifying.

Description

제지 슬러지소각재를 이용한 건축재의 제조방법Manufacturing Method of Building Materials Using Paper Sludge Incinerator

본 발명은 제지공장에서 나오는 제지슬러지로 건축재를 만들 수 있도록 한 제지슬러지 소각재를 이용한 건축재의 제조방법에 관한 것이다. 펄프와 기타 첨가물로 종이를 제조하고 남은 슬러지는 공해물질이라서 방지할 수 없고, 게다가 그 량이 많으므로 처리에 많은 어려움을 겪고 있다. 통상적으로 제지슬러지는 그대로 또는 소각하여 중량을 경감시켜 매립처분되고 있었으나, 근자에 슬러지소각제를 활용하는 방법이 제안되어 이 분야에 관한 연구가 활발히 행해지고 있다. 이러한 제지 슬러지 소각제를 활용하는 방법은 제품의 품질이 불안정하여 그 용도는 시멘트 중량제, 아스팔드 포장재, 경량골재, 요업원료, 토질안정제, 건축용 천정재 등으로 국부적인 활용에 그치고 있다. 현재까지 실시되고 있는 건축제 제조 방법은 규조로, 소석회등과 혼합하여 90-100℃에서 예비반응을 일으키고, 석면등을 혼합하여 증기양생하거나, 규석과 소석회를 혼합하여 고온 고압하에서 수열반응을 일으킨후 석면을 혼합하여 증기양생하는 방법이 주로 실시되고 있다. 이러한 방법은 예비반응에 열원을 필요로 하기 때문에 제조비의 상승을 초래하고, 석면등의 혼합성형으로 사용상 난점이 많다. 본 발명자는 상기한 결점을 해결하기 위하여 제지슬러지의 성분을 분석연구한 결과, 대체로 Al2O345%, SiO230%, Mg 0.7%, Fe2O36% 기타 12%로 구성되어 있음을 알게 되었고, 이를 토대로 SiO2를 내화성물질인 규산석회질로 유도하면 내화건축재로의 활용이 가능함에 착안하였다. 이에따라 본 발명의 목적은 제지슬러지소각제를 내화 성건축제로 활용하고, 그 제조공정에 있어서 예비반응을 상온에서 20분정도 행함으로써 제조비를 절감할 수 있는 제지 슬러지소각제를 이용한 건축재의 제조방법을 제공함에 있다.The present invention relates to a method for manufacturing a building material using paper sludge incineration material to be made of paper sludge from the paper mill. Sludge left after making paper from pulp and other additives is a pollutant and cannot be prevented. Furthermore, the sludge has a lot of difficulties in processing. In general, paper sludge has been disposed of by incineration or incineration to reduce the weight. However, a method of using sludge incinerators in the roots has been proposed, and studies in this field have been actively conducted. The use of these paper sludge incinerators is unstable in the quality of the product, and its use is limited to local applications such as cement weights, asphalt pavements, lightweight aggregates, ceramics, soil stabilizers and building ceilings. The method of manufacturing building materials to date is diatom, which is mixed with slaked lime and the like to cause preliminary reaction at 90-100 ℃, steam curing by mixing asbestos, or hydrothermal reaction under high temperature and high pressure by mixing silica and slaked lime. After the asbestos mixing and steam curing is mainly carried out. Since this method requires a heat source for the preliminary reaction, it causes an increase in manufacturing cost, and there are many difficulties in use due to mixed molding such as asbestos. The present inventors have analyzed the components of the papermaking sludge to solve the above-mentioned defects, and as a result, Al 2 O 3 45%, SiO 2 30%, Mg 0.7%, Fe 2 O 3 6% and other 12% Based on this, it was conceived that if SiO 2 was induced into the refractory calcite silicate, it could be used as a refractory building material. Accordingly, an object of the present invention is to use a paper sludge incinerator as a fire-resistant building agent, and to manufacture a building material using a paper sludge incinerator which can reduce the manufacturing cost by performing a preliminary reaction at room temperature for about 20 minutes. In providing.

본발명은 100 멧쉬이상 200멧쉬이하의 슬러지소각재 분말 30 내지 80부에 소석회 10내지 30부, 석면 10-20부와 제지슬러지 1내지 5부 및 규산소다 3호 10내지 30부, 그리고 적당량을 물을 첨가 혼합하여 예비반응시킨 후 증기 양생함을 특징으로 한다. 또한 적당량의 물을 투입혼합하여 성형시 균일한 분산을 위한 최종 농도는 1내지 3%범위내이다. 이하 본 발명을 실시예로서 상세히 설명한다.The present invention is in the range of 30 to 80 parts of sludge incinerator powder of 100 mesh to 200 mesh, 10 to 30 parts of hydrated lime, 10 to 20 parts of asbestos, 1 to 5 parts of papermaking sludge and 10 to 30 parts of soda silicate No. 3 It is characterized by the steam curing after the addition of the pre-reaction by mixing. In addition, the final concentration for uniform dispersion during molding by mixing the appropriate amount of water is in the range of 1 to 3%. Hereinafter, the present invention will be described in detail by way of examples.

[실시예]EXAMPLE

슬러지 소각재 분말 50부Sludge incineration powder 50 parts

소석회 25부25 slaked lime

석면 20부Asbestos Part 20

제지슬러지 2부Paper Sludge Part 2

규산소다 3로 15부Part 3 of Soda Silicate

물 적당량을 투입 혼합하여 농도를 2%로 만들어 상온에서 예비반응 시킨다. 상기 공정에서 슬러지 소각재 분말을 체로 걸러서 입자 150 메쉬이하의 것을 사용하면 반응효과가 높아지는 이점이 있고, 석면은 섬유질로 투입되는 것이며, 소각되지 않은 제지슬러지는 석면의 분산을 도모하기 위하여 첨가한다. 슬러지소각제분말은 소석회와 규산소다 3호를 투입함에 따라 제지 슬러지 소각재 분말과 규산소다 3호의 성분 중의 SiO2를 제외한 다른 성분은 충전재로서 잔류한다. 상온에서의 예비반응이 끝나면 증기양생법으로 온도 150℃, 압력18Kg/cm2의 고온고압증기의 양생으로써 본 발명의 제품이 생성된다. 이러한 방법에 의해 얻어진 시료를 물성테스트한 결과는 다음과 같다.After mixing the appropriate amount of water to make a concentration of 2% to pre-react at room temperature. In the above process, when the sludge incinerator powder is sieved and used with particles of 150 mesh or less, the reaction effect is increased, asbestos is introduced into the fiber, and the unincinerated paper sludge is added to promote asbestos dispersion. As the sludge incinerator powder is charged with slaked lime and soda silicate 3, other components except SiO 2 in the paper sludge incinerator powder and soda silicate 3 remain as fillers. After the preliminary reaction at room temperature, the product of the present invention is produced by curing the high temperature and high pressure steam at a temperature of 150 ° C. and a pressure of 18 Kg / cm 2 by the steam curing method. The physical property test results of the sample obtained by this method are as follows.

[표][table]

Figure kpo00001
Figure kpo00001

* 열전도율 : 30℃에서 측정* Thermal conductivity: measured at 30 ℃

* 흡수시팽창율 : 실온에서 3시간 침적후 측정* Expansion rate at absorption: measured after 3 hours deposition at room temperature

상술한 본 발명에 의하면 상온에서 예비반응이 가능하므로 종래와 같이 열원을 필요로 않게되어, 제조비를 절감할 수 있고, 표로 나타낸 바와 같이 양호한 물성을 갖게 되므로 그 용도는 기와나 블럭과 같은 건축재 전반에 걸쳐 널리 활용할 수 있으며 특히 내화성을 겸비하게 되므로 벽면 내장재로도의 활용도 할수 있는 등의 우수성을 나타낸다.According to the present invention described above, since the preliminary reaction is possible at room temperature, a heat source is not required as in the prior art, and thus the manufacturing cost can be reduced, and the physical properties as shown in the table have good physical properties. It can be widely used throughout, especially because it has fire resistance, it can also be used as a wall interior material.

Claims (2)

제지슬러지소각재로 건축재를 제조하는 방법에 있어서, 슬러지소각제분말 30 내지 80부, 소석회 10 내지 30부, 석면 10내지 20부, 제지슬러지 1 내지 5부, 규산소다 3호 10 내지 30부를 혼합하고 적당량의 물을 투입하여 상온에서 예비 반응시킴을 특징으로 하는 제지슬러지 소각재를 이용한 건축제의 제조방법.In the method of manufacturing a building material from paper sludge incineration ash, 30 to 80 parts of sludge incinerator powder, 10 to 30 parts of slaked lime, 10 to 20 parts of asbestos, 1 to 5 parts of paper sludge, 10 to 30 parts of soda silicate 3 are mixed, A method of manufacturing a building material using paper sludge incineration, characterized in that the reaction is preliminarily reacted at room temperature by adding an appropriate amount of water. 제1항에 있어서 제지슬러지 소각재 분말을 100멧쉬 이상 200멧쉬 이하로 분쇄시킴을 특징으로 하는 건축재의 제조방법.The method of manufacturing a building material according to claim 1, wherein the paper sludge incineration ash powder is pulverized to 100 mesh or more and 200 mesh or less.
KR1019860010053A 1986-11-27 1986-11-27 Method for preparing architectural material by using burned paper slurry KR890002566B1 (en)

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KR1019860010053A KR890002566B1 (en) 1986-11-27 1986-11-27 Method for preparing architectural material by using burned paper slurry

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KR1019860010053A KR890002566B1 (en) 1986-11-27 1986-11-27 Method for preparing architectural material by using burned paper slurry

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KR100588488B1 (en) * 2004-11-05 2006-06-09 박종원 Pulpsludge ash composite for producing construction materials

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